NO122197B - - Google Patents
Download PDFInfo
- Publication number
- NO122197B NO122197B NO2675/68A NO267568A NO122197B NO 122197 B NO122197 B NO 122197B NO 2675/68 A NO2675/68 A NO 2675/68A NO 267568 A NO267568 A NO 267568A NO 122197 B NO122197 B NO 122197B
- Authority
- NO
- Norway
- Prior art keywords
- catalyst
- nickel
- hydrogen
- sulfur
- fraction
- Prior art date
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 101
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 57
- 229910052739 hydrogen Inorganic materials 0.000 claims description 55
- 239000001257 hydrogen Substances 0.000 claims description 55
- 239000003054 catalyst Substances 0.000 claims description 52
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 51
- 238000005984 hydrogenation reaction Methods 0.000 claims description 47
- 229910052717 sulfur Inorganic materials 0.000 claims description 47
- 239000011593 sulfur Substances 0.000 claims description 47
- 229910052759 nickel Inorganic materials 0.000 claims description 43
- 239000007858 starting material Substances 0.000 claims description 42
- 238000000034 method Methods 0.000 claims description 41
- 150000001491 aromatic compounds Chemical class 0.000 claims description 27
- 230000008569 process Effects 0.000 claims description 19
- 229930195733 hydrocarbon Natural products 0.000 claims description 16
- 150000002430 hydrocarbons Chemical class 0.000 claims description 16
- 239000004215 Carbon black (E152) Substances 0.000 claims description 15
- 239000007791 liquid phase Substances 0.000 claims description 15
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 13
- 239000004113 Sepiolite Substances 0.000 claims description 10
- 229910052624 sepiolite Inorganic materials 0.000 claims description 10
- 235000019355 sepiolite Nutrition 0.000 claims description 10
- 239000005864 Sulphur Substances 0.000 claims description 9
- 239000012808 vapor phase Substances 0.000 claims description 8
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 6
- 238000006477 desulfuration reaction Methods 0.000 claims description 5
- 230000023556 desulfurization Effects 0.000 claims description 5
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 33
- 239000007789 gas Substances 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 15
- 239000000047 product Substances 0.000 description 13
- 230000000694 effects Effects 0.000 description 9
- 125000003118 aryl group Chemical group 0.000 description 8
- 238000001816 cooling Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 6
- 150000002431 hydrogen Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- 230000001105 regulatory effect Effects 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002826 coolant Substances 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- -1 benzene and toluene Chemical class 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- GODZNYBQGNSJJN-UHFFFAOYSA-N 1-aminoethane-1,2-diol Chemical compound NC(O)CO GODZNYBQGNSJJN-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003463 sulfur Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3177167 | 1967-07-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO122197B true NO122197B (enrdf_load_stackoverflow) | 1971-06-01 |
Family
ID=10328163
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO2675/68A NO122197B (enrdf_load_stackoverflow) | 1967-07-11 | 1968-07-04 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3714030A (enrdf_load_stackoverflow) |
| JP (1) | JPS4927170B1 (enrdf_load_stackoverflow) |
| AT (1) | AT286476B (enrdf_load_stackoverflow) |
