MXPA01000273A - Plant growth enhancement against phytopathogenic fungi and/or soil borne pests. - Google Patents

Plant growth enhancement against phytopathogenic fungi and/or soil borne pests.

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Publication number
MXPA01000273A
MXPA01000273A MXPA01000273A MXPA01000273A MXPA01000273A MX PA01000273 A MXPA01000273 A MX PA01000273A MX PA01000273 A MXPA01000273 A MX PA01000273A MX PA01000273 A MXPA01000273 A MX PA01000273A MX PA01000273 A MXPA01000273 A MX PA01000273A
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MX
Mexico
Prior art keywords
mixture
use according
alcohols
apg
fatty alcohols
Prior art date
Application number
MXPA01000273A
Other languages
Spanish (es)
Inventor
Bettina Kopp-Holtwiesche
Original Assignee
Cognis Deutschland Gmbh
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Filing date
Publication date
Priority claimed from DE1998130889 external-priority patent/DE19830889A1/en
Priority claimed from DE19849253A external-priority patent/DE19849253A1/en
Application filed by Cognis Deutschland Gmbh filed Critical Cognis Deutschland Gmbh
Publication of MXPA01000273A publication Critical patent/MXPA01000273A/en

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01PBIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P3/00Fungicides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G7/00Botany in general
    • A01G7/06Treatment of growing trees or plants, e.g. for preventing decay of wood, for tingeing flowers or wood, for prolonging the life of plants
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants

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  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Zoology (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Ecology (AREA)
  • Forests & Forestry (AREA)
  • Toxicology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Botany (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical & Material Sciences (AREA)
  • Mycology (AREA)
  • Microbiology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Saccharide Compounds (AREA)
  • Cultivation Of Plants (AREA)

Abstract

The invention relates to the use of aqueous fatty alcohol preparations and/or fatty acid partial esters with low multi-functional alcohols in admixtures with ecologically compatible surface active agent compounds from the class consisting of O/W-type alkyl(poly)glycosides as a mixture of useful materials having a plant-enhancing and/or plant-healing effect against the attack by phytopathogenic fungi and/or soil borne pests.

Description

PROMOTION OF GROWTH OF PLANTS AGAINST FITOPATHOGENIC FUNGI AND / OR SOIL PESTS The unpublished document DE 19701127.6 describes concentrates of surfactants with limited foam formation for use in the field of promoting the growth of plants. With details are described crosslinking aids in the form of an aqueous concentrate that can flow and be emptied, highly concentrated, based on surfactants to intensify the penetration and diffusion of water in the root zone of plants at the time of Irrigation, containing ecologically compatible surfactant components composed of alkyl (poly) glycoside type O / W - also known hereinafter as "APG compounds" - and in mixture with olefinically unsaturated fatty alcohols and optionally additional partial esters of fatty acids with alcohols polyfunctional foam-limiter / foam removers and additional water-soluble lower alcohols as viscosity regulating agents. The technical teaching of the additional development presented below uses the principles of technical education presented in the German patent application mentioned above. The disclosure of this oldest German patent application is hereby incorporated explicitly as an object of the disclosure of the present invention. The technical teaching of the previous application mentioned above is based on the following problem: the apparently simple measure of irrigating soil surfaces, especially in the case where there is a high density of plants, can present significant difficulties. An example is the case of pedestrian traffic and / or vehicular traffic on grass surfaces, where despite regular irrigation small or large areas of grass can dry. When trying to humidify these places, the water does not penetrate the soil and especially does not penetrate the root zone of the plants. As a result the corresponding lawn area can become sick due to dryness and lack of nutrients. It is known that by means of the combined use of auxiliaries with a crosslinking character with the water used for sprinkler irrigation, a better penetration of the aqueous phase in the soil zone and consequently also in the field of the roots of the plants is obtained. In accordance with the teaching of the aforementioned prior application, surfactant auxiliaries composed of type O / APG must be used, which are used today on a large scale in totally different technical fields. The APG compounds are surfactant auxiliaries in the field of washing and cleaning agents, including textile washing substances. The teachings of the above-mentioned prior application are based on the determination that aqueous APC-based crosslinking agents are also valuable crosslinking agents for increasing the growth of plants relative to soil irrigation. However, in this case the following problem must be solved: the APG-based surfactant auxiliaries of the type in question have a particularly high foam-forming capacity in aqueous preparations. For its use in the field of washing and cleaning agents this characteristic is generally desired by the consumer; however, in the field of work of the present invention this characteristic is not only not desired but can represent a major problem. Common auxiliaries for limiting the formation of foam are known in the field of washing and cleaning agents, however they are not suitable for use in the scope of the present invention for the promotion of the growth of healthy plants. The aforementioned technical teachings of the aforementioned prior patent application employ, together with the surfactant components based on APG, foam removers or selected foam delimiters, which do not affect the growth of the plants, and preferably on the contrary promote said growth. In this case, these are fatty alcohols mentioned above and / or partial fatty acid esters with lower polyhydric alcohols. The teaching of the above application is also based on the purpose of being able to offer the combination of active substances desired here jointly in concentrated form easily dilutable with water, so that in addition the sufficient capacity of dilution of the concentrate should be ensured in the normal temperature range of use. The technical solution within the framework of the teaching of the above application is found in the combination of several aforementioned substances containing the type 0 / APG compounds together with foaming delimiters selected from the aforementioned technique in an aqueous concentrate , whose viscosity is regulated by the joint use of limited amounts of water-soluble lower alcohols. In