NO136203B - - Google Patents
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- NO136203B NO136203B NO4785/69A NO478569A NO136203B NO 136203 B NO136203 B NO 136203B NO 4785/69 A NO4785/69 A NO 4785/69A NO 478569 A NO478569 A NO 478569A NO 136203 B NO136203 B NO 136203B
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- Norway
- Prior art keywords
- carbon atoms
- detergent
- mixture
- complex
- alkyl
- Prior art date
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- 239000003599 detergent Substances 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 18
- 125000004432 carbon atom Chemical group C* 0.000 claims description 16
- 238000004383 yellowing Methods 0.000 claims description 13
- 239000004014 plasticizer Substances 0.000 claims description 10
- -1 alkali metal alkyl sulfate Chemical class 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 4
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
- 150000001450 anions Chemical group 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 2
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 2
- 239000000271 synthetic detergent Substances 0.000 claims description 2
- BTOOAFQCTJZDRC-UHFFFAOYSA-N 1,2-hexadecanediol Chemical compound CCCCCCCCCCCCCCC(O)CO BTOOAFQCTJZDRC-UHFFFAOYSA-N 0.000 claims 1
- 239000004141 Sodium laurylsulphate Substances 0.000 claims 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims 1
- 229910021653 sulphate ion Inorganic materials 0.000 claims 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- 125000005233 alkylalcohol group Chemical group 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 150000008051 alkyl sulfates Chemical class 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 239000004665 cationic fabric softener Substances 0.000 description 3
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 3
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 239000002979 fabric softener Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000002752 cationic softener Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- VJQGGZWPOMJLTP-UHFFFAOYSA-N octadecane-1,1-diol Chemical compound CCCCCCCCCCCCCCCCCC(O)O VJQGGZWPOMJLTP-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
- C11D3/2013—Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
- D06M13/473—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
Description
Hittil har man dempet gulningen som følger av myk- So far, the yellowing that results from soft-
gjøring med konvensjonelle kationiske tøymyknere, ved å til- with conventional cationic fabric softeners, by adding
føre et anionisk overflateaktivt middel i kombinasjon med den kationiske mykner. Det anioniske overflateaktive middel dan- lead an anionic surfactant in combination with the cationic plasticizer. The anionic surfactant dan-
ner et kompleks med den kationiske mykner, som under de riktige betingelser kan avsettes på tøyet som skal mykgjøres, uten at det fremkommer gulning. Denne fremgangsmåte har en stor ulempe ved det at nærværet av et anionisk overflateaktivt middel interfererer med mykningseffektiviteten til de fleste kation- ner a complex with the cationic softener, which under the right conditions can be deposited on the fabric to be softened, without yellowing occurring. This method has a major disadvantage in that the presence of an anionic surfactant interferes with the softening efficiency of most cationic
aktive myknere. active plasticizers.
Oppfinnelsen vedrører en bygget tøyvaskemiddel- The invention relates to a built laundry detergent
blanding, inneholdende som vaskemiddelkomponent et ikke-ionisk syntetisk vaskemiddel, og en mykner som er basert på en kvater- mixture, containing as a detergent component a non-ionic synthetic detergent, and a softener which is based on a quaternary
nær amoniumforbindelse med formelen close ammonium compound with the formula
hvor R og R2 hver er langkjedede, i alt vesentlig lineære grupper med 16-22 karbonatomer, R og R^ hver er lavere alkyl- where R and R2 are each long-chain, essentially linear groups with 16-22 carbon atoms, R and R^ are each lower alkyl-
grupper med 1-3 karbonatomer, og X er et anion som gir vann-dispergerhet, f.eks. klorid, bromid, jodid, sulfat og metosulfat, groups with 1-3 carbon atoms, and X is an anion that gives water dispersibility, e.g. chloride, bromide, iodide, sulfate and methosulfate,
eller et imidazolin med formelen or an imidazoline of the formula
hvor R,_ og R^ hver er i alt vesentlig lineære alkylgrupper med 15-21 karbonatomer, R er en toverdig alkylgruppe med 1-3 karbonatomer, og R^°g X er som definert ovenfor, samt en antigulningskomponent, karakterisert ved at blandingen inneholder som antigulningskomponent et i og for seg kjent kompleks av en alkanol eller alkandiol med 12-22 karbonatomer og et alkalimetallalkyl-sulfat hvor alkylgruppen har 12-18 karbonatomer, i en slik mengde at vektforholdet mellom mykner og kompleks ligger mellom 1,4:1 og 10:1. where R,_ and R^ are each essentially linear alkyl groups with 15-21 carbon atoms, R is a divalent alkyl group with 1-3 carbon atoms, and R^°g X is as defined above, as well as an anti-yellowing component, characterized in that the mixture contains as an anti-yellowing component a per se known complex of an alkanol or alkanediol with 12-22 carbon atoms and an alkali metal alkyl sulfate where the alkyl group has 12-18 carbon atoms, in such an amount that the weight ratio between plasticizer and complex is between 1.4:1 and 10:1.