| BE (1) | BE717937A (enrdf_load_stackoverflow) |
| FR (1) | FR1573584A (enrdf_load_stackoverflow) |
| GB (1) | GB1232393A (enrdf_load_stackoverflow) |
| NL (1) | NL6809780A (enrdf_load_stackoverflow) |
| NO (1) | NO122197B (enrdf_load_stackoverflow) |
| SE (1) | SE350981B (enrdf_load_stackoverflow) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3884797A (en) * | 1971-09-27 | 1975-05-20 | Union Oil Co | Hydrofining-reforming process |
| US4152250A (en) * | 1975-12-09 | 1979-05-01 | Chiyoda Chemical Engineering & Construction | Demetallation of hydrocarbons with catalysts supported on sepiolite |
| GB2031011B (en) * | 1978-10-05 | 1983-01-06 | Chiyoda Chem Eng Construct Co | Processing heavy hydrocarbon oils |
| JPS59120640A (ja) * | 1982-12-27 | 1984-07-12 | Takeda Chem Ind Ltd | 山皮複合体 |
| WO1996017039A1 (en) * | 1994-12-01 | 1996-06-06 | Mobil Oil Corporation | Integrated process for the production of reformate having reduced benzene content |
| JP3553258B2 (ja) * | 1995-02-14 | 2004-08-11 | 新日本石油株式会社 | 炭化水素油中の芳香族炭化水素の水素化方法及びそれに用いる触媒 |
| US6495029B1 (en) | 1997-08-22 | 2002-12-17 | Exxon Research And Engineering Company | Countercurrent desulfurization process for refractory organosulfur heterocycles |
| CA2243267C (en) | 1997-09-26 | 2003-12-30 | Exxon Research And Engineering Company | Countercurrent reactor with interstage stripping of nh3 and h2s in gas/liquid contacting zones |
| US6623621B1 (en) | 1998-12-07 | 2003-09-23 | Exxonmobil Research And Engineering Company | Control of flooding in a countercurrent flow reactor by use of temperature of liquid product stream |
| US6569314B1 (en) | 1998-12-07 | 2003-05-27 | Exxonmobil Research And Engineering Company | Countercurrent hydroprocessing with trickle bed processing of vapor product stream |
| US6497810B1 (en) | 1998-12-07 | 2002-12-24 | Larry L. Laccino | Countercurrent hydroprocessing with feedstream quench to control temperature |
| US6579443B1 (en) | 1998-12-07 | 2003-06-17 | Exxonmobil Research And Engineering Company | Countercurrent hydroprocessing with treatment of feedstream to remove particulates and foulant precursors |
| US6835301B1 (en) | 1998-12-08 | 2004-12-28 | Exxon Research And Engineering Company | Production of low sulfur/low aromatics distillates |
| US7374667B2 (en) * | 2001-03-12 | 2008-05-20 | Bp Corporation North America, Inc. | Process for the production of gasoline with a low sulfur content comprising a stage for transformation of sulfur-containing compounds, an acid-catalyst treatment and a desulfurization |
| US6884531B2 (en) * | 2001-05-21 | 2005-04-26 | Saudi Arabian Oil Company | Liquid hydrocarbon based fuels for fuel cell on-board reformers |
| US7081555B2 (en) * | 2002-08-07 | 2006-07-25 | Shell Oil Company | Process for hydrogenation of aromatics in hydrocarbon feedstocks containing thiopheneic compounds |
| ATE359119T1 (de) * | 2002-09-23 | 2007-05-15 | Shell Int Research | Katalysatorteilchen und ihre verwendung bei der entschwefelung |
| EP2013316A2 (en) * | 2006-04-21 | 2009-01-14 | Shell Internationale Research Maatschappij B.V. | A process for the hydrogenation of aromatics in a hydrocarbon feedstock that contains a thiopheneic compound |
| KR101111006B1 (ko) * | 2008-08-14 | 2012-02-15 | 에스케이에너지 주식회사 | 석유계 탄화수소 탈황 공정의 수소 회수 방법 및 장치 |
| EP2486109A4 (en) * | 2009-10-05 | 2013-03-27 | Exxonmobil Res & Eng Co | STACKING OF A REGENERATED CATALYST OR CATALYST OF LOW ACTIVITY VIA A CATALYST OF HIGHER ACTIVITY |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE571792A (enrdf_load_stackoverflow) * | ||||
