MXPA04000429A - Procedimiento y composicion para incrementar la reactividad de oxidos de eliminacion de azufre. - Google Patents

Procedimiento y composicion para incrementar la reactividad de oxidos de eliminacion de azufre.

Info

Publication number
MXPA04000429A
MXPA04000429A MXPA04000429A MXPA04000429A MXPA04000429A MX PA04000429 A MXPA04000429 A MX PA04000429A MX PA04000429 A MXPA04000429 A MX PA04000429A MX PA04000429 A MXPA04000429 A MX PA04000429A MX PA04000429 A MXPA04000429 A MX PA04000429A
Authority
MX
Mexico
Prior art keywords
oxide
sulfur
manganese
hydroxide
oxides
Prior art date
Application number
MXPA04000429A
Other languages
English (en)
Inventor
C Scranton Delbert
Original Assignee
Mi Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/882,156 external-priority patent/US6703341B2/en
Application filed by Mi Llc filed Critical Mi Llc
Publication of MXPA04000429A publication Critical patent/MXPA04000429A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds

Abstract

Para liberar a fluidos, incluyendo fluidos de hidrocarburo tanto gaseosos y liquidos, de compuestos de azufre que incluyen sulfuro de hidrogeno, oxidos de azufre y tioles, la presente invencion utiliza una pequena cantidad de un activador, generalmente un oxido de metal noble, preferiblemente de la especie del cobre y/o de la especie del manganeso, con un producto de oxido conocido, como oxido de hierro, hidroxido de hierro, oxido de zinc, hidroxido de zinc, oxido de manganeso, hidroxido de manganeso o combinaciones de los mismos, para remover profusamente los contaminantes de azufre en una cantidad de tiempo corta; el activador permite el uso de contenedores de reactor mas pequenos y la produccion de fluidos de hidrocarburos sustancialmente libres de productos de azufre.
MXPA04000429A 2001-06-15 2002-06-12 Procedimiento y composicion para incrementar la reactividad de oxidos de eliminacion de azufre. MXPA04000429A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/882,156 US6703341B2 (en) 1996-08-20 2001-06-15 Composition for increasing the reactivity of sulfur scavenging oxides
US09/683,988 US6887445B2 (en) 1998-08-04 2002-03-08 Process for sulfur scavenging
PCT/US2002/018855 WO2002102931A2 (en) 2001-06-15 2002-06-12 Process and composition for increasing the reactivity of sulfur scavenging oxides

Publications (1)

Publication Number Publication Date
MXPA04000429A true MXPA04000429A (es) 2004-03-18

Family

ID=27103240

Family Applications (1)

Application Number Title Priority Date Filing Date
MXPA04000429A MXPA04000429A (es) 2001-06-15 2002-06-12 Procedimiento y composicion para incrementar la reactividad de oxidos de eliminacion de azufre.

Country Status (7)