the further development described below within the teaching framework in accordance with the present invention, the following additional knowledge is found: the APG-based crosslinking agents of the type in question here promote not only the penetration of the spray water into the structure of the soil and therefore especially in the area of the roots of the plants, but the mixture of aqueous active substances applied here in the soil and / or in the aerial parts of the plants shows an effect of strengthening of the plants and / or improvement of plant health not anticipated against the attack of plants by phytopathogenic fungi and / or against pests found in the soil. Mushroom populations that promote the growth of plants in the mycorrhiza zone and therefore in the area of the soil surrounding the roots of the plants are not affected. On the contrary, the combination of active substances according to the present invention promotes the metabolism and consequently provides the plants with an invigorating effect in the zone of the rhizosphere and / or in the area of the mycorrhiza, as can be seen from the promotion of plant growth. Together with this effect, a reinforcement of the healthy growth of the plants is observed through an elevation of the defense capacity against plagues found in the soil, especially against insects and / or corresponding nematodes. Without pretending to provide a complete explanation of these effects, we can mention the following: the foaming limiters based on fatty alcohols and / or partial esters of fatty acids introduced into the soil thanks to the surfactant APG components have an influence, as suppliers valuable of C, in the life of the numerous microorganisms of the plants in the zone of the roots and in this way also indirectly promote the reinforcement and consequently the resistance of the plants against attacks of phytopathogenic fungi. The teaching of EP 0 230 598 Bl describes the use of alkyl glycoside compounds as an active substance that fights against harmful organisms in means to protect crop and ornamental plants. The APG compounds cited in this publication encompass, in addition to the APG components suitable also in accordance with the present invention, a much broader range of APG compounds, especially corresponding APG ethoxylates. With details, there is described the use of aqueous preparations of APG compounds against attacks by aphids, spiders and mussels. Mixtures of substances based on APG within the framework of the aforementioned prior German patent application and also in accordance with the present invention employing surfactant APG components in admixture with fatty alcohols and / or partial esters of fatty alcohols, especially also in the soil zone and consequently in the root zone of the plants, are not disclosed in the aforementioned publication. Neither is the problem of the limitation of undesired foam formation or a technical solution in the sense of the teaching of the present invention mentioned. OBJECT OF THE INVENTION The object of the present invention is therefore the use of aqueous solutions of fatty alcohols and / or partial esters of fatty alcohols with lower polyfunctional alcohols in admixture with ecologically compatible surface-active compounds of the class of alkyl (poly) glycosides of type O / W (compounds APG) as a mixture of active substances with an effect of strengthening the plants and / or healthy growth of the plants against attacks by phytopathogenic fungi and / or other pests found in the soil. The mixtures of several components defined herein are used, within the framework of the present invention, especially in the field of commercial production of plants, in agriculture as well as in commercial or private gardening. Details regarding the teaching of the present invention Next, detailed data of the individual components, in accordance with the present invention, of the mixtures of multiple components employed will be presented. The APG compounds of type 0 / W Here we refer first to the technical knowledge and the extensive documents for the preparation and the obtaining of APG compounds, especially of the type in question in the present invention, as for example the publications that appeared in the form of books by HILL et al "alkyl polyglycosides", VCH-Verlagsgesellschaft bH, Weinheim 1997. We also refer to the publication of EP 0 230598 Bl mentioned above that provides complete data for the preparation and obtaining of the class of substances in question in the present invention of APG compounds, to which we refer for simplicity. Preferred APG compounds according to the present invention are characterized in that they employ at least partially and preferably at least mainly alkyl (oligo) glucoside compounds whose alkyl radical is at least mainly derived from straight-chain fatty alcohols. Compounds of this type are surfactant auxiliaries of a wide range of uses. Many factors are currently considered for use in practice: crosslinkers based on APG can be based on natural substances in a known manner. They are obtained as reaction products by reaction of fatty alcohols with monosaccharides, oligosaccharides and / or polysaccharides. In the case of the use of higher polysaccharides and / or oligosaccharides with fatty alcohols, a depolymerization is caused in the course of the acid catalysis reaction first by hydrolysis and / or alcoholysis, before the formation of the desired APG compounds. Preferred saccharide components for the formation of APG are glucose or corresponding oligoglucoses or polyglucose. Suitable reagents are also saccharide compounds based on mannose, galactose, arabinose as well as monomer glycosides, oligoglycosides and / or additional similar polyglycosides. Suitable APG compounds for the present invention are obtained as products of the reaction of the general formula R-0- (G) x / wherein R represents an aliphatic hydrocarbon radical and preferably straight chain with at least 6 carbon atoms , preferably with 8 to 24 carbon atoms, and especially with 8 to 18 carbon atoms, and G represents a glycosa unit with 5 or 6 carbon atoms, preferably represents glucose. The degree of oligomerization x - and therefore the DP value - provided by the distribution of monoglycosides and oligoglycosides, in the class of surfactants in question is usually within a range between 1 and 10, and is found, for example, within a range of about 1.2 to 5, preferably within a range of about 1.2 to 4 and especially within a range of 1.2 to 2. The O / W type APG compounds, ie surfactant components of the specified technique, which they lead to the formation of oil-in-water emulsions - they present in a known manner a relatively high HLB value, which is preferably within a range greater than 7 and especially greater than 8 or 9, so that a range of HLB of 10 to 18 has a special importance. The fatty alcohols used in accordance with the present invention As described above, these blend components are employed in the multi-component mixtures according to the present invention with multifunctional significance.
