NO127917B - - Google Patents
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- Publication number
- NO127917B NO127917B NO02810/68A NO281068A NO127917B NO 127917 B NO127917 B NO 127917B NO 02810/68 A NO02810/68 A NO 02810/68A NO 281068 A NO281068 A NO 281068A NO 127917 B NO127917 B NO 127917B
- Authority
- NO
- Norway
- Prior art keywords
- allyl alcohol
- column
- peracetic acid
- solvent
- zone
- Prior art date
Links
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims description 158
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims description 138
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 93
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims description 38
- 238000004821 distillation Methods 0.000 claims description 35
- 239000002904 solvent Substances 0.000 claims description 34
- 238000006243 chemical reaction Methods 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 29
- 238000009835 boiling Methods 0.000 claims description 21
- 239000000376 reactant Substances 0.000 claims description 17
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 12
- 238000006735 epoxidation reaction Methods 0.000 claims description 12
- 239000007795 chemical reaction product Substances 0.000 claims description 7
- 239000003960 organic solvent Substances 0.000 claims description 6
- 239000006227 byproduct Substances 0.000 claims description 5
- 239000007810 chemical reaction solvent Substances 0.000 claims description 2
- 238000010924 continuous production Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- WSGCRAOTEDLMFQ-UHFFFAOYSA-N nonan-5-one Chemical compound CCCCC(=O)CCCC WSGCRAOTEDLMFQ-UHFFFAOYSA-N 0.000 claims 1
- 239000000243 solution Substances 0.000 description 22
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- 238000010992 reflux Methods 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 230000001105 regulatory effect Effects 0.000 description 5
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 4
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 4
- 238000001944 continuous distillation Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 150000004967 organic peroxy acids Chemical class 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- GWHJZXXIDMPWGX-UHFFFAOYSA-N 1,2,4-trimethylbenzene Chemical compound CC1=CC=C(C)C(C)=C1 GWHJZXXIDMPWGX-UHFFFAOYSA-N 0.000 description 2
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- XUPYJHCZDLZNFP-UHFFFAOYSA-N butyl butanoate Chemical compound CCCCOC(=O)CCC XUPYJHCZDLZNFP-UHFFFAOYSA-N 0.000 description 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 239000012442 inert solvent Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VKCYHJWLYTUGCC-UHFFFAOYSA-N nonan-2-one Chemical compound CCCCCCCC(C)=O VKCYHJWLYTUGCC-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- -1 8.15% Chemical compound 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- KZPGKZWAVAXZQU-UHFFFAOYSA-N acetic acid;ethaneperoxoic acid Chemical compound CC(O)=O.CC(=O)OO KZPGKZWAVAXZQU-UHFFFAOYSA-N 0.000 description 1
- 229940072049 amyl acetate Drugs 0.000 description 1
- PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 1
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 235000021438 curry Nutrition 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/14—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US65384767A | 1967-07-17 | 1967-07-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO127917B true NO127917B (nl) | 1973-09-03 |
Family
ID=24622519
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO02810/68A NO127917B (nl) | 1967-07-17 | 1968-07-16 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US3509183A (nl) |
| JP (1) | JPS4842622B1 (nl) |
| AT (1) | AT281781B (nl) |
| BE (1) | BE717896A (nl) |
| CH (1) | CH505814A (nl) |
| DE (1) | DE1768953C3 (nl) |
| ES (1) | ES356216A1 (nl) |
| FR (1) | FR1576674A (nl) |
| GB (1) | GB1180367A (nl) |
| NL (1) | NL6810128A (nl) |
| NO (1) | NO127917B (nl) |
| SE (1) | SE350039B (nl) |
| SU (1) | SU368746A3 (nl) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3655524A (en) * | 1970-04-27 | 1972-04-11 | Fmc Corp | Glycidol isolation by azeotropic distillation with a lower-boiling entrainer |
| JPS5752341B2 (nl) * | 1972-12-27 | 1982-11-06 | ||
| IT1027410B (it) * | 1974-02-25 | 1978-11-20 | Degussa | Procedimento continuc per la produzione di glicide |
| JPS51100122U (nl) * | 1975-02-08 | 1976-08-11 | ||
| JPH0167073U (nl) * | 1987-10-22 | 1989-04-28 | ||
| US4935101A (en) * | 1989-10-13 | 1990-06-19 | Arco Chemical Technology, Inc. | Process for the recovery of a water-insoluble epoxy alcohol |
| JP3027133U (ja) * | 1996-01-23 | 1996-07-30 | 株式会社ジ−・シ− | ノ−ト |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL294814A (nl) * | 1962-07-02 | |||
| GB1053972A (nl) * | 1962-08-30 | 1967-01-04 | ||
| US3238229A (en) * | 1962-09-24 | 1966-03-01 | Monsanto Co | Process for the liquid phase direct oxidation of olefins to olefin oxides |
| NL131724C (nl) * | 1962-11-20 | |||
| NL302305A (nl) * | 1962-12-20 | 1900-01-01 | British Celanese | |
| FR1430891A (fr) * | 1964-06-30 | 1966-03-11 | Inst Francais Du Petrole | Procédé de fabrication d'acides monocarboxyliques alpha-éthyléniques |
| US3404163A (en) * | 1965-07-02 | 1968-10-01 | Ashalnd Oil & Refining Company | Epoxidation process |
-
1967
- 1967-07-17 US US653847A patent/US3509183A/en not_active Expired - Lifetime
-
1968
- 1968-06-28 SE SE08991/68A patent/SE350039B/xx unknown
- 1968-07-10 AT AT664868A patent/AT281781B/de not_active IP Right Cessation
- 1968-07-10 BE BE717896D patent/BE717896A/xx unknown
- 1968-07-11 FR FR1576674D patent/FR1576674A/fr not_active Expired
- 1968-07-11 CH CH1035768A patent/CH505814A/de not_active IP Right Cessation
- 1968-07-12 JP JP43048567A patent/JPS4842622B1/ja active Pending
- 1968-07-16 GB GB33737/68A patent/GB1180367A/en not_active Expired
- 1968-07-16 SU SU1258361A patent/SU368746A3/ru active
- 1968-07-16 NO NO02810/68A patent/NO127917B/no unknown
- 1968-07-17 DE DE1768953A patent/DE1768953C3/de not_active Expired
- 1968-07-17 ES ES356216A patent/ES356216A1/es not_active Expired
- 1968-07-17 NL NL6810128A patent/NL6810128A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES356216A1 (es) | 1970-01-16 |
| AT281781B (de) | 1970-06-10 |
| US3509183A (en) | 1970-04-28 |
| DE1768953B2 (de) | 1974-04-18 |
| BE717896A (nl) | 1968-12-16 |
| SE350039B (nl) | 1972-10-16 |
| CH505814A (de) | 1971-04-15 |
| JPS4842622B1 (nl) | 1973-12-13 |
| GB1180367A (en) | 1970-02-04 |
| SU368746A3 (nl) | 1973-01-26 |
| FR1576674A (nl) | 1969-08-01 |
| DE1768953C3 (de) | 1974-11-14 |
| DE1768953A1 (de) | 1972-04-27 |
| NL6810128A (nl) | 1969-01-21 |
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