Country Link
US (1) US6887445B2 (es)
EP (1) EP1404445A4 (es)
AU (1) AU2002315137B2 (es)
BR (1) BR0210921B1 (es)
CA (1) CA2451655C (es)
MX (1) MXPA04000429A (es)
WO (1) WO2002102931A2 (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0031710D0 (en) * 2000-12-27 2001-02-07 Dyno Oil Field Chemicals Process for the reduction or elimination of hydrogen sulphide
GB0804572D0 (en) * 2008-03-12 2008-04-16 Johnson Matthey Plc Preparation of desulphurisation materials
GB0804570D0 (en) * 2008-03-12 2008-04-16 Johnson Matthey Plc Desulphurisation materials
US9347010B2 (en) * 2008-04-18 2016-05-24 Schlumberger Norge As Method of predicting/optimizing hydrogen sulfide scavenging capacity and reduction of scale formation
US8404031B1 (en) 2009-10-06 2013-03-26 Michael Callaway Material and method for the sorption of hydrogen sulfide
US8759252B1 (en) 2010-10-06 2014-06-24 Michael D. and Anita Kaye Material and method for the sorption of hydrogen sulfide
GB201112606D0 (en) 2011-07-22 2011-09-07 Johnson Matthey Plc Desulphurisation materials
US9068128B2 (en) * 2011-10-18 2015-06-30 Baker Hughes Incorporated Method for reducing hydrogen sulfide evolution from asphalt and heavy fuel oils
US9847543B2 (en) 2013-03-06 2017-12-19 Fuelcell Energy, Inc. Fuel cell system having biogas desulfurizer assembly with manganese oxide desulfurizer material
DE102014113016B4 (de) 2014-09-10 2023-08-31 Umicore Ag & Co. Kg Beschichtungssuspension
US10081006B2 (en) * 2014-12-17 2018-09-25 University Of Connecticut Adsorptive desulfurization
MX2020002011A (es) 2017-08-23 2020-07-13 Ecolab Usa Inc Dispersante de azufre elemental para controlar las incrustaciones en sistemas de agua.
US10800684B2 (en) 2019-02-18 2020-10-13 Multi-Chem Group, Llc Zinc ammonium carbonate sulfide scavengers
CN110314536B (zh) * 2019-06-19 2021-05-04 东华大学 一种Fe3O4纳米颗粒耦合微纳米气泡吸收烟气的体系及方法