On the one hand, they are valuable components as foam delimiters for the practical use of multi-component mixtures in dilute aqueous preparations, on the other hand they are useful in the soil and especially in the root zone of plants as carbon suppliers. for the growth of microorganisms and especially for promoting the growth of organotrophic microorganisms. Fatty alcohols are degradable both by natural degradation processes and by aerobic and anaerobic degradation. As an important source of C according to the present invention for organotrophic growth they have in their molecular structure lipophilic hydrocarbon radicals with a fatty structure and consequently a relatively high concentration of C-H groups that provide energy. Preferred fatty alcohols according to the present invention in the mixture of multiple components are characterized by having at least 6 to 8 carbon atoms in the molecule, wherein mono and / or polyunsaturated olefinic fatty alcohols with 10 to 28 carbon atoms and especially fatty alcohols corresponding with 12 to 24 carbon atoms are especially preferred. A further preferred parameter for the choice of suitable fatty alcohols is the solidification temperature of these components of the mixture. Preferred components with a range of solidification temperatures equal to / less than 20 ° C and especially temperatures within a range equal to / less than 10 to 15 ° C. Although the use of fatty alcohols based on natural substances of the type mentioned herein is preferred in accordance with the present invention, the teaching in accordance with the present invention is not limited thereto. It is also possible to use fatty alcohols of synthetic origin which have a branched chain, and are suitable components of the mixture within the framework of the present invention. In this case, the coordination of the solidification range of this (these) alcohol component (s) can be especially influenced. Partial esters of fatty alcohols suitable according to the present invention In addition to the fatty alcohols defined above and / or instead of the fatty alcohols defined above, partial fatty acid esters of lower polyfunctional alcohols can be important compounds of the mixture within the framework of the present invention. Suitable compounds are, especially on the side of the polyfunctional lower alcohols, corresponding compounds having 2 to 6 carbon atoms and especially 3 to 5 carbon atoms. Of particular importance, due to their ease of obtaining as a natural element, the corresponding partial glycerin esters. The fatty acids of the class mentioned here of partial esters usually belong to the group of the corresponding compounds with 10 to 24 carbon atoms, whereby corresponding monocarboxylic acids in the range C? 2-2o are especially suitable. Fatty acids of the type mentioned herein are known as materials based on natural substances and can be obtained easily. The use of olefinically monounsaturated and / or polyunsaturated fatty acids may be preferred. A particularly suitable class of the active substances in question here are partial glycerin esters with olefinically unsaturated Ciß / ia monocarboxylic acids, whereby corresponding monoesters are of particular importance. A fatty acid ester of this type that can be obtained in large amounts is the glycerin monooleate. Fatty acid esters of the constitution described herein can be degraded by natural degradation processes in the soil both aerobic and anaerobic as the fatty alcohols described above. They are also important sources of C for the organotrophic growth of microorganisms in the area near the roots of plants. As well by means of its use, a reinforcement of the growth of the plants is obtained through the stimulation of the growth of microorganisms found in the soil. Further details regarding the teaching of the present invention Within the scope of the present invention, only fatty alcohols or only partial fatty acid esters can be used as components of the mixture together with APG compounds. In one embodiment, however, combinations of fatty alcohols and partial fatty acid esters are used. Mixture ratios are preferred - relative to the parts by weight of the anhydrous components - which are within a range of about 1: 1 to 1:10. Mixing ratios between fatty alcohols and partial esters of fatty alcohols (parts by weight of anhydrous components) are preferred within a range of 1: 1 to 1: 5., mixtures being especially preferred within a range of 1: 1 to 1: 3. In the mixture of several components for use in accordance with the present invention, the APG components are at least in approximately equal weight amounts in relation to fatty alcohols and / or partial ester, so mixing proportions between APG and fatty alcohol and / or partial ester are preferred within a range of from 1: 1 to 5: 1, preferably from 1: 1 to 3: 1 and especially from 1.5 to 2.5: 1. The values mentioned here refer each time to the parts by weight of the mixture of elements and each time in relation to anhydrous components of the mixture. However, the teaching of the present invention is not limited to a use of this type of excess APG components. Also mixtures of elements with a corresponding excess of fatty alcohols and / or partial esters of fatty acids which are used as foaming limiters are found within the teaching of the present invention. The mixtures of various components according to the present invention are provided in accordance with the data of the introduction of the aforementioned prior German application 19701127.6 usually in the form of fluid aqueous concentrates on the market and for the user, and these concentrates can be diluted with water additionally for the application of the mixture of the elements in the soil and in the plants. In order to be able to provide a combination of elements in the form of concentrates that are easy to dilute with water, sufficient cleavability must be ensured at normal temperatures as well. The teaching of the aforementioned prior application clearly states that in the case of a mixture of APG aqueous concentrates with foaming delimiters / foam removers based on fatty alcohol and / or partial ester easily dense gels are obtained which can no longer flow. Accordingly, it is proposed in the aforementioned document to maintain the flow and drainage capacity also in the range of ambient temperatures by the addition of limited amounts of lower monofunctional alcohols and especially by the addition of limited amounts of ethanol. The same applies in the case of mixtures of elements within the framework of the application of the present invention. Preferred lower monofunctional alcohols are corresponding compounds with up to 4 carbon atoms. The teaching according to the present invention contemplates in an important embodiment the use, in addition to the components mentioned above of the mixture of elements, of further lower polyvalent alcohols, and especially lower polyvalent alcohols which flow at room temperature as components of the mixture. Likewise, these polyvalent alcohols can have a polyfunctional importance within the framework of the mixture of several elements. As parts of the fluid mixture with relatively high boiling points they promote the desired fluidity especially for the handling of the concentrate and thus their diffusion, on the other hand these components, after their application to the soil have a nutrient character in the sense that they represent an additional source of C for the growth of microorganisms, especially in the rhizosphere and / or in the mycorrhiza zone. Preferred polyhydric alcohols are corresponding compounds with 2 to 6 carbon atoms, preferably with 2 to 4 carbon atoms, so glycerin and / or glycol can be mentioned here as especially relevant. The high solubility in water of the components mentioned here can be an additional aid within the framework of the practical use of mixtures of multiple components. Preferred amounts for the blend components discussed herein are usually at a maximum of 30 to 35% by weight, preferably at a maximum of 20 to 25% by weight, and especially within a range of 5 to 15% by weight, each time they are percentages by weight in relation to the mixture of several elements in the form of the concentrate described above, which can then be diluted with water for application in the areas of the soil to be treated. In addition to the unsaturated fatty alcohols described above as components of the mixture or alternatively in place of said fatty alcohols, olefinically unsaturated terpene alcohols can also be used as foam delimiters / foam removers. In the case of terpene alcohols, these are acyclic or monocyclic, bicyclic