NO136090B - - Google Patents
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- Publication number
- NO136090B NO136090B NO1870/72A NO187072A NO136090B NO 136090 B NO136090 B NO 136090B NO 1870/72 A NO1870/72 A NO 1870/72A NO 187072 A NO187072 A NO 187072A NO 136090 B NO136090 B NO 136090B
- Authority
- NO
- Norway
- Prior art keywords
- mol
- ammonium
- sulfur
- hour
- reaction
- Prior art date
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 36
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 28
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 28
- 238000006243 chemical reaction Methods 0.000 claims description 27
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 25
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 25
- 239000003638 chemical reducing agent Substances 0.000 claims description 24
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 21
- 229910052717 sulfur Inorganic materials 0.000 claims description 21
- 239000011593 sulfur Substances 0.000 claims description 21
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 20
- 239000001166 ammonium sulphate Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 15
- 229910021529 ammonia Inorganic materials 0.000 claims description 13
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 230000007935 neutral effect Effects 0.000 claims description 8
- 239000005864 Sulphur Substances 0.000 claims description 7
- 230000002378 acidificating effect Effects 0.000 claims description 5
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 claims description 5
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 239000007791 liquid phase Substances 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 20
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- 229910001868 water Inorganic materials 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 229910021653 sulphate ion Inorganic materials 0.000 description 7
- 150000003863 ammonium salts Chemical class 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000000567 combustion gas Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 3
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical class [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- -1 polythionates Chemical class 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 150000004763 sulfides Chemical class 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910017315 Mo—Cu Inorganic materials 0.000 description 1
- 229910003204 NH2 Inorganic materials 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- WTKSIEBUEFVINF-UHFFFAOYSA-N [NH4+].[NH4+].[O-]S(=O)(=O)SSS([O-])(=O)=O Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)SSS([O-])(=O)=O WTKSIEBUEFVINF-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- BIGPRXCJEDHCLP-UHFFFAOYSA-N ammonium bisulfate Chemical compound [NH4+].OS([O-])(=O)=O BIGPRXCJEDHCLP-UHFFFAOYSA-N 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- OYLGLPVAKCEIKU-UHFFFAOYSA-N diazanium;sulfonato sulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OS([O-])(=O)=O OYLGLPVAKCEIKU-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/48—Sulfur dioxide; Sulfurous acid
- C01B17/50—Preparation of sulfur dioxide
- C01B17/501—Preparation of sulfur dioxide by reduction of sulfur compounds
- C01B17/504—Preparation of sulfur dioxide by reduction of sulfur compounds of ammonium sulfates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/026—Preparation of ammonia from inorganic compounds
- C01C1/028—Preparation of ammonia from inorganic compounds from ammonium sulfate or sulfite
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Treating Waste Gases (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fireproofing Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR717119411A FR2138545B1 (ro) | 1971-05-27 | 1971-05-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO136090B true NO136090B (ro) | 1977-04-12 |
