JPH09227347A - One package hair decolorant - Google Patents
One package hair decolorantInfo
- Publication number
- JPH09227347A JPH09227347A JP6190396A JP6190396A JPH09227347A JP H09227347 A JPH09227347 A JP H09227347A JP 6190396 A JP6190396 A JP 6190396A JP 6190396 A JP6190396 A JP 6190396A JP H09227347 A JPH09227347 A JP H09227347A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- hair bleaching
- component
- composition
- bleaching agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Cosmetics (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、毛髪脱色性組成物
を泡状に吐出する1剤式毛髪脱色剤に関する。TECHNICAL FIELD The present invention relates to a one-component hair bleaching agent for discharging a hair bleaching composition in the form of foam.
【0002】[0002]
【従来の技術】従来より、過酸化水素を利用して毛髪を
脱色することが行われているが、一般には、アルカリ剤
を含有する第1剤と過酸化水素水を含有する第2剤とか
らなる2剤式毛髪脱色剤が使用されている。このような
2剤式毛髪脱色剤は、使用時に第1剤と第2剤とを混合
するという繁雑な操作が必須であるという問題がある。2. Description of the Related Art Conventionally, it has been practiced to bleach hair using hydrogen peroxide. Generally, a first agent containing an alkaline agent and a second agent containing hydrogen peroxide solution are used. A two-part hair bleaching agent consisting of Such a two-component hair bleaching agent has a problem that a complicated operation of mixing the first agent and the second agent at the time of use is essential.
【0003】このため、最近、使用前にそのような混合
操作が不要な1剤式毛髪脱色剤が広く使用されるように
なっている。For this reason, recently, one-component hair bleaching agents, which do not require such a mixing operation before use, have been widely used.
【0004】このような1剤式毛髪脱色剤としては、内
容液を霧状に吐出させる手段を有するスプレー容器に、
少なくとも過酸化水素を含有する液状の毛髪脱色性組成
物を充填したスプレー式毛髪脱色剤や、内容液を噴射剤
とともに泡状に吐出させる手段を有するエアゾール容器
に毛髪脱色性組成物を充填したエアゾール式毛髪脱色剤
が知られている。As such a one-component hair bleaching agent, a spray container having means for ejecting the content liquid in a mist form is used.
A spray-type hair decolorizing agent filled with a liquid hair decolorizing composition containing at least hydrogen peroxide, and an aerosol in which the hair decolorizing composition is filled in an aerosol container having means for discharging the content liquid together with a propellant into a foam form. Hair bleaching agents are known.
【0005】[0005]
【発明が解決しようとする課題】しかしながら、スプレ
ー式毛髪脱色剤の場合、内容液が飛び散るために目等に
毛髪脱色性組成物が入る危険性が高く、そのため使用時
に顔面等を覆うという面倒な操作が必要となる。また、
エアゾール式毛髪脱色剤の場合、毛髪脱色性組成物が泡
状に吐出されるために飛び散る危険性はないが、金属製
の耐圧容器やマウンテンカップを使用するために、それ
らが過酸化水素により酸化されて腐食したり、過酸化水
素の分解により耐圧容器の内圧が過度に上昇したりする
という危険性があり、保管上問題がある。However, in the case of the spray-type hair decolorizing agent, there is a high risk that the hair decolorizing composition will enter the eyes and the like because the content liquid scatters, so that the face and the like are cumbersome to cover during use. Operation is required. Also,
In the case of an aerosol type hair decolorizing agent, there is no risk of the hair decolorizing composition being scattered because it is discharged in the form of foam, but since it uses a metal pressure resistant container or mountain cup, it is oxidized by hydrogen peroxide. There is a risk of being corroded and corroded, or the internal pressure of the pressure-resistant container rising excessively due to decomposition of hydrogen peroxide, which poses a problem in storage.
【0006】このため、容器が過酸化水素により腐食し
たり、容器内圧が過度に高まったりすることがなく、し
かも泡状に毛髪脱色性組成物を吐出できるノンエアゾー
ル式の1剤式毛髪脱色剤が強く求められている。[0006] Therefore, the non-aerosol type one-part hair bleaching agent capable of discharging the hair bleaching composition in the form of foam without causing the vessel to be corroded by hydrogen peroxide or the pressure inside the vessel being excessively increased. Is strongly demanded.
【0007】また、そのような1剤式毛髪脱色剤から吐
出される泡についても、毛髪になじみ易い良好な泡質で
あり、しかも毛髪へ適用された後にはべたつかず、良好
な感触を実現できることが求められている。Further, the foam discharged from such a one-component hair bleaching agent has a good foam quality which is easily adapted to the hair and is not sticky after being applied to the hair, and a good feeling can be realized. Is required.
【0008】本発明は以上のような従来技術の課題を解
決しようとするものであり、容器が過酸化水素により腐
食されたり、容器内圧が異常に高まったりすることがな
く、しかも泡状に毛髪脱色性組成物を吐出するノンエア
ゾール式の1剤式毛髪脱色剤を提供することを第1の目
的とする。また、そのような1剤式毛髪脱色剤から吐出
された泡が、毛髪になじみ易い泡質を有し、しかも毛髪
への適用後にはべたつかず、良好な感触を毛髪に付与で
きるようにすることを第2の目的とする。The present invention is intended to solve the problems of the prior art as described above, and does not cause the container to be corroded by hydrogen peroxide or to abnormally increase the internal pressure of the container, and further, to make the hair foamy. A first object is to provide a non-aerosol, one-agent type hair bleaching agent for discharging a bleaching composition. In addition, the foam discharged from such a one-component hair bleaching agent has a foam quality that is easily adapted to the hair, and is not sticky after application to the hair, and imparts a good feel to the hair. Is the second purpose.