or tricyclic alcohols of various olefinically unsaturated alcohols containing from 10 to 40 carbon atoms. The terpene alcohols are preferably used in the form of their natural mixtures as foam delimiters / foam removers. A preferred representative here is what is known as pine oil, a mixture of several terpinoles such as a- and β-terpinoles, a-fencialcohol, borneol and isoborneol as described in the Dictionary of Chemistry of Roppp, page 3451, volume 4, 9a. edition, 1991. In addition, pine oil also contains in minor amounts other non-alcohol compounds, for example, camphor, anethole and estragole. The pine oil is also obtained from pieces containing resin and from the roots of various types of pines by extraction for example with benzene or chloroform and subsequently by fractionation and distillation. The foam removal components are as mentioned before usually in small amounts as the components of APG - each time in relation to the active substance. Mixtures are preferred in which the foam removal components can be used in markedly smaller amounts. Accordingly, concentrates of various elements are suitable within the framework of the present invention whose content of foam remover is within a range of about 10 to 25% by weight and preferably within a range of about 15 to 20% by weight . The lower water-soluble monofunctional alcohols which are used as viscosity regulators are determined in terms of type and amount by the above-mentioned principal components, the lower water-soluble polyvalent alcohols optionally employed as well as the amount of water found. globally in the mixture of several elements. Additional amounts of viscosity regulator are especially suitable within a range of at least about 5 to 7% by weight as the lower limit and from 12 to 25% by weight as the upper limit. Amounts of ethanol within a range of about 5 to 20% by weight and especially 10 to 15% by weight in general have a sufficient influence on the viscosity in the direction of flowability and the desired emptying of the mixture of several components also in the range of ambient temperatures. The water content of the concentrates of various elements generally reaches at most about 50% by weight, and yet is in preferred embodiments at lower levels. For the water content of the mixture of multiple component ranges from a maximum of about 30 to 45% by weight are especially suitable. In general, the water content is selected such that it has a clearly lower level and such that it is, for example, within a range of 10 to 20% by weight, preferably within a range of 10 to 15. % in weigh. In practical use, the mixtures of several components are applied in aqueous form diluted in such amounts on the soils to be treated and / or on the plants to be treated, in such a way that the mixture of multiple components applied - in relation to the mixture without water - is in amounts of at least about 0.5 g / m2 and preferably in amounts of at least 1 g / m2. Application rates are also suitable within a range of 0.5 to 35 g / m2 and especially amounts within a range of 1 to 20 g / m2, in each case with anhydrous ratio of several elements consisting especially of APG compounds, fatty alcohols and / or partial esters of fatty acids. A preferred upper limit for the application amounts discussed herein is within a range of 10 to 15 g / m2. In practical use the concentrates of active substances described above are further diluted with water and sprayed in the form of fine aqueous emulsions / dispersions. It is preferred to use dilute aqueous mixtures in which the proportion by weight mixture of active substance-poly-components: water is at least 1:10 and preferably at least 1:15 to 20. In practical use the teaching of conformity with the present invention it allows unknown possibilities of reinforcement of the plants on the one hand against the attack of populations of unintended phytopathogenic fungi and also against the attack of soil pests such as, for example, unwanted insects and especially nematodes. Unlike the usual fight against these pests today by "selected" synthetic active substances, which often have no relation to the natural molecules, molecular structures based exclusively on the active substance mixtures according to the present invention can be used. in natural elements or at least they are based mainly on natural elements.The mechanism of action desired is therefore especially the reinforcement of the plants, influencing and reinforcing the self-defense potential of the plants, especially through a corresponding influence on the processes metabolic processes in the field of plant roots and, consequently, the vital processes of the populations of microorganisms that make exchanges with the vital processes of the plants In relation to this point the important knowledge described below for the teaching of with With the present invention and its effects in practical use within the framework of the stimulation of the growth of soil microorganisms: the application of the mixtures of active substances in accordance with the present invention in the soil causes a measurable increase in the soluble parts in water of phosphorus compounds and consequently causes an increase of the phosphate parts that are available for the growth of the plants. The reinforcement and the increase of the growth of the flora of microorganisms in the soil evidently also causes the reinforcement of the aspects in question in the zone of the roots of the plants. This secondary effect of the elevation of root growth can be established very clearly, for example in the case of grass surfaces which have an irregular density of plants. It is known that the addition of available phosphorus for the growth of the plants in the affected soil area causes a mainly horizontal extension of the roots of the grass and consequently an expansion of the root zone, especially in the spaces of the ground where it does not there are plants, so that an additional greening of the areas of the soil without plants or with an insufficient density of plants is obtained in this way. The use of the combinations of active substances described according to the present invention causes these effects. Especially the expansion of the growth of the roots can be quickly verified as the primary consequence of the reinforcement of the plants. Regarding this point, the determination of the soluble phosphate part in the area of the affected soil shows this increase in the phosphate content already described above. In this way, an initial additional effect to the date known to achieve the objective in accordance with the present invention of plant strengthening and / or sanitation becomes evident and understandable. The following examples describe selected concrete embodiments of the teaching of the present invention. Example 1 In the following examples, comparative research and the results obtained are proposed, where in identical working conditions the development and growth promotion of lettuce in pots filled with standard soil is determined. The dependence of the growth of the plants, each time under standard conditions, on the use and concentration employed of the mixtures of active substances defined according to the present invention based on fatty alcohols and / or partial fatty acid esters is determined in particular. mixture with APG compounds of type O / W. Additionally, in comparative studies, the effect of the use of different amounts of classic fertilizers is determined. The following are the details of these studies: As mixtures of active substances within the framework of the teaching according to the present invention APG compounds of type 0 / W in mixture with fatty alcohols and / or partial esters of fatty acids - preparations were used of the commercial product of the "Magic Wet" brand of the applicant in different standard concentrations. If additional conventional fertilizers are used in the comparison studies, it is treated as a liquid fertilizer of the product of the "Substral" brand, which has a N-P20s-K20 ratio of 6-2-4. Details of the concentrations used in each case of auxiliaries and active substances are presented in relation to the following examples. Materials and methods of comparison culture trials As a place to carry out the study, balcony pots with a capacity of 6.7 1 and a surface of 0.06 m2 were used. Lettuce was grown in the pots filled with standard soil until maturity to be harvested at 8 weeks. Within this period of time the pots received an application of test solution at regular intervals (1 x before planting, 9 x after sowing) and on 4 additional occasions the plants were watered only with water.
