MX370708B - Reactor para reacciones de fluoración en fase líquida. - Google Patents
Reactor para reacciones de fluoración en fase líquida.Info
- Publication number
- MX370708B MX370708B MX2016010291A MX2016010291A MX370708B MX 370708 B MX370708 B MX 370708B MX 2016010291 A MX2016010291 A MX 2016010291A MX 2016010291 A MX2016010291 A MX 2016010291A MX 370708 B MX370708 B MX 370708B
- Authority
- MX
- Mexico
- Prior art keywords
- reactor
- reaction zone
- liquid phase
- hydrofluorination
- fluoroolefin
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/07—Preparation of halogenated hydrocarbons by addition of hydrogen halides
- C07C17/087—Preparation of halogenated hydrocarbons by addition of hydrogen halides to unsaturated halogenated hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0053—Details of the reactor
- B01J19/0066—Stirrers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/42—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
- C07C19/08—Acyclic saturated compounds containing halogen atoms containing fluorine
- C07C19/10—Acyclic saturated compounds containing halogen atoms containing fluorine and chlorine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1868—Stationary reactors having moving elements inside resulting in a loop-type movement
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
- Catalysts (AREA)
Abstract
La presente invención se refiere a un procedimiento de hidrofluoración que comprende hacer reaccionar una fluoroolefina con fluoruro de hidrógeno en la fase líquida en presencia de un catalizador de hidrofluoración en la zona de reacción de un reactor, dicho reactor compuesto de un cuerpo del reactor que tiene una relación de longitud a diámetro de aproximadamente 2: 1 o mayor; una zona de reacción agitada que contiene el catalizador de hidrofluoración, que se puede preparar in situ, al menos una entrada para el suministro del fluoruro de hidrógeno y fluoroolefina a la zona de reacción y al menos una salida para recuperar dicho fluoroalcano, el agitador dispuesto en la zona de reacción y que comprende una pluralidad de aspas unidas fijamente al eje accionable por un motor, las aspas que se extienden desde aproximadamente la parte inferior de la zona de reacción a aproximadamente la parte superior de la zona de reacción y el eje que se extiende en un eje longitudinal de la parte inferior del reactor a la parte superior del reactor, el agitador se hace girar a una velocidad suficiente para promover un remolino de líquido para efectuar la ocurrencia de la reacción de hidrofluoración y minimizar sobrefluoración. La presente invención se refiere también al reactor de hidrofluoración.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201461937822P | 2014-02-10 | 2014-02-10 | |
PCT/US2015/014759 WO2015120234A1 (en) | 2014-02-10 | 2015-02-06 | Reactor for liquid phase fluorination reactions |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2016010291A MX2016010291A (es) | 2016-10-17 |
MX370708B true MX370708B (es) | 2019-12-20 |
Family
ID=53774351
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2016010291A MX370708B (es) | 2014-02-10 | 2015-02-06 | Reactor para reacciones de fluoración en fase líquida. |
Country Status (8)
Country | Link |
---|---|
US (1) | US9353028B2 (es) |
EP (1) | EP3104965B1 (es) |
JP (1) | JP6648039B2 (es) |
KR (1) | KR20160122786A (es) |
CN (1) | CN107073429A (es) |
ES (1) | ES2753547T3 (es) |
MX (1) | MX370708B (es) |
WO (1) | WO2015120234A1 (es) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105026350A (zh) * | 2013-03-13 | 2015-11-04 | 霍尼韦尔国际公司 | 分级氟化方法和反应器系统 |
GB201712775D0 (en) * | 2017-08-09 | 2017-09-20 | Mexichem Fluor Sa De Cv | Compositions and uses thereof |
WO2019035145A1 (en) * | 2017-08-18 | 2019-02-21 | Ganapati Dadasaheb Yadav | ENHANCED CONTINUOUSLY CONTINUOUS IMPROVED MULTIPHASE REACTOR |
