MXPA06003822A - Hoja ionomerica de capas multiples que tiene resistencia mejorada a las condiciones ambientales. - Google Patents
Hoja ionomerica de capas multiples que tiene resistencia mejorada a las condiciones ambientales.Info
- Publication number
- MXPA06003822A MXPA06003822A MXPA06003822A MXPA06003822A MXPA06003822A MX PA06003822 A MXPA06003822 A MX PA06003822A MX PA06003822 A MXPA06003822 A MX PA06003822A MX PA06003822 A MXPA06003822 A MX PA06003822A MX PA06003822 A MXPA06003822 A MX PA06003822A
- Authority
- MX
- Mexico
- Prior art keywords
- layer
- ethylene
- acid
- clear
- copolymer
- Prior art date
Links
- 229920000554 ionomer Polymers 0.000 title claims description 26
- 239000010410 layer Substances 0.000 claims abstract description 145
- 229920000098 polyolefin Polymers 0.000 claims abstract description 13
- 239000013047 polymeric layer Substances 0.000 claims abstract description 12
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 10
- 239000002253 acid Substances 0.000 claims description 41
- 229920001577 copolymer Polymers 0.000 claims description 36
- 229920005989 resin Polymers 0.000 claims description 33
- 239000011347 resin Substances 0.000 claims description 33
- 239000005977 Ethylene Substances 0.000 claims description 32
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 31
- 239000000049 pigment Substances 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 22
- 150000001412 amines Chemical class 0.000 claims description 10
- 239000004611 light stabiliser Substances 0.000 claims description 10
- 229920001866 very low density polyethylene Polymers 0.000 claims description 10
- 239000004708 Very-low-density polyethylene Substances 0.000 claims description 9
- 239000003086 colorant Substances 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 229920001038 ethylene copolymer Polymers 0.000 claims description 7
- 229920001897 terpolymer Polymers 0.000 claims description 7
- 229910021645 metal ion Inorganic materials 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 239000006096 absorbing agent Substances 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 5
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims 1
- 239000012790 adhesive layer Substances 0.000 abstract description 14
- 239000004416 thermosoftening plastic Substances 0.000 abstract description 9
- 239000000463 material Substances 0.000 description 33
- -1 polyethylene Polymers 0.000 description 29
- 230000007613 environmental effect Effects 0.000 description 27
- 229920000642 polymer Polymers 0.000 description 24
- 239000002344 surface layer Substances 0.000 description 18
- 239000000654 additive Substances 0.000 description 15
- 238000000034 method Methods 0.000 description 15
- 239000004743 Polypropylene Substances 0.000 description 14
- 229920001155 polypropylene Polymers 0.000 description 14
- 229920003946 DuPont™ Surlyn® 1706 Polymers 0.000 description 13
- 239000002932 luster Substances 0.000 description 13
- 230000008569 process Effects 0.000 description 10
- 230000015556 catabolic process Effects 0.000 description 9
- 238000006731 degradation reaction Methods 0.000 description 9
- 125000000217 alkyl group Chemical group 0.000 description 8
- 238000010276 construction Methods 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 238000006386 neutralization reaction Methods 0.000 description 8
- 230000002787 reinforcement Effects 0.000 description 8
- 239000004952 Polyamide Substances 0.000 description 7
- 230000006866 deterioration Effects 0.000 description 7
- 238000001125 extrusion Methods 0.000 description 7
- 229920002647 polyamide Polymers 0.000 description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 230000003014 reinforcing effect Effects 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 150000001768 cations Chemical class 0.000 description 5
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 238000007747 plating Methods 0.000 description 5
- 239000005020 polyethylene terephthalate Substances 0.000 description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 229920000058 polyacrylate Polymers 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 229910052724 xenon Inorganic materials 0.000 description 4
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical class C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920005606 polypropylene copolymer Polymers 0.000 description 3