Four different dilutions of Magic Wet were used as test solutions, which are summarized in the following table 1. Within the individual dilutions of Magic Wet, 3 different levels of fertilizer were tested: a) without fertilizer (variants 3, 6, 9, 12, 15) b) 15 g long-term subsurface fertilizer per pot (variants 2, 5, 8, 11, 14) c) 30 g Subsurface long-term fertilizer per pot (variants 1, 4, 7, 10, 13) As details of the study variants mentioned here, we provide the data offered in table 1 for use and dilution of Magic Wet solutions. Table 1 Variants product dilution total amount per pot (0.06 m2) in the study period 1, 2, 3 Magic Wet 1.0% 27.5 g 4, 5, 6 Magic Wet 0.5% 13.75 g 7, 8, 9 Magic Wet 0.25% 6.88 g 1 100 ,, 1111 ,, 1 122 M Maaqgiicc WWeett 0 0..112255 %% 3.44 g 13, 14, 15 Water - A first test was carried out in December (test I) and repeated in February (test II). In this case we can mention the following limitation: the highest concentrations of Magic Wet in the irrigation water in accordance with variants 1, 2 and 3 are so high that for the practice no applicable data can be obtained. Growth trials using this higher concentration were therefore not continued. Within the framework of the tests, the following general observation is made: especially in the case of trial I, the plants not treated with Magic Wet presented a very high reduction that may be due to an excessive water supply. In the corresponding plants of variants 13, 14 and 15 root putrefaction was observed, that is, plants not treated with Magic Wet were attacked by fungi and presented corresponding root rot. On the contrary, with identical conditions of irrigation and cultivation, by adding the lowest concentrations of Magic Wet in variants 4 to 12, the appearance of fungal attack could be avoided. Regarding the production of the plants of trial 1 we can mention the following data: in all the investigations, in each case 5 balcony pots separated from each other but treated in the same way were used for each variant (n = 5). The highest level of fertilizer (30 g of Substral per pot) always obtained in the trial I comparatively lower biomasses (= harvest) than the unpaid variants and the variants fertilized with 15 g of Substral. In the following table 2 data of the average biomasses are presented. Table 2 Variants of dilution of biomass fertilizer Magic Wet 5 0.5% 5 15 g 42.4 g 6 0.5% 5 35.8 g 8 0.25% 5 15 g 43.5 g 9 0.25% 5 43.9 g 11 0.125% 5 15 g 41.5 g 12 0.125% 5 42.6 g 14 0 4 15 g 31.0 g 15 0 5 33.3 g Variants 14 and 15 not treated with Magic Wet presented an average biomass of 31 to 33 g. In comparison, the variants treated with Magic Wet (especially 5, 8, 9, 11, 12) obtained a biomass approximately 10 g higher. No significant difference is shown between the Magic Wet concentration levels of 0.5%, 0.25% and 0.125%. Also in the II trial the treatment with Magic Wet with a dilution of 0.5%, 0.25% and 0.125% - data every time in percentages by weight - achieved higher biomasses than in the case of the untreated controls. The following table 3 shows a summary of the values obtained from the series of tests in question. As "fertilizer" is also used here Substral in quantities of 30 g, 15 g or Substral is not used. The biomasses obtained with the use of Magic Wet are in all the series of comparable tests significantly higher compared to parallel tests without use of Magic Wet. It is especially noticeable in the case of the highest amount of Substral fertilizer used (30 g). This amount of excessive fertilizer is better tolerated by the plants with the use of Magic Wet, and the damages expected by salts were cushioned. The following table 3 presents interesting additional data: The 13 'and 14' assays used a comparable amount of pure 0 / W type APG compounds instead of Magic Wet with its multicomponent mixture. In this case, the additional carbon suppliers found in Magic Wet were not used for the growth of the bacteria. The comparison of the biomass production from these 13 'and 14' tests with the comparable variants of the 8 'and 9' tests shows the remarkable decrease in biomass production. In fact, the harvest values of the 13 'and 14' tests are below the biomass production of the 10 'test., that is, the comparison test, which was handled with the same amount of Substral fertilizer but without the addition of Magic Wet. It can be seen here very clearly that the effect of reinforcement of plants, plant stimulation of Magic Wet is not based only on the components of .APG but in the entire mixture Table 3 ariantes dilution of n fertilizer Magic Wet 3 '0.25 5 30 g 15.8 g 4 '0.125 5 30 g 8.7 g 5 0 5 30 g 5.7 g 16 0.5 5 - 36.8 g 17 0.25 5 - 41.5 g 19 0 5 - 35.6 g 8' 0.25 5 15 g 37.4 g 9 '0.125 5 15 g 39.0 g 10 '0 5 15 g 28.1 g 13' 0.114% APG (= = 0.25%] «W) 5 15 g 26.4 g 14 '0.057% APG (= = 0 .125% MW) 5 15 g 19.6 g E p p p 2. 