【0009】[0009]
【課題を解決するための手段】本発明者らは、過酸化水
素と起泡剤とを含有する液状の毛髪脱色性組成物を、内
容液と空気とを混合して泡状に吐出可能な泡吐出手段を
有するフォーマー容器に内容液として充填することによ
り、上述の第1の目的を達成できることを見出し、本発
明を完成させるに至った。また、特に、毛髪脱色性組成
物の起泡剤として、両性界面活性剤とカチオン性界面活
性剤とを併用することにより上述の第2の目的を達成で
きることを見出し、本発明を完成させるに至った。Means for Solving the Problems The present inventors can discharge a liquid hair decolorizing composition containing hydrogen peroxide and a foaming agent in a foam form by mixing a content liquid and air. The present invention has been completed by finding that the above-mentioned first object can be achieved by filling the former container having a foam discharge means as the content liquid. Further, in particular, it was found that the above-mentioned second object can be achieved by using an amphoteric surfactant and a cationic surfactant in combination as a foaming agent for a hair decolorizing composition, and completed the present invention. It was
【0010】即ち、本発明は、以下の成分(A)及び
(B): (A)過酸化水素 (B)起泡剤 を含有する毛髪脱色性組成物が、内容液と空気とを混合
して泡状に吐出可能な泡吐出手段を有するフォーマー容
器に内容液として充填されていることを特徴とする1剤
式毛髪脱色剤を提供する。That is, according to the present invention, a hair bleaching composition containing the following components (A) and (B): (A) hydrogen peroxide (B) foaming agent is prepared by mixing the content liquid and air. A one-component type hair bleaching agent is provided, which is filled as a content liquid in a foamer container having a foam discharging means capable of discharging a foam.
【0011】また、本発明は、特に好ましい態様の一つ
として成分(B)の起泡剤として、両性界面活性剤及び
カチオン性界面活性剤を使用する1剤式毛髪脱色剤を提
供する。The present invention also provides, as one of the particularly preferred embodiments, a one-pack hair bleaching agent which uses an amphoteric surfactant and a cationic surfactant as a foaming agent for component (B).
【0012】[0012]
【発明の実施の形態】以下、本発明を詳細に説明する。BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below.
【0013】本発明の1剤式毛髪脱色剤は、毛髪脱色性
組成物と、それが充填されるフォーマー容器とから構成
される。The one-component hair bleaching agent of the present invention comprises a hair bleaching composition and a foamer container filled with the composition.
【0014】ここで、毛髪脱色性組成物は成分(A)過
酸化水素と成分(B)起泡剤とを含有する。Here, the hair bleaching composition contains component (A) hydrogen peroxide and component (B) a foaming agent.
【0015】成分(A)の過酸化水素は、毛髪のメラニ
ン色素を酸化脱色する成分である。The component (A), hydrogen peroxide, is a component that oxidizes and decolorizes the melanin pigment of hair.
【0016】毛髪脱色性組成物中の成分(A)の過酸化
水素の含有量は、特に制限されず、所望の脱色力に応じ
て含有量を決定することができるが、皮膚に対する過度
の刺激を避けるためには、好ましくは6重量%以下、よ
り好ましくは4重量%以下とする。The content of the component (A) hydrogen peroxide in the hair decolorizing composition is not particularly limited, and the content can be determined according to the desired decolorizing power, but excessive irritation to the skin. To avoid this, the amount is preferably 6% by weight or less, more preferably 4% by weight or less.
【0017】成分(B)の起泡剤は、フォーマー容器の
泡吐出手段において空気と毛髪脱色剤組成物を混合して
容易に泡を形成し且つその泡を安定化するための成分で
あり、公知の起泡剤を使用することができる。例えば、
アルキル硫酸塩、ポリオキシエチレンアルキルエーテル
硫酸塩等のアニオン性界面活性剤、塩化アルキルトリメ
チルアンモニウム、塩化ジアルキルジメチルアンモニウ
ム等のカチオン性界面活性剤、脂肪酸アミドプロピルベ
タイン、アルキルジメチルアミンオキサイド、アルキル
カルボキシメチルヒドロキシエチルイミダゾリニウムベ
タイン、アルキルジメチルアミノ酢酸ベタイン等の両性
界面活性剤、ポリオキシエチレンアルキルエーテル、ア
ルキルアルカノールアミド等のノニオン性界面活性剤、
ヒドロキシエチルセルロースヒドロキシプロピルアルキ
ルジメチルアンモニウムクロライド等のイオン性ポリマ
ーなどを単独もしくは混合して成分(B)の起泡剤とし
て使用することができる。The foaming agent as the component (B) is a component for easily mixing the air and the hair decolorizing agent composition in the foam discharging means of the former container to form a foam and stabilizing the foam. Known foaming agents can be used. For example,
Anionic surfactants such as alkyl sulfates and polyoxyethylene alkyl ether sulfates, cationic surfactants such as alkyl trimethyl ammonium chloride and dialkyl dimethyl ammonium chloride, fatty acid amide propyl betaine, alkyl dimethyl amine oxide, alkyl carboxymethyl hydroxy Amphoteric surfactants such as ethylimidazolinium betaine and alkyldimethylaminoacetic acid betaine, nonionic surfactants such as polyoxyethylene alkyl ether and alkylalkanolamides,
An ionic polymer such as hydroxyethyl cellulose hydroxypropylalkyldimethylammonium chloride or the like can be used alone or in combination as a foaming agent of the component (B).