- 229920005630 polypropylene random copolymer Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- 229940116351 sebacate Drugs 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 238000003856 thermoforming Methods 0.000 description 3
- 229920002397 thermoplastic olefin Polymers 0.000 description 3
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 239000002648 laminated material Substances 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- 210000000056 organ Anatomy 0.000 description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000006748 scratching Methods 0.000 description 2
- 230000002393 scratching effect Effects 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000012748 slip agent Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 150000003918 triazines Chemical class 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- FANGQVKSFHFPBY-UHFFFAOYSA-N 2-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical class OC(=O)C(C)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 FANGQVKSFHFPBY-UHFFFAOYSA-N 0.000 description 1
- OLFNXLXEGXRUOI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-phenylpropan-2-yl)phenol Chemical compound C=1C(N2N=C3C=CC=CC3=N2)=C(O)C(C(C)(C)C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=CC=C1 OLFNXLXEGXRUOI-UHFFFAOYSA-N 0.000 description 1
- IYAZLDLPUNDVAG-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 IYAZLDLPUNDVAG-UHFFFAOYSA-N 0.000 description 1
- CCMLIFHRMDXEBM-UHFFFAOYSA-N 2-phenyl-1,3-thiazol-4-ol Chemical class OC1=CSC(C=2C=CC=CC=2)=N1 CCMLIFHRMDXEBM-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 206010059837 Adhesion Diseases 0.000 description 1
- 229920012753 Ethylene Ionomers Polymers 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- DFLXWAISOFFYEE-UHFFFAOYSA-N OC1(O)C=CC=CC1C(=O)C1=NN(C=2C=CC=CC=2)N=C1 Chemical class OC1(O)C=CC=CC1C(=O)C1=NN(C=2C=CC=CC=2)N=C1 DFLXWAISOFFYEE-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- 241000872198 Serjania polyphylla Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000013036 UV Light Stabilizer Substances 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- VPWFPZBFBFHIIL-UHFFFAOYSA-L disodium 4-[(4-methyl-2-sulfophenyl)diazenyl]-3-oxidonaphthalene-2-carboxylate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 VPWFPZBFBFHIIL-UHFFFAOYSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- HPRNUNPPTKMTAU-UHFFFAOYSA-N ethene octane Chemical group C=C.CCCCCCCC HPRNUNPPTKMTAU-UHFFFAOYSA-N 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 210000003195 fascia Anatomy 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- FDAKZQLBIFPGSV-UHFFFAOYSA-N n-butyl-2,2,6,6-tetramethylpiperidin-4-amine Chemical compound CCCCNC1CC(C)(C)NC(C)(C)C1 FDAKZQLBIFPGSV-UHFFFAOYSA-N 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000021715 photosynthesis, light harvesting Effects 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- XOFYZVNMUHMLCC-ZPOLXVRWSA-N prednisone Chemical compound O=C1C=C[C@]2(C)[C@H]3C(=O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 XOFYZVNMUHMLCC-ZPOLXVRWSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- LYDRKKWPKKEMNZ-UHFFFAOYSA-N tert-butyl benzoate Chemical compound CC(C)(C)OC(=O)C1=CC=CC=C1 LYDRKKWPKKEMNZ-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 229940124543 ultraviolet light absorber Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
- B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/261—In terms of molecular thickness or light wave length
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31928—Ester, halide or nitrile of addition polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon
Landscapes
- Laminated Bodies (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US50918803P | 2003-10-07 | 2003-10-07 | |
PCT/US2004/033439 WO2005035244A1 (en) | 2003-10-07 | 2004-10-07 | Multi-layer ionomer sheet having improved weathering |
Publications (1)
Publication Number | Publication Date |
---|---|
MXPA06003822A true MXPA06003822A (es) | 2006-06-14 |
Family
ID=34434951
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MXPA06003822A MXPA06003822A (es) | 2003-10-07 | 2004-10-07 | Hoja ionomerica de capas multiples que tiene resistencia mejorada a las condiciones ambientales. |
Country Status (8)
