JPS6146450B2 - - Google Patents
Info
- Publication number
- JPS6146450B2 JPS6146450B2 JP57060724A JP6072482A JPS6146450B2 JP S6146450 B2 JPS6146450 B2 JP S6146450B2 JP 57060724 A JP57060724 A JP 57060724A JP 6072482 A JP6072482 A JP 6072482A JP S6146450 B2 JPS6146450 B2 JP S6146450B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- sodium
- sulfate
- carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000013040 bath agent Substances 0.000 claims description 21
- 238000005187 foaming Methods 0.000 claims description 21
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 18
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 15
- 150000007524 organic acids Chemical class 0.000 claims description 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 230000000694 effects Effects 0.000 description 13
- 239000000203 mixture Substances 0.000 description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 10
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 10
- 239000001569 carbon dioxide Substances 0.000 description 9
- 229910002092 carbon dioxide Inorganic materials 0.000 description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 238000003860 storage Methods 0.000 description 9
- 239000007789 gas Substances 0.000 description 8
- 239000000654 additive Substances 0.000 description 7
- 239000005022 packaging material Substances 0.000 description 6
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 5
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 5
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 5
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 5
- 239000001630 malic acid Substances 0.000 description 5
- 235000011090 malic acid Nutrition 0.000 description 5
- -1 polyethylene Polymers 0.000 description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 description 5
- 235000011152 sodium sulphate Nutrition 0.000 description 5
- 239000011975 tartaric acid Substances 0.000 description 5
- 235000002906 tartaric acid Nutrition 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 230000005856 abnormality Effects 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 239000005001 laminate film Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 235000017550 sodium carbonate Nutrition 0.000 description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 3
- 235000015165 citric acid Nutrition 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 3
- 235000018341 sodium sesquicarbonate Nutrition 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000013112 stability test Methods 0.000 description 3
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 229920000298 Cellophane Polymers 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 159000000011 group IA salts Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000004060 metabolic process Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 1
- FAYYUXPSKDFLEC-UHFFFAOYSA-L calcium;dioxido-oxo-sulfanylidene-$l^{6}-sulfane Chemical compound [Ca+2].[O-]S([O-])(=O)=S FAYYUXPSKDFLEC-UHFFFAOYSA-L 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000019700 dicalcium phosphate Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- CHKVPAROMQMJNQ-UHFFFAOYSA-M potassium bisulfate Chemical compound [K+].OS([O-])(=O)=O CHKVPAROMQMJNQ-UHFFFAOYSA-M 0.000 description 1
- 229910000343 potassium bisulfate Inorganic materials 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- HLJWMCUZPYEUDI-UHFFFAOYSA-L sodium hyponitrite Chemical compound [Na+].[Na+].[O-]N=N[O-] HLJWMCUZPYEUDI-UHFFFAOYSA-L 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Description
【発明の詳細な説明】 本発明は発泡性浴剤に関する。[Detailed description of the invention] The present invention relates to foaming bath additives.
更に詳しくは、通常の保存時においては炭酸塩
の分散及び劣化を起こすことなく極めて安定性に
優れ、使用時、湯浴中では炭酸ガスの気泡が発生
して、配合されている温泉成分の効果を効率的に
助長する発泡性浴剤に関するものである。 More specifically, during normal storage, it is extremely stable without dispersion or deterioration of carbonates, and when used, carbon dioxide gas bubbles are generated in a hot water bath, reducing the effect of the hot spring ingredients contained in it. This invention relates to a foaming bath agent that efficiently promotes foaming.
発泡性浴剤は、一般に、湯浴中で炭酸ガスや酸
素を発生させるもので、入浴時発泡した泡によつ
て皮膚表面を摩擦し、毛細血管を拡張し、新陳代
謝に寄与することを目的とする。 Effervescent bath additives generally generate carbon dioxide gas and oxygen in a hot water bath, and their purpose is to use the bubbles generated during bathing to rub against the skin surface, dilate capillaries, and contribute to metabolism. do.