【0018】毛髪脱色性組成物中の成分(B)の起泡剤
の含有量は、少なすぎると安定な泡が得られず、多すぎ
ると毛髪にベタツキやきしみ感が生ずるので、好ましく
は0.1〜5重量%、より好ましくは0.5〜3重量%
である。When the content of the foaming agent of the component (B) in the hair decolorizing composition is too small, stable foam cannot be obtained, and when it is too large, the hair becomes sticky or squeaky, so that it is preferably 0. .1 to 5% by weight, more preferably 0.5 to 3% by weight
It is.
【0019】なお、毛髪のベタツキやきしみ感を改善し
て使用後の毛髪に更に良好な感触を実現するために、成
分(B)の起泡剤として、好ましくは、上述の両性界面
活性剤及びカチオン性界面活性剤、特に、両性界面活性
剤として脂肪酸アミドプロピルベタイン及びカチオン性
界面活性剤として塩化アルキルトリメチルアンモニウム
を併用することが好ましい。この場合、毛髪脱色性組成
物中の両性界面活性剤の含有量は、少なすぎると安定な
泡が得られず、多すぎると毛髪にベタつきやきしみ感が
生ずるので、好ましくは0.1〜3重量%、より好まし
くは0.1〜1重量%である。また、カチオン性界面活
性剤の含有量は、少なすぎると毛髪に良好な感触を付与
できず、多すぎると毛髪にベタつきが生ずるので、好ま
しくは0.01〜1重量%、より好ましくは0.05〜
0.5重量%である。In order to improve the stickiness and squeaky feeling of the hair and to realize a better feeling on the hair after use, the foaming agent of the component (B) is preferably the above-mentioned amphoteric surfactant and It is preferable to use a cationic surfactant, in particular, fatty acid amide propyl betaine as the amphoteric surfactant and alkyl trimethyl ammonium chloride as the cationic surfactant. In this case, if the content of the amphoteric surfactant in the hair decolorizing composition is too small, stable foam cannot be obtained, and if it is too large, the hair becomes sticky or squeaky. %, More preferably 0.1 to 1% by weight. Further, if the content of the cationic surfactant is too small, a good feel cannot be imparted to the hair, and if it is too large, the hair becomes sticky. Therefore, the content is preferably 0.01 to 1% by weight, more preferably 0. 05-
0.5% by weight.
【0020】更に、本発明においては、、毛髪に良好な
感触を付与することを目的として、シリコーン化合物を
毛髪脱色性組成物中に配合することが好ましい。Further, in the present invention, it is preferable to add a silicone compound to the hair decolorizing composition for the purpose of imparting a good feel to the hair.
【0021】このようなシリコーン化合物としては、ア
ミノ変性シリコーン、ポリエーテル変性シリコーン、ジ
メチルポリシロキサンなどを挙げることができる。ま
た、毛髪脱色性組成物中のシリコーン化合物の含有量
は、好ましくは0.01〜2重量%、より好ましくは
0.05〜0.5重量%である。Examples of such silicone compounds include amino-modified silicone, polyether-modified silicone and dimethylpolysiloxane. The content of the silicone compound in the hair decolorizing composition is preferably 0.01 to 2% by weight, more preferably 0.05 to 0.5% by weight.
【0022】本発明において、毛髪脱色性組成物の粘度
は、粘度が高過ぎると低温での発泡性が低下するので、
25℃において好ましくは30cp以下、より好ましく
は0.1〜20cpとする。In the present invention, the viscosity of the hair bleaching composition is such that if the viscosity is too high, the foamability at low temperatures will decrease.
At 25 ° C., it is preferably 30 cp or less, more preferably 0.1 to 20 cp.
【0023】また、毛髪脱色性組成物のpHは、低すぎ
ると皮膚刺激が高まり、高過ぎると過酸化水素の分解が
促進されてしまうので、好ましくは2〜6、より好まし
くは2.5〜4に設定する。When the pH of the hair bleaching composition is too low, skin irritation is increased, and when it is too high, decomposition of hydrogen peroxide is promoted. Therefore, the pH is preferably 2 to 6, more preferably 2.5 to. Set to 4.
【0024】なお、毛髪脱色性組成物には、上述した成
分に加えて、香料、紫外線吸収剤、金属封鎖剤、殺菌
剤、防腐剤、水溶性溶剤(エタノール等)、水、水溶性
高分子化合物、保湿剤等を必要に応じて配合することが
できる。The hair bleaching composition contains, in addition to the above-mentioned components, a fragrance, an ultraviolet absorber, a sequestering agent, a bactericide, an antiseptic, a water-soluble solvent (ethanol, etc.), water and a water-soluble polymer. A compound, a moisturizer, etc. can be blended as needed.
