MX357878B - Proceso para la purificación del ácido fluorhídrico incluyendo la obtención del subproducto ácido arsenioso. - Google Patents

Proceso para la purificación del ácido fluorhídrico incluyendo la obtención del subproducto ácido arsenioso.

Info

Publication number
MX357878B
MX357878B MX2014015885A MX2014015885A MX357878B MX 357878 B MX357878 B MX 357878B MX 2014015885 A MX2014015885 A MX 2014015885A MX 2014015885 A MX2014015885 A MX 2014015885A MX 357878 B MX357878 B MX 357878B
Authority
MX
Mexico
Prior art keywords
purification
arsenic
product
acid
hydrofluoric acid
Prior art date
Application number
MX2014015885A
Other languages
English (en)
Other versions
MX2014015885A (es
Inventor
Samantha Duran Castillo Iris
Alberto Juarez Garcia Juan
Martinez Robles Nilo
Original Assignee
Mexichem Fluor Sa De Capital Variable
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mexichem Fluor Sa De Capital Variable filed Critical Mexichem Fluor Sa De Capital Variable
Priority to MX2014015885A priority Critical patent/MX357878B/es
Priority to US14/640,387 priority patent/US9896334B2/en
Publication of MX2014015885A publication Critical patent/MX2014015885A/es
Publication of MX357878B publication Critical patent/MX357878B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/19—Fluorine; Hydrogen fluoride
    • C01B7/191—Hydrogen fluoride
    • C01B7/195—Separation; Purification
    • C01B7/196—Separation; Purification by distillation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/007—Energy recuperation; Heat pumps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B01D3/143—Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G28/00—Compounds of arsenic
    • C01G28/005—Oxides; Hydroxides; Oxyacids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G28/00—Compounds of arsenic
    • C01G28/007—Halides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Removal Of Specific Substances (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)

Abstract

El proceso para la purificación del ácido fluorhídrico aquí expuesto, logra reducir el contenido de metales pesados, en particular el arsénico a valores menores de 5 ppm sin utilizar ningún agente químico y con diseño integrado de corrientes frías y calientes que proporcionan un bajo consumo energético. ASÍ mismo, logra la extracción de los metales pesados, en particular el arsénico, con una mínima generación de residuo y manteniendo su estado de oxidación original, que para el caso del arsénico es +3, de manera que el residuo puede ser convertido en un producto con valor comercial, que este proceso se obtiene como ácido arsenioso. El proceso consiste en 4 sistemas: sistema de purificación de HF, sistema de concentración de arsénico, sistema de agua caliente y sistema de agua fría. En el presente documento se detalla la operación sincronizada de estos 4 sistemas que en conjunto logran lo mencionado en el párrafo anterior.
MX2014015885A 2014-12-18 2014-12-18 Proceso para la purificación del ácido fluorhídrico incluyendo la obtención del subproducto ácido arsenioso. MX357878B (es)

Priority Applications (2)

Application Number Priority Date Filing Date Title
MX2014015885A MX357878B (es) 2014-12-18 2014-12-18 Proceso para la purificación del ácido fluorhídrico incluyendo la obtención del subproducto ácido arsenioso.
US14/640,387 US9896334B2 (en) 2014-12-18 2015-03-06 Process for purification of hydrofluoric acid including obtaining arsenious acid by-product

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MX2014015885A MX357878B (es) 2014-12-18 2014-12-18 Proceso para la purificación del ácido fluorhídrico incluyendo la obtención del subproducto ácido arsenioso.

Publications (2)

Publication Number Publication Date
MX2014015885A MX2014015885A (es) 2016-06-17
MX357878B true MX357878B (es) 2018-07-27

Family

ID=56128628

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014015885A MX357878B (es) 2014-12-18 2014-12-18 Proceso para la purificación del ácido fluorhídrico incluyendo la obtención del subproducto ácido arsenioso.

Country Status (2)

Country Link
US (1) US9896334B2 (es)
MX (1) MX357878B (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2653034C9 (ru) * 2017-06-01 2019-04-11 Общество с ограниченной ответственностью "Новые химические продукты" Способ извлечения фторида водорода из его водных растворов
CN112010263B (zh) * 2020-08-31 2022-08-02 北京化工大学 一种电子级氢氟酸的生产装置及生产方法
CN115501635B (zh) * 2022-10-09 2023-07-04 中船(邯郸)派瑞特种气体股份有限公司 一种高效去除卤代烃中杂质的精馏装置和方法

Family Cites Families (32)