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005105438A1 (en) | 2004-04-14 | 2005-11-10 | Mayco Plastics, Inc. | Article having a multilayer film outer skin including at least one layer containing a pigmented layer and method of making the same |
WO2005105439A1 (en) * | 2004-04-14 | 2005-11-10 | Mayco Plastics, Inc. | Article having multilayer film including at least one layer containing metallic components and method of making the same |
US20080108734A1 (en) * | 2006-11-03 | 2008-05-08 | Smith Dennis C | Ionomer pigmentation |
US20080302461A1 (en) * | 2007-06-08 | 2008-12-11 | E. I. Du Pont De Nemours And Company | Transparent Colored High Modulus Interlayers and Laminates Therefrom |
US20080318063A1 (en) * | 2007-06-22 | 2008-12-25 | Anderson Jerrel C | Glass laminates with improved weatherability |
US20090155576A1 (en) * | 2007-12-18 | 2009-06-18 | E. I. Du Pont De Nemours And Company | Glass-less glazing laminates |
EP2142369B1 (en) * | 2008-05-05 | 2012-06-20 | A. Schulman, Inc. | Multilayer clear over color polyolefin sheets |
US10434756B2 (en) | 2009-07-23 | 2019-10-08 | Francois Rummens | Photovoltaic modules with polypropylene based backsheet |
HK1258340A1 (zh) * | 2015-09-15 | 2019-11-08 | G3 Enterprises, Inc. | 適用於金屬的替代塗層的設備和方法 |
MX2021005897A (es) | 2018-11-20 | 2021-10-13 | G3 Entpr Inc | Aparatos y metodos que utilizan recubrimientos para aplicaciones metalicas. |
CN116003902B (zh) * | 2022-12-15 | 2024-07-12 | 金发科技股份有限公司 | 一种高性能彩色母粒及其制备的聚丙烯组合物 |
Family Cites Families (45)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1155558A (en) * | 1915-01-23 | 1915-10-05 | Lenpha A Folsom | Display-rack. |
US4351931A (en) * | 1961-06-26 | 1982-09-28 | E. I. Du Pont De Nemours And Company | Polyethylene copolymers |
BE621846A (enrdf_load_stackoverflow) * | 1961-08-31 | 1900-01-01 | ||
US3791915A (en) * | 1971-07-06 | 1974-02-12 | American Can Co | Multilayer laminated polyethylene copolymer-polyamide film |
US4335175A (en) * | 1980-10-01 | 1982-06-15 | W. R. Grace & Co. | Thermoplastic film laminates |
US5324800A (en) * | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
US4868030A (en) * | 1986-07-02 | 1989-09-19 | General Motors Corporation | Article covered with painted carrier films |
US5342666A (en) * | 1986-10-28 | 1994-08-30 | Rexham Industries Corp. | Injection molded plastic article with integral weatherable pigmented film surface |
US4943680A (en) * | 1986-10-28 | 1990-07-24 | Rexham Corporation | Method of making a decorative sheet material simulating the appearance of a base coat/clear coat paint finish |
US4810540A (en) * | 1986-10-28 | 1989-03-07 | Rexham Corporation | Decorative sheet material simulating the appearance of a base coat/clear coat paint finish |
US4931324A (en) * | 1986-10-28 | 1990-06-05 | Rexham Corporation | Decorative sheet material simulating the appearance of a base coat/clear coat paint finish |
US5198401A (en) * | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
US5707697A (en) * | 1987-03-27 | 1998-01-13 | Avery Dennison Corporation | Dry paint transfer product having high DOI automotive paint coat |
US6835267B1 (en) * | 1987-03-27 | 2004-12-28 | Avery Dennison Corporation | Dry paint transfer process and product |
US4863784C1 (en) * | 1987-05-28 | 2001-05-01 | Bt Commercial Corp | Multilayer film containing very low density polyethylene |
US5114789A (en) * | 1987-11-03 | 1992-05-19 | Eastman Kodak Company | Protective and decorative sheet material having a transparent topcoat |
US4844955A (en) * | 1987-12-18 | 1989-07-04 | American Standard, Inc. | Multilayer polymeric composite and method for its manufacture |
US5037680A (en) * | 1989-07-10 | 1991-08-06 | Decoma International Inc. | Exterior automotive component with pigmented substrate and clear coating |
JP2599794B2 (ja) * | 1989-08-01 | 1997-04-16 | 三井・デュポンポリケミカル株式会社 | アイオノマー組成物 |
ATE118188T1 (de) * | 1990-04-04 | 1995-02-15 | American National Can Co | Kontrollierbare, leicht zu öffnende verpackung. |
US4999227A (en) * | 1990-05-07 | 1991-03-12 | Vander Togt Robbert T | Bumper and process to bond ionomers to plastic |
US5028674A (en) * | 1990-06-06 | 1991-07-02 | E. I. Du Pont De Nemours And Company | Methanol copolymerization of ethylene |
US5272236A (en) * | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
US5447772A (en) * | 1990-11-21 | 1995-09-05 | E. I. Du Pont De Nemours And Company | Reclosable packaging seal and methods relating thereto |