【0025】次に、本発明において毛髪脱色性組成物を
収容するフォーマー容器は、噴射剤を使用することな
く、内容液と空気とを混合して泡状に吐出可能な泡吐出
手段を有する。従って、毛髪脱色剤の使用時における毛
髪脱色性組成物が飛び散ることを防止することができ
る。Next, in the present invention, the foamer container for accommodating the hair decolorizing composition has a foam discharge means capable of mixing the content liquid and air without using a propellant and discharging the foam. Therefore, it is possible to prevent the hair bleaching composition from scattering when the hair bleaching agent is used.
【0026】以上説明した毛髪脱色性組成物が充填され
るフォーマー容器としては、内容液と空気とを混合して
泡状に吐出可能な泡吐出手段を有する公知のポンプフォ
ーマー容器、スクイズフォーマー容器あるいは蓄圧式ポ
ンプフォーマー容器等を使用することができる。例え
ば、食品と容器(vol.35,No.10,p588
〜593(1994);vol.35,No.11,p
624〜627(1994);vol.36,No.
3,p154〜158(1995))に記載のポンプフ
ォーマーE3タイプ、同F2タイプ(以上、大和製罐社
製)、スクイズフォーマー(大和製罐社製)、エアスプ
レーフォーマー(エアスプレーインターナショナル社
製)等が挙げられる。As the former container filled with the hair decolorizing composition described above, a known pump former container or squeeze former having a foam discharging means capable of discharging a foam by mixing the content liquid and air. A container or an accumulator pump former container can be used. For example, food and containers (vol.35, No.10, p588)
~ 593 (1994); vol. 35, No. 11, p
624-627 (1994); vol. 36, no.
3, p154-158 (1995)), pump former E3 type, same F2 type (above, Yamato Seikan Co., Ltd.), squeeze former (Daiwa Seikan Co., Ltd.), air spray former (Air Spray International). Manufactured by the company) and the like.
【0027】なお、本発明において使用するフォーマー
容器において、内容物である毛髪脱色性組成物に接触す
る部分(容器内壁、泡吐出手段内壁等)には、過酸化水
素により腐食せず、また、過酸化水素が分解して発生し
た酸素が透過するような材質で構成することが好まし
い。これにより、容器の腐食と内圧の過度の上昇を防止
して、毛髪脱色剤の保管上の安全性を確保することがで
きる。In the former container used in the present invention, the portion (the inner wall of the container, the inner wall of the foam discharging means, etc.) that comes into contact with the hair decolorizing composition as the content is not corroded by hydrogen peroxide, and It is preferable to use a material that allows the oxygen generated by decomposition of hydrogen peroxide to permeate. Thereby, the corrosion of the container and the excessive rise of the internal pressure can be prevented, and the safety in storage of the hair decolorizing agent can be ensured.
【0028】本発明の毛髪脱色剤は、過酸化水素と起泡
剤と必要に応じて他の成分とを均一に混合して毛髪脱色
性組成物を調製し、それを上述のフォーマー容器に常法
により充填することにより製造することができる。The hair bleaching agent of the present invention is prepared by uniformly mixing hydrogen peroxide, a foaming agent and, if necessary, other components to prepare a hair bleaching composition, which is always stored in the above-mentioned former container. It can be manufactured by filling by the method.
【0029】本発明の毛髪脱色剤は、フォーマー容器か
ら吐出させた毛髪脱色性組成物の泡を毛髪に塗布し、必
要により乾燥もしくは洗浄することにより使用すること
ができる。The hair bleaching agent of the present invention can be used by applying foam of the hair bleaching composition discharged from the former container to the hair, and drying or washing if necessary.
【0030】[0030]
【実施例】以下、本発明を実施例に基づいて具体的に説
明する。DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be specifically described below based on embodiments.
【0031】実施例1〜9 表1に示す組成の毛髪脱色性組成物を常法により調製
し、それを表1に示すフォーマー容器に常法により充填
することにより毛髪処理剤を製造した。Examples 1 to 9 Hair decolorizing compositions having the compositions shown in Table 1 were prepared by a conventional method, and filled in a foamer container shown in Table 1 by a conventional method to prepare a hair treatment composition.
【0032】まず、得られた毛髪処理剤を常温で365
日間保管し、保管終了時の容器の腐食と容器の異常な膨
らみに関し、目視にて外観検査した。その結果を表1及
び表2に示す。First, the hair treating agent thus obtained was subjected to 365 at room temperature.
It was stored for a day and visually inspected for corrosion and abnormal swelling of the container at the end of storage. The results are shown in Tables 1 and 2.
【0033】次に、10名のパネラーの頭髪に、毛髪処
理剤から吐出させた泡を塗布し乾燥してもらい、その際
の泡の「毛髪への塗布性」、頭髪に塗布して乾燥した後
の「しっとり感」及び頭髪に塗布して乾燥した後の「べ
たつき」のそれぞれについて、以下の得点表に従って4
段階に官能評価させ、得られた得点の平均点を以下の判
定基準にしたがって評価した。その結果を表1及び表2
に示す。Next, the hair discharged from the hair treatment agent was applied to the hair of 10 panelists and dried, and the "applicability to the hair" of the foam at that time was applied to the hair and dried. For each of the following "moist feeling" and "stickiness" after applying to hair and drying, 4 according to the following score table.
Sensory evaluation was performed in stages, and the average score of the obtained scores was evaluated according to the following criteria. The results are shown in Table 1 and Table 2.
