MX2016004602A - Resina de rotomoldeo bimodal con resistencia mejorada al agrietamiento por estrés ambiental (escr). - Google Patents

Resina de rotomoldeo bimodal con resistencia mejorada al agrietamiento por estrés ambiental (escr).

Info

Publication number
MX2016004602A
MX2016004602A MX2016004602A MX2016004602A MX2016004602A MX 2016004602 A MX2016004602 A MX 2016004602A MX 2016004602 A MX2016004602 A MX 2016004602A MX 2016004602 A MX2016004602 A MX 2016004602A MX 2016004602 A MX2016004602 A MX 2016004602A
Authority
MX
Mexico
Prior art keywords
resin
astm
determined according
bimodal
rotomolding
Prior art date
Application number
MX2016004602A
Other languages
English (en)
Other versions
MX370346B (es
Inventor
Marie Therese Celine Bellehumeur
Mark Hoidas
Original Assignee
Nova Chem Int Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nova Chem Int Sa filed Critical Nova Chem Int Sa
Publication of MX2016004602A publication Critical patent/MX2016004602A/es
Publication of MX370346B publication Critical patent/MX370346B/es

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/003—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
    • B29C41/04—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18—Bulk density
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

La presente invención proporciona una resina adecuada para el uso en el moldeo rotacional que tiene una resistencia al agrietamiento por esfuerzo ambiental mayor de1000 horas. La resina tiene una densidad de 0.937 a 0.942 g/cm3, un índice de fusión I2 determinado de acuerdo a ASTM D 1238 (2.16 kg 190°C - I2) de 4.0 a 7.0 g/10 min, un I21 determinado de acuerdo a ASTM D 1238 (2.16 kg 190°C -I21) de 160 a 200 g/10 min, una I21/I2 de 30 a 40 y una insaturación de vinilo terminal mayor de 0.06, por 1000 átomos de carbono; y un parámetro de estructura primaria (PSP2) de 4-7, y una Mw/Mn total de 2.7 a 3.5 que comprende de 2 a 5% en peso de uno o más comonómeros de C4-8 alfa olefina.
MX2016004602A 2013-11-18 2014-11-06 Resina de rotomoldeo bimodal con resistencia mejorada al agrietamiento por estrés ambiental (escr). MX370346B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA2834068A CA2834068C (en) 2013-11-18 2013-11-18 Enhanced escr bimodal rotomolding resin
PCT/IB2014/065855 WO2015071807A1 (en) 2013-11-18 2014-11-06 Enhanced escr bimodal rotomolding resin

Publications (2)

Publication Number Publication Date
MX2016004602A true MX2016004602A (es) 2016-07-06
MX370346B MX370346B (es) 2019-12-10

Family

ID=51945966

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016004602A MX370346B (es) 2013-11-18 2014-11-06 Resina de rotomoldeo bimodal con resistencia mejorada al agrietamiento por estrés ambiental (escr).

Country Status (11)

Country Link
US (2) US9181422B2 (es)
EP (2) EP3540007B1 (es)
JP (2) JP6445578B2 (es)
KR (1) KR102256256B1 (es)
CN (1) CN105705572B (es)
BR (1) BR112016011268B1 (es)
CA (1) CA2834068C (es)
DK (2) DK3071643T3 (es)
ES (2) ES2749153T3 (es)
MX (1) MX370346B (es)
WO (1) WO2015071807A1 (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2834068C (en) * 2013-11-18 2020-07-28 Nova Chemicals Corporation Enhanced escr bimodal rotomolding resin
JP6778481B2 (ja) * 2015-11-11 2020-11-04 旭化成株式会社 ポリエチレン系重合体及びその製造方法、ポリエチレン系重合体組成物、並びに架橋パイプ
US9783664B1 (en) * 2016-06-01 2017-10-10 Nova Chemicals (International) S.A. Hinged component comprising polyethylene composition
SG11201903393RA (en) * 2016-11-08 2019-05-30 Univation Tech Llc Bimodal polyethylene
KR101958015B1 (ko) 2016-11-08 2019-07-04 주식회사 엘지화학 에틸렌/알파-올레핀 공중합체
EP3415540B1 (en) 2016-11-15 2022-09-14 LG Chem, Ltd. Ethylene/alpha-olefin copolymer having excellent environmental stress crack resistance
KR102658325B1 (ko) * 2019-05-31 2024-04-19 노바 케미컬즈 (인터내셔널) 소시에테 아노님 향상된 escr 및 연성 바이모달 회전성형 수지
MX2022000615A (es) * 2019-07-25 2022-03-11 Nova Chem Int Sa Piezas rotomoldeadas preparadas a partir de polietileno bimodal.
CN110540690A (zh) * 2019-09-04 2019-12-06 浙江大学 一种双峰高密度聚乙烯树脂及其制备方法
MX2022012176A (es) * 2020-04-20 2022-10-27 Nova Chem Int Sa Composiciones para rotomoldeo de baja elasticidad relativa.
US11746220B2 (en) 2020-06-12 2023-09-05 Braskem S.A. High flow rotomolding compositions, processes thereof, and articles therefrom
JP2024507555A (ja) 2021-02-24 2024-02-20 ノバ ケミカルズ（インターナショナル）ソシエテ アノニム 二峰性ポリエチレン組成物
BR112023018965A2 (pt) 2021-03-19 2023-10-17 Nova Chem Int Sa Composição de polietileno de alta densidade