2. A common grass mix in the case of grass surrounding a golf hole (DSV 414 with 80% of Festuca rubra and 20% of Agrostis stolonifera; 20 g / m2) was planted in a 144 cm2 pot, which was filled with a standard grass layer consisting of 20% upper soil and 80% sand (0.2 mm). During the 8-week greenhouse crop, the pasture was liquidly fertilized five times and cut three times (it includes the determination of fresh mass and dry mass). The treatment with the mixture according to the present invention of the applicant under the trade name "Magic Wet" was carried out three times during this period of 8 weeks (week 5, week 7, week 8) in two concentrations, and always after a cut and in conjunction with a liquid fertilizer application (a 0.5% solution of NPK 12-4-6). After 8 weeks of cultivation the plants were transferred to the heated chamber (10 ° C, lit 14/10). After a day of acclimation, inoculation was carried out with a diluted mixture of three isolates of Microdochium nivale, the mold pathogen, through irrigation. After the plants were covered for 8 days with filter paper, under a sheet of plastic in the heated chamber. Then the qualification was made as an optical evaluation ("Bonitur") of the attack with mold. For this purpose, the amount of visible mycelium in percentage of the surface per pot was evaluated. The following treatment variants were tested in each case repeated 10 times: Variants concentration total concentration in the investigation period Control = water Magic wet 1 g / m2 3 g / m3 Magic wet 2 g / m2 6 g / m2 The attack of the Lawn with mold mycelium was found in the control variants at an average of 78%, in the pots treated with Magic Wet, the mold attack was reduced by more than half (comparison table 1). Apart from this health maintenance effect by means of a mixture of active substances according to the present invention, it was also possible to determine a growth promotion, which for example in the case of the variant of 2 g / m2 reached a grass mass fresh greater in 25%. Variants attack-fresh mass dry mass average average fungus (g / pot) (g / pot) Control = water 78% 0.80 0.19 Magic wet 1 g / m2 35% 0.91 0.20 Magic wet 36% 0.97 0.21 The mixture of active ingredients according to the present invention is suitable, in the case of prophylactic use in pastures of golf courses, to protect against strong attacks of fungi. Example 2.2 A mixture of grass usual for turf surrounding the golf hole (DSV 414, 20 g / m2) was planted in 144 cm2 pots, which were filled with a layer of soil for standard turf that consisted of 20% soil upper and 80% sand (0.2 mm). During the 7-week greenhouse culture, the turf was fertilized five times and cut three times (including the determination of fresh mass and dry mass). After 8 weeks of culture, the inoculation with the mold mixture was carried out. Ten days after the inoculation of the harmful pathogens, the grass was sprayed with the treatment variants. The effect of the treatment variants was determined fourteen days after the application by optical evaluation (Bonitur). For this purpose, the amount of mold mycelium visible as a percentage surface area per pot was evaluated. The following treatment variants were made 10 times each: Amount of Derosal Magic Wet 100% = 18 mg / m2 75% 50% 75% 2 g / m2 50% 2 g / m2 control = water The lowest level of mycelium of fungus was achieved in accordance with expectations after treatment with a standard dose of fungicide. However, even the fungicide could not completely eliminate the fungal attack (attack of 25% of the pot surface) (table 4). Reduced amounts of fungicide resulted in a stronger mushroom attack. The addition of 2 g / m2 of "Magic Wet" achieved an increase in the effect, for example in the case of the application of 75% of the usual dose of fungicide a fungal attack of 40% was obtained, with the combined use of Magic Wet, this attack was only 35%. The combined use of Magic Wet also had an effect of promoting biomass. Table 4 Variants of mass: dry mass average average fungus (g / maceta) (g / pot) Control = water 80% 4.0 0.82 100% fungicide 25% 4.1 0.87 75% fungicide 40% 4.1 0.86 75% fungicide + 35 % 4.3 0.88 Magic wet 2 g / m2 50% fungicide 50% 4.1 0.85 50% fungicide + 45% 4.2 0.88 Magic wet 2 g / m2 Since the mixture of active substances according to the present invention - as shown in the examples above - supports the curative effect of fungicides (in the example: Derosal), it can be used especially in cases in which resistance formation can be contemplated, for example in the case of Drechslera, Pythium or Microdochium. The mixture of active substances according to the present invention thus extended the possibilities of using conventional fungicides. For starters, thanks to the use of the active substance mixture according to the present invention, the applied amount of usual fungicides can be reduced, so that the known unfavorable contamination of water, soil and the environment can be limited. The reduction claimed here of the amounts of customary fungicides employed can also be understood as an extension of the period between two applications. In this way the danger of the formation of additional resistance of harmful pathogens is diminished. The mixture of active substances according to the present invention is different from the usual fungicides both for its rapid and complete biological degradation and for its totally different mechanism of action. While the usual fungicides directly transform the metabolism of the harmful pathogens, the mixture of active substances according to the present invention causes a change in the soil which is not yet understood with precision. In this way, the protection of the crop plants against harmful mold-type pathogens that are found in the soil in the case of combined use claimed here of a usual fungicide and the mixture of active substances according to the present invention is based in two different principles that complement each other. EXAMPLE 3 Plant pathogens isolated and cleared in the laboratory were inoculated each time in 4 agar test dishes and the mycelial growth was determined after 5 days of incubation at room temperature. PDA nutrients were used, which after sterile filtration in an autoclave were mixed with the active substance mixture according to the present invention or with the individual components in different concentrations. As control, agar plates without active substance (only with PDA medium) were used. Since many harmful pathogens resistant to fungicides could be developed due to the use of