ここで、炭酸ガスによる発泡性浴剤は、アルカ
リ塩類と酸類の配合により、溶解時に中和反応に
より炭酸ガスを発生せしめるもので、アルカリ塩
類としては炭酸ナトリウム、重炭酸ナトリウム、
セスキ炭酸ナトリウのような炭酸塩が、また、酸
類としては酒石酸、クエン酸、リンゴ酸等の有機
酸が配合される。これらに、香料、着色料等を配
合し、浴湯に香り、色調を与え、皮膚表面への適
度な刺激により、血液の循環を活発にし、疲労回
復、新陳代謝を増進させるもので一般に広く普及
している。しかしこれらの発泡性浴剤は、気密性
の良好なセロハン、ポリエチレン、アルミニウ
ム、ポリエチレンの構成からなるサンドウイツチ
ラミネートフイルム包材にて密閉して保存した場
合でも、空気中の湿気を吸収して炭酸塩が分解し
炭酸ガスが発生し、密閉した包材が膨張あるいは
破裂すると同時に、使用時、浴湯中での発泡性能
が低下して商品価値が著しく低下する。 Here, effervescent bath agents using carbon dioxide gas generate carbon dioxide gas through a neutralization reaction when dissolved by a combination of alkaline salts and acids. Examples of the alkaline salts include sodium carbonate, sodium bicarbonate,
Carbonates such as sodium sesquicarbonate are blended, and organic acids such as tartaric acid, citric acid, and malic acid are blended as acids. These are mixed with fragrances, colorants, etc. to give the bath water a scent and color, and by moderately stimulating the skin surface, it activates blood circulation, recovers from fatigue, and improves metabolism, and is widely used in general. ing. However, these foaming bath additives absorb moisture from the air and produce carbon dioxide, even when stored in airtight sandwich laminate film packaging made of cellophane, polyethylene, aluminum, and polyethylene. The salt decomposes and carbon dioxide gas is generated, causing the sealed packaging to expand or rupture, and at the same time, the foaming performance in bath water during use decreases, significantly reducing the product value.
かかる欠点を改良するために、上掲の一般の発
泡性浴剤に、硫酸ナトリウム、塩化ナトリウム、
セルローズ類（特開昭55−7246）、無水硫酸ナト
リウム等の無機無水塩（特開昭54−44013）等を
配合することが知られているが、単に配合しただ
けでは炭酸塩の分解を防止するのに十分でなく、
大幅な改良効果は認められない。 In order to improve these drawbacks, sodium sulfate, sodium chloride,
It is known to incorporate cellulose (Japanese Patent Application Laid-open No. 55-7246), inorganic anhydrous salts such as anhydrous sodium sulfate (Japanese Patent Application Publication No. 54-44013), etc., but simply adding them prevents the decomposition of carbonates. not enough to
No significant improvement effect was observed.
本発明者等は、このような問題点を解決すべく
鋭意研究を重ねた結果、炭酸塩と硫酸塩との混合
処理物を有機酸と共に配合すると、発泡性浴剤に
要求されている性能を十分満足することを見い出
し、本発明を完成するに至つた。 As a result of extensive research to solve these problems, the inventors of the present invention have found that when a mixed treatment of carbonate and sulfate is blended with an organic acid, the performance required for foaming bath agents can be achieved. They have found that the results are completely satisfactory and have completed the present invention.
即ち、本発明は炭酸塩と硫酸塩との混合処理物
を有機酸とともに配合することにより、長期保存
しても炭酸塩の分解および劣化を生起することな
く、使用時に炭酸塩が適度に分解を起し、浴湯中
で炭酸ガスの気泡が発生し、温泉の効果を助長す
る発泡性浴剤に関するものである。 That is, in the present invention, by blending a mixed product of carbonate and sulfate with an organic acid, the carbonate does not decompose or deteriorate even during long-term storage, and the carbonate does not decompose appropriately during use. This relates to foaming bath additives that generate carbon dioxide gas bubbles in the bath water and enhance the effects of hot springs.
本発明の発泡性浴剤に用いる炭酸塩としては、
炭酸ナトリウム、炭酸水素ナトリウム、セスキ炭
酸ナトリウム、あるいはこれらの無水物等があげ
られ、これらの１種又は２種以上が使用される。
硫酸塩としては、硫酸ナトリウム、硫酸カリウ
ム、硫酸水素ナトリウム、硫酸水素カリウム、亜
硫酸ナトリウム、亜硫酸カリウムあるいはこれら
の無水物等を挙げることができ、これらの１種ま
たは２種以上が使用されるが、好ましくは硫酸ナ
トリウムがよい。 Carbonates used in the foaming bath agent of the present invention include:
Examples include sodium carbonate, sodium hydrogen carbonate, sodium sesquicarbonate, and anhydrides thereof, and one or more of these may be used.
