MXPA04006508A - Proceso de polimerizacion acuosa para preparar una dispersion acuosa de polimeros. - Google Patents
Proceso de polimerizacion acuosa para preparar una dispersion acuosa de polimeros.Info
- Publication number
- MXPA04006508A MXPA04006508A MXPA04006508A MXPA04006508A MXPA04006508A MX PA04006508 A MXPA04006508 A MX PA04006508A MX PA04006508 A MXPA04006508 A MX PA04006508A MX PA04006508 A MXPA04006508 A MX PA04006508A MX PA04006508 A MXPA04006508 A MX PA04006508A
- Authority
- MX
- Mexico
- Prior art keywords
- polymer
- polymer particles
- particles
- mode
- weight
- Prior art date
Links
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 110
- 239000004815 dispersion polymer Substances 0.000 title claims abstract description 41
- 229920000642 polymer Polymers 0.000 claims abstract description 371
- 239000002245 particle Substances 0.000 claims abstract description 291
- 239000000178 monomer Substances 0.000 claims abstract description 185
- 238000000034 method Methods 0.000 claims abstract description 59
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 57
- 239000000203 mixture Substances 0.000 claims abstract description 47
- 239000012736 aqueous medium Substances 0.000 claims abstract description 35
- 230000009477 glass transition Effects 0.000 claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 claims abstract description 10
- 239000006185 dispersion Substances 0.000 claims description 75
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 74
- 239000004094 surface-active agent Substances 0.000 claims description 42
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- 238000009826 distribution Methods 0.000 claims description 16
- 230000000379 polymerizing effect Effects 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 10
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- 238000009833 condensation Methods 0.000 claims description 5
- 230000005494 condensation Effects 0.000 claims description 5
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- 238000000576 coating method Methods 0.000 abstract description 29
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- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 37
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- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
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- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
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- 125000003172 aldehyde group Chemical group 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 125000003118 aryl group Chemical class 0.000 description 3
- ZGRWZUDBZZBJQB-UHFFFAOYSA-N benzenecarbodithioic acid Chemical compound SC(=S)C1=CC=CC=C1 ZGRWZUDBZZBJQB-UHFFFAOYSA-N 0.000 description 3
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 description 3
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- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 3
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- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
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- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
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- 230000003287 optical effect Effects 0.000 description 1
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- DBSDMAPJGHBWAL-UHFFFAOYSA-N penta-1,4-dien-3-ylbenzene Chemical compound C=CC(C=C)C1=CC=CC=C1 DBSDMAPJGHBWAL-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
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- 102000004196 processed proteins & peptides Human genes 0.000 description 1
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- AXLMPTNTPOWPLT-UHFFFAOYSA-N prop-2-enyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCC=C AXLMPTNTPOWPLT-UHFFFAOYSA-N 0.000 description 1
- OCAAZRFBJBEVPS-UHFFFAOYSA-N prop-2-enyl carbamate Chemical compound NC(=O)OCC=C OCAAZRFBJBEVPS-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- ARENMZZMCSLORU-UHFFFAOYSA-N propan-2-yl naphthalene-1-sulfonate Chemical class C1=CC=C2C(S(=O)(=O)OC(C)C)=CC=CC2=C1 ARENMZZMCSLORU-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
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- 239000006254 rheological additive Substances 0.000 description 1