many years, the dishes were treated with the usual fungicides Derosal and Folicur in concentrations of 10 ppm and 100 ppm. Component 1 = Glucopon 215 45.4% by weight Component 2 = HD-Ocenol 80/85 4.9% by weight Component 3 = Edenor GMO 14.6% by weight Results: Pathogen: Pythi um ul timum The mixture of active substances according to the present invention invention is suitable for controlling the growth of Pythium ul timum (table 5). This purpose is achieved from the effect of the entire mixture since the three components tested participate in the inhibition effect. The Derosal * fungicide is not effective against the pathogen, the Folicur fungicide has only limited effectiveness. Table 5 Pythi um ulumum mycelium growth reduction in Average radial variants (mm) compared to control Control = water 54.5 Derosal 10 ppm * 54.3 Derosal 100 ppm * 51.7 5% Folicur 10 ppm 42.3 22% Folicur 100 ppm 0.0 100% Magic wet 150 ppm 31.0 43% Component 1 100 ppm 35 35% Component 2 100 ppm 54 Component 2 5000 ppm 31 43% Component 3 100 ppm 54 Component 3 5000 ppm 35 35% Pathogen: Microdochium nivale Mixture of active substances according to the present invention is suitable for limiting the growth of the pathogen Microdochium nivale (see table 6: for example Magic Wet 150 ppm = 2 g / m2: suppression of the isolate "Nor77" in 50%). This effect is obtained from the total mixture since the three components tested participate in the inhibition effect. Table 6 Microdochium nivale radial mycelial growth variants average (mm) isolated isolated isolated isolated Nor77 386 Sick Nor2 Control = water 22.5 22.3 21.8 22.3 Derosal 10 ppm * 0.0 0.0 0.0 0.0 Derosal 100 ppm * 0.0 0.0 0.0 0.0 Folicur 10 ppm 0.0 3.2 0.0 5.5 Folicur 100 ppm 0.0 0.0 0.0 0.0 Magic wet 10 ppm 20.8 21.0 21.5 22.0 Magic wet 150 ppm 11.0 12.8 14.5 12.3 Microdochium nivale reduction in comparison variants with control insulated isolated insulated isolated Nor77 386 Sick Nor2 Control = water - - - - Derosal 10 ppm * 100% 100% 100% 100% Derosal 100 ppm * 100% 100% 100% 100% Folicur 10 ppm 100% 85% 100% 75% Folicur 100 ppm 100% 100% 100% 100% Magic wet 10 ppm 7.5% 6 %% 1% 1% Magic wet 150 ppm 51% 43% 33% 451 Microdochium nivale growth reduction in radial mycelium variants compared to average (mm) isolated isolated isolated control Nor77 Nor2 Nor77 Nor2 Control = water 24.3 26.5 - - Component 1 100 ppm 29.8 22.0 - 17% Component 1 1500 ppm 12.5 11.8 48% 44% Component 2 100 ppm 17.8 23.7 27% 10% Component 2 5000 ppm 15.9 20.3 34% 23% Component 3 10 ppm 21.3 22.3 12% 16% Component 3 100 ppm 23.8 24.0 2% 9% Especially notable is the finding in isolates that have developed some resistance to the usual fungicides, for example, as shown here: two out of four isolates of M. nivale (table 6). Pathogenic agent: Laetisaria fuciformis The mixture of active substances according to the present invention is suitable for suppressing the growth of the pathogen Laetisaria fuciformis (table 7). The effect is based on the entire mixture since the three components tested participate in the inhibition effect. Table 7 Laetisaria fuciformis reduction growth in radial mycelium variants average comparison (mm) with control Control = water 14.5 Derosal 10 ppm * 0.0 100% Derosal 100 ppm * 0.0 100% Folicur 10 ppm 0.0 100% Folicur 100 ppm 0.0 100% Magic wet 150 ppm 8.5 41% Laetisaria fuciformis reduction growth in radial mycelium variants average comparison (mm) with control Control = water 47.0 Component 1 10 ppm 41.8 11% Component 1 100 ppm 43.0 Component 2 100 ppm 43.0 Component 2 5000 ppm 32.5 31% Component 3 100 ppm 43.3 8% Pathogen: Drechslera dictyoides The mixture of active substances according to the present invention is suitable for suppressing the pathogen Drechslera dictyoides (table 8). The Derosal * fungicide is less efficient than the active substance mixture according to the present invention. Table 8 Drechslera dictyoides reduction growth in radial mycelium variants average comparison (mm) with control Control = water 19.5 Derosal 10 ppm * 16.8 14% Derosal 100 ppm * 14.3 27% Folicur 10 ppm 0.0 100% Folicur 100 ppm 0.0 100% Magic Wet 10 ppm 19.3 1% Magic Wet 100 ppm 12.0 33% Pathogen: Drechslera siccans The mixture of active substances according to the present invention is suitable for suppressing the growth of the pathogen Drechslera siccans (table 9). The fungicide Derosal * is totally ineffective against the harmful pathogen. Table 9 Drechslera siccans reduction growth in radial mycelium variants average comparison (mm) with control Control = water 18.3 Derosal 10 ppm * 19.8 Derosal 100 ppm * 20.0 Folicur 10 ppm 0.0 100% Folicur 100 ppm 0.0 100% Magic Wet 10 ppm 17.5 4 % Magic Wet 100 ppm 16.5 10% Pathogen: Drechslera poae The mixture of active substances according to the present invention is suitable for suppressing the growth of the pathogen Drechslera poae (Table 10). The fungicide Derosal * was ineffective against the harmful pathogen, fungicide Folicur was effective only with high dose. Table 10 Drechslera poae reduction growth in radial mycelium variants average comparison (mm) with control Control = water 6.5 Derosal 10 ppm * 6.5 Derosal 100 ppm * 6.2 5% Folicur 10 ppm 6.2 5% Folicur 100 ppm 0.0 100% Magic Wet 10 ppm 6.5 Magic Wet 100 ppm 5.8 11% The mixture of active substances according to the present invention - as shown in the previous examples - supports the curing effect of the fungicides (in this example: Derosal) and can be used especially in cases where which can be expected to form a resistance, for example in the case of Drechslera, Pythi um or Microdochi um. The mixture of active substances according to the present invention thus expands the possibilities of using conventional fungicides.