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5382630A (en) 1988-09-30 1995-01-17 Exxon Chemical Patents Inc. Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distribution
US5382631A (en) 1988-09-30 1995-01-17 Exxon Chemical Patents Inc. Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distributions
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
JPH03115445A (ja) * 1989-09-29 1991-05-16 Nippon Petrochem Co Ltd エチレン系重合体組成物
US5292845A (en) 1992-01-23 1994-03-08 Mitsui Petrochemical Industries, Ltd. Ethylene/alpha-olefin/7-methyl-1,6-octadiene copolymer rubber and composition of the same
CA2245375C (en) * 1998-08-19 2006-08-15 Nova Chemicals Ltd. Dual reactor polyethylene process using a phosphinimine catalyst
DE19849426A1 (de) * 1998-10-27 2000-05-04 Elenac Gmbh Bimodale Polyethylen-Blends mit hoher Mischgüte
JP2001089615A (ja) * 1999-07-16 2001-04-03 Mitsui Chemicals Inc 回転成形用ポリエチレン樹脂組成物およびその組成物を用いた回転成形体
EP1304353A1 (en) * 2001-10-18 2003-04-23 Atofina Research S.A. Physical blends of polyethylenes
CN100420711C (zh) * 2002-10-01 2008-09-24 埃克森美孚化学专利公司 用于注塑的聚乙烯组合物
BR0314857A (pt) * 2002-10-01 2005-08-02 Exxonmobil Chemical Patentes I Composições de polietileno para moldagem de rotação
US7790826B2 (en) 2004-05-06 2010-09-07 DowGlobal Technologies Inc. Polymer molding compositions
US7230054B2 (en) * 2004-06-29 2007-06-12 Equistar Chemicals, Lp Polymer resins with improved environmental stress crack resistance
US7393916B2 (en) * 2005-11-01 2008-07-01 Univation Technologies, Llc Method of reducing gels in polyolefins
US7803629B2 (en) 2006-06-27 2010-09-28 Chevron Phillips Chemical Company, Lp Method for employing SEC-FTIR data to predict mechanical properties of polyethylene
CA2629576C (en) * 2008-04-21 2016-01-05 Nova Chemicals Corporation Closures for bottles
US8114946B2 (en) 2008-12-18 2012-02-14 Chevron Phillips Chemical Company Lp Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches
MY162909A (en) 2009-08-28 2017-07-31 Univation Tech Llc Rotational molded articles, and method of making the same
US8492498B2 (en) 2011-02-21 2013-07-23 Chevron Phillips Chemical Company Lp Polymer compositions for rotational molding applications
CA2752407C (en) * 2011-09-19 2018-12-04 Nova Chemicals Corporation Polyethylene compositions and closures for bottles
CA2777386C (en) * 2012-05-17 2020-06-30 Nova Chemicals Corporation Rotomolding resin
US9115233B2 (en) * 2012-06-21 2015-08-25 Nova Chemicals (International) S.A. Ethylene copolymer compositions, film and polymerization processes
CA2798854C (en) * 2012-12-14 2020-02-18 Nova Chemicals Corporation Polyethylene compositions having high dimensional stability and excellent processability for caps and closures
CA2800056A1 (en) * 2012-12-24 2014-06-24 Nova Chemicals Corporation Polyethylene blend compositions
CA2834068C (en) * 2013-11-18 2020-07-28 Nova Chemicals Corporation Enhanced escr bimodal rotomolding resin

Also Published As

Publication number Publication date
JP6707613B2 (ja) 2020-06-10
CA2834068A1 (en) 2015-05-18
CN105705572A (zh) 2016-06-22
EP3071643A1 (en) 2016-09-28
WO2015071807A1 (en) 2015-05-21
EP3540007A1 (en) 2019-09-18
BR112016011268A2 (pt) 2017-08-08
DK3540007T3 (da) 2021-01-25
US9181422B2 (en) 2015-11-10
DK3071643T3 (da) 2019-10-21
ES2853731T3 (es) 2021-09-17
CA2834068C (en) 2020-07-28
EP3540007B1 (en) 2020-12-30
JP6445578B2 (ja) 2018-12-26
KR20160088876A (ko) 2016-07-26
BR112016011268B1 (pt) 2021-10-05
CN105705572B (zh) 2018-12-14
JP2019044195A (ja) 2019-03-22
ES2749153T3 (es) 2020-03-19
KR102256256B1 (ko) 2021-05-27
MX370346B (es) 2019-12-10
EP3071643B1 (en) 2019-08-14
US20160002448A1 (en) 2016-01-07
JP2016538413A (ja) 2016-12-08
US20150141579A1 (en) 2015-05-21
US9540505B2 (en) 2017-01-10

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