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- 229910052710 silicon Inorganic materials 0.000 description 1
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- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
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- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
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- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
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- 229940116411 terpineol Drugs 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
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- 229940075466 undecylenate Drugs 0.000 description 1
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- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (1)
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| US48752303P | 2003-07-14 | 2003-07-14 |
Publications (1)
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| MXPA04006508A true MXPA04006508A (es) | 2005-03-31 |
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| Application Number | Title | Priority Date | Filing Date |
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| MXPA04006508A MXPA04006508A (es) | 2003-07-14 | 2004-07-01 | Proceso de polimerizacion acuosa para preparar una dispersion acuosa de polimeros. |
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|---|---|
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| EP (1) | EP1498430B1 (enExample) |
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| AU (1) | AU2004203020B2 (enExample) |
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| DE (1) | DE602004008839T2 (enExample) |
| MX (1) | MXPA04006508A (enExample) |
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| US7598303B2 (en) * | 2005-02-17 | 2009-10-06 | Rohm And Haas Company | Process for making an aqueous dispersion |
| AU2006201172B2 (en) * | 2005-04-04 | 2010-11-25 | Rohm And Haas Company | Aqueous polymer dispersions |
| DE102005033516A1 (de) * | 2005-07-14 | 2007-01-18 | Basf Ag | Verfahren zur Herstellung von Emulsionspolymerisaten |
| US8482035B2 (en) * | 2005-07-29 | 2013-07-09 | International Rectifier Corporation | Enhancement mode III-nitride transistors with single gate Dielectric structure |
| JP2007091782A (ja) * | 2005-09-27 | 2007-04-12 | Asahi Kasei Chemicals Corp | 架橋性水系コーティング組成物 |
| US7642314B2 (en) * | 2005-12-30 | 2010-01-05 | Columbia Insurance Company | Emulsion polymers having multimodal molecular weight distributions |
| CN101558111B (zh) * | 2006-09-20 | 2013-07-17 | 阿克佐诺贝尔化学国际公司 | 用于密封剂和粘合剂配料的含水二氧化硅分散体 |
| DE102006045384A1 (de) * | 2006-09-26 | 2008-04-03 | H.C. Starck Gmbh | Wässrige Siliciumdioxid Dispersionen für Klebstoffformulierungen |
| US8338861B2 (en) * | 2007-01-10 | 2012-12-25 | International Rectifier Corporation | III-nitride semiconductor device with stepped gate trench and process for its manufacture |
| AU2008200079B2 (en) * | 2007-01-16 | 2012-03-29 | Rohm And Haas Company | Fast-drying aqueous compositions with hollow particle binders and traffic paints made therewith |
| CN102112529B (zh) * | 2008-06-03 | 2014-10-15 | 陶氏环球技术有限责任公司 | 复合分散体、其制备方法、以及由其得到的制品 |
| JP5518397B2 (ja) * | 2009-08-12 | 2014-06-11 | 富士フイルム株式会社 | 水性インク組成物、複合粒子の製造方法、インクセット、及び、画像形成方法 |
| MX2012003026A (es) * | 2009-09-11 | 2012-08-15 | Nat Gypsum Properties Llc | Compuesto para juntas con baja emisión de polvo y método para fabricar el mismo. |
| CN102834566B (zh) * | 2010-03-23 | 2016-04-27 | 巴斯夫欧洲公司 | 纸张涂布或粘合配制剂及其制备方法和用途 |
| KR101761452B1 (ko) * | 2010-06-10 | 2017-07-25 | 미쯔비시 케미컬 주식회사 | 아크릴계 중합체의 제조 방법, 이 제조 방법에 의해 얻어지는 아크릴계 중합체 및 이를 이용한 플라스티졸 조성물 |
| US9102848B2 (en) | 2011-02-28 | 2015-08-11 | Basf Se | Environmentally friendly, polymer dispersion-based coating formulations and methods of preparing and using same |
| US10160891B2 (en) | 2012-02-08 | 2018-12-25 | Honeywell International Inc. | High performance water-based tackified acrylic pressure sensitive adhesives |
| US10167416B2 (en) | 2012-02-08 | 2019-01-01 | Honeywell International Inc. | High performance water-based adhesion compositions and applications |
| US9062224B2 (en) * | 2013-02-06 | 2015-06-23 | Xerox Corporation | Stretchable ink composition |