Shown in
【0034】また、泡を吐出させた際に毛髪脱色剤が飛
び散るか否かについても目視にて観察した。その結果も
表1及び表2に示す。Further, it was visually observed whether or not the hair decolorizing agent was scattered when the foam was discharged. The results are also shown in Tables 1 and 2.
【0035】「毛髪への塗布性」得点表 得点 評価内容 3: 頭髪に非常に塗りやすい 2: 頭髪に塗りやすい 1: どちらともいえない 0: 頭髪に塗りにくい"Applicability to hair" score table Score evaluation content 3: Very easy to apply to hair 2: Easy to apply to hair 1: Neither can be said 0: Difficult to apply to hair
【0036】「しっとり感」評価基準 得点 評価内容 3: しっとりする 2: ややしっとりする 1: どちらともいえない 0: しっとりしない"Moisture" Evaluation Criteria Score Evaluation Contents 3: Moisturize 2: Mild Moisture 1: Neither can be said 0: No Moisture
【0037】「べたつき」 得点 評価内容 3: ベタつかない 2: ほとんどベタつかない 1: どちらともいえない 0: ベタつく"Stickiness" score Evaluation contents 3: Not sticky 2: Hardly sticky 1: Neither can be said 0: Sticky
【0038】「判定基準」 ランク 平均点 ◎: 2.4以上 ○: 1.8以上2.4未満 △: 1.0以上1.8未満 ×: 1.0未満"Judgment Criteria" Rank Average Score ◎: 2.4 or more ○: 1.8 or more and less than 2.4 △: 1.0 or more and less than 1.8 ×: less than 1.0
【0039】[0039]
【表1】 (重量%) 実施例 毛髪脱色性組成物成分 1 2 3 4 5 過酸化水素水(35%) 8.57 ← ← ← ← ラウリン酸アミト゛フ゜ロヒ゜ルヘ゛タイン 0.3 ← ← ← ← ラウリルシ゛メチルアミノ酢酸ヘ゛タイン / / / / / 2-アルキル-N-カルホ゛キシメチル-N-ヒト゛ロキシエチルイミタ゛ソ゛リニウムヘ゛タイン / / / / / 塩化トリメチルセチルアンモニウム 0.1 ← ← ← / 塩化シ゛メチルステアリルアンモニウム / / / / / ホ゜リオキシエチレン(20)ラウリルエーテル 1.0 ← ← ← ← アミノ変性シリコーン 0.05 ← ← / 0.05 95%エタノール 8.0 ← ← ← ← 香料 0.1 ← ← ← ← りん酸 適量 ← ← ← ← 精製水 ハ゛ランス ← ← ← ← 毛髪脱色剤組成物 pH 3.0 ← ← ← ← 粘度(cp/25℃) 1.4 ← ← 1.7 1.4 フォーマー容器*1 A B C A A (評価) 保管上の安全性 問題なし ← ← ← ← 泡の飛び散りの有無 無し ← ← ← ← 毛髪への塗布性 ◎ ◎ ◎ ◎ ◎ しっとり感 ◎ ◎ ◎ ○ ○べたつき ◎ ◎ ◎ ○ ○ [Table 1] (% by weight) Example hair bleaching composition component 1 2 3 4 5 hydrogen peroxide solution (35%) 8.57 ← ← ← ← amidopropropyl betaine laurate 0.3 ← ← ← lauryl dimethyl aminoamino acetic acid betaine / / / / / / 2-Alkyl-N-carboxymethyl-N-human maloxyethylimidazolinium betaine / / / / / / Trimethylcetylammonium chloride 0.1 ← ← ← / Dimethylstearyl ammonium chloride / / / / / / Polyoxyethylene (20) Lauryl ether 1.0 ← ← ← ← Amino-modified silicone 0.05 ← ← / 0.05 95% Ethanol 8.0 ← ← ← ← fragrance 0.1 ← ← ← ← Phosphoric acid Appropriate amount ← ← ← ← Purified water balance ← ← ← ← Hair decolorizer composition pH 3.0 ← ← ← ← Viscosity (cp / 25 ℃) 1.4 ← ← 1.7 1.4 Foamer container * 1 A B C A A (Evaluation) Safety in storage No problem ← ← ← ← No scattering of bubbles None ← ← ← ← Applicability to hair ◎ ◎ ◎ ◎ ◎ ◎ Moisture ◎ ◎ ◎ ◎ ○ ○ Sticky ◎ ◎ ◎ ◎ ○ ○
【0040】表1及び表2注 フォーマー容器*1 A: ポンプフォーマー(F2タイプ(ボール材とスプ
リング材としてSUS316を使用),大和製罐社製) B: 蓄圧式ポンプフォーマー(エアスプレーフォーマ
ー(ボール材とスプリング材としてSUS316を使
用),エアスプレーインターナショナル社製) C: スクイズフォーマー(正立タイプ,大和製罐社
製)Table 1 and Table 2 Note: Foamer container * 1 A: Pump former (F2 type (using SUS316 as ball material and spring material), manufactured by Yamato Can Co., Ltd.) B: Accumulation type pump former (air spray four Mar (using SUS316 as ball and spring material), made by Air Spray International Co., Ltd. C: Squeeze former (upright type, made by Daiwa Can Co., Ltd.)
