NO134289B - - Google Patents
Download PDFInfo
- Publication number
- NO134289B NO134289B NO287769A NO287769A NO134289B NO 134289 B NO134289 B NO 134289B NO 287769 A NO287769 A NO 287769A NO 287769 A NO287769 A NO 287769A NO 134289 B NO134289 B NO 134289B
- Authority
- NO
- Norway
- Prior art keywords
- flotation
- niobium
- pyrochlore
- concentrate
- mica
- Prior art date
Links
- 238000005188 flotation Methods 0.000 claims description 91
- 239000012141 concentrate Substances 0.000 claims description 54
- 239000010955 niobium Substances 0.000 claims description 48
- 229910052758 niobium Inorganic materials 0.000 claims description 41
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 37
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 27
- 239000011707 mineral Substances 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 21
- 239000006260 foam Substances 0.000 claims description 12
- 150000002500 ions Chemical class 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 239000012190 activator Substances 0.000 claims description 8
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 5
- 239000004088 foaming agent Substances 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 4
- 239000007900 aqueous suspension Substances 0.000 claims description 4
- 125000002091 cationic group Chemical group 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 description 35
- 229910052618 mica group Inorganic materials 0.000 description 35
- 235000010755 mineral Nutrition 0.000 description 25
- 229910052586 apatite Inorganic materials 0.000 description 24
- 238000000746 purification Methods 0.000 description 20
- 239000007858 starting material Substances 0.000 description 20
- 230000001143 conditioned effect Effects 0.000 description 19
- 239000000463 material Substances 0.000 description 19
- 229910001729 niobium mineral Inorganic materials 0.000 description 19
- 239000007787 solid Substances 0.000 description 19
- 230000003750 conditioning effect Effects 0.000 description 18
- 239000003153 chemical reaction reagent Substances 0.000 description 16
- 238000011282 treatment Methods 0.000 description 15
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 12
- 238000000926 separation method Methods 0.000 description 12
- 229920002472 Starch Polymers 0.000 description 11
- 238000007792 addition Methods 0.000 description 11
- 235000019698 starch Nutrition 0.000 description 11
- 239000008107 starch Substances 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 10
- 229940032147 starch Drugs 0.000 description 10
- 238000007885 magnetic separation Methods 0.000 description 9
- 229910021532 Calcite Inorganic materials 0.000 description 8
- 239000003513 alkali Substances 0.000 description 8
- 238000000605 extraction Methods 0.000 description 8
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 8
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 7
- 229910052683 pyrite Inorganic materials 0.000 description 7
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 7
- 239000011028 pyrite Substances 0.000 description 7
- 238000011084 recovery Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 6
- 150000004760 silicates Chemical class 0.000 description 6
- WGTDLPBPQKAPMN-MDZDMXLPSA-N 2-[2-[(e)-heptadec-8-enyl]-4,5-dihydroimidazol-1-yl]ethanol Chemical compound CCCCCCCC\C=C\CCCCCCCC1=NCCN1CCO WGTDLPBPQKAPMN-MDZDMXLPSA-N 0.000 description 5
- 229920002907 Guar gum Polymers 0.000 description 5
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000000665 guar gum Substances 0.000 description 5
- 235000010417 guar gum Nutrition 0.000 description 5
- 229960002154 guar gum Drugs 0.000 description 5
- 235000021317 phosphate Nutrition 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910052976 metal sulfide Inorganic materials 0.000 description 4
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 239000003518 caustics Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229940104869 fluorosilicate Drugs 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- -1 oil Chemical class 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910000592 Ferroniobium Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000002385 cottonseed oil Substances 0.000 description 2
- 235000012343 cottonseed oil Nutrition 0.000 description 2
- 238000010908 decantation Methods 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 229910052637 diopside Inorganic materials 0.000 description 2
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- ZFGFKQDDQUAJQP-UHFFFAOYSA-N iron niobium Chemical compound [Fe].[Fe].[Nb] ZFGFKQDDQUAJQP-UHFFFAOYSA-N 0.000 description 2
- 239000006148 magnetic separator Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 229910052611 pyroxene Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000012991 xanthate Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241001251094 Formica Species 0.000 description 1
