NO126957B - - Google Patents

Info

Publication number
NO126957B
NO126957B NO04108/71*[A NO410871A NO126957B NO 126957 B NO126957 B NO 126957B NO 410871 A NO410871 A NO 410871A NO 126957 B NO126957 B NO 126957B
Authority
NO
Norway
Prior art keywords
dust
pellets
sio
sintered
metallurgical
Prior art date
Application number
NO04108/71*[A
Other languages
Norwegian (no)
Inventor
Einar Onarheim
Original Assignee
Elkem As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Elkem As filed Critical Elkem As
Priority to NO04108/71*[A priority Critical patent/NO126957B/no
Priority to ZA727319A priority patent/ZA727319B/en
Priority to IT3080272A priority patent/IT969803B/en
Priority to AU48280/72A priority patent/AU475509B2/en
Priority to CA155,264A priority patent/CA965958A/en
Priority to DE2253590A priority patent/DE2253590A1/en
Priority to CH1607372A priority patent/CH588560A5/xx
Priority to ES408285A priority patent/ES408285A1/en
Priority to JP11082572A priority patent/JPS5337295B2/ja
Priority to BR783672A priority patent/BR7207836D0/en
Priority to CS755272A priority patent/CS192501B2/en
Priority to FR7239604A priority patent/FR2159391A1/en
Publication of NO126957B publication Critical patent/NO126957B/no
Priority to US49640474 priority patent/US3925058A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/02Working-up flue dust
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2/00Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/113Silicon oxides; Hydrates thereof
    • C01B33/12Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/24Binding; Briquetting ; Granulating
    • C22B1/2406Binding; Briquetting ; Granulating pelletizing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Metallurgy (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Silicon Compounds (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Processing Of Solid Wastes (AREA)

Description

Fremgangsmåte ved metallurgiske Procedure by metallurgical

prosesser hvor SiC>2 inngår som char.gekomponent. processes where SiC>2 is included as charge component.

Det er kjent at røken fra metallurgiske ovner for fremstilling av Si-metall It is known that the smoke from metallurgical furnaces for the production of Si metal

og Si-rike legeringer fører med seg store mengder av finfordelt amorft støv, and Si-rich alloys carry with them large amounts of finely divided amorphous dust,

som hovedsaklig består av SiC^. Støvet som er meget voluminøst, kan ut- which mainly consists of SiC^. The dust, which is very voluminous, can

felles fra røkgassene på forskjellig vis, f. eks. i elektrofilter, posefilter, gassvasker eller annet rensesystem. Støvet er imidlertid et uønsket bi- separated from the flue gases in different ways, e.g. in an electrofilter, bag filter, gas washer or other cleaning system. However, the dust is an unwanted by-

produkt, som produsentene har store problemer med å disponere. product, which the producers have great difficulty in disposing of.

Den metallurgiske industri blir i stadig større grad pålagt å fjerne støv og skadelige-bestanddeler fra avgassene før de slippes ut i atmosfæren. Mengden av oppsamlet støv er derfor sterkt økendej og det har i den senere tid oppstått større problemer med å bli kvitt, respektive finne anvendelser for det utskilte Kfr. kl. 40a-l/14 The metallurgical industry is increasingly required to remove dust and harmful components from the exhaust gases before they are released into the atmosphere. The amount of collected dust is therefore increasing stronglyj and in recent times there have been greater problems with getting rid of, or finding uses for, the secreted Kfr. 40a-l/14

støv som hoper seg opp i stadig større mengder. dust that accumulates in ever greater quantities.

Søkeren har i lengre tid drevet forsøk og undersøkelser for å finne anvend-elsesområder for dette støv. En del av disse forsøk har falt meget heldig ut, men de mengder som kan avtas er langt mindre enn de mengder som produseres, så opphopningen av støv vil likevel fortsette. The applicant has for a long time carried out experiments and investigations to find areas of application for this dust. Some of these attempts have turned out to be very successful, but the quantities that can be removed are far less than the quantities that are produced, so the accumulation of dust will still continue.