US5278272A (en) * | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
DE4205418C2 (de) * | 1992-02-22 | 1993-11-18 | Du Pont | Bei der Verarbeitung in der Schmelze verbrauchbare Packung |
US6019923A (en) * | 1992-08-25 | 2000-02-01 | Hp-Chemie Pelzer Research & Development Ltd. | Process for manufacturing decorable moulded parts |
US5468532A (en) * | 1992-12-10 | 1995-11-21 | Minnesota Mining And Manufacturing Company | Multilayer graphic article with color layer |
WO1994025495A1 (en) * | 1993-05-20 | 1994-11-10 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
WO1995004655A2 (en) * | 1993-08-06 | 1995-02-16 | Minnesota Mining And Manufacturing Company | Chlorine-free multilayered film medical device assemblies |
US5622780A (en) * | 1994-05-11 | 1997-04-22 | W. R. Grace & Co.-Conn. | Microwaveable multilayer films with metal-like appearance |
US5679422A (en) * | 1995-01-25 | 1997-10-21 | American National Can Company | Coextruded film for chub packages |
US5643999A (en) * | 1995-03-28 | 1997-07-01 | E. I. Du Pont De Nemours And Company | Co-extrudable adhesives with good age-down resistance |
US5985079A (en) * | 1996-03-28 | 1999-11-16 | Rexam Industries Corp. | Flexible composite surfacing film and method for producing same |
US5866658A (en) * | 1996-08-26 | 1999-02-02 | E. I. Du Pont De Nemours And Company | High performance ionomer blends |
US6060135A (en) * | 1996-10-07 | 2000-05-09 | E. I. Du Pont De Nemours And Company | Lustrous laminate film structures |
AU738131B2 (en) * | 1997-06-03 | 2001-09-06 | Minnesota Mining And Manufacturing Company | Multilayer electronic cutter film for image graphics |
US6010792A (en) * | 1998-03-31 | 2000-01-04 | American National Can Company | Poultry shrink bags |
BR9911836A (pt) * | 1998-06-12 | 2001-10-16 | Avery Dennison Corp | Película termoplástica de multicamadas, método para corte de sinal e película de delineamento eletrônico |
US6319438B1 (en) * | 1998-12-15 | 2001-11-20 | Guardian Automotive Trim, Inc. | Extruded automotive trim and method of making same |
JP4690517B2 (ja) * | 2000-03-22 | 2011-06-01 | 三井・デュポンポリケミカル株式会社 | エチレン共重合体組成物 |
PT1274571E (pt) * | 2000-04-14 | 2005-09-30 | Du Pont | Revestimento decorativo ionomerico, coextrudido, multicamada |
US6998084B2 (en) * | 2001-02-16 | 2006-02-14 | Daimlerchrysler Corporation | Co-extruded pigmented/clear coated polymeric coating for an article such as automotive exterior body panels |
EP1383651A4 (en) * | 2001-03-29 | 2009-02-25 | Exxonmobil Chem Patents Inc | IONOMERLAMINATES AND ARTICLES MANUFACTURED THEREOF |
WO2004106058A1 (en) * | 2003-05-27 | 2004-12-09 | Exxonmobil Chemical Patents Inc. | Tie-layer materials for use with ionomer-based films and sheets as skins on other materials |
-
2004
- 2004-10-07 MX MXPA06003822A patent/MXPA06003822A/es unknown
- 2004-10-07 CA CA 2541064 patent/CA2541064A1/en not_active Abandoned
- 2004-10-07 KR KR1020067006755A patent/KR20060135624A/ko not_active Ceased
- 2004-10-07 EP EP20040794712 patent/EP1687140A1/en not_active Withdrawn
- 2004-10-07 WO PCT/US2004/033439 patent/WO2005035244A1/en active Application Filing
- 2004-10-07 US US10/960,454 patent/US20050074623A1/en not_active Abandoned
- 2004-10-07 CN CNA2004800364017A patent/CN1890095A/zh active Pending
- 2004-10-07 JP JP2006534443A patent/JP2007507377A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
WO2005035244A1 (en) | 2005-04-21 |
KR20060135624A (ko) | 2006-12-29 |
US20050074623A1 (en) | 2005-04-07 |
CA2541064A1 (en) | 2005-04-21 |
CN1890095A (zh) | 2007-01-03 |
EP1687140A1 (en) | 2006-08-09 |
JP2007507377A (ja) | 2007-03-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US7488399B2 (en) | Multi-layer sheet having a weatherable surface layer | |
CA2404849C (en) | Multilayer, co-extruded, ionomeric decorative surfacing | |
JP4778902B2 (ja) | アイオノマー層を含む多層シート | |
JP2004525002A (ja) | イオノマーラミネート及びイオノマーラミネートからなる製品 | |
EP1093911A2 (en) | Impact resistant protective multilayer film | |
CA2102054C (en) | Polyamide/polyolefin alloy-based laminates and objects obtained therefrom | |
MXPA06003822A (es) | Hoja ionomerica de capas multiples que tiene resistencia mejorada a las condiciones ambientales. | |
EP1680277B1 (en) | Thermoformable multi-layer sheet | |
MXPA06003824A (en) | Thermoformable multi-layer sheet |