NL7801430A - Mfr. of activated titanium tri:chloride used as catalyst - by treating violet titanium tri:chloride with titanium tetra:chloride and a di:alkyl ether - Google Patents

Mfr. of activated titanium tri:chloride used as catalyst - by treating violet titanium tri:chloride with titanium tetra:chloride and a di:alkyl ether

Info

Publication number
NL7801430A
NL7801430A NL7801430A NL7801430A NL7801430A NL 7801430 A NL7801430 A NL 7801430A NL 7801430 A NL7801430 A NL 7801430A NL 7801430 A NL7801430 A NL 7801430A NL 7801430 A NL7801430 A NL 7801430A
Authority
NL
Netherlands
Prior art keywords
ticl3
chloride
titanium
purple
improved
Prior art date
Application number
NL7801430A
Other languages
Dutch (nl)
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Priority to NL7801430A priority Critical patent/NL7801430A/en
Publication of NL7801430A publication Critical patent/NL7801430A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Activated TiCl3 is prepd. by reducing TiCl4 at 5 degrees C with a trialkylaluminium cpd. or a dialkylaluminiumhalide to give brown TiCl3. This is then converted into purple TiCl3 by heat treatment at >120 degrees C and the purple TiCl3 is then treated with added TiCl4 and a dialkyl ether with 2-8C alkyl gps. The process gives a TiCl3 having equal activity and sterospecificty to known purple TiCl3 made by known b brown-violet conversion, and which has improved morphology in that the particle size is smaller and can be varied over wider limits from the av. value. The catalysts are useful in olefin polymerisation, giving improved removal of liq. diluents (i.e. liquefiable monomers) in block polymerisation processes or liq. inert hydrocarbon diluents in other slurry polymerisation processes, and improved dispersion of amorphous copolymer phase in the crystalline homopolymer phase in the prodn. of propylene copolymers with improved brittleness at low temps.
NL7801430A 1978-02-08 1978-02-08 Mfr. of activated titanium tri:chloride used as catalyst - by treating violet titanium tri:chloride with titanium tetra:chloride and a di:alkyl ether NL7801430A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
NL7801430A NL7801430A (en) 1978-02-08 1978-02-08 Mfr. of activated titanium tri:chloride used as catalyst - by treating violet titanium tri:chloride with titanium tetra:chloride and a di:alkyl ether

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7801430A NL7801430A (en) 1978-02-08 1978-02-08 Mfr. of activated titanium tri:chloride used as catalyst - by treating violet titanium tri:chloride with titanium tetra:chloride and a di:alkyl ether

Publications (1)

Publication Number Publication Date
NL7801430A true NL7801430A (en) 1979-08-10

Family

ID=19830296

Family Applications (1)

Application Number Title Priority Date Filing Date
NL7801430A NL7801430A (en) 1978-02-08 1978-02-08 Mfr. of activated titanium tri:chloride used as catalyst - by treating violet titanium tri:chloride with titanium tetra:chloride and a di:alkyl ether

Country Status (1)

Country Link
NL (1) NL7801430A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0099026A2 (en) * 1982-07-13 1984-01-25 Mitsubishi Kasei Corporation Process for preparing solid titanium trichloride useful for the polymerization of an alpha-olefin

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0099026A2 (en) * 1982-07-13 1984-01-25 Mitsubishi Kasei Corporation Process for preparing solid titanium trichloride useful for the polymerization of an alpha-olefin
EP0099026A3 (en) * 1982-07-13 1984-09-12 Mitsubishi Chemical Industries Limited Process for preparing solid titanium trichloride useful for the polymerization of an alpha-olefin

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Legal Events

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