| US3274275A (en) * | 1963-11-26 | 1966-09-20 | Phillips Petroleum Co | Method for production of cyclohexane |
| US3318965A (en) * | 1964-09-04 | 1967-05-09 | Phillips Petroleum Co | Hydrogenation of benzene to cyclohexane |
| US3254134A (en) * | 1965-04-05 | 1966-05-31 | Texaco Inc | Plural stage hydrogenation of aromatics |
| GB1098698A (en) * | 1965-10-04 | 1968-01-10 | British Petroleum Co | Improvements relating to the desulphurisation of petroleum fractions |
-
1967
- 1967-07-11 GB GB3177167A patent/GB1232393A/en not_active Expired
-
1968
- 1968-07-04 NO NO2675/68A patent/NO122197B/no unknown
- 1968-07-09 SE SE09428/68A patent/SE350981B/xx unknown
- 1968-07-10 FR FR1573584D patent/FR1573584A/fr not_active Expired
- 1968-07-10 NL NL6809780A patent/NL6809780A/xx unknown
- 1968-07-11 JP JP43048767A patent/JPS4927170B1/ja active Pending
- 1968-07-11 BE BE717937D patent/BE717937A/xx unknown
- 1968-07-11 AT AT669568A patent/AT286476B/de not_active IP Right Cessation
-
1970
- 1970-11-13 US US00089445A patent/US3714030A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| NL6809780A (enrdf_load_stackoverflow) | 1969-01-14 |
| BE717937A (enrdf_load_stackoverflow) | 1969-01-13 |
| JPS4927170B1 (enrdf_load_stackoverflow) | 1974-07-16 |
| SE350981B (enrdf_load_stackoverflow) | 1972-11-13 |
| GB1232393A (enrdf_load_stackoverflow) | 1971-05-19 |
| US3714030A (en) | 1973-01-30 |
| AT286476B (de) | 1970-12-10 |
| FR1573584A (enrdf_load_stackoverflow) | 1969-07-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| NO122197B (enrdf_load_stackoverflow) | ||
| RU2149172C1 (ru) | Способ обессеривания бензина | |
| JP6470760B2 (ja) | エチレンおよびｂｔｘの収率が改善された、原油を石油化学製品に転化するための方法および装置 | |
| CA2038824C (en) | Combination process for hydrogenation and isomerization of benzene- and paraffin-containing feedstocks | |
| KR102374848B1 (ko) | 열분해를 이용하여 혼합 탄화수소 급원으로부터 btx를 생산하는 방법 | |
| ES2716382T3 (es) | Proceso e instalación para la conversión de petróleo crudo en petroquímicos que tiene una eficacia mejorada del carbono | |
| NO121735B (enrdf_load_stackoverflow) | ||
| EA030559B1 (ru) | Способ получения ароматических соединений и легких олефинов из углеводородного сырья | |
| US2288336A (en) | Catalytic reforming of naphthas | |
| US20120074039A1 (en) | Upgrading light naphtas for increased olefins production | |
| US2799627A (en) | Process for obtaining concentrated aromatic hydrocarbons | |
| NO169816B (no) | Middel for oxyderende farving av haar | |
| EA030392B1 (ru) | Способ конверсии высококипящего углеводородного сырья в более легкокипящие углеводородные продукты | |
| AU2009272608B2 (en) | Process for the hydrogenation of benzene | |
| EA017890B1 (ru) | Способ снижения содержания серы в углеводородном потоке (варианты) | |
| US2770578A (en) | Saturating of a hydrocarbon fraction with hydrogen and then hydrodesulfurizing said fraction | |
| US10240097B2 (en) | Methods and apparatuses for an integrated isomerization and platforming process | |
| US3413216A (en) | Process for selectively desulfurizing mercaptans | |
| KR20240058165A (ko) | 원유를 올레핀으로 변환하기 위한 통합 공정 | |
| US2143078A (en) | Catalytic desulphurization of petroleum | |
| US3655621A (en) | Adding mercaptan sulfur to a selective hydrogenation process | |
| RU2224784C2 (ru) | Способ получения водорода и гидроочищенного продукта из углеводородного сырья | |
| US3484496A (en) | Desulphurisation and hydrogenation of aromatic hydrocarbons | |
| NO121270B (enrdf_load_stackoverflow) | ||
| US5770781A (en) | Method for eliminating carbon oxides in feeds to a C5 and C6 paraffin isomerization process |