NO136601B - - Google Patents

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Publication number
NO136601B
NO136601B NO174071A NO174071A NO136601B NO 136601 B NO136601 B NO 136601B NO 174071 A NO174071 A NO 174071A NO 174071 A NO174071 A NO 174071A NO 136601 B NO136601 B NO 136601B
Authority
NO
Norway
Prior art keywords
boric acid
flame
glue
ammonia
added
Prior art date
Application number
NO174071A
Other languages
Norwegian (no)
Other versions
NO136601C (en
Inventor
Horst Wippermann
Werner Henze
Burchard Schmidtmann
Original Assignee
Telefunken Patent
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Telefunken Patent filed Critical Telefunken Patent
Publication of NO136601B publication Critical patent/NO136601B/no
Publication of NO136601C publication Critical patent/NO136601C/en

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Classifications

    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04NPICTORIAL COMMUNICATION, e.g. TELEVISION
    • H04N9/00Details of colour television systems
    • H04N9/44Colour synchronisation
    • H04N9/455Generation of colour burst signals; Insertion of colour burst signals in colour picture signals or separation of colour burst signals from colour picture signals
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04NPICTORIAL COMMUNICATION, e.g. TELEVISION
    • H04N9/00Details of colour television systems
    • H04N9/44Colour synchronisation
    • H04N9/465Synchronisation of the PAL-switch

Landscapes

  • Engineering & Computer Science (AREA)
  • Multimedia (AREA)
  • Signal Processing (AREA)
  • Processing Of Color Television Signals (AREA)
  • Color Television Systems (AREA)
  • Cylinder Crankcases Of Internal Combustion Engines (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)

Description

Flammemotstandsdyktig tresponplate. Flame-resistant chipboard.

Som flammebeskyttende middel for im-pregnering eller maling av tre, vev og andre brennbare stoffer, blir som bekjent brukt metallsalter, som f. eks. kalsium-, sink-eller ammoniumklorid og ammoniumfosfat i oppløst form, og slike blir allerede fremstillet. Man har også brukt flammebeskyttende midler i form av pulvere hvor de enkelte metallsalter er forenet til en fast masse, som bl. a. også inneholder borsyre-pulver. Denne blanding blir sluttelig brukt i en 10 til 15 pst. oppløsning. Metal salts, such as e.g. calcium, zinc or ammonium chloride and ammonium phosphate in dissolved form, and such are already being produced. Flame retardants have also been used in the form of powders where the individual metal salts are combined into a solid mass, such as a. also contains boric acid powder. This mixture is finally used in a 10 to 15 percent solution.

Forsøk med å bruke det kjente, flam-mehemmende sekundære eller primære ammoniumfosfat som impregneringsmid-del for tresponplater, ga ikke noe særlig gunstig resultat, da kvaliteten av platen ved slik tilsetning ble betydelig redusert uten at det ble oppnådd tilsvarende for-bedring av den brannhemmende virkning. Virkningen av ammoniumfosfatet beror som bekjent på at dette salt ved høyere temperatur spaltes i ammoniakk, vann og fosforpentoksyd, hvorved den frigjorte ikke brennbare ammoniakk forsinker oppflam-mingen. En merkbar virkning av dette salt inntrer imidlertid først ved tilsetning av ca. 5—10 pst. av sponvekten. Attempts to use the known, flame-retardant secondary or primary ammonium phosphate as an impregnation agent for chipboards did not give any particularly favorable results, as the quality of the board was significantly reduced by such addition without a corresponding improvement in the fire-retardant being achieved effect. The effect of the ammonium phosphate is due, as is well known, to the fact that this salt breaks down at a higher temperature into ammonia, water and phosphorus pentoxide, whereby the released non-flammable ammonia delays the ignition. However, a noticeable effect of this salt only occurs when approx. 5-10 percent of the chip weight.

Bruker man imidlertid en slik mengde, så er ammoniakkutviklingen i løpet av However, if such a quantity is used, the ammonia development is during

pressetiden ved en pressetemperatur på ca. 150° C allerede så stor at platene brister. Den alkaliske reaksjon av ammoniakken hindrer dessuten bindemidlets herdning. Man kan følgelig bare tilsette 2 til 3 pst. the press time at a press temperature of approx. 150° C already so great that the plates burst. The alkaline reaction of the ammonia also prevents the binder from hardening. You can therefore only add 2 to 3 percent.

av dette kjemikalium, men dermed vil man neppe oppnå en tilstrekkelig brannhemmende virkning. of this chemical, but this will hardly achieve a sufficient fire-retardant effect.

De øvrige nevnte salter som sink- eller kalsiumklorid, kan ikke benyttes i sponplater da de er hygroskopiske. Heller ikke ammoniumklorid kan brukes, da det på grunn av sin sterkt sure reaksjon ville be-virke en alt for hurtig herding av de urinstoff-, melamin- eller fenolharpikser som anvendes som bindemiddel. Likeledes ville det ved de nevnte midler bli frigjort skade-lige gasser, som hydrogenklorid og ammoniakk. The other mentioned salts, such as zinc or calcium chloride, cannot be used in chipboard as they are hygroscopic. Ammonium chloride cannot be used either, as due to its strongly acidic reaction it would cause the urea, melamine or phenolic resins used as binder to harden too quickly. Likewise, harmful gases, such as hydrogen chloride and ammonia, would be released by the means mentioned.