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical class NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- DYMNZCGFRHLNMT-UHFFFAOYSA-N Glyodin Chemical compound CC(O)=O.CCCCCCCCCCCCCCCCCC1=NCCN1 DYMNZCGFRHLNMT-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 240000008299 Pinus lambertiana Species 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- GPZPVAIBXPRLFD-UHFFFAOYSA-N acetic acid;azane Chemical compound N.N.CC(O)=O GPZPVAIBXPRLFD-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052626 biotite Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 230000004992 fission Effects 0.000 description 1
- 210000002683 foot Anatomy 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910001608 iron mineral Inorganic materials 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 210000001699 lower leg Anatomy 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000006249 magnetic particle Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 125000005608 naphthenic acid group Chemical group 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000002821 niobium Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229910052592 oxide mineral Inorganic materials 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- QWENMOXLTHDKDL-UHFFFAOYSA-N pentoxymethanedithioic acid Chemical compound CCCCCOC(S)=S QWENMOXLTHDKDL-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011403 purification operation Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Chemical class 0.000 description 1
- 229920005989 resin Chemical class 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- 229940080313 sodium starch Drugs 0.000 description 1
- 241000894007 species Species 0.000 description 1
- WGPCGCOKHWGKJJ-UHFFFAOYSA-N sulfanylidenezinc Chemical compound [Zn]=S WGPCGCOKHWGKJJ-UHFFFAOYSA-N 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42B—PERMANENTLY ATTACHING TOGETHER SHEETS, QUIRES OR SIGNATURES OR PERMANENTLY ATTACHING OBJECTS THERETO
- B42B2/00—Permanently attaching together sheets, quires or signatures by stitching with filamentary material, e.g. textile threads
- B42B2/02—Machines for stitching with thread
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Folding Of Thin Sheet-Like Materials, Special Discharging Devices, And Others (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD13337968 | 1968-07-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO134289B true NO134289B (ru) | 1976-06-08 |
| NO134289C NO134289C (ru) | 1976-09-15 |
Family
ID=5480158
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO287769A NO134289C (ru) | 1968-07-11 | 1969-07-09 |
Country Status (4)
| Country | Link |
|---|---|
| CH (1) | CH504975A (ru) |
| DE (1) | DE1931337C3 (ru) |
| NO (1) | NO134289C (ru) |
| SU (1) | SU383631A1 (ru) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD95830A1 (ru) * | 1971-03-10 | 1973-02-20 | ||
| DE2823087C2 (de) * | 1978-05-26 | 1984-10-11 | Nefele Holzentrindungsmaschinen GmbH, 8081 Waltenhofen | Fahrbare Entrindungsmaschine für Baumstämme |
| DE2823046C3 (de) * | 1978-05-26 | 1987-01-22 | Ernst 7547 Wildbad Hauer | Fahrbare Entrindungsanlage für Stammholz |
| JP3470803B2 (ja) | 1999-03-19 | 2003-11-25 | ケーニツヒ ウント バウエル アクチエンゲゼルシヤフト | 少なくとも１つのペーパウェブを引き込む方法及び装置 |
-
1969
- 1969-06-20 DE DE19691931337 patent/DE1931337C3/de not_active Expired
- 1969-07-09 NO NO287769A patent/NO134289C/no unknown
- 1969-07-10 CH CH1057569A patent/CH504975A/de not_active IP Right Cessation
- 1969-07-11 SU SU1345601A patent/SU383631A1/ru active
Also Published As
| Publication number | Publication date |
|---|---|
| DE1931337A1 (de) | 1970-01-15 |
| DE1931337B2 (de) | 1973-07-19 |
| CH504975A (de) | 1971-03-31 |
| SU383631A1 (ru) | 1973-05-23 |
| NO134289C (ru) | 1976-09-15 |
| DE1931337C3 (de) | 1974-02-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110694788B (zh) | 一种高钙镁型低品位锂辉石矿的选矿方法 | |
| US4098687A (en) | Beneficiation of lithium ores by froth flotation | |
| CN107029870B (zh) | 一种尾矿综合回收铅、锌、锡、萤石的方法 | |
| CN105597926A (zh) | 一种含铷长石矿的选矿方法 | |
| CN111715399B (zh) | 一种高钙高镁细粒嵌布白钨矿的预处理方法 | |
| CN102151607A (zh) | 一种含复杂磁黄铁矿铜硫铁矿石磁浮联合分选的方法 | |
| CN103521344A (zh) | 低品位萤石重晶石共生矿分离提纯方法 | |
| RU2096498C1 (ru) | Способ извлечения металлов из комплексного минерального рудного сырья | |
| CN112354683A (zh) | 一种萤石精选尾矿中再回收萤石的方法 | |
| US2959281A (en) | Flotation of niobium-bearing minerals | |
| CN101392326B (zh) | 从全泥氰化浸金渣中回收黄金的方法 | |
| NO134289B (ru) | ||
| CN111437989A (zh) | 一种回收榴辉岩绿辉石产品中金红石的方法 | |
| US3078997A (en) | Flotation process for concentration of phenacite and bertrandite | |
| US2838369A (en) | Process for the concentration of ores containing gold and uranium | |
| US2168762A (en) | cacos | |
| US4584096A (en) | Process to beneficiate phosphate and sand products from debris and phosphate tailing ores | |
| CN106733204B (zh) | 高效浮选组合药剂及其用于萤石浮选中预脱碳酸钙的方法 | |
| CN112517223B (zh) | 一种低品质铜锌混合精矿的富集方法 | |
| US4040519A (en) | Froth flotation process for recovering sheelite | |
| US2811254A (en) | Method for the beneficiation of phosphate ores | |
| US2922522A (en) | Method of recovering mineral values from ore | |
| US3097162A (en) | Method for concentrating aluminum silicates and zircon from beach sand | |
| CN112619878A (zh) | 一种铁共生有色金属铜铅锌综合回收工艺 | |
| US4440636A (en) | Recovery in phosphate ore flotation process |