MX355586B - Materiales compuestos degradables y usos. - Google Patents
Materiales compuestos degradables y usos.Info
- Publication number
- MX355586B MX355586B MX2014007880A MX2014007880A MX355586B MX 355586 B MX355586 B MX 355586B MX 2014007880 A MX2014007880 A MX 2014007880A MX 2014007880 A MX2014007880 A MX 2014007880A MX 355586 B MX355586 B MX 355586B
- Authority
- MX
- Mexico
- Prior art keywords
- degradable
- materials
- degradable composite
- days
- water
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/50—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
- C09K8/516—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls characterised by their form or by the form of their components, e.g. encapsulated material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/50—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/80—Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open
- C09K8/805—Coated proppants
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/262—Alkali metal carbonates
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B2200/00—Special features related to earth drilling for obtaining oil, gas or water
- E21B2200/08—Down-hole devices using materials which decompose under well-bore conditions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mining & Mineral Resources (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- Fluid Mechanics (AREA)
- Environmental & Geological Engineering (AREA)
- Physics & Mathematics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Materials For Medical Uses (AREA)
Abstract
La presente invención se refiere a materiales compuestos y materiales de combinación degradables que tienen una degradación acelerada en agua en condiciones de baja temperatura, y sus diversos usos industriales, médicos y de consumo. En algunas realizaciones, la composición de material compuesto degradable comprende un polímero degradable mezclado con partículas diferenciadas de un relleno que actúa para acelerar la degradación del polímero degradable. Dichos materiales se degradan en agua a 60°C en menos de 30 días, <14 días e incluso <7 días. Se proporcionan diversos materiales que pueden degradarse igualmente rápido a temperaturas bajas, tales como 50°C, o incluso 40°C.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161631184P | 2011-12-28 | 2011-12-28 | |
| PCT/US2012/071166 WO2013101712A1 (en) | 2011-12-28 | 2012-12-21 | Degradable composite materials and uses |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2014007880A MX2014007880A (es) | 2014-09-22 |
| MX355586B true MX355586B (es) | 2018-04-24 |
Family
ID=48698564
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014007880A MX355586B (es) | 2011-12-28 | 2012-12-21 | Materiales compuestos degradables y usos. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9617462B2 (es) |
| CN (2) | CN109456580A (es) |
| AU (1) | AU2012362652B2 (es) |
| BR (1) | BR112014016047A8 (es) |
| CA (1) | CA2861787C (es) |
| MX (1) | MX355586B (es) |
| WO (1) | WO2013101712A1 (es) |
Families Citing this family (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9682425B2 (en) | 2009-12-08 | 2017-06-20 | Baker Hughes Incorporated | Coated metallic powder and method of making the same |
| US10240419B2 (en) | 2009-12-08 | 2019-03-26 | Baker Hughes, A Ge Company, Llc | Downhole flow inhibition tool and method of unplugging a seat |
| US9080098B2 (en) | 2011-04-28 | 2015-07-14 | Baker Hughes Incorporated | Functionally gradient composite article |
| US8631876B2 (en) | 2011-04-28 | 2014-01-21 | Baker Hughes Incorporated | Method of making and using a functionally gradient composite tool |
| US9139928B2 (en) | 2011-06-17 | 2015-09-22 | Baker Hughes Incorporated | Corrodible downhole article and method of removing the article from downhole environment |
| US9707739B2 (en) | 2011-07-22 | 2017-07-18 | Baker Hughes Incorporated | Intermetallic metallic composite, method of manufacture thereof and articles comprising the same |
| US9643250B2 (en) | 2011-07-29 | 2017-05-09 | Baker Hughes Incorporated | Method of controlling the corrosion rate of alloy particles, alloy particle with controlled corrosion rate, and articles comprising the particle |