På grunnlag av tallrike forsøk er det nå fastslått at tilsetning av 3—15 vekt-prosent borsyre i granulat eller pulverform til tresponen, etter at den er tørret, men før limpåføringen, gir en sponplate som er flammemotstandsdyktig. Virkningen av borsyren ligger i at den ved temperaturer over 100° C spaltes i vann og bortrioksyd. Bortrioksydet smelter ved videre oppvarm-ing allerede ved 294° C, og blir nå oppsugd av tresponen, som blir impregnert av den glasslignende bortrioksydsmelte og ikke kan flamme opp mer. On the basis of numerous experiments, it has now been established that the addition of 3-15% by weight of boric acid in granular or powder form to the wood shavings, after it has been dried, but before the application of glue, produces a chipboard that is flame resistant. The effect of boric acid lies in the fact that at temperatures above 100° C it splits into water and boron trioxide. The boron trioxide melts on further heating already at 294° C, and is now absorbed by the wood shavings, which are impregnated by the glass-like molten boron trioxide and can no longer ignite.

I og for seg kunne borsyren settes til tresponene etter limtilsetningen. Dette ville imidlertid være vesentlig ugunstigere fordi borsyrepulveret ville legge seg på lim-laget slik at limets bindekraft ikke ville komme til sin fulle rett. Ved at borsyrepulveret kom til å ligge mellom de flater som skulle belegges med lim, ville de en-kelte spon bindes svakere sammen, hvilket ville føre til sponplater med dårligere me-kaniske egenskaper. Således vil for eksem-pel skjærfastheten av plater med samme In and of itself, the boric acid could be added to the wood shavings after the addition of glue. However, this would be significantly less favorable because the boric acid powder would settle on the glue layer so that the glue's binding power would not reach its full potential. As the boric acid powder came to lie between the surfaces to be coated with glue, the individual chips would be bound together more weakly, which would lead to chipboards with poorer mechanical properties. Thus, for example, the shear strength of plates will with the same

spesifikke vekt som er fremstillet av spon specific weight which is made from shavings

med samme kvalitet og samme belimings-grad dvs. samme innhold av harpiksfast-stoff, være 4,8 kg/cm- og 6,0 kg/cm- når with the same quality and the same degree of gluing, i.e. the same content of resin solids, be 4.8 kg/cm- and 6.0 kg/cm- when

borsyren tilsettes henholdsvis etter og før the boric acid is added respectively after and before

limpåføringen. For å oppnå den samme the adhesive application. To achieve the same

platekvalitet ved tilsetning av borsyre etter plate quality by adding boric acid after

limpåføringen som ved borsyretilsetning the glue application as with the addition of boric acid

før limpåføringen ville det i det førstnevnte before the glue application, it would in the former

tilfelle være nødvendig med vesentlig større in the event that a significantly larger one is required

bindemiddelmengder, hvilket ville resul-. tere i en mindre økonomisk fremstillings-prosess. amounts of binder, which would resul-. tere in a less economical manufacturing process.

Platene motstår brann minst dobbelt The boards resist fire at least twice

så lenge som en vanlig plate uten tilsetning. Heller ikke utvikler borsyren skade-lige gasser, som f. eks. hydrogenklorid eller as long as a regular plate without additives. Nor does the boric acid develop harmful gases, such as e.g. hydrogen chloride or

ammoniakk. Videre har borsyren en for-delaktig virkning på sponplaten, forsåvidt ammonia. Furthermore, the boric acid has a beneficial effect on the chipboard, of course

som den minsker vannopptagning og svel-ling av platen, hvilket oppnås ved en bedre herdning av de vanlige kunstharpiksbinde-midler som urinstoff-, melamin og fenolharpikser. Denne bedre herdning blir frem-met ved den svakt sure reaksjon av borsyren (pH-verdi ca. 5). as it reduces water absorption and swelling of the plate, which is achieved by a better hardening of the usual synthetic resin binders such as urea, melamine and phenolic resins. This better hardening is brought about by the slightly acidic reaction of the boric acid (pH value approx. 5).

Denne plate brenner ikke ved å utsette for en flamme, og heller ikke gløder eller ulmer den etter at flammen er fjernet. Ved sterk flammepåvirkning inntrer bare en forkulling. Motstandsdyktigheten mot brann er minst dobbelt så stor som for en vanlig uimpregnert plate. This plate does not burn when exposed to a flame, nor does it glow or smolder after the flame is removed. In the case of strong flame exposure, only charring occurs. The resistance to fire is at least twice as great as for a normal non-impregnated board.

I det etterfølgende er gitt en sammen-lignende oversikt av prøveresultater for en uimpregnert sponplate, en som er impregnert med 5 pst. ammonfosfat og en som er impregnert med ca. 10 pst. borsyre. In what follows, a comparative overview of test results is given for an unimpregnated chipboard, one that is impregnated with 5% ammonium phosphate and one that is impregnated with approx. 10 percent boric acid.