【0041】[0041]
【表2】 (重量%) 実施例 毛髪脱色性組成物成分 6 7 8 9 過酸化水素水(35%) 8.57 ← ← ← ラウリン酸アミト゛フ゜ロヒ゜ルヘ゛タイン 1.0 0.3 / / ラウリルシ゛メチルアミノ酢酸ヘ゛タイン / / 0.5 / 2-アルキル-N-カルホ゛キシメチル-N-ヒト゛ロキシエチルイミタ゛ソ゛リニウムヘ゛タイン / / / 0.5 塩化トリメチルセチルアンモニウム 0.1 0.3 / / 塩化シ゛メチルステアリルアンモニウム / / 0.15 ← ホ゜リオキシエチレン(20)ラウリルエーテル 0.5 1.0 ← ← アミノ変性シリコーン 0.05 ← ← ← 95%エタノール 8.0 ← ← ← 香料 0.1 ← ← ← りん酸 適量 ← ← ← 精製水 ハ゛ランス ← ← ← 毛髪脱色剤組成物 pH 3.0 ← ← ← 粘度(cp/25℃) 1.4 1.7 1.5 1.5 フォーマー容器*1 A C A B (評価) 保管上の安全性 問題なし ← ← ← 泡の飛び散りの有無 無し ← ← ← 毛髪への塗布性 ◎ ◎ ◎ ◎ しっとり感 ◎ ◎ ◎ ◎ べたつき ◎ ◎ ◎ ◎ [Table 2] (% by weight) Example hair bleaching composition component 6 7 8 9 Hydrogen peroxide solution (35%) 8.57 ← ← ← Amidoplopropyl betaine laurate 1.0 0.3 / / Lauryl dimethyl aminoamino acetic acid betaine / / 0.5 / 2-Alkyl-N-carboxymethyl-N-human ethoxyethylimidazolinium betaine / / / / 0.5 trimethylcetylammonium chloride 0.1 0.3 / / dimethylstearylammonium chloride / / 0.15 ← polyoxyethylene (20) lauryl ether 0.5 1.0 ← ← amino Modified silicone 0.05 ← ← ← 95% ethanol 8.0 ← ← ← Perfume 0.1 ← ← ← Phosphoric acid Suitable amount ← ← ← Purified water balance ← ← ← Hair decolorizer composition pH 3.0 ← ← ← Viscosity (cp / 25 ℃) 1.4 1.7 1.5 1.5 foamer container * 1 a C a B (evaluation) Nashi safety problems on the storage ← ← ← Tobichi of foam Without the presence or absence of ← ← ← coating properties to the hair ◎ ◎ ◎ ◎ moist feeling ◎ ◎ ◎ ◎ sticky ◎ ◎ ◎ ◎
【0042】表1及び表2から、実施例1〜9の本発明
の1剤式毛髪脱色剤は、容器の腐食や内圧の過度の上昇
などの保管上の安全性に関する問題がなく、しかも使用
時に毛髪脱色性組成物が飛び散ることがない。From Tables 1 and 2, the one-part hair bleaching agents of the present invention of Examples 1 to 9 are free from problems concerning storage safety such as corrosion of containers and excessive rise of internal pressure, and are used. Sometimes the hair bleaching composition does not scatter.
【0043】更に、起泡剤として両性界面活性剤とカチ
オン性界面活性剤とを併用した実施例1〜3の結果と、
起泡剤として両性界面活性剤のみを使用した実施例5の
結果から、両性界面活性剤とカチオン性界面活性剤とを
併用することにより、毛髪に対する良好な塗布性を有
し、しかも毛髪に適用された後にはべたつかず、良好な
感触(しっとり感)を毛髪に付与できることがわかる。Further, the results of Examples 1 to 3 in which an amphoteric surfactant and a cationic surfactant were used together as a foaming agent,
From the results of Example 5 in which only the amphoteric surfactant was used as the foaming agent, it was found that by using the amphoteric surfactant and the cationic surfactant in combination, the composition has good coatability on hair and is applied to hair. It can be seen that after being applied, it does not become sticky and a good feeling (moisturizing feeling) can be imparted to the hair.
【0044】また、シリコーン化合物を使用した実施例
1〜3の結果とシリコーン化合物を使用しない実施例4
の結果から、シリコーン化合物を使用することにより、
毛髪に適用した後のベタつきとしっとり感とを改善でき
ることがわかる。The results of Examples 1 to 3 using a silicone compound and Example 4 not using a silicone compound.
From the results of, by using a silicone compound,
It can be seen that the stickiness and moist feeling after application to hair can be improved.
【0045】[0045]
【発明の効果】本発明によれば、容器が過酸化水素によ
り腐食されたり、容器内圧が異常に高まったりすること
がなく、しかも泡状に毛髪脱色性組成物を吐出するノン
エアゾール式の1剤式毛髪脱色剤を提供することができ
る。しかも、本発明の毛髪脱色剤から吐出される泡は、
毛髪になじみ易い泡質を有し、毛髪へ適用された後には
ベタつかず、良好な感触を毛髪に付与することができ
る。According to the present invention, the container is not corroded by hydrogen peroxide and the pressure inside the container is not abnormally increased, and the hair bleaching composition is discharged in the form of foam. A formula hair bleaching agent can be provided. Moreover, the foam discharged from the hair decolorizing agent of the present invention is
It has a foam quality that is easy to adapt to the hair, does not become sticky after being applied to the hair, and can impart a good feel to the hair.