* Cited by examiner, † Cited by third party
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BE632837A (es) 1962-06-04 1963-10-21
US3663382A (en) 1969-08-19 1972-05-16 Du Pont Process of recovering hydrogen fluoride free of arsenic by distillation
US3689370A (en) 1970-02-20 1972-09-05 Daikin Ind Ltd Process for purifying hydrofluoric acid by distillation with an oxidizing agent and a ferrous salt
US3687622A (en) 1970-11-30 1972-08-29 Du Pont High pressure purification of hydrogen fluoride
US4032621A (en) 1975-11-24 1977-06-28 E. I. Du Pont De Nemours And Company Preparation of hydrogen fluoride with low levels of arsenic, iron and sulfite
US4083941A (en) 1977-04-18 1978-04-11 E. I. Du Pont De Nemours And Company Purification of anhydrous hydrogen fluoride
US4491570A (en) 1984-05-03 1985-01-01 Pennwalt Corporation Removal of arsenic from hydrogen fluoride
US4668497A (en) 1984-12-25 1987-05-26 Hashimoto Chemical Industries Co., Ltd. Process for purifying hydrogen fluoride
US4756899A (en) 1987-02-12 1988-07-12 Allied-Signal Inc. Manufacture of high purity low arsenic anhydrous hydrogen fluoride
US4929435A (en) 1987-02-12 1990-05-29 Allied-Signal Inc. Manufacture of high purity low arsenic anhydrous hydrogen fluoride
US4952386A (en) 1988-05-20 1990-08-28 Athens Corporation Method and apparatus for purifying hydrogen fluoride
US5047226A (en) 1988-12-12 1991-09-10 Fluorex, S.A. De C.V. Process for the removal of arsenic in the manufacture of hydrofluoric acid
US4990320A (en) 1989-10-31 1991-02-05 E. I. Du Pont De Nemours And Company Process for purifying hydrogen fluoride
US4960580A (en) 1989-10-31 1990-10-02 E. I. Du Pont De Nemours And Company Process for purifying hydrogen fluoride
US4954330A (en) 1989-11-30 1990-09-04 E. I. Dupont De Nemours And Company Process for purifying hydrogen fluoride
DE69112391T2 (de) 1990-03-02 1996-04-04 Du Pont Verfahren zur reinigung von fluorwasserstoff.
US5100639A (en) 1990-03-02 1992-03-31 E. I. Du Pont De Nemours And Company Process for purifying hydrogen fluoride
US5089241A (en) * 1990-12-20 1992-02-18 Allied-Signal Inc. Process for converting hexafluoroarsenic acid or any salt thereof to arsenic acid or salt thereof which can then be rendered nonhazardous
DE4135918A1 (de) 1991-10-31 1993-05-06 Solvay Fluor Und Derivate Gmbh, 3000 Hannover, De Herstellung von hochreinem fluorwasserstoff
US5108559A (en) 1991-12-17 1992-04-28 E. I. Du Pont De Nemours And Company Process for purifying hydrogen fluoride
US5294303A (en) * 1992-12-08 1994-03-15 The Dow Chemical Company Method for removing dissolved immiscible organics from am aqueous medium at ambient temperatures
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US5785820A (en) 1994-01-07 1998-07-28 Startec Ventures, Inc. On-site manufacture of ultra-high-purity hydrofluoric acid for semiconductor processing
NZ310404A (en) * 1995-06-19 1999-07-29 Refrigerant Services Inc Chang Refrigerant separation system comprising a fractional distillation column in conjunction with a chilling unit and a generator for forming liquid and gas phases of the mixture to be separated
DE19905798A1 (de) 1999-02-12 2000-08-17 Bayer Ag Verfahren zum Herstellen reiner Flußsäure
DE10049805A1 (de) 2000-10-09 2002-04-18 Bayer Ag Verfahren zur Abtrennung von Arsenverbindungen aus dem Destillationssumpf der Fluorwasserstoffherstellung
US20030057165A1 (en) * 2001-09-25 2003-03-27 Carson Thomas Powell Process for the separation of a liquid or liquids from another liquid or liquids, or from a solid or mixture of solids, with the minimum energy required for separation and recovery and recovered for re-use within the process
RU2246444C1 (ru) 2003-06-10 2005-02-20 ФГУП "Ангарский электролизный химический комбинат" (ФГУП "АЭХК") Способ получения безводного фтористого водорода с низким содержанием мышьяка и диоксида серы
JP2005281048A (ja) 2004-03-29 2005-10-13 Stella Chemifa Corp フッ化水素酸の精製法及び精製装置
US20080003172A1 (en) * 2006-06-29 2008-01-03 Honeywell International Inc. Continuous hydrolysis of hexafluoroarsenic acid
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CN101597032A (zh) 2009-05-15 2009-12-09 广东光华化学厂有限公司 电子级高纯氢氟酸的制备方法

Also Published As

Publication number Publication date
MX2014015885A (es) 2016-06-17
US20160176711A1 (en) 2016-06-23
US9896334B2 (en) 2018-02-20

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