Man har også gjort tallrike forsøk for å finne en metode til å resirkulere Numerous attempts have also been made to find a method to recycle

støvet, dvs. til å føre det tilbake til smelteovnen, respektive andre smelteovner som SiO^-kilde, slik at man både blir kvitt støvet og samtidig kan spare kvarts som ellers er den vanlige SiC^-kilden. the dust, i.e. to return it to the melting furnace, respectively other melting furnaces as a SiO^ source, so that you both get rid of the dust and at the same time save quartz, which is otherwise the usual SiC^ source.

Søkeren har nu funnet at støvet kan pelletiseres med bare tilsats av vann, hvorpå de rå pellets overføres direkte til en sjaktovn hvor de sintres ved temperaturer på 600 - 1200°C uten forutgående tørking. The applicant has now found that the dust can be pelletised with only the addition of water, after which the raw pellets are transferred directly to a shaft furnace where they are sintered at temperatures of 600 - 1200°C without prior drying.

Støvet er meget finfordelt med en spesifikk overflate på opptil over 400.000 cm<2 >pr. cm <3>. Dette medfører at det må tilsettes adskillig vann under pelleti-seringen slik at de dannede pellets inneholder 20 - 25% vann eller endog mer. Det er meget vanskelig å tørke slike sterkt vannholdige pellets og vanlig erfaring er at pelletene vil eksplodere og falle fra hverandre allerede på toppen av sjaktovnen hvis de tilføres denne uten forutgående tørking. Det var derfor meget overraskende og uventet at man kunne brenne slike pellets direkte i sjaktovn uten fortørking. The dust is very finely divided with a specific surface of up to over 400,000 cm<2 >per cm <3>. This means that a lot of water must be added during pelletisation so that the formed pellets contain 20 - 25% water or even more. It is very difficult to dry such highly water-containing pellets and common experience is that the pellets will explode and fall apart already at the top of the shaft furnace if they are fed to it without prior drying. It was therefore very surprising and unexpected that such pellets could be burned directly in a shaft furnace without pre-drying.

De sintrede pellets er mekanisk meget faste med en trykkstyrke på 50-150 kg, hvilket er tilstrekkelig for anvendelse i smelteovner. Støvdannelsen (■♦• 1 mm) etter 5000 omdreininger i spesialtrommel med innvendig ribber varierte fra 2 - 40%, hvilket også er innenfor den kritiske grense. The sintered pellets are mechanically very firm with a compressive strength of 50-150 kg, which is sufficient for use in melting furnaces. The dust formation (■♦• 1 mm) after 5000 revolutions in a special drum with internal ribs varied from 2 - 40%, which is also within the critical limit.

Støv fra posefilter ble pelletisert under tilsats av 25% vann. Pelletene ble sintret i sjakt uten fortørking og prøver uttatt ved forskjellige temperaturer for måling av trykkstyrke og støvdannelse (%> + 1 mm etter 5000 omdreininger i spesialtrommel). Dust from bag filters was pelletized with the addition of 25% water. The pellets were sintered in a shaft without pre-drying and samples taken at different temperatures for measuring compressive strength and dust formation (%> + 1 mm after 5000 revolutions in a special drum).

Claims (1)

Fremgangsmåte ved metallurgiske prosesser hvor SiO-, inngår som charge-komponent,karakterisert ved at det finfordelte SiO^-holdige støv som på i og for seg kjent vis kan utfelles fra avgasser fra smelteovner som produserer Si-metall eller Si-rike legeringer, pelletiseres under tilsats av vann, hvorpå de rå pellets uten fortørking tilføres en sjaktovn hvor de sintres ved temperaturer på 600 - 1200°C, hvoretter de sintrede pellets anvendes som SiO.,-kilde i metallurgiske smelteprosesser.Procedure for metallurgical processes where SiO-, is included as a charge component, characterized in that the finely divided SiO^-containing dust, which can be precipitated in a known manner from exhaust gases from smelting furnaces that produce Si metal or Si-rich alloys, is pelletized with the addition of water, after which the raw pellets without pre-drying are fed to a shaft furnace where they are sintered at temperatures of 600 - 1200°C, after which the sintered pellets are used as a SiO., source in metallurgical smelting processes.
NO04108/71*[A 1971-11-08 1971-11-08 NO126957B (en)