Examples of sulfates include sodium sulfate, potassium sulfate, sodium hydrogen sulfate, potassium hydrogen sulfate, sodium sulfite, potassium sulfite, anhydrides thereof, and one or more of these may be used. Preferred is sodium sulfate.
炭酸塩と硫酸塩とからなる混合処理物を製造す
るには、炭酸塩と硫酸塩の配合比率は５／95〜
90／10、好ましくは10／90〜80／20の重量比がよ
い。得られた混合処理物を用いて発泡性浴剤を製
造した場合、炭酸塩の量が硫酸塩の量に比し、
５／95以下の量であると十分な発泡性が得られ
ず、90／10以上の量であると、保存安定性の面で
十分な効果が得られない。 To produce a mixed product consisting of carbonate and sulfate, the blending ratio of carbonate and sulfate should be 5/95 to 5/95.
A weight ratio of 90/10, preferably 10/90 to 80/20 is good. When producing a foaming bath agent using the obtained mixed product, the amount of carbonate is compared to the amount of sulfate,
If the amount is less than 5/95, sufficient foamability will not be obtained, and if the amount is more than 90/10, sufficient effects in terms of storage stability will not be obtained.
この混合処理物の製造方法について以下に例示
する。 The method for producing this mixed product will be exemplified below.
(1) 炭酸塩５重量部、硫酸塩95重部の混合物を水
に対して10重量％（以下、％は重量％を表
す。）加え、このものを180℃で乾燥すると炭酸
塩と硫酸塩の複塩からなる混合処理物が得られ
る。(1) Add a mixture of 5 parts by weight of carbonate and 95 parts by weight of sulfate to water in an amount of 10% by weight (hereinafter, % means % by weight), and dry this mixture at 180°C to form carbonate and sulfate. A mixed product consisting of a double salt of is obtained.
(2) 炭酸塩20重量部と硫酸塩80重量部の混合物
を、水に対して、40％加え、この物をスプレイ
ドライヤーで120℃で乾燥すると、複塩より成
る混合処理物が得られる。(2) Add 40% of a mixture of 20 parts by weight of carbonate and 80 parts by weight of sulfate to water and dry this mixture with a spray dryer at 120°C to obtain a mixed product consisting of double salts.
(3) 炭酸塩70重量部対硫酸塩30重量部の混合物
を、水に対して60％加え、この物を110℃で乾
燥すると複塩より成る混合処理物が得られる。(3) Add a mixture of 70 parts by weight of carbonate and 30 parts by weight of sulfate at 60% to water and dry this mixture at 110°C to obtain a mixed product consisting of double salts.
(4) 炭酸塩90重量部対硫酸塩10重量部の混合物を
水に対して80％加え、この物を85℃で送風乾燥
すると複塩より成る混合処理物が得られる。(4) Add a mixture of 90 parts by weight of carbonate and 10 parts by weight of sulfate to water at 80% and dry this mixture with air at 85°C to obtain a mixed product consisting of double salts.
上掲のようにして得られた混合処理物の、起泡
性浴剤中への配合量は、５〜95％、好ましくは10
〜80％の範囲で配合される。５％未満又は98％を
越えると十分な起泡性が得られず、保存安完性の
面においても十分な効果が得られない。 The blending amount of the mixed product obtained as above in the foaming bath agent is 5 to 95%, preferably 10%.
It is blended in a range of ~80%. If it is less than 5% or more than 98%, sufficient foaming properties will not be obtained, and sufficient effects will not be obtained in terms of storage stability.
本発明は上掲の如く炭酸塩と硫酸塩とからなる
混合処理物を有機酸と共に配合することを特徴と
する発泡性浴剤である。 The present invention is a foaming bath agent characterized by blending a mixed product of a carbonate and a sulfate as described above together with an organic acid.
有機酸の種類としては、コハク酸、クエン酸、
リンゴ酸、マレイン酸、フタル酸、フマル酸、マ
ロン酸および酒石酸等を挙げることが出来、これ
らの１種または２種以上が使用されるが、好まし
くはコハク酸、クエン酸、リンゴ酸および酒石酸
が良い。 Types of organic acids include succinic acid, citric acid,
Examples include malic acid, maleic acid, phthalic acid, fumaric acid, malonic acid and tartaric acid, and one or more of these are used, but succinic acid, citric acid, malic acid and tartaric acid are preferred. good.