CN109988101B (zh) * | 2017-12-29 | 2022-06-07 | 沈阳化工研究院有限公司 | 2-氟-6-三氟甲基吡啶的合成方法 |
JP2021084077A (ja) * | 2019-11-28 | 2021-06-03 | 住友金属鉱山株式会社 | 攪拌装置及び気液混合方法 |
JP7447471B2 (ja) * | 2019-12-19 | 2024-03-12 | 住友金属鉱山株式会社 | 攪拌装置 |
CN113457579B (zh) * | 2021-06-25 | 2022-11-22 | 中核四0四有限公司 | 一种二氧化铀氢氟化工艺尾气中氟化氢的再利用工艺 |
CN117695947A (zh) * | 2024-02-05 | 2024-03-15 | 上海联风气体有限公司 | 氢氟酸回收装置 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62183848A (ja) * | 1986-02-07 | 1987-08-12 | Shokuhin Sangyo Baioriakutaa Syst Gijutsu Kenkyu Kumiai | 撹拌式充填層型反応器 |
DE19544871C2 (de) * | 1995-12-01 | 1998-02-26 | Hoechst Ag | Verfahren zur Herstellung und Aufarbeitung von fluorhaltigen organischen Verbindungen |
AU9402398A (en) * | 1997-09-22 | 1999-04-12 | Allied-Signal Inc. | Pipe reactor |
CA2333472C (en) * | 1998-06-02 | 2008-12-16 | E.I. Du Pont De Nemours And Company | Processes for the production of hexafluoropropene and optionally other halogenated hydrocarbons containing fluorine |
US20090182179A1 (en) * | 2008-01-15 | 2009-07-16 | Honeywell International Inc. | Hydrofluorination of 2-chloro-3,3,3-trifluoropropene to 2-chloro-1,1,1,2-tetrafluoropropane with catalysts of sbcl3, sbcl5, sbf5, ticl4, sncl4, cr2o3 and fluorinated cr2o3 |
US8058486B2 (en) * | 2004-04-29 | 2011-11-15 | Honeywell International Inc. | Integrated process to produce 2,3,3,3-tetrafluoropropene |
US8084653B2 (en) * | 2004-04-29 | 2011-12-27 | Honeywell International, Inc. | Method for producing fluorinated organic compounds |
CN101597209A (zh) * | 2008-03-20 | 2009-12-09 | 霍尼韦尔国际公司 | 用于制备2,3,3,3-四氟丙烯的一体式方法 |
US8916733B2 (en) * | 2008-06-17 | 2014-12-23 | Honeywell International Inc. | Processes for hydrofluorination of 2-chloro-3,3,3-trifluoropropene to 2-chloro-1,1,1,2-tetrafluoropropane |
US8975454B2 (en) * | 2008-07-31 | 2015-03-10 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
US8252965B2 (en) * | 2008-08-22 | 2012-08-28 | Honeywell International Inc. | Method for separating halocarbons |
KR20120084729A (ko) * | 2009-10-09 | 2012-07-30 | 다우 글로벌 테크놀로지스 엘엘씨 | 염화 및/또는 불화 프로펜 및 고급 알켄의 제조 방법 |
US9890096B2 (en) * | 2011-01-19 | 2018-02-13 | Honeywell International Inc. | Methods of making 2,3,3,3-tetrafluoro-2-propene |
MX336250B (es) * | 2011-06-08 | 2016-01-13 | Dow Agrosciences Llc | Proceso para la produccion de propenos clorados y/o fluorados. |
CN102442880B (zh) * | 2011-10-22 | 2014-05-21 | 山东东岳高分子材料有限公司 | 一种2,3,3,3-四氟丙烯的制备方法 |
CN203002341U (zh) * | 2012-12-20 | 2013-06-19 | 杭州索孚机械有限公司 | 新型高效气-液-固三相混合自吸式搅拌机 |
CN105026350A (zh) * | 2013-03-13 | 2015-11-04 | 霍尼韦尔国际公司 | 分级氟化方法和反应器系统 |
CN103508842B (zh) * | 2013-09-28 | 2016-01-13 | 西安近代化学研究所 | 1,2-二氯-3,3,3-三氟丙烯的制备方法 |
-
2015
- 2015-02-06 JP JP2016568467A patent/JP6648039B2/ja active Active
- 2015-02-06 MX MX2016010291A patent/MX370708B/es active IP Right Grant
- 2015-02-06 WO PCT/US2015/014759 patent/WO2015120234A1/en active Application Filing
- 2015-02-06 ES ES15747067T patent/ES2753547T3/es active Active
- 2015-02-06 KR KR1020167025080A patent/KR20160122786A/ko not_active Application Discontinuation
- 2015-02-06 EP EP15747067.5A patent/EP3104965B1/en active Active
- 2015-02-06 CN CN201580007960.3A patent/CN107073429A/zh active Pending
- 2015-02-10 US US14/618,500 patent/US9353028B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
EP3104965A4 (en) | 2017-08-02 |
CN107073429A (zh) | 2017-08-18 |
KR20160122786A (ko) | 2016-10-24 |
JP2017511811A (ja) | 2017-04-27 |
MX2016010291A (es) | 2016-10-17 |
EP3104965A1 (en) | 2016-12-21 |
US9353028B2 (en) | 2016-05-31 |
US20150225316A1 (en) | 2015-08-13 |
EP3104965B1 (en) | 2019-09-25 |
WO2015120234A1 (en) | 2015-08-13 |
JP6648039B2 (ja) | 2020-02-14 |
ES2753547T3 (es) | 2020-04-13 |
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Legal Events
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