| NO136090C NO136090C (no) | 1977-07-20 |
Family
ID=9077772
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO1870/72A NO136090C (no) | 1971-05-27 | 1972-05-26 | Fremgangsm}te for fremstilling av svoveldioksyd og ammoniakk fra ammoniumsulfat. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3810968A (ro) |
| BE (1) | BE783781A (ro) |
| CA (1) | CA975928A (ro) |
| DE (1) | DE2225293C3 (ro) |
| FR (1) | FR2138545B1 (ro) |
| GB (1) | GB1370258A (ro) |
| IT (1) | IT955880B (ro) |
| NL (1) | NL7207028A (ro) |
| NO (1) | NO136090C (ro) |
| SE (1) | SE385576B (ro) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4036943A (en) * | 1972-09-15 | 1977-07-19 | Institut Francais Du Petrole | Process for removing sulfur dioxide from a gas and producing sulfur therefrom |
| FR2280711A1 (fr) * | 1974-08-01 | 1976-02-27 | Inst Francais Du Petrole | Procede de reduction des sulfates d'ammonium fondus contenant des impuretes metalliques |
| US4053573A (en) * | 1975-11-20 | 1977-10-11 | Allied Chemical Corporation | Recovery of sulfur values from spent sulfuric acid |
| US4043822A (en) * | 1975-11-20 | 1977-08-23 | Allied Chemical Corporation | Treatment of water-soluble metal sulfate residues |
| NL7601061A (nl) * | 1976-02-03 | 1977-08-05 | Stamicarbon | Werkwijze voor het winnen van epsilon-caprolac- tam uit een epsilon-caprolactamzwavelzuur-reac- tiemengsel. |
| FR2414023A1 (fr) * | 1978-01-10 | 1979-08-03 | Inst Francais Du Petrole | Procede de conversion d'imidodisulfate d'ammonium et de dithionate d'ammonium en dioxyde de soufre et ammoniac |
| DE2900426A1 (de) * | 1978-01-10 | 1979-07-12 | Inst Francais Du Petrol | Verfahren zur umwandlung von ammonium- imidodisulfat, ammoniumsulfamat und ammoniumdithionat in schwefeldioxid und ammoniak |
| FR2424229B2 (fr) * | 1978-04-27 | 1985-07-19 | Inst Francais Du Petrole | Procede de conversion de sulfamate d'ammonium en dioxyde de soufre et ammoniac |
| US4832930A (en) * | 1988-05-02 | 1989-05-23 | Tekatch William M | Decomposition of ammonium thiocyanate |
| DE4221874A1 (de) * | 1992-07-03 | 1994-01-05 | Basf Ag | Verfahren zur thermischen Spaltung von Ammoniumsulfat in Ammoniak und Ammoniumhydrogensulfat |
| US10266404B2 (en) * | 2017-06-07 | 2019-04-23 | Chitlig Enerji Uretim Ve Pazarlama A.S. | Method for obtaining combustible gases from rocks for energy production |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL282684A (ro) * | 1961-08-30 | 1900-01-01 | ||
| NL136780C (ro) * | 1963-10-31 | |||
| DE1229995B (de) * | 1964-01-17 | 1966-12-08 | Chemiebau Dr A Zieren Ges Mit | Verfahren zur Gewinnung von Ammoniak und Schwefeldioxyd |
-
1971
- 1971-05-27 FR FR717119411A patent/FR2138545B1/fr not_active Expired
-
1972
- 1972-05-23 BE BE783781A patent/BE783781A/xx unknown
- 1972-05-23 US US00256078A patent/US3810968A/en not_active Expired - Lifetime
- 1972-05-23 GB GB2422572A patent/GB1370258A/en not_active Expired
- 1972-05-25 NL NL7207028A patent/NL7207028A/xx not_active Application Discontinuation
- 1972-05-25 DE DE2225293A patent/DE2225293C3/de not_active Expired
- 1972-05-26 IT IT24883/72A patent/IT955880B/it active
- 1972-05-26 NO NO1870/72A patent/NO136090C/no unknown
- 1972-05-26 CA CA143,367A patent/CA975928A/en not_active Expired
- 1972-05-26 SE SE7206921A patent/SE385576B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR2138545B1 (ro) | 1973-05-25 |
| DE2225293C3 (de) | 1982-03-04 |
| GB1370258A (en) | 1974-10-16 |
| IT955880B (it) | 1973-09-29 |
| NO136090C (no) | 1977-07-20 |
| SE385576B (sv) | 1976-07-12 |
| NL7207028A (ro) | 1972-11-29 |
| FR2138545A1 (ro) | 1973-01-05 |
| DE2225293A1 (de) | 1973-01-11 |
| CA975928A (en) | 1975-10-14 |
| DE2225293B2 (de) | 1981-04-16 |
| BE783781A (fr) | 1972-11-23 |
| US3810968A (en) | 1974-05-14 |
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