MX370346B - Resina de rotomoldeo bimodal con resistencia mejorada al agrietamiento por estrés ambiental (escr). - Google Patents
Resina de rotomoldeo bimodal con resistencia mejorada al agrietamiento por estrés ambiental (escr).Info
- Publication number
- MX370346B MX370346B MX2016004602A MX2016004602A MX370346B MX 370346 B MX370346 B MX 370346B MX 2016004602 A MX2016004602 A MX 2016004602A MX 2016004602 A MX2016004602 A MX 2016004602A MX 370346 B MX370346 B MX 370346B
- Authority
- MX
- Mexico
- Prior art keywords
- resin
- astm
- determined according
- bimodal
- rotomolding
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/003—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/04—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/18—Bulk density
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Moulding By Coating Moulds (AREA)
Abstract
La presente invención proporciona una resina adecuada para el uso en el moldeo rotacional que tiene una resistencia al agrietamiento por esfuerzo ambiental mayor de1000 horas. La resina tiene una densidad de 0.937 a 0.942 g/cm3, un índice de fusión I2 determinado de acuerdo a ASTM D 1238 (2.16 kg 190°C - I2) de 4.0 a 7.0 g/10 min, un I21 determinado de acuerdo a ASTM D 1238 (2.16 kg 190°C -I21) de 160 a 200 g/10 min, una I21/I2 de 30 a 40 y una insaturación de vinilo terminal mayor de 0.06, por 1000 átomos de carbono; y un parámetro de estructura primaria (PSP2) de 4-7, y una Mw/Mn total de 2.7 a 3.5 que comprende de 2 a 5% en peso de uno o más comonómeros de C4-8 alfa olefina.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2834068A CA2834068C (en) | 2013-11-18 | 2013-11-18 | Enhanced escr bimodal rotomolding resin |
PCT/IB2014/065855 WO2015071807A1 (en) | 2013-11-18 | 2014-11-06 | Enhanced escr bimodal rotomolding resin |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2016004602A MX2016004602A (es) | 2016-07-06 |
MX370346B true MX370346B (es) | 2019-12-10 |
Family
ID=51945966
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2016004602A MX370346B (es) | 2013-11-18 | 2014-11-06 | Resina de rotomoldeo bimodal con resistencia mejorada al agrietamiento por estrés ambiental (escr). |
Country Status (11)
Country | Link |
---|---|
US (2) | US9181422B2 (es) |
EP (2) | EP3540007B1 (es) |
JP (2) | JP6445578B2 (es) |
KR (1) | KR102256256B1 (es) |
CN (1) | CN105705572B (es) |
BR (1) | BR112016011268B1 (es) |
CA (1) | CA2834068C (es) |
DK (2) | DK3071643T3 (es) |
ES (2) | ES2853731T3 (es) |
MX (1) | MX370346B (es) |
WO (1) | WO2015071807A1 (es) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2834068C (en) * | 2013-11-18 | 2020-07-28 | Nova Chemicals Corporation | Enhanced escr bimodal rotomolding resin |
JP6778481B2 (ja) * | 2015-11-11 | 2020-11-04 | 旭化成株式会社 | ポリエチレン系重合体及びその製造方法、ポリエチレン系重合体組成物、並びに架橋パイプ |
US9783664B1 (en) * | 2016-06-01 | 2017-10-10 | Nova Chemicals (International) S.A. | Hinged component comprising polyethylene composition |
KR101958015B1 (ko) * | 2016-11-08 | 2019-07-04 | 주식회사 엘지화학 | 에틸렌/알파-올레핀 공중합체 |
SG11201903393RA (en) * | 2016-11-08 | 2019-05-30 | Univation Tech Llc | Bimodal polyethylene |
EP3415540B1 (en) | 2016-11-15 | 2022-09-14 | LG Chem, Ltd. | Ethylene/alpha-olefin copolymer having excellent environmental stress crack resistance |
US20220227902A1 (en) * | 2019-05-31 | 2022-07-21 | Nova Chemicals (International) S.A. | Enhanced escr and ductility bimodal rotomolding resin |
EP4003684A1 (en) * | 2019-07-25 | 2022-06-01 | Nova Chemicals (International) S.A. | Rotomolded parts prepared from bimodal polyethylene |
CN110540690A (zh) * | 2019-09-04 | 2019-12-06 | 浙江大学 | 一种双峰高密度聚乙烯树脂及其制备方法 |
CN115362207B (zh) * | 2020-04-20 | 2024-01-09 | 诺瓦化学品(国际)股份有限公司 | 具有低相对弹性的滚塑组合物 |
US11746220B2 (en) | 2020-06-12 | 2023-09-05 | Braskem S.A. | High flow rotomolding compositions, processes thereof, and articles therefrom |
JP2024507555A (ja) | 2021-02-24 | 2024-02-20 | ノバ ケミカルズ(インターナショナル)ソシエテ アノニム | 二峰性ポリエチレン組成物 |
CN117015463A (zh) | 2021-03-19 | 2023-11-07 | 诺瓦化学品(国际)股份有限公司 | 高密度聚乙烯组合物 |