Priority Applications (13)

Application Number Priority Date Filing Date Title
NO04108/71*[A NO126957B (en) 1971-11-08 1971-11-08
ZA727319A ZA727319B (en) 1971-11-08 1972-10-13 Method for preparing sintered sio2 pellets which can be used as a charge component in metallurgical processes
IT3080272A IT969803B (en) 1971-11-08 1972-10-23 METHOD FOR METALLUR GIC PROCEDURES THAT INCLUDE SIO2 AS A CHARGING COMPONENT
AU48280/72A AU475509B2 (en) 1971-11-08 1972-10-30 Treatment of sio containing dust from metallurgical smelting processes
CA155,264A CA965958A (en) 1971-11-08 1972-10-31 Method of recycling silicon dioxide
DE2253590A DE2253590A1 (en) 1971-11-08 1972-11-02 METHOD OF MANUFACTURING PELLETS FROM SILICON DIOXIDE DUST
CH1607372A CH588560A5 (en) 1971-11-08 1972-11-03
ES408285A ES408285A1 (en) 1971-11-08 1972-11-04 Method for metalurgical procedures that include sio as a loading component. (Machine-translation by Google Translate, not legally binding)
JP11082572A JPS5337295B2 (en) 1971-11-08 1972-11-07
BR783672A BR7207836D0 (en) 1971-11-08 1972-11-08 PROCESS FOR RECOVERY OF RESIDUAL GAS SILICA
CS755272A CS192501B2 (en) 1971-11-08 1972-11-08 Method of producing metals with charge containing silicon dioxide
FR7239604A FR2159391A1 (en) 1971-11-08 1972-11-08 Silicon dioxide dust - pelletisation and re-use of dust from silicon and silicon alloy manufacture
US49640474 US3925058A (en) 1971-11-08 1974-08-12 Method of recycling silicon dioxide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NO04108/71*[A NO126957B (en) 1971-11-08 1971-11-08

Publications (1)

Publication Number Publication Date
NO126957B true NO126957B (en) 1973-04-16

Family

ID=19880078

Family Applications (1)

Application Number Title Priority Date Filing Date
NO04108/71*[A NO126957B (en) 1971-11-08 1971-11-08

Country Status (12)

Country Link
JP (1) JPS5337295B2 (en)
AU (1) AU475509B2 (en)
BR (1) BR7207836D0 (en)
CA (1) CA965958A (en)
CH (1) CH588560A5 (en)
CS (1) CS192501B2 (en)
DE (1) DE2253590A1 (en)
ES (1) ES408285A1 (en)
FR (1) FR2159391A1 (en)
IT (1) IT969803B (en)
NO (1) NO126957B (en)
ZA (1) ZA727319B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2519810C2 (en) * 1975-05-03 1983-01-13 Fried. Krupp Gmbh, 4300 Essen Process for processing powdery material from metallurgical exhaust gases
JPH0131221Y2 (en) * 1981-05-08 1989-09-25
JPS5864332U (en) * 1981-10-26 1983-04-30 合資会社伸高工業 Pine surge device for bathtub

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3039165A (en) * 1954-04-28 1962-06-19 Solite Corp Method and apparatus for production of lightweight aggregate from dust

Also Published As

Publication number Publication date
BR7207836D0 (en) 1974-09-05
DE2253590A1 (en) 1973-05-17
FR2159391B1 (en) 1975-06-13
AU4828072A (en) 1974-05-16
AU475509B2 (en) 1976-08-26
CH588560A5 (en) 1977-06-15
CA965958A (en) 1975-04-15
ZA727319B (en) 1974-05-29
CS192501B2 (en) 1979-08-31
JPS5337295B2 (en) 1978-10-07
ES408285A1 (en) 1975-11-16
JPS4857821A (en) 1973-08-14
FR2159391A1 (en) 1973-06-22
IT969803B (en) 1974-04-10

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