I US-patentskrift 2.166.314 er det beskrevet anvendelse av alkylsulfater (sulfaterte alkoholer) sammen med høyere alkoholer. Disse materialer gir et kompleks av den type som er definert i denne beskrivelse. Imidlertid er kompleksene i den tidligere publikasjon- foreslått som hjelpemiddel for forbedring av vaskeevnen, og det er ingen véiledning om å anvende dette kompleks sammen med en mykner for tilveiebringelse av en anti-gulningseffekt. US patent 2,166,314 describes the use of alkyl sulphates (sulphated alcohols) together with higher alcohols. These materials provide a complex of the type defined in this description. However, the complexes in the earlier publication are suggested as aids for improving washability, and there is no guidance on using this complex together with a plasticizer to provide an anti-yellowing effect.
Et foretrukket vektforhqld mellom mykner og kompleks i vaskemiddelblandingen i henhold til oppfinnelsen er mellom 2:1 A preferred weight ratio between plasticizer and complex in the detergent mixture according to the invention is between 2:1
og 4:1. Anvendelse av komplekset i et overskudd av ca. 0,7 del pr. del mykner, gir ytterligere forbedring med hensyn til reduk-sjon av misfarvning'. Imidlertid- har disse høye konsentrasjoner av komplekset tendens til å bevirke uforholdsmessige tap i tøy-mykningseffektiviteten. and 4:1. Application of the complex in an excess of approx. 0.7 part per part softener, provides further improvement with respect to reduction of discoloration'. However, these high concentrations of the complex tend to cause disproportionate losses in fabric softening efficiency.
Komplekset mellom alkanoler og alkylsulfater er tidligere beskrevet (se en artikkel av Godhard & Kung i "Soap &Chemical Specialities", feb. 1966) i teknikkens stand på området. Det angis vanligvis med formelen 2ROS03Na.R'OH hvor det anvendes en alkanol. Liknende komplekser antas å dannes også fra-alkandioler. The complex between alkanols and alkyl sulfates has previously been described (see an article by Godhard & Kung in "Soap & Chemical Specialties", Feb. 1966) in the state of the art in the field. It is usually indicated with the formula 2ROS03Na.R'OH where an alkanol is used. Similar complexes are believed to form also from alkanediols.
Egnede alkanoler kan være lineære, naturlige eller syntetiske i sin opprinnelse, som for eksempel dodecylalkohol, myristylalkohol, stearylalkohol og blandede alkoholer som for eksempel c^^ - til C^g-alkoholer fremstilt ved ziegler-polymerisa-sjon av etylen. Alkandioler som for eksempel oktadekandiol kan også brukes om ønskes. Suitable alkanols can be linear, natural or synthetic in origin, such as for example dodecyl alcohol, myristyl alcohol, stearyl alcohol and mixed alcohols such as, for example, c^^ - to C^g alcohols produced by Ziegler polymerization of ethylene. Alkanediols such as octadecanediol can also be used if desired.
