NO131786B - - Google Patents

Info

Publication number

NO131786B

NO131786B NO3528/73A NO352873A NO131786B NO 131786 B NO131786 B NO 131786B NO 3528/73 A NO3528/73 A NO 3528/73A NO 352873 A NO352873 A NO 352873A NO 131786 B NO131786 B NO 131786B

Authority

NO

Norway

Prior art keywords

oil

capsules

substance

monomer

colloidal

Prior art date

1973-09-10

Links

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• Global Dossier
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• 239000002775 capsule Substances 0.000 claims description 46
• 239000000178 monomer Substances 0.000 claims description 25
• 239000007788 liquid Substances 0.000 claims description 24
• 239000000126 substance Substances 0.000 claims description 17
• 239000003054 catalyst Substances 0.000 claims description 13
• 238000000034 method Methods 0.000 claims description 12
• 229920000642 polymer Polymers 0.000 claims description 11
• MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 10
• 238000004519 manufacturing process Methods 0.000 claims description 8
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 7
• 239000000839 emulsion Substances 0.000 claims description 6
• 239000006185 dispersion Substances 0.000 claims description 5
• 239000000975 dye Substances 0.000 claims description 5
• 239000004342 Benzoyl peroxide Substances 0.000 claims description 4
• OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical group C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 4
• 239000007864 aqueous solution Substances 0.000 claims description 4
• 235000019400 benzoyl peroxide Nutrition 0.000 claims description 4
• 239000002304 perfume Substances 0.000 claims description 4
• USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 4
• 239000003795 chemical substances by application Substances 0.000 claims description 2
• 230000000379 polymerizing effect Effects 0.000 claims 1
• 239000003921 oil Substances 0.000 description 61
• 235000019198 oils Nutrition 0.000 description 61
• 239000000463 material Substances 0.000 description 39
• 239000007787 solid Substances 0.000 description 20
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
• 229920000084 Gum arabic Polymers 0.000 description 12
• 239000000205 acacia gum Substances 0.000 description 12
• 244000215068 Acacia senegal Species 0.000 description 11
• 235000010489 acacia gum Nutrition 0.000 description 11
• 239000008384 inner phase Substances 0.000 description 11
• 238000006116 polymerization reaction Methods 0.000 description 11
• 239000000203 mixture Substances 0.000 description 9
• 239000000243 solution Substances 0.000 description 9
• 239000000084 colloidal system Substances 0.000 description 8
• 239000003350 kerosene Substances 0.000 description 7
• 238000005354 coacervation Methods 0.000 description 6
• 238000005538 encapsulation Methods 0.000 description 6
• 238000003756 stirring Methods 0.000 description 6
• LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 description 5
• XOMKZKJEJBZBJJ-UHFFFAOYSA-N 1,2-dichloro-3-phenylbenzene Chemical group ClC1=CC=CC(C=2C=CC=CC=2)=C1Cl XOMKZKJEJBZBJJ-UHFFFAOYSA-N 0.000 description 5
• 108010010803 Gelatin Proteins 0.000 description 5
• 238000004945 emulsification Methods 0.000 description 5
• 239000003995 emulsifying agent Substances 0.000 description 5
• 239000008273 gelatin Substances 0.000 description 5
• 229920000159 gelatin Polymers 0.000 description 5
• 235000019322 gelatine Nutrition 0.000 description 5
• 235000011852 gelatine desserts Nutrition 0.000 description 5
• 239000008385 outer phase Substances 0.000 description 5
• WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
• 239000006229 carbon black Substances 0.000 description 4
• 238000006243 chemical reaction Methods 0.000 description 4
• DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
• 239000012071 phase Substances 0.000 description 4
• 239000000049 pigment Substances 0.000 description 4
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
• PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
• 239000004159 Potassium persulphate Substances 0.000 description 3
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
• 235000012343 cottonseed oil Nutrition 0.000 description 3
• 239000002385 cottonseed oil Substances 0.000 description 3
• 239000000976 ink Substances 0.000 description 3
• 235000019394 potassium persulphate Nutrition 0.000 description 3
• -1 sodium alkyl sulfates Chemical class 0.000 description 3
• 230000007704 transition Effects 0.000 description 3
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
• MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
• BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
• ZKURGBYDCVNWKH-UHFFFAOYSA-N [3,7-bis(dimethylamino)phenothiazin-10-yl]-phenylmethanone Chemical compound C12=CC=C(N(C)C)C=C2SC2=CC(N(C)C)=CC=C2N1C(=O)C1=CC=CC=C1 ZKURGBYDCVNWKH-UHFFFAOYSA-N 0.000 description 2
• 239000011248 coating agent Substances 0.000 description 2
• 238000000576 coating method Methods 0.000 description 2
• 229920001577 copolymer Polymers 0.000 description 2
• ZQMIGQNCOMNODD-UHFFFAOYSA-N diacetyl peroxide Chemical compound CC(=O)OOC(C)=O ZQMIGQNCOMNODD-UHFFFAOYSA-N 0.000 description 2
• 238000001704 evaporation Methods 0.000 description 2
• 230000008020 evaporation Effects 0.000 description 2
• 238000001914 filtration Methods 0.000 description 2
• 239000000446 fuel Substances 0.000 description 2
• 239000000499 gel Substances 0.000 description 2
• 238000001879 gelation Methods 0.000 description 2
• 238000010438 heat treatment Methods 0.000 description 2
• OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 2
• 239000003208 petroleum Substances 0.000 description 2
• 230000001105 regulatory effect Effects 0.000 description 2
• 239000000725 suspension Substances 0.000 description 2
• SLPPJGVJIHMJLY-UHFFFAOYSA-N 3,3-bis(6-amino-1,4-dimethylcyclohexa-2,4-dien-1-yl)-6-(dimethylamino)-2-benzofuran-1-one Chemical compound C=1C(N(C)C)=CC=C2C=1C(=O)OC2(C1(C)C(C=C(C)C=C1)N)C1(C)C=CC(C)=CC1N SLPPJGVJIHMJLY-UHFFFAOYSA-N 0.000 description 1
• XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
• 239000004343 Calcium peroxide Substances 0.000 description 1
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical class C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
• JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
• 241001465754 Metazoa Species 0.000 description 1
• VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
• CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
• 235000019483 Peanut oil Nutrition 0.000 description 1
• OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
• IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 1
• FHNINJWBTRXEBC-UHFFFAOYSA-N Sudan III Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC(C=C1)=CC=C1N=NC1=CC=CC=C1 FHNINJWBTRXEBC-UHFFFAOYSA-N 0.000 description 1
• XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
• 239000000853 adhesive Substances 0.000 description 1
• 230000001070 adhesive effect Effects 0.000 description 1
• IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
• 239000011230 binding agent Substances 0.000 description 1
• 125000006267 biphenyl group Chemical group 0.000 description 1
• 239000001055 blue pigment Substances 0.000 description 1
• 210000000988 bone and bone Anatomy 0.000 description 1
• LHJQIRIGXXHNLA-UHFFFAOYSA-N calcium peroxide Chemical compound [Ca+2].[O-][O-] LHJQIRIGXXHNLA-UHFFFAOYSA-N 0.000 description 1
• 235000019402 calcium peroxide Nutrition 0.000 description 1
• 229910052799 carbon Inorganic materials 0.000 description 1
• 239000004359 castor oil Substances 0.000 description 1
• 235000019438 castor oil Nutrition 0.000 description 1
• 238000006555 catalytic reaction Methods 0.000 description 1
• 239000007824 chemical reaction participant Substances 0.000 description 1
• 239000003153 chemical reaction reagent Substances 0.000 description 1
• 238000001816 cooling Methods 0.000 description 1