Claims (1)

  1. CLAIMS The use of aqueous preparations of fatty alcohols and / or partial esters of fatty acids with lower polyfunctional alcohols in mixture with ecologically acceptable surfactant compounds of the class of alkyl (poly) glycosides of type 0 / W (APG compounds) as a mixture of active substances with an effect of strengthening plants and / or plant sanitation against attacks by phytopathogenic fungi and / or soil pests. Use according to claim 1, characterized in that .APG surfactant compounds based at least mainly on Cs-i4 fatty alcohols are used, wherein the preferred APG compounds are compounds which have at least mainly Cs / io fatty alcohols. in the molecular structure of APG. The use according to claims 1 and 2, characterized in that alkyl oligoglucosides are used as APG compounds. The use according to claims 1 to 3, characterized in that in the mixture of several components fatty alcohols with at least 6 to 8 carbon atoms in the molecule and preferably olefinically monounsaturated and / or polyunsaturated fatty alcohols with 10 to 28 carbon atoms, especially with 12 to 24 carbon atoms in the molecule. 5. The use according to claims 1 to 4, characterized in that fatty alcohols are used which solidify at temperatures equal to / less than 20 ° C and preferably at temperatures equal to / less than 10 to 15 ° C. 6. The use according to claims 1 to 5, characterized in that partial fatty acid esters of polyfunctional alcohols having 2 to 6 carbon atoms, preferably 3 to 5 carbon atoms and especially partial glycerin esters are used. The use according to claims 1 to 6, characterized in that the partial fatty acid esters are derived from C?-2 and especially C-xz-zo fatty acids, so monounsaturated fatty acids are also preferred here. / or polyunsaturated. The use according to claims 1 to 7, characterized in that the partial glycerin esters are used with olefinically unsaturated U.sub.β / isomers and especially glycerin monooleate. The use according to claims 1 to 8, characterized in that the fatty alcohols and the partial esters and also the APG compounds are preferably based on natural elements. 10. The use according to claims 1 to 9, characterized in that the fatty alcohols and partial fatty acid esters are used in mixing ratios (parts by weight of anhydrous components) of 1: 1 to 1:10, preferably from 1: 1 to 1: 5, and especially from 1: 1 to 1: 3. 11 The employment in accordance with claims 1 to 10, characterized in that the APG components are used in at least similar amounts by weight - in relation to fatty alcohols and / or partial esters - for which preference is given to mixing proportions of APG: fatty alcohol and / or partial ester within a range from 1: 1 to 5: 1, preferably from 1: 1 to 3: 1, and especially from 1.5 to 2.5: 1 - parts by weight each time relative to the anhydrous component or to the anhydrous components of the mixture. 12 The employment according to claims 1 to 11, characterized in that lower polyvalent alcohols are preferably added to the active compound mixtures, preferably with 2 to 6 carbon atoms, especially with 2 to 4 carbon atoms, and very particularly glycerin and / or glycol. The use according to claims 1 to 12, characterized in that dilute aqueous preparations prepared from fluid concentrates of the mixtures of active substances provided are used, which, as additional viscosity regulators, contain monofunctional alcohols preferably lower than 1. to 4 carbon atoms, and especially ethanol. The use according to claims 1 to 13, characterized in that the mixtures of several components contain, apart from the fatty alcohols or instead of the fatty alcohols, terpene alcohols as components of the mixture. The use according to claims 1 to 14, characterized in that the mixtures of several components - in relation to the anhydrous mixture - are applied in quantities of 0.5 to 35 g / m2, preferably in quantities of 1 to 20 g / m2 and with special preference in amounts up to 15 g / m2 and preferably sprayed in the form of fine aqueous emulsions / dispersions. The use according to claims 1 to 15, characterized in that dilute aqueous mixtures are used in which the weight ratio of active ingredient mixture of several components: water is at least 1:10, and preferably at least 1: 15 to 20. The use according to claims 1 to 16, characterized in that the mixtures of several components are used in the field of commercial production of plants, in agriculture as well as in commercial or private gardening.
MXPA01000273A 1998-07-10 1999-07-01 Plant growth enhancement against phytopathogenic fungi and/or soil borne pests. MXPA01000273A (en)

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