Claims (12)
して泡状に吐出可能な泡吐出手段を有するフォーマー容
器に内容液として充填されていることを特徴とする1剤
式毛髪脱色剤。1. A hair bleaching composition containing the following components (A) and (B): (A) hydrogen peroxide (B) foaming agent is mixed with the content liquid and air to form a foam. A one-component type hair decolorizing agent, which is filled as a content liquid in a former container having a discharging means for discharging bubbles.
器、スクイズフォーマー容器又は蓄圧式ポンプフォーマ
ー容器である請求項1記載の1剤式毛髪脱色剤。2. The one-component hair bleaching agent according to claim 1, wherein the foamer container is a pump former container, a squeeze foamer container, or a pressure-accumulation pump former container.
性剤、カチオン性界面活性剤、両性界面活性剤、ノニオ
ン性界面活性剤又はイオン性ポリマーである請求項1又
は2記載の1剤式毛髪脱色剤。3. The foaming agent of component (B) is an anionic surfactant, a cationic surfactant, an amphoteric surfactant, a nonionic surfactant or an ionic polymer. Formulated hair bleaching agent.
中の含有量が0.1〜5重量%である請求項3記載の1
剤式毛髪脱色剤。4. The hair decolorizing composition according to claim 3, wherein the foaming agent of component (B) is contained in the hair decolorizing composition in an amount of 0.1 to 5% by weight.
Formulated hair bleaching agent.
及びカチオン性界面活性剤である請求項1又は2記載の
1剤式毛髪脱色剤。5. The one-component hair bleaching agent according to claim 1, wherein the foaming agent as the component (B) is an amphoteric surfactant and a cationic surfactant.
ルベタイン、アルキルジメチルアミンオキサイド、アル
キルカルボキシメチルヒドロキシエチルイミダゾリニウ
ムベタイン又はアルキルジメチルアミノ酢酸ベタインで
あり、カチオン性界面活性剤が、塩化アルキルトリメチ
ルアンモニウム又は塩化ジアルキルジメチルアンモニウ
ムである請求項5記載の1剤式毛髪脱色剤。6. The amphoteric surfactant is fatty acid amide propyl betaine, alkyl dimethyl amine oxide, alkyl carboxymethyl hydroxyethyl imidazolinium betaine or alkyl dimethyl amino acetic acid betaine, and the cationic surfactant is alkyl trimethyl ammonium chloride. Alternatively, the one-component hair bleaching agent according to claim 5, which is dialkyldimethylammonium chloride.
ベタインであり、カチオン性界面活性剤が塩化アルキル
トリメチルアンモニウムである請求項6記載の1剤式毛
髪脱色剤。7. The one-component hair bleaching agent according to claim 6, wherein the amphoteric surfactant is fatty acid amidopropyl betaine and the cationic surfactant is alkyltrimethylammonium chloride.
含有量が0.1〜3重量%であり、カチオン性界面活性
剤の含有量が0.01〜1重量%である請求項5〜7の
いずれかに記載の1剤式毛髪脱色剤。8. The hair bleaching composition has an amphoteric surfactant content of 0.1 to 3% by weight and a cationic surfactant content of 0.01 to 1% by weight. The one-component hair bleaching agent according to any one of 5 to 7.
成物中に0.01〜2重量%含有する請求項1〜8のい
ずれかに記載の1剤式毛髪脱色剤。9. The one-component hair bleaching agent according to claim 1, further comprising 0.01 to 2% by weight of a silicone compound in the hair bleaching composition.
いて30cp以下である請求項1〜9のいずれかに記載
の1剤式毛髪脱色剤。10. The one-component hair bleaching agent according to claim 1, wherein the viscosity of the hair bleaching composition is 30 cp or less at 25 ° C.
る請求項1〜10のいずれかに記載の1剤式毛髪脱色
剤。11. The one-component type hair bleaching agent according to claim 1, wherein the hair bleaching composition has a pH of 2-6.