有機酸の配合量は、５〜90％の範囲で配合され
るが好ましくは10〜80％がよい。５％以下では発
泡性浴剤の使用時における炭酸ガス発生量が少く
なり、炭酸泉等の温泉効果が低下する。90％以上
では、保存安定性の面で十分な効果が得られな
い。 The amount of organic acid blended is in the range of 5 to 90%, preferably 10 to 80%. If it is less than 5%, the amount of carbon dioxide gas generated during use of the foaming bath agent will be reduced, and the hot spring effect of carbonated springs will be reduced. If it exceeds 90%, sufficient effects cannot be obtained in terms of storage stability.
本発明における発泡性浴剤は、上掲の通り炭酸
塩と硫酸塩の混合処理物及び有機酸の他に香料、
色素等も通常添加するが、従来、入浴剤一般に用
いられる無機塩類、薬剤等をさらに添加すること
ができる。 The effervescent bath agent in the present invention includes, as mentioned above, a mixture of carbonate and sulfate, an organic acid, and a fragrance.
Although pigments and the like are usually added, inorganic salts, chemicals, etc. conventionally used in bath additives can also be added.
無機塩類としては、前記の炭酸塩および硫酸塩
以外に、たとえば、塩化ナトリウム、ホウ砂、硫
化ナトリウム、硫化カリウム、硝酸ナトリウム、
硝酸カリウム、硝酸カルシウム、硫酸アルミニウ
ム、炭酸マグネシユウム、チオ硫酸ナトリウム、
ポリリン酸ナトリウム、リン酸水素カルシウム、
臭化カリウム、塩化カリウム、塩化アンモニウ
ム、硫酸鉄、リン酸ナトリウム、次亜硝酸ナトリ
ウム、チオ硫酸カルシウムおよびケイ酸ナトリウ
ム等が挙げられる。 In addition to the carbonates and sulfates mentioned above, examples of inorganic salts include sodium chloride, borax, sodium sulfide, potassium sulfide, sodium nitrate,
Potassium nitrate, calcium nitrate, aluminum sulfate, magnesium carbonate, sodium thiosulfate,
Sodium polyphosphate, calcium hydrogen phosphate,
Examples include potassium bromide, potassium chloride, ammonium chloride, iron sulfate, sodium phosphate, sodium hyponitrite, calcium thiosulfate, and sodium silicate.
本発明の発泡性浴剤の剤型は粉末状、顆粒状、
タブレツト状等の固体状のものが挙げられるが、
タブレツト状のものにはバインダーとしてカルボ
キシメチルセルローズナトリウム塩、ポリオキシ
エチレン重合物等の水溶性高分子が添加される。 The dosage form of the foaming bath agent of the present invention is powder, granule,
Examples include solid forms such as tablets,
A water-soluble polymer such as carboxymethylcellulose sodium salt or polyoxyethylene polymer is added as a binder to the tablet-like product.
上掲の方法で得られた発泡性浴剤は、保存時に
おいても極めて安定であり、使用時には浴湯に香
り、色調を与え、温泉成分（無機塩類）の効能効
果に加えて浴湯中で炭酸塩が適度に分解し、炭酸
ガスの気泡が発生し、温泉のような効果を助長す
ることができる。 The effervescent bath agent obtained by the above method is extremely stable even during storage, and when used, it gives scent and color to the bath water, and in addition to the efficacy of hot spring ingredients (inorganic salts), The carbonate decomposes appropriately, generating carbon dioxide gas bubbles, which can promote a hot spring-like effect.
次に本発明の効果を実施例に基き説明する。 Next, the effects of the present invention will be explained based on examples.