Family Cites Families (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3832445A (en) * 1964-09-14 1974-08-27 Shell Oil Co Sulfur dioxide removal
DE1913885B2 (de) * 1968-03-21 1974-06-20 The Gas Council, London Verfahren zur Entschwefelung von KohlenwasserstofFdestillatölen
US3907666A (en) * 1971-07-15 1975-09-23 Gulf Research Development Co Hydrocarbon sweetening with a calcined pellet of copper salt and ferric oxide
US4014982A (en) * 1975-06-30 1977-03-29 Texaco Development Corporation Combined process for upgrading spent alkylation acid and reducing noxious gas content of waste gaseous streams
FR2340763A1 (fr) * 1976-02-12 1977-09-09 Hitachi Ltd Procede pour traiter un gaz d'echappement renfermant des oxydes de soufre
US4113606A (en) * 1976-09-28 1978-09-12 Chevron Research Company Method of removing sulfur-containing impurities from hydrocarbons
JPS5390186A (en) * 1977-01-20 1978-08-08 Kureha Chem Ind Co Ltd Catalyst for reducing of nitrogen
FR2384712A1 (fr) * 1977-03-25 1978-10-20 Inst Francais Du Petrole Procede de regeneration de solutions aqueuses de sulfures de sodium, de potassium et/ou d'ammonium
FR2432887A1 (fr) * 1978-08-08 1980-03-07 Inst Francais Du Petrole Procede d'epuration d'un gaz contenant du sulfure d'hydrogene
SU791411A1 (ru) 1978-11-09 1980-12-30 Ивановский Химико-Технологический Институт Катализатор-поглотитель дл очистки газа от сернистых соединений
FR2456543A1 (fr) * 1979-05-15 1980-12-12 Inst Francais Du Petrole Procede d'epuration d'un gaz contenant du sulfure d'hydrogene
US4344842A (en) * 1979-05-31 1982-08-17 Irwin Fox Reactive iron oxide agents for scavenging hydrogen sulfide from hydrocarbon liquids
US4366131A (en) * 1979-05-31 1982-12-28 Irwin Fox Highly reactive iron oxide agents and apparatus for hydrogen sulfide scavenging
US4246244A (en) * 1979-05-31 1981-01-20 Gas Sweetener, Inc. Process for scavenging hydrogen sulfide from hydrocarbon gases
US4455286A (en) * 1982-07-07 1984-06-19 The United States Of America As Represented By The United States Department Of Energy High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures
US4550098A (en) * 1982-11-12 1985-10-29 The Boc Group, Inc. Methods for the removal of gaseous impurities from mixed gas streams
JPS60166033A (ja) * 1984-02-06 1985-08-29 Mitsubishi Heavy Ind Ltd 脱硫剤
US4695366A (en) * 1984-12-11 1987-09-22 Union Oil Company Of California Desulfurization process
US4634539A (en) * 1985-03-11 1987-01-06 Irwin Fox Scavenging oxygen from aqueous systems
US4593148A (en) * 1985-03-25 1986-06-03 Phillips Petroleum Company Process for removal of arsine impurities from gases containing arsine and hydrogen sulfide
US4729889A (en) * 1985-03-29 1988-03-08 California Institute Of Technology High temperature regenerative H2 S sorbents
US4722799A (en) * 1985-04-24 1988-02-02 Ashbrook Clifford L Natural gas desulphurizing apparatus and method
GB8610196D0 (en) * 1986-04-25 1986-05-29 Ici Plc Sulphur compounds removal
US4690806A (en) * 1986-05-01 1987-09-01 Exxon Research And Engineering Company Removal of sulfur from process streams
US4939113A (en) * 1987-11-03 1990-07-03 Engelhard Corporation Hydrogen sulfide suppressing catalyst system using an oxide of copper, manganese, nickel or iron
DK165969C (da) 1989-05-29 1993-11-08 Haldor Topsoe As Fremgangsmaade til fjernelse af sulfider fra gasstroemme
US4959202A (en) * 1989-05-31 1990-09-25 Medalert Incorporated Recovery of chlorine from hydrogen chloride by carrier catalyst process
US4990318A (en) * 1989-06-07 1991-02-05 Phillips Petroleum Company Selective removal of hydrogen sulfide over a nickel-promoted absorbing composition
US5147620A (en) * 1989-06-08 1992-09-15 Linko Enterprises, Inc. Process for the purification of gaseous streams
US5320992A (en) * 1989-08-30 1994-06-14 Irwin Fox Disposable oxide carrier for scavenging hydrogen sulfide
US5227351A (en) * 1991-03-13 1993-07-13 The United States Of America As Represented By The United States Department Of Energy Sorbent for use in hot gas desulfurization
US5244641A (en) * 1992-04-28 1993-09-14 Phillips Petroleum Company Absorption of hydrogen sulfide and absorbent composition therefor
US6126911A (en) * 1992-05-04 2000-10-03 The Sulfatreat Company Metal oxide product suitable for use in dehydrated gas
US5472633A (en) * 1992-10-06 1995-12-05 The Dow Chemical Company Process for the preparation of a stable salt-free iron chelate for use in hydrogen sulfide abatement
CN1037778C (zh) * 1992-11-28 1998-03-18 大阪瓦斯株式会社 烃的脱硫方法
US5447551A (en) * 1993-05-28 1995-09-05 Georgetown Steel Corporation Method and apparatus for the removal of hydrogen sulfide from a process gas stream
CA2120046C (en) * 1994-01-27 1999-09-14 M-I L.L.C. Separately removing mercaptans and hydrogen sulfide from gas streams
US5726117A (en) * 1995-06-07 1998-03-10 Phillips Petroleum Company Sorbent compositions containing zinc subjected to a steam treatment
US5792438A (en) * 1996-08-20 1998-08-11 The Sulfatreat Company Process and composition for increasing the reactivity of sulfur scavenging iron oxides
US5928980A (en) * 1997-02-06 1999-07-27 Research Triangle Institute Attrition resistant catalysts and sorbents based on heavy metal poisoned FCC catalysts

Also Published As

Publication number Publication date
WO2002102931A2 (en) 2002-12-27
BR0210921A (pt) 2006-10-10
US6887445B2 (en) 2005-05-03
EP1404445A2 (en) 2004-04-07
WO2002102931A3 (en) 2003-03-27
US20020182135A1 (en) 2002-12-05
BR0210921B1 (pt) 2013-09-10
AU2002315137B2 (en) 2006-10-19
EP1404445A4 (en) 2006-07-26
CA2451655A1 (en) 2002-12-27
CA2451655C (en) 2013-11-05

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