組成物中に6重量%以下である請求項1〜11のいずれ
かに記載の1剤式毛髪脱色剤。12. The one-component hair bleaching agent according to claim 1, wherein the component (A) hydrogen peroxide is 6% by weight or less in the hair bleaching composition.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6190396A JPH09227347A (en) | 1996-02-24 | 1996-02-24 | One package hair decolorant |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6190396A JPH09227347A (en) | 1996-02-24 | 1996-02-24 | One package hair decolorant |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH09227347A true JPH09227347A (en) | 1997-09-02 |
Family
ID=13184583
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6190396A Pending JPH09227347A (en) | 1996-02-24 | 1996-02-24 | One package hair decolorant |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH09227347A (en) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000010515A1 (en) * | 1998-08-21 | 2000-03-02 | Unilever Plc | A composition for lightening and highlighting hair |
JP2008156354A (en) * | 2006-12-21 | 2008-07-10 | L'oreal Sa | Cationic surfactant, bio-heteropolysaccharide, ampholytic surfactant, and direct dye composition containing direct dye |
WO2008136441A1 (en) * | 2007-04-27 | 2008-11-13 | Kao Corporation | Two-pack type hair dyeing or bleaching preparation |
JP2009051856A (en) * | 2003-04-25 | 2009-03-12 | Kao Corp | Hair cosmetic product |
JP2009161491A (en) * | 2008-01-09 | 2009-07-23 | Milbon Co Ltd | Second agent composition for dyeing hair and oxidation type hair dyestuff |
JP2011093824A (en) * | 2009-10-27 | 2011-05-12 | Hoyu Co Ltd | Hydrogen peroxide-containing composition |
JP2012026887A (en) * | 2010-07-23 | 2012-02-09 | Rei Sho | Reagent for quantitative determination of cell or substance |
US8152858B2 (en) | 2007-10-24 | 2012-04-10 | Kao Corporation | Head hair dyeing method |
US8349022B2 (en) | 2009-03-11 | 2013-01-08 | Kao Corporation | Two-part hair dye |
US8394151B2 (en) | 2007-10-24 | 2013-03-12 | Kao Corporation | Head hair dyeing method |
US8636812B2 (en) | 2010-08-31 | 2014-01-28 | Kao Corporation | Two-part foam hair dye |
US10226649B2 (en) | 2007-04-27 | 2019-03-12 | Kao Corporation | Hair dyeing or bleaching method |
-
1996
- 1996-02-24 JP JP6190396A patent/JPH09227347A/en active Pending
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000010515A1 (en) * | 1998-08-21 | 2000-03-02 | Unilever Plc | A composition for lightening and highlighting hair |
US6274126B1 (en) | 1998-08-21 | 2001-08-14 | Helene Curtis, Inc. | Composition for lightening and highlighting hair |
DE202004021775U1 (en) | 2003-04-25 | 2010-11-25 | Kao Corp. | Hair cosmetic product |
EP1470812B1 (en) * | 2003-04-25 | 2014-03-05 | Kao Corporation | Hair cosmetic product |
JP2009051856A (en) * | 2003-04-25 | 2009-03-12 | Kao Corp | Hair cosmetic product |
US8158112B2 (en) | 2003-04-25 | 2012-04-17 | Kao Corporation | Hair cosmetic product |
DE202004021806U1 (en) | 2003-04-25 | 2011-02-17 | Kao Corporation | Hair cosmetic product |
EP2319481A1 (en) | 2003-04-25 | 2011-05-11 | Kao Corporation | Hair cosmetic product |
US8277784B2 (en) | 2003-04-25 | 2012-10-02 | Kao Corporation | Hair cosmetic product |
US8246936B2 (en) | 2003-04-25 | 2012-08-21 | Kao Corporation | Hair cosmetic product |
US8153108B2 (en) | 2003-04-25 | 2012-04-10 | Kao Corporation | Hair cosmetic product |
DE202004021884U1 (en) | 2003-04-25 | 2012-05-02 | Kao Corp. | Hair cosmetic product |
JP2008156354A (en) * | 2006-12-21 | 2008-07-10 | L'oreal Sa | Cationic surfactant, bio-heteropolysaccharide, ampholytic surfactant, and direct dye composition containing direct dye |
US8388696B2 (en) | 2007-04-27 | 2013-03-05 | Kao Corporation | Two-part hair dye or bleach composition |
WO2008136441A1 (en) * | 2007-04-27 | 2008-11-13 | Kao Corporation | Two-pack type hair dyeing or bleaching preparation |
US10226649B2 (en) | 2007-04-27 | 2019-03-12 | Kao Corporation | Hair dyeing or bleaching method |
US8152858B2 (en) | 2007-10-24 | 2012-04-10 | Kao Corporation | Head hair dyeing method |
US8394151B2 (en) | 2007-10-24 | 2013-03-12 | Kao Corporation | Head hair dyeing method |
US8529638B2 (en) | 2007-10-24 | 2013-09-10 | Kao Corporation | Head hair dyeing composition |
JP2009161491A (en) * | 2008-01-09 | 2009-07-23 | Milbon Co Ltd | Second agent composition for dyeing hair and oxidation type hair dyestuff |
US8349022B2 (en) | 2009-03-11 | 2013-01-08 | Kao Corporation | Two-part hair dye |
US8449627B2 (en) | 2009-03-11 | 2013-05-28 | Kao Corporation | Two-part hair dye |
JP2011093824A (en) * | 2009-10-27 | 2011-05-12 | Hoyu Co Ltd | Hydrogen peroxide-containing composition |
JP2012026887A (en) * | 2010-07-23 | 2012-02-09 | Rei Sho | Reagent for quantitative determination of cell or substance |
US8636812B2 (en) | 2010-08-31 | 2014-01-28 | Kao Corporation | Two-part foam hair dye |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4663251B2 (en) | Hair cosmetics | |
RU2493820C2 (en) | Two-component foam-forming hair dye | |
AU628115B2 (en) | Self-foaming oil compositions and process for making and using same | |
JP4007501B2 (en) | Hair bleaching products | |
JPH09227347A (en) | One package hair decolorant | |
JP2024069683A (en) | Hair dye composition | |
JP2000297008A (en) | Foaming cosmetic | |
JP2003206221A (en) | Hair bleach | |
JP2000297007A (en) | Foaming cosmetic | |
JP5986394B2 (en) | Foam forming aerosol composition | |
KR101906857B1 (en) | Foamy cosmetic material | |
JP3755903B2 (en) | Gel spray composition | |
JP3500805B2 (en) | Denture cleaner | |
JP6591245B2 (en) | Aerosol type foamy hair dye 1st agent composition | |
JP2002302427A (en) | Decoloration treatment agent for hair | |
JP6340395B2 (en) | Foam-based water-based cosmetic | |
JP2999729B2 (en) | Clothes finish |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20040106 |
|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20040212 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20040330 |