実施例 １
水33重量部に無水炭酸ナトリウム25重量部と無
水硫酸ナトリウム42重量部とを混合し、熱風乾燥
機にて150℃で乾燥処理した。この処理物67重量
部とリンゴ酸30重量部と、カルボキシメチルセル
ローズナトリウム塩３重量部、香料及び色素適量
を充分混合し打錠して発泡性浴剤を得た。この浴
剤を、厚さ20ミクロンのセロハン、15ミクロンの
ポリエチレン、20ミクロンのアルミニウム、30ミ
クロンのポリエチレンの構成からなるサンドイツ
チラミネートフイルム包材に分包し、密閉包装し
た。この密閉包装物を温度50℃、湿度75％の恒温
恒湿室に２カ月放置したが、発泡性浴剤は安定
で、炭酸ナトリウムの分解が全く起らず、ラミネ
ートフイルム包材は膨張あるいは破裂することな
く何等異状のない事を確認した。Example 1 25 parts by weight of anhydrous sodium carbonate and 42 parts by weight of anhydrous sodium sulfate were mixed with 33 parts by weight of water, and the mixture was dried at 150°C in a hot air dryer. 67 parts by weight of this treated product, 30 parts by weight of malic acid, 3 parts by weight of sodium carboxymethyl cellulose, and appropriate amounts of fragrance and coloring matter were thoroughly mixed and tableted to obtain an effervescent bath agent. This bath additive was packaged in a sandwiched German laminate film packaging material consisting of cellophane with a thickness of 20 microns, polyethylene with a thickness of 15 microns, aluminum with a thickness of 20 microns, and polyethylene with a thickness of 30 microns, and sealed. This sealed package was left in a constant temperature and humidity room at a temperature of 50°C and a humidity of 75% for two months, but the foaming bath additive was stable, the sodium carbonate did not decompose at all, and the laminated film packaging material did not swell or burst. Without further ado, I confirmed that there was no abnormality.
また、この発泡性浴剤を開封して、浴場中で使
用したところ、容易に溶解し、適度に発泡し、炭
酸泉と芒硝泉の温泉効果がより助長された。 Furthermore, when this effervescent bath agent was opened and used in a bath, it dissolved easily and foamed appropriately, further promoting the hot spring effects of carbonated spring and mirabilite spring.
比較例 １
無水炭酸ナトリウム25重量部と、無水硫酸ナト
リウム42重量部とを単純に混合する他は実施例１
と全く同様に行なつた（特開昭54−44013の方法
による。）。その結果、１カ月放置したミネラート
フイルム包材は破裂し、炭酸水素ナトリウムはか
なり分解を起している。この結果からも明らかな
ように無水炭酸塩と無水硫酸塩の複塩からなる混
合物処理物物と、無水炭酸塩と無水硫酸塩とを単
純に混合した混合物との作用効果の違いが明らか
に見られる。Comparative Example 1 Example 1 except that 25 parts by weight of anhydrous sodium carbonate and 42 parts by weight of anhydrous sodium sulfate were simply mixed.
It was carried out in exactly the same manner as (according to the method of Japanese Patent Application Laid-open No. 1983-44013). As a result, the Mineralto film packaging material that had been left for one month burst, and the sodium bicarbonate had significantly decomposed. As is clear from these results, it is clear that there is a difference in action and effect between the treated mixture consisting of the double salt of anhydrous carbonate and anhydrous sulfate and the simple mixture of anhydrous carbonate and anhydrous sulfate. It will be done.
実施例 ２
水90重量部に炭酸ナトリウム0.7重量部、硫酸
ナトリウム9.3重量部を溶解させ、スプレイドラ
イヤーにて130℃で乾燥処理した。この混合深理
物90重量部とリンゴ酸10重量部、香料及び色素適
量を十分混合し、粉末状の発泡性浴剤を得た。実
施例１と全く同様に包装し、実施例１と同一の条
件で、保存安定性試験を行つた。２カ月放置後、
発泡性浴剤は安定でミネラートフイルム包材は何
等異状のないことを確認した。Example 2 0.7 parts by weight of sodium carbonate and 9.3 parts by weight of sodium sulfate were dissolved in 90 parts by weight of water, and the solution was dried at 130°C using a spray dryer. 90 parts by weight of this mixed substance, 10 parts by weight of malic acid, and appropriate amounts of perfume and coloring matter were thoroughly mixed to obtain a powdered foaming bath agent. It was packaged in exactly the same manner as in Example 1, and a storage stability test was conducted under the same conditions as in Example 1. After leaving it for 2 months,
It was confirmed that the foaming bath agent was stable and that there was no abnormality in the Mineralto film packaging material.
実施例 ３
水20重量部に炭酸水素ナトリウム60重量部、セ
スキ炭酸ナトリウム11重量部、硫酸ナトリウム９
重量部を混合し、熱風乾燥機にて110℃で乾燥処
理した。Example 3 20 parts by weight of water, 60 parts by weight of sodium bicarbonate, 11 parts by weight of sodium sesquicarbonate, 9 parts by weight of sodium sulfate
Parts by weight were mixed and dried at 110°C in a hot air dryer.