Egnede alkylsulfater for bruk i forbindelse med oppfinnelsen, har fra ca. 12 til ca. 18 karbonatomer. Typisk er alkylgruppen lineær, slik som n-dodecyl, myristyl og stearyl. Alkylsulfatene kan være enten i alt vesentlig rene eller blandet. For komersielle formål foretrekkes natrium- eller kaliumsaltene, men andre alkalimetaller kan substitueres om ønskes. Suitable alkyl sulphates for use in connection with the invention have from approx. 12 to approx. 18 carbon atoms. Typically, the alkyl group is linear, such as n-dodecyl, myristyl and stearyl. The alkyl sulfates can be either essentially pure or mixed. For commercial purposes, the sodium or potassium salts are preferred, but other alkali metals may be substituted if desired.
Ved fremstilling av myknere for anvendelse i produkter i overensstemmelse med oppfinnelsen kan mykneren, alkylalkoholen eller diolen og sulfatet kombineres i hvilken som helst passende rekkefølge. Mens alkylalkohol/alkylsulfat-komplekset kan dannes før disse ingredienser blandes med mykneren om så ønskes, er det således ikke nødvendig å gjøre det. In preparing plasticizers for use in products in accordance with the invention, the plasticizer, the alkyl alcohol or diol, and the sulfate may be combined in any suitable order. Thus, while the alkyl alcohol/alkyl sulfate complex can be formed before these ingredients are mixed with the plasticizer if desired, it is not necessary to do so.
Disse produkter er nyttige i skylletrinnet i en vaske-prosess. På grunn av overføringen fra vaskesyklusen til skylle-syklusen har gulning vært et hårdnakket problem ved anvendelse av forskjellige vaskemidler. Bruken av en blanding av en kationisk mykner og et kompleks i henhold til oppfinnelsen reduserer dette problem. These products are useful in the rinse step of a washing process. Due to the transfer from the wash cycle to the rinse cycle, yellowing has been a stubborn problem when using various detergents. The use of a mixture of a cationic plasticizer and a complex according to the invention reduces this problem.
Oppfinnelsen omfatter tøyvaskemiddelblandinger eller multifunksjonelle vaskemidler. På grunn av den velkjente kationisk/anioniske vekselvirkning som fører til tap både i vaske-evne og tøymyknings-effektivitet, vil antigulningsmidler være spesielt nyttige når det settes opp resepter for multifunksjonelle vaskemidler basert på ikke-ionisk vaskeaktivt stoff og kationiske tøymykningsmidler. The invention includes laundry detergent mixtures or multifunctional detergents. Due to the well-known cationic/anionic interaction that leads to loss of both detergency and fabric softening efficiency, anti-yellowing agents will be particularly useful when preparing recipes for multi-functional detergents based on non-ionic detergents and cationic fabric softeners.
Typiske tøyvaskemiddelblandinger/multifunksjonelle vaskemidler som nyttiggjør seg oppfinnelsen, har følgende sammen-setning: Typical laundry detergent mixtures/multifunctional detergents that make use of the invention have the following composition:
Foretrukne sammensetninger har generelt følgende vektforhold: Preferred compositions generally have the following weight ratios:
Det ikke-ioniske vaskeaktive stoff som er brukt, er en konvensjonell type. Eksempler på slike er kondensater av hydrofobe forbindelser med reaktivt hydrogen og etylenoksyd, idet mengden av etylenoksyd i kondensatet skal være tilstrekkelig til å gi produkt-ene overflateaktive egenskaper. Typiske ikke-ioniske vaskemidler som kan brukes, omfatter etylenoksyd/polypropylenoksyd-blokkpolymer-er som markedsføres under handelsbetegnelsen "Pluronic" (RTM)-serier; videre etylenoksydkondensater av alkylalkoholer med fra 8 til 20 karbonatomer i alkylgruppen og som inneholder opp til 80% etylenoksyd; etylenoksydkondensater av fettsyrer som for eksempel etoksylerte tallolje-fettsyrer; etylenoksydkondensater av fettsyre-aminene; og mange andre. Denne vaskemiddelklasse er velkjent for fagmannen på området. The non-ionic detergent used is a conventional type. Examples of such are condensates of hydrophobic compounds with reactive hydrogen and ethylene oxide, the amount of ethylene oxide in the condensate must be sufficient to give the products surface-active properties. Typical nonionic detergents that can be used include ethylene oxide/polypropylene oxide block polymers marketed under the trade name "Pluronic" (RTM) series; further ethylene oxide condensates of alkyl alcohols with from 8 to 20 carbon atoms in the alkyl group and which contain up to 80% ethylene oxide; ethylene oxide condensates of fatty acids such as ethoxylated tall oil fatty acids; ethylene oxide condensates of the fatty acid amines; and many others. This detergent class is well known to the person skilled in the art.