Brannprøven ble utført på den måten at like store platestykker ble utsatt for en flamme i 5 minutter under like betingelser. The fire test was carried out in such a way that equal-sized pieces of plate were exposed to a flame for 5 minutes under the same conditions.

Som det fremgår av oversikten er den As can be seen from the overview, it is

plate som er behandlet med borsyre, ikke plate treated with boric acid does not

bare flammefri, men oppviser også en al-minnelighet kvalitetsforbedring således f. only flame-free, but also shows an al-like quality improvement, thus e.g.

eks. med hensyn til vannopptagning, tyk-kelse-svelling og bøyefasthet. e.g. with regard to water absorption, thickness swelling and flexural strength.

i in

Claims (2)

1. Fremgangsmåte for fremstilling av1. Procedure for the production of flammemotstandsdyktige tresponplater,karakterisert ved at tresponene etter tørring og før limpåføringen blir tilsatt borsyre i korn- eller pulverform. flame-resistant chipboards, characterized in that the chips after drying and before applying glue, boric acid is added in granular or powder form. 2. Fremgangsmåte som angitt i påstand 1, karakterisert ved at borsyren blir tilsatt i en mengde av fra 3 til 15 pst. av den tørrede trevekt.2. Method as stated in claim 1, characterized in that the boric acid is added in an amount of from 3 to 15 per cent. of the dried wood weight.
NO174071A 1967-07-19 1971-05-10 PAL COLOR TV RECEIVER WITH CONNECTING AND DISCONNECTING THE MODULATED COLOR FARMER. NO136601C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE1967T0034350 DE1278494B (en) 1967-07-19 1967-07-19 Circuit in a PAL color television receiver to correct the switching phase of the line-frequency switch
DE1967T0034815 DE1537479B2 (en) 1967-07-19 1967-09-19 Circuit in a PAL color television receiver to correct the switching phase of the line-frequency switch
NO282568A NO122989B (en) 1967-07-19 1968-07-17

Publications (2)

Publication Number Publication Date
NO136601B true NO136601B (en) 1977-06-20
NO136601C NO136601C (en) 1977-09-28

Family

ID=48537728

Family Applications (2)

Application Number Title Priority Date Filing Date
NO282568A NO122989B (en) 1967-07-19 1968-07-17
NO174071A NO136601C (en) 1967-07-19 1971-05-10 PAL COLOR TV RECEIVER WITH CONNECTING AND DISCONNECTING THE MODULATED COLOR FARMER.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
NO282568A NO122989B (en) 1967-07-19 1968-07-17

Country Status (13)

Country Link
AT (1) AT282717B (en)
AU (2) AU425473B2 (en)
BE (1) BE718244A (en)
DE (2) DE1278494B (en)
DK (1) DK126080C (en)
ES (1) ES356250A1 (en)
FI (1) FI42730C (en)
FR (1) FR1593556A (en)
GB (1) GB1239052A (en)
NL (1) NL6810041A (en)
NO (2) NO122989B (en)
NZ (2) NZ153808A (en)
SE (1) SE330219B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS531608B1 (en) * 1971-05-04 1978-01-20
JPS5426789Y2 (en) * 1974-07-23 1979-09-03
JPS5346226A (en) * 1976-10-08 1978-04-25 Toshiba Corp Color television receiving circuit for pal
US4148058A (en) * 1977-09-26 1979-04-03 Rca Corporation PAL switching control circuit
JPS5542482A (en) * 1978-09-19 1980-03-25 Sanyo Electric Co Ltd Color signal circuit of pal color television receiver
JPS5730486A (en) * 1980-07-30 1982-02-18 Matsushita Electric Ind Co Ltd Chrominance demodulator

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1248708B (en) * 1965-05-21 1967-08-31 Telefunken Patentverwertungsgesellschaft mbH, Ulm/Donau Circuit arrangement m a color television receiver with cell-sequential switching to synchronize the order switching phase of the color sync pulse

Also Published As

Publication number Publication date
NO122989B (en) 1971-09-13
BE718244A (en) 1968-12-31
AU426913B2 (en) 1972-08-07
AT282717B (en) 1970-07-10
GB1239052A (en) 1971-07-14
FI42730B (en) 1970-06-30
FI203568A (en) 1969-01-20
FI42730C (en) 1970-10-12
ES356250A1 (en) 1970-01-01
DK348468A (en)
NO136601C (en) 1977-09-28
AU425473B2 (en) 1972-06-26
NZ153182A (en)
NZ153808A (en)
SE330219B (en) 1970-11-09
DE1278494B (en) 1968-09-26
AU4290668A (en) 1970-03-12
DK126080C (en) 1976-07-19
AU4068468A (en) 1970-01-22
NL6810041A (en) 1969-01-21
DK126080B (en) 1973-06-04
DE1537479A1 (en) 1969-09-25
DE1537479B2 (en) 1975-07-24
FR1593556A (en) 1970-06-01

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