| WO2015152318A1 (ja) * | 2014-04-02 | 2015-10-08 | 東洋インキＳｃホールディングス株式会社 | エマルション型樹脂組成物およびその製造方法 |
| EP3131859B1 (en) * | 2014-04-15 | 2021-08-11 | Honeywell International Inc. | High performance water-based adhesion compositions and applications |
| BR112017003352B1 (pt) * | 2014-08-20 | 2022-05-03 | Dow Global Technologies Llc | Método para formar um substrato não tecido dispersível em um meio aquoso, produto de limpeza dispersível, lenço umedecido para bebês, lenço umedecido para cuidados pessoais e lenço umedecido para limpeza |
| US9421758B2 (en) * | 2014-09-30 | 2016-08-23 | Xerox Corporation | Compositions and use of compositions in printing processes |
| EP3286378B1 (en) * | 2015-04-20 | 2019-04-10 | Kotkamills Group Oyj | Method and system for manufacturing a coated paperboard and a coated paperboard |
| US10363572B2 (en) * | 2015-05-06 | 2019-07-30 | Basf Coatings Gmbh | Method for producing a multicoat paint system on plastics substrates |
| JPWO2017051683A1 (ja) * | 2015-09-24 | 2018-07-12 | 荒川化学工業株式会社 | エマルジョン組成物及びその製造方法、並びに積層体及びその製造方法 |
| GB201522691D0 (en) * | 2015-12-22 | 2016-02-03 | Lucite Internat Speciality Polymers And Resins Ltd | Additive manufacturing composition |
| JP6970197B2 (ja) * | 2016-11-08 | 2021-11-24 | ダウ グローバル テクノロジーズ エルエルシー | 制御された粒径分布 |
| US10526480B2 (en) * | 2016-11-15 | 2020-01-07 | Hercules Llc | Ultra-high solids emulsion and application |
| EP3372649B1 (en) | 2017-03-07 | 2019-09-25 | Organik Kimya Sanayi Ve Tic. A.S. | Polymodal polymer composition |
| US11299571B2 (en) * | 2017-09-26 | 2022-04-12 | Dow Global Technologies, Llc | Aqueous polymer composition |
| EP3611197A1 (en) | 2018-08-17 | 2020-02-19 | Organik Kimya Sanayi Ve Tic. A.S. | Use of a polymodal polymer composition |
| CN110872367B (zh) * | 2018-09-04 | 2023-10-03 | 罗门哈斯公司 | 多级聚合物颗粒的水分散体 |
| PL3623391T3 (pl) | 2018-09-11 | 2021-10-11 | Organik Kimya Sanayi Ve Tic. A.S. | Wielomodalne kompozycje polimerowe do zastosowań powłokowych |
| JP7014307B2 (ja) | 2018-11-22 | 2022-02-01 | 株式会社村田製作所 | 伸縮性配線基板及び伸縮性配線基板の製造方法 |
| CN114340754B (zh) * | 2019-09-30 | 2024-02-02 | 陶氏环球技术有限责任公司 | 汽提聚合物珠粒的水分散体的工艺 |
| CN114536212B (zh) * | 2022-01-29 | 2024-02-09 | 浙江环龙新材料科技有限公司 | 一种微孔热塑性聚氨酯抛光垫及其半连续制备方法 |
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| US4254004A (en) | 1979-05-09 | 1981-03-03 | Scm Corporation | Emulsion process for polymer particles |
| JP2646770B2 (ja) * | 1989-12-13 | 1997-08-27 | 日本合成ゴム株式会社 | 共重合体ラテックスの製造方法 |
| JP3000654B2 (ja) * | 1990-10-19 | 2000-01-17 | ダイキン工業株式会社 | ポリテトラフルオロエチレン微粒子および粉末 |
| US5308890A (en) | 1993-02-26 | 1994-05-03 | Rohm And Haas Company | Emulsion polymer blend of a multi-stage latex and a non-film forming latex |
| GB2298208B (en) | 1995-02-23 | 1998-09-09 | Cray Valley Ltd | Aqueous polymer dispersions |
| CA2179681A1 (en) | 1995-07-05 | 1997-01-06 | Peter C. Hayes | Bimodal latex binder |
| JPH09241310A (ja) * | 1996-03-06 | 1997-09-16 | Hitachi Chem Co Ltd | 単分散樹脂微粒子の製造法 |
| US6139961A (en) * | 1998-05-18 | 2000-10-31 | Rohm And Haas Company | Hollow sphere organic pigment for paper or paper coatings |
| GB9927432D0 (en) | 1999-11-20 | 2000-01-19 | Avecia Bv | Aqueous polymer emulsions |
| US6673451B2 (en) * | 2000-10-12 | 2004-01-06 | Rohn And Haas Company | Process for forming an aqueous polymeric dispersion |
| CA2446016A1 (en) * | 2001-05-02 | 2002-11-07 | 3M Innovative Properties Company | Emulsifier free aqueous emulsion polymerization process for making fluoropolymers |
| CN1289547C (zh) * | 2001-05-02 | 2006-12-13 | 3M创新有限公司 | 在醚类链转移剂存在下制备含氟聚合物的水乳液聚合方法 |
| US6503680B1 (en) * | 2001-08-29 | 2003-01-07 | Xerox Corporation | Latex processes |
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Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0402631A (pt) | 2005-05-24 |
| JP2005036189A (ja) | 2005-02-10 |
| AU2004203020A1 (en) | 2005-02-03 |
| DE602004008839D1 (de) | 2007-10-25 |
| JP2008019451A (ja) | 2008-01-31 |
| DE602004008839T2 (de) | 2008-06-12 |
| US7776975B2 (en) | 2010-08-17 |
| AU2004203020B2 (en) | 2009-08-20 |
| CN1576282A (zh) | 2005-02-09 |
| CN100340580C (zh) | 2007-10-03 |
| EP1498430B1 (en) | 2007-09-12 |
| US20050014883A1 (en) | 2005-01-20 |
| EP1498430A1 (en) | 2005-01-19 |
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