Som byggere kan organiske sådanne brukes, for eksempel ni tr iltr i eddik syre eller de konvensjonelle alkaliske byggere, for eksempel alkalimetall-fosfåtene, -pyrofosfåtene,-tripolyfosfåtene og -heksametafosfåtene. Fyllstoffer som for eksempel alkalimetall-karbonater kan brukes. Mengden av. bygger vil være slik som vanligvis brukt. Normalt, når byggere brukes i et vaskemiddel system, As builders, organic ones can be used, for example ni tri iltr in acetic acid or the conventional alkaline builders, for example the alkali metal phosphates, -pyrophosphates, -tripolyphosphates and -hexametaphosphates. Fillers such as alkali metal carbonates can be used. The amount of. builds will be as normally used. Normally, when builders are used in a detergent system,
er den anvendte mengde i størrelsesorden 25 til 50% av hele sammen-setningen. is the amount used in the order of 25 to 50% of the entire composition.
Hjelpemidler kan tilsettes, for eksempel skumforsterkere, for eksempel fettsyreamider, videre smussbærende midler, for eksempel karboksymetylcellulose og hydroksyetylcellulose, anti-korrosjonsmidler, for eksempel, natriumsulikat, og dessuten optiske hvitemidler, farvemidler, parfyme, fyllstoff, germicider og enzymer.. Auxiliaries can be added, for example foam enhancers, for example fatty acid amides, further dirt-carrying agents, for example carboxymethyl cellulose and hydroxyethyl cellulose, anti-corrosion agents, for example, sodium silicate, and also optical brighteners, coloring agents, perfumes, fillers, germicides and enzymes..
Oppfinnelsen skal i det følgende belyses ved hjelp av eksempler. In the following, the invention will be illustrated by means of examples.
Eksempler 1.- 8 Examples 1.- 8
En tøyvaske/multifunksjonell vaskemiddelblanding . A laundry/multifunctional detergent mix.
ble fremstilt og bestod av en konvensjonelt bygget ikke-ionisk vaskemiddelblanding, som omfattet natriumtripolyfosfat som bygger, distearyl-dimetylammoniumklorid. som tøymykningsmiddel, n at r iumlaurylsulfat was prepared and consisted of a conventionally constructed non-ionic detergent composition comprising sodium tripolyphosphate as builder, distearyl dimethyl ammonium chloride. as a fabric softener, n at r ium lauryl sulfate
som alkylsulfat og forskjellige alkylalkoholer. Fem 10 cm x 15 cm frottébiter ble behandlet i et Terg-O-Tometer i 15 minutter med 1000 ml vann av 90 ppm hardhet sqm var kunstig hardgjort med kalsium such as alkyl sulfate and various alkyl alcohols. Five 10 cm x 15 cm terry cloth pieces were treated in a Terg-O-Tometer for 15 minutes with 1000 ml of water of 90 ppm hardness sqm was artificially hardened with calcium
+3 og magnesium i forholdet 2sl og som i tillegg inneholdt 4 ppm Fe Vasketemperaturen var 49°c. 1,94 g av det byggete ikke-ioniske vaskemiddel og 0,1 g distearyldimetylammoniumklorid ble brukt, idet mengdene av natriumlaurylsulfatet og alkylalkoholen ble variert som angitt i tabell I. +3 and magnesium in the ratio 2sl and which also contained 4 ppm Fe. The washing temperature was 49°c. 1.94 g of the constructed nonionic detergent and 0.1 g of distearyldimethylammonium chloride were used, the amounts of the sodium lauryl sulfate and the alkyl alcohol being varied as indicated in Table I.