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US5382631A (en) | 1988-09-30 | 1995-01-17 | Exxon Chemical Patents Inc. | Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distributions |
US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
JPH03115445A (ja) * | 1989-09-29 | 1991-05-16 | Nippon Petrochem Co Ltd | エチレン系重合体組成物 |
DE69309726T2 (de) | 1992-01-23 | 1997-08-21 | Mitsui Petrochemical Ind | Ethylen/Alpha-Olefin/7-Methyl-1,6-Octadien Copolymerisat-Kautschuk und Zusammensetzungen desselben |
CA2245375C (en) * | 1998-08-19 | 2006-08-15 | Nova Chemicals Ltd. | Dual reactor polyethylene process using a phosphinimine catalyst |
DE19849426A1 (de) * | 1998-10-27 | 2000-05-04 | Elenac Gmbh | Bimodale Polyethylen-Blends mit hoher Mischgüte |
JP2001089615A (ja) * | 1999-07-16 | 2001-04-03 | Mitsui Chemicals Inc | 回転成形用ポリエチレン樹脂組成物およびその組成物を用いた回転成形体 |
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DE60331562D1 (es) * | 2002-10-01 | 2010-04-15 | Exxonmobil Chem Patents Inc | |
CN1313528C (zh) * | 2002-10-01 | 2007-05-02 | 埃克森美孚化学专利公司 | 用于旋转模塑的聚乙烯组合物 |
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CA2777386C (en) * | 2012-05-17 | 2020-06-30 | Nova Chemicals Corporation | Rotomolding resin |
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CA2798854C (en) * | 2012-12-14 | 2020-02-18 | Nova Chemicals Corporation | Polyethylene compositions having high dimensional stability and excellent processability for caps and closures |
CA2800056A1 (en) * | 2012-12-24 | 2014-06-24 | Nova Chemicals Corporation | Polyethylene blend compositions |
CA2834068C (en) * | 2013-11-18 | 2020-07-28 | Nova Chemicals Corporation | Enhanced escr bimodal rotomolding resin |
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2013
- 2013-11-18 CA CA2834068A patent/CA2834068C/en active Active
-
2014
- 2014-11-06 DK DK14802198.3T patent/DK3071643T3/da active
- 2014-11-06 ES ES19172134T patent/ES2853731T3/es active Active
- 2014-11-06 DK DK19172134.9T patent/DK3540007T3/da active
- 2014-11-06 BR BR112016011268-7A patent/BR112016011268B1/pt active IP Right Grant
- 2014-11-06 WO PCT/IB2014/065855 patent/WO2015071807A1/en active Application Filing
- 2014-11-06 ES ES14802198T patent/ES2749153T3/es active Active
- 2014-11-06 KR KR1020167013706A patent/KR102256256B1/ko active IP Right Grant
- 2014-11-06 MX MX2016004602A patent/MX370346B/es active IP Right Grant
- 2014-11-06 EP EP19172134.9A patent/EP3540007B1/en active Active
- 2014-11-06 JP JP2016553750A patent/JP6445578B2/ja active Active
- 2014-11-06 EP EP14802198.3A patent/EP3071643B1/en active Active
- 2014-11-06 CN CN201480062852.1A patent/CN105705572B/zh active Active
- 2014-11-07 US US14/535,612 patent/US9181422B2/en active Active
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2015
- 2015-09-17 US US14/856,622 patent/US9540505B2/en active Active
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2018
- 2018-11-28 JP JP2018222599A patent/JP6707613B2/ja active Active
Also Published As
Publication number | Publication date |
---|---|
CN105705572A (zh) | 2016-06-22 |
WO2015071807A1 (en) | 2015-05-21 |
BR112016011268B1 (pt) | 2021-10-05 |
US20160002448A1 (en) | 2016-01-07 |
CA2834068C (en) | 2020-07-28 |
JP2019044195A (ja) | 2019-03-22 |
JP2016538413A (ja) | 2016-12-08 |
US9181422B2 (en) | 2015-11-10 |
US20150141579A1 (en) | 2015-05-21 |
EP3071643B1 (en) | 2019-08-14 |
DK3540007T3 (da) | 2021-01-25 |
JP6445578B2 (ja) | 2018-12-26 |
JP6707613B2 (ja) | 2020-06-10 |
CA2834068A1 (en) | 2015-05-18 |
MX2016004602A (es) | 2016-07-06 |
CN105705572B (zh) | 2018-12-14 |
BR112016011268A2 (pt) | 2017-08-08 |
ES2853731T3 (es) | 2021-09-17 |
EP3540007B1 (en) | 2020-12-30 |
DK3071643T3 (da) | 2019-10-21 |
US9540505B2 (en) | 2017-01-10 |
KR102256256B1 (ko) | 2021-05-27 |
KR20160088876A (ko) | 2016-07-26 |
ES2749153T3 (es) | 2020-03-19 |
EP3071643A1 (en) | 2016-09-28 |
EP3540007A1 (en) | 2019-09-18 |
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