この混合処理物55重量部、酒石酸40重量部、カ
ルボキシメチルセルローズナトリウム塩５重量
部、香料及び色素適量を十分混合し打錠して発泡
性浴剤を得た。実施例１と全く同様に包装し、実
施例１と同一の条件で保存安定性試験を行つた。
２カ月放置後発泡性浴剤は安定で、ラミネートフ
イルム包材は何等異状ないことを確認した。 55 parts by weight of this mixed product, 40 parts by weight of tartaric acid, 5 parts by weight of sodium carboxymethyl cellulose, and appropriate amounts of fragrance and coloring matter were thoroughly mixed and tableted to obtain an effervescent bath agent. It was packaged in exactly the same manner as in Example 1, and a storage stability test was conducted under the same conditions as in Example 1.
After being left for two months, it was confirmed that the foaming bath agent was stable and that there was no abnormality in the laminate film packaging material.
この錠剤タイプの浴剤性浴剤を開封して浴場中
で使用したところ、容易に溶解し、強力に発泡が
起り、皮膚にマツサージ効果を与え、重曹泉、炭
酸泉及び芒硝泉の温泉効果が助長された。 When this tablet-type bath agent was opened and used in a bath, it dissolved easily and foamed strongly, giving a pine surge effect to the skin and promoting the hot spring effects of sodium bicarbonate, carbonated, and saltwater. It was done.
実施例 ４
水50重量部と炭酸水素ナトリウム15重量部、硫
酸ナトリウム35重量部を溶解させ、スプレイドラ
イヤーにて130℃で乾燥処理した。この混合処理
物20重量部と酒石酸80重量部と香料及び色素適量
を十分混合し、粉末状の発泡浴剤を得た。実施例
１と全く同様に包装し、実施例１と同一の条件
で、保存安定性試験を行つた。Example 4 50 parts by weight of water, 15 parts by weight of sodium bicarbonate, and 35 parts by weight of sodium sulfate were dissolved and dried at 130°C using a spray dryer. 20 parts by weight of this mixed product, 80 parts by weight of tartaric acid, and appropriate amounts of perfume and pigment were thoroughly mixed to obtain a powdered foaming bath agent. It was packaged in exactly the same manner as in Example 1, and a storage stability test was conducted under the same conditions as in Example 1.
２カ月放置後、発泡性浴剤は安定でラミネート
フイルム包材は何等異状のないことを確認した。 After being left for two months, it was confirmed that the foaming bath agent was stable and that there was no abnormality in the laminate film packaging material.
Claims (1)
を配合することを特徴とする発泡性浴剤。1. A foaming bath agent characterized by containing a mixed product of carbonate and sulfate and an organic acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6072482A JPS58177912A (en) | 1982-04-12 | 1982-04-12 | Foamable bath agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6072482A JPS58177912A (en) | 1982-04-12 | 1982-04-12 | Foamable bath agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58177912A JPS58177912A (en) | 1983-10-18 |
| JPS6146450B2 true JPS6146450B2 (en) | 1986-10-14 |
Family
ID=13150505
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6072482A Granted JPS58177912A (en) | 1982-04-12 | 1982-04-12 | Foamable bath agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58177912A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0788295B2 (en) * | 1986-05-27 | 1995-09-27 | 忠生 白石 | Bath salt bag |
| JPH02149511A (en) * | 1988-11-29 | 1990-06-08 | King Kagaku Kk | Foaming bath liquid |
| JP5072570B2 (en) * | 2007-12-18 | 2012-11-14 | 花王株式会社 | Granular foam bath agent |
| JP2010024184A (en) * | 2008-07-22 | 2010-02-04 | Tsumura Lifescience Co Ltd | Swelling-ameliorating composition and method for ameliorating swelling by utilizing the same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50116622A (en) * | 1974-02-23 | 1975-09-12 | ||
| JPS5444013A (en) * | 1977-08-15 | 1979-04-07 | Kuroisutaa Kemikaruzu Kk | Production of foamable tablet |
| JPS5638124A (en) * | 1979-06-11 | 1981-04-13 | Uss Eng & Consult | Purifier for waste gas |
-
1982
- 1982-04-12 JP JP6072482A patent/JPS58177912A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50116622A (en) * | 1974-02-23 | 1975-09-12 | ||
| JPS5444013A (en) * | 1977-08-15 | 1979-04-07 | Kuroisutaa Kemikaruzu Kk | Production of foamable tablet |
| JPS5638124A (en) * | 1979-06-11 | 1981-04-13 | Uss Eng & Consult | Purifier for waste gas |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58177912A (en) | 1983-10-18 |
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