I hvert forsøk som ble utført, ble forbedringer med hensyn til mykhet og gulning målt i forhold til mykheten og gul-heten som ble observert på tøybiter vasket i blandinger som i alt vesentlig bestod av bare bygger og ikke-ionisk vaskemiddel, og av bygger/ikke-ionisk vaskemiddel/kationisk tøymykningsmiddel, for kontrollens skyld. Ved avlesning av forskjellene i mykhet ( ^ S) og gulning ( j\ b) kan mer betydelige sammenligninger utføres mellom suksessive forsøk. Blant de data som er gjengitt nedenunder indikerer en økning i verdien av £± S forbedret mykhet i sluttproduktet i forhold til mykheten i kontrollprøven. En økning i verdien av /\ b indikerer en forringelse av hvithet eller økning av gulhet på de vaskete tøybiter. In each trial conducted, improvements in softness and yellowing were measured relative to the softness and yellowing observed on pieces of fabric washed in mixtures consisting essentially of builder only and nonionic detergent, and of builder/ non-ionic detergent/cationic fabric softener, for the sake of control. By reading the differences in softness ( ^ S ) and yellowing ( j\ b ), more significant comparisons can be made between successive trials. Among the data reproduced below, an increase in the value of £± S indicates improved softness in the final product relative to the softness in the control sample. An increase in the value of /\ b indicates a deterioration in whiteness or an increase in yellowness of the washed pieces of cloth.
Eksempler 9- 12 Examples 9-12
Det forsøk som er beskrevet i eksemplene 1-8, ble gjen-tatt ved at tøymykneren l-metyl-l-alkylamid-etyl-2-alkylimidazolin-ium-metosulfat ble brukt i stedet for distearyldimetylammoniumklorid som tidligere er beskrevet. Følgende resultater ble oppnådd: The experiment described in examples 1-8 was repeated in that the fabric softener 1-methyl-1-alkylamide-ethyl-2-alkylimidazolinium methosulphate was used instead of the distearyldimethylammonium chloride previously described. The following results were obtained:
På samme måte ble en rekke komplekser laget av alkylsulfater med fra 12 til 18 karbonatomer og alkylalkoholer med fra 12 til 22 karbonatomer og undersøkt som antigulningsmidler. Similarly, a number of complexes were made from alkyl sulfates with from 12 to 18 carbon atoms and alkyl alcohols with from 12 to 22 carbon atoms and investigated as anti-yellowing agents.
De komplekser som ble funnet å være effektive, var de følgende: The complexes found to be effective were the following:
Claims (4)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US78246968A | 1968-12-09 | 1968-12-09 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO136203B true NO136203B (en) | 1977-04-25 |
| NO136203C NO136203C (en) | 1977-08-03 |
Family
ID=25126152
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO4785/69A NO136203C (en) | 1968-12-09 | 1969-12-03 | BUILT DETERGENT MIXTURE. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3644203A (en) |
| AT (1) | AT298402B (en) |
| BE (1) | BE742879A (en) |
| CH (2) | CH498976A (en) |
| DE (1) | DE1961451C3 (en) |
| DK (2) | DK131432B (en) |
| FR (1) | FR2025683A1 (en) |
| GB (1) | GB1282428A (en) |
| NL (1) | NL161827C (en) |
| NO (1) | NO136203C (en) |
| SE (1) | SE368027B (en) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4000077A (en) * | 1972-05-04 | 1976-12-28 | Colgate-Palmolive Company | Enhancement of cationic softener |