• 235000005687 corn oil Nutrition 0.000 description 1
• 239000002285 corn oil Substances 0.000 description 1
• 239000013078 crystal Substances 0.000 description 1
• 230000006378 damage Effects 0.000 description 1
• 230000008021 deposition Effects 0.000 description 1
• LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
• 239000012969 di-tertiary-butyl peroxide Substances 0.000 description 1
• 238000004090 dissolution Methods 0.000 description 1
• 239000003814 drug Substances 0.000 description 1
• 229940079593 drug Drugs 0.000 description 1
• 230000000694 effects Effects 0.000 description 1
• SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
• 239000012530 fluid Substances 0.000 description 1
• 239000008098 formaldehyde solution Substances 0.000 description 1
• DDSRCCOGHFIQDX-UHFFFAOYSA-N furan-2,5-dione;methoxymethane Chemical compound COC.O=C1OC(=O)C=C1 DDSRCCOGHFIQDX-UHFFFAOYSA-N 0.000 description 1
• ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
• DLINORNFHVEIFE-UHFFFAOYSA-N hydrogen peroxide;zinc Chemical compound [Zn].OO DLINORNFHVEIFE-UHFFFAOYSA-N 0.000 description 1
• WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
• 238000002347 injection Methods 0.000 description 1
• 239000007924 injection Substances 0.000 description 1
• 229910052500 inorganic mineral Inorganic materials 0.000 description 1
• WNZQDUSMALZDQF-UHFFFAOYSA-N isobenzofuranone Natural products C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 description 1
• 239000010699 lard oil Substances 0.000 description 1
• 239000010687 lubricating oil Substances 0.000 description 1
• 229940107698 malachite green Drugs 0.000 description 1
• 239000011976 maleic acid Substances 0.000 description 1
• 229960001047 methyl salicylate Drugs 0.000 description 1
• 239000011707 mineral Substances 0.000 description 1
• 239000010466 nut oil Substances 0.000 description 1
• 239000004006 olive oil Substances 0.000 description 1
• 235000008390 olive oil Nutrition 0.000 description 1
• 239000002245 particle Substances 0.000 description 1
• 239000000312 peanut oil Substances 0.000 description 1
• PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
• 239000002798 polar solvent Substances 0.000 description 1
• 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
• 239000002861 polymer material Substances 0.000 description 1
• 238000003825 pressing Methods 0.000 description 1
• 108090000623 proteins and genes Proteins 0.000 description 1
• 229920005989 resin Polymers 0.000 description 1
• 239000011347 resin Substances 0.000 description 1
• 239000000779 smoke Substances 0.000 description 1
• 239000011734 sodium Substances 0.000 description 1
• 229910052708 sodium Inorganic materials 0.000 description 1
• 229940083542 sodium Drugs 0.000 description 1
• 229940045845 sodium myristate Drugs 0.000 description 1
• JUQGWKYSEXPRGL-UHFFFAOYSA-M sodium;tetradecanoate Chemical compound [Na+].CCCCCCCCCCCCCC([O-])=O JUQGWKYSEXPRGL-UHFFFAOYSA-M 0.000 description 1
• 239000011343 solid material Substances 0.000 description 1
• 239000002195 soluble material Substances 0.000 description 1
• 239000002904 solvent Substances 0.000 description 1
• 229940035044 sorbitan monolaurate Drugs 0.000 description 1
• 239000001570 sorbitan monopalmitate Substances 0.000 description 1
• 235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
• 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
• 238000005507 spraying Methods 0.000 description 1
• 229940099373 sudan iii Drugs 0.000 description 1
• 239000003760 tallow Substances 0.000 description 1
• WODGXFMUOLGZSY-UHFFFAOYSA-J tetrasodium phosphonatooxy phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OOP([O-])([O-])=O WODGXFMUOLGZSY-UHFFFAOYSA-J 0.000 description 1
• VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
• 235000013799 ultramarine blue Nutrition 0.000 description 1
• 235000013311 vegetables Nutrition 0.000 description 1
• 229940105296 zinc peroxide Drugs 0.000 description 1