MX9706651A - Preparacion de pirazoles sustituidos en la posicion n. - Google Patents
Preparacion de pirazoles sustituidos en la posicion n.Info
- Publication number
- MX9706651A MX9706651A MX9706651A MX9706651A MX9706651A MX 9706651 A MX9706651 A MX 9706651A MX 9706651 A MX9706651 A MX 9706651A MX 9706651 A MX9706651 A MX 9706651A MX 9706651 A MX9706651 A MX 9706651A
- Authority
- MX
- Mexico
- Prior art keywords
- general formula
- alkyl
- preparing
- phenylalkyl
- pyrazole
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Plural Heterocyclic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Un proceso para la preparacion de pirazoles sustituidos en N, de la formula general I, en donde R1 es alquilo de C1-C12 o fenilalquilo de C7-C20 y R2 y R4 son, independientemente entre sí, hidrogeno, alquilo de C1-C12-, fenilalquilo de C7-C20 o radicales arilo no sustituidos o sustituidos, mediante la reaccion de los pirazoles de la formula general II; en donde R2, R3 y R4 tienen los significados antes mencionados, con un alcohol de la formula general III, en donde R1 tiene el significado antes mencionado, a 50 - 400 degree C en presencia de un catalizador, en donde la reaccion del pirazol II con el compuesto III en la proporcion molar desde 0.001:1 a 1:1 se lleva a cabo en fase líquida bajo una presion que es ligeramente abajo de la atmosférica o hasta una presion de 250 bar y se utilizan ácidos y/o sus ésteres de alquilo o sus anhídridos, en una relacion molar desde 0.0001:1 hasta 0.5:1 con respecto al pirazol II, como catalizador.
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19507600.1 | 1995-03-04 | ||
DE19507600 | 1995-03-04 | ||
DE19509361.5 | 1995-03-15 | ||
DE1995109361 DE19509361A1 (de) | 1995-03-15 | 1995-03-15 | Verfahren zur Herstellung von N-substituierten Pyrazolen |
DE19509958.3 | 1995-03-18 | ||
DE1995109958 DE19509958A1 (de) | 1995-03-18 | 1995-03-18 | Verfahren zur Herstellung von N-substituierten Pyrazolen |
PCT/EP1996/000790 WO1996027589A1 (de) | 1995-03-04 | 1996-02-27 | Verfahren zur herstellung von n-substituierten pyrazolen |
Publications (2)
Publication Number | Publication Date |
---|---|
MX9706651A true MX9706651A (es) | 1997-11-29 |
MXPA97006651A MXPA97006651A (es) | 1998-07-03 |
Family
ID=
Also Published As
Publication number | Publication date |
---|---|
EP0813526B1 (de) | 2004-02-04 |
NZ303185A (en) | 1999-01-28 |
ES2216045T3 (es) | 2004-10-16 |
FI973592A (fi) | 1997-09-03 |
EA199700192A1 (ru) | 1998-02-26 |
WO1996027589A1 (de) | 1996-09-12 |
KR100403092B1 (ko) | 2004-02-18 |
NO307882B1 (no) | 2000-06-13 |
ATE258922T1 (de) | 2004-02-15 |
FI973592A0 (fi) | 1997-09-03 |
BG101908A (en) | 1998-05-29 |
JPH11501040A (ja) | 1999-01-26 |
KR19980702736A (ko) | 1998-08-05 |
EA000257B1 (ru) | 1999-02-25 |
TR199700896T1 (xx) | 1998-01-21 |
US5840913A (en) | 1998-11-24 |
PL183813B1 (pl) | 2002-07-31 |
FI120395B (fi) | 2009-10-15 |
PL322114A1 (en) | 1998-01-05 |
EP0813526A1 (de) | 1997-12-29 |
IL117290A0 (en) | 1996-06-18 |
AU698827B2 (en) | 1998-11-05 |
AU4941896A (en) | 1996-09-23 |
IL117290A (en) | 2001-01-11 |
CZ268697A3 (en) | 1997-12-17 |
CA2213853A1 (en) | 1996-09-12 |
BR9607649A (pt) | 1998-06-16 |
DE59610910D1 (de) | 2004-03-11 |
NO974044D0 (no) | 1997-09-03 |
BG63304B1 (bg) | 2001-09-28 |
TW340114B (en) | 1998-09-11 |
CN1070479C (zh) | 2001-09-05 |
SK117697A3 (en) | 1998-02-04 |
CN1177348A (zh) | 1998-03-25 |
NO974044L (no) | 1997-09-03 |
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