| US3954632A (en) * | 1973-02-16 | 1976-05-04 | The Procter & Gamble Company | Softening additive and detergent composition |
| US3928213A (en) * | 1973-03-23 | 1975-12-23 | Procter & Gamble | Fabric softener and soil-release composition and method |
| US3968042A (en) * | 1974-09-13 | 1976-07-06 | Phillips Petroleum Company | Finishing agent and nonscroopy polyolefin fibers |
| US3936537A (en) * | 1974-11-01 | 1976-02-03 | The Procter & Gamble Company | Detergent-compatible fabric softening and antistatic compositions |
| US4073735A (en) * | 1976-02-19 | 1978-02-14 | Colgate Palmolive Company | Rinse cycle fabric softener |
| FR2376994A1 (en) * | 1977-01-11 | 1978-08-04 | Snecma | IMPROVEMENTS TO RESONANT CAVITY DEVICES FOR THE REDUCTION OF NOISE IN A DUCT IN THE PRESENCE OF A GAS FLOW |
| US4213867A (en) * | 1978-12-29 | 1980-07-22 | Domtar Inc. | Fabric conditioning compositions |
| US4264457A (en) * | 1980-02-04 | 1981-04-28 | Desoto, Inc. | Cationic liquid laundry detergent and fabric softener |
| US4388077A (en) * | 1981-08-07 | 1983-06-14 | W. E. Greer Ltd. | Composition for washing fabric |
| DE3309569A1 (en) * | 1982-03-22 | 1983-10-27 | Colgate-Palmolive Co., 10022 New York, N.Y. | CONCENTRATED SOFT SOFTENER |
| US4493773A (en) * | 1982-05-10 | 1985-01-15 | The Procter & Gamble Company | Low phosphate, softening laundry detergent containing ethoxylated nonionic, alkylpolysaccharide and cationic surfactants |
| US4497716A (en) * | 1982-12-23 | 1985-02-05 | Lever Brothers Company | Fabric softening composition |
| US4661270A (en) * | 1983-05-11 | 1987-04-28 | Colgate-Palmolive Company | Concentrated fabric softening composition and methods for making same |
| GB8421800D0 (en) * | 1984-08-29 | 1984-10-03 | Unilever Plc | Detergent compositions |
| US4772403A (en) * | 1985-01-30 | 1988-09-20 | Colgate Palmolive Company | Fabric softener composition |
| GB8520803D0 (en) * | 1985-08-20 | 1985-09-25 | Procter & Gamble | Textile treatment compositions |
| US4661269A (en) * | 1985-03-28 | 1987-04-28 | The Procter & Gamble Company | Liquid fabric softener |
| US4855072A (en) * | 1985-03-28 | 1989-08-08 | The Procter & Gamble Company | Liquid fabric softener |
| GB8508129D0 (en) * | 1985-03-28 | 1985-05-01 | Procter & Gamble Ltd | Textile treatment composition |
| US4976878A (en) * | 1990-01-18 | 1990-12-11 | The Procter & Gamble Company | Process for recovering gelled aqueous liquid fabric softener |
| DE4405702A1 (en) * | 1994-02-23 | 1995-08-24 | Witco Surfactants Gmbh | Highly concentrated aqueous fabric softener with improved storage stability |
| MX9605097A (en) * | 1994-04-25 | 1997-08-30 | Procter & Gamble | Stable, aqueous laundry detergent composition having improved softening properties. |
| US5466394A (en) * | 1994-04-25 | 1995-11-14 | The Procter & Gamble Co. | Stable, aqueous laundry detergent composition having improved softening properties |
| US5584888A (en) * | 1994-08-31 | 1996-12-17 | Miracle; Gregory S. | Perhydrolysis-selective bleach activators |
| JP3916666B2 (en) * | 1995-07-11 | 2007-05-16 | ザ、プロクター、エンド、ギャンブル、カンパニー | Concentrated stable fabric softening composition comprising a chelating agent |
| CN1110541C (en) * | 1995-07-11 | 2003-06-04 | 普罗格特-甘布尔公司 | Concentrated, water dispersible, stable, fabric softening compositions |
| EP0763592B1 (en) | 1995-09-18 | 2002-04-17 | The Procter & Gamble Company | Stabilised fabric softening compositions |
| US6323172B1 (en) * | 1996-03-22 | 2001-11-27 | The Procter & Gamble Company | Concentrated, stable fabric softening composition |
| EP0839899B1 (en) | 1996-10-30 | 2003-03-26 | The Procter & Gamble Company | Fabric softening compositions |
| AU2105999A (en) | 1998-01-09 | 1999-07-26 | Witco Corporation | Novel quaternary ammonium compounds, compositions containing them, and uses thereof |
| DE19855366A1 (en) | 1998-12-01 | 2000-06-08 | Witco Surfactants Gmbh | Low-concentration, highly viscous aqueous fabric softener |
| GB0121806D0 (en) * | 2001-09-10 | 2001-10-31 | Unilever Plc | A method of reducing the viscosity of fabric conditioning compositions |
| GB0121802D0 (en) * | 2001-09-10 | 2001-10-31 | Unilever Plc | Fabric conditioning compositions |
| GB0121803D0 (en) * | 2001-09-10 | 2001-10-31 | Unilever Plc | Fabric conditioning compositions |
| DE102007012910A1 (en) | 2007-03-19 | 2008-09-25 | Momentive Performance Materials Gmbh | Fragrance-modified, branched polyorganosiloxanes |
| DE102007012909A1 (en) | 2007-03-19 | 2008-09-25 | Momentive Performance Materials Gmbh | Fragrance-modified, reactive polyorganosiloxanes |
| ES2421162T3 (en) | 2011-04-04 | 2013-08-29 | Unilever Nv | Fabric washing procedure |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2166314A (en) * | 1935-08-13 | 1939-07-18 | Procter & Gamble | Preparation of detergents |
| US2679482A (en) * | 1949-10-08 | 1954-05-25 | Colgate Palmolive Co | Synthetic detergent compositions |
| BE572404A (en) * | 1957-10-31 | |||
| US3095373A (en) * | 1959-01-30 | 1963-06-25 | Wyandotte Chemicals Corp | Fabric softeners |
| US3360470A (en) * | 1963-05-28 | 1967-12-26 | Colgate Palmolive Co | Laundering compositions |
-
0
- DK DK131432D patent/DK131432A/da unknown
- CH CH1824769D patent/CH1824769D/xx unknown
-
1968
- 1968-12-09 US US782469A patent/US3644203A/en not_active Expired - Lifetime
-
1969
- 1969-12-03 NO NO4785/69A patent/NO136203C/en unknown
- 1969-12-05 AT AT1135669A patent/AT298402B/en not_active IP Right Cessation
- 1969-12-08 DK DK648069AA patent/DK131432B/en not_active IP Right Cessation
- 1969-12-08 FR FR6942390A patent/FR2025683A1/fr not_active Withdrawn
- 1969-12-08 CH CH1824769A patent/CH498976A/en not_active IP Right Cessation
- 1969-12-08 DE DE1961451A patent/DE1961451C3/en not_active Expired
- 1969-12-08 NL NL6918426.A patent/NL161827C/en not_active IP Right Cessation
- 1969-12-09 GB GB59977/69A patent/GB1282428A/en not_active Expired
- 1969-12-09 BE BE742879D patent/BE742879A/xx not_active IP Right Cessation
- 1969-12-09 SE SE16989/69A patent/SE368027B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AT298402B (en) | 1972-05-10 |
| SE368027B (en) | 1974-06-17 |
| DE1961451B2 (en) | 1978-04-13 |
| FR2025683A1 (en) | 1970-09-11 |
| DK131432C (en) | 1975-12-15 |
| DE1961451A1 (en) | 1970-07-02 |
| GB1282428A (en) | 1972-07-19 |
| CH498976A (en) | 1970-11-15 |
| NO136203C (en) | 1977-08-03 |
| NL161827B (en) | 1979-10-15 |
| DK131432A (en) | |
| CH1824769D (en) | |
| DK131432B (en) | 1975-07-14 |
| DE1961451C3 (en) | 1978-12-14 |
| BE742879A (en) | 1970-06-09 |
| US3644203A (en) | 1972-02-22 |
| NL161827C (en) | 1980-03-17 |
| NL6918426A (en) | 1970-06-11 |
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