| US9833838B2 (en) | 2011-07-29 | 2017-12-05 | Baker Hughes, A Ge Company, Llc | Method of controlling the corrosion rate of alloy particles, alloy particle with controlled corrosion rate, and articles comprising the particle |
| US9033055B2 (en) | 2011-08-17 | 2015-05-19 | Baker Hughes Incorporated | Selectively degradable passage restriction and method |
| US9856547B2 (en) | 2011-08-30 | 2018-01-02 | Bakers Hughes, A Ge Company, Llc | Nanostructured powder metal compact |
| US9090956B2 (en) | 2011-08-30 | 2015-07-28 | Baker Hughes Incorporated | Aluminum alloy powder metal compact |
| US9109269B2 (en) | 2011-08-30 | 2015-08-18 | Baker Hughes Incorporated | Magnesium alloy powder metal compact |
| US9643144B2 (en) | 2011-09-02 | 2017-05-09 | Baker Hughes Incorporated | Method to generate and disperse nanostructures in a composite material |
| US9309733B2 (en) | 2012-01-25 | 2016-04-12 | Baker Hughes Incorporated | Tubular anchoring system and method |
| US9284803B2 (en) | 2012-01-25 | 2016-03-15 | Baker Hughes Incorporated | One-way flowable anchoring system and method of treating and producing a well |
| US9010416B2 (en) | 2012-01-25 | 2015-04-21 | Baker Hughes Incorporated | Tubular anchoring system and a seat for use in the same |
| US9605508B2 (en) | 2012-05-08 | 2017-03-28 | Baker Hughes Incorporated | Disintegrable and conformable metallic seal, and method of making the same |
| US9085968B2 (en) * | 2012-12-06 | 2015-07-21 | Baker Hughes Incorporated | Expandable tubular and method of making same |
| US20160185920A1 (en) * | 2013-08-08 | 2016-06-30 | Aspen Research Corporation | Methods and systems for promoting and controlling degradation of polymers |
| US9816339B2 (en) | 2013-09-03 | 2017-11-14 | Baker Hughes, A Ge Company, Llc | Plug reception assembly and method of reducing restriction in a borehole |
| WO2015127174A1 (en) | 2014-02-21 | 2015-08-27 | Terves, Inc. | Fluid activated disintegrating metal system |
| US10689740B2 (en) | 2014-04-18 | 2020-06-23 | Terves, LLCq | Galvanically-active in situ formed particles for controlled rate dissolving tools |
| US11167343B2 (en) | 2014-02-21 | 2021-11-09 | Terves, Llc | Galvanically-active in situ formed particles for controlled rate dissolving tools |
| EP3031847A1 (en) * | 2014-12-11 | 2016-06-15 | Solvay Acetow GmbH | Polymer composition comprising basic additive, process and articles comprising said polymer composition |
| US11136461B2 (en) * | 2014-12-22 | 2021-10-05 | Schlumberger Technology Corporation | Degradable composite structures |
| US9910026B2 (en) | 2015-01-21 | 2018-03-06 | Baker Hughes, A Ge Company, Llc | High temperature tracers for downhole detection of produced water |
| US10378303B2 (en) | 2015-03-05 | 2019-08-13 | Baker Hughes, A Ge Company, Llc | Downhole tool and method of forming the same |
| WO2016186675A1 (en) * | 2015-05-21 | 2016-11-24 | Halliburton Energy Services, Inc. | Enhancing complex fracture networks using near-wellbore and far-field diversion |
| CN104893268A (zh) * | 2015-06-10 | 2015-09-09 | 中国科学院化学研究所 | 一种可降解复合材料及其用途 |
| US10221637B2 (en) | 2015-08-11 | 2019-03-05 | Baker Hughes, A Ge Company, Llc | Methods of manufacturing dissolvable tools via liquid-solid state molding |
| CA2998768A1 (en) * | 2015-09-18 | 2017-03-23 | Schlumberger Canada Limited | Control of thermoplastic composite degradation in downhole conditions |
| US10016810B2 (en) | 2015-12-14 | 2018-07-10 | Baker Hughes, A Ge Company, Llc | Methods of manufacturing degradable tools using a galvanic carrier and tools manufactured thereof |
| DE102016107223B4 (de) * | 2016-04-19 | 2018-05-24 | Karl Leibinger Medizintechnik Gmbh & Co. Kg | Hybridimplantat aus einem Kompositmaterial |
| WO2018057500A1 (en) * | 2016-09-20 | 2018-03-29 | Fairmount Santrol Inc. | Degradable ball sealers with improved solubility characteristics |
| US10435554B2 (en) | 2016-09-20 | 2019-10-08 | Schlumberger Technology Corporation | Degradable polymer and fiber components |
| CN106633709B (zh) * | 2016-09-22 | 2018-08-07 | 无锡海特新材料研究院有限公司 | 一种纺丝用高耐温聚乳酸复合材料及其制备方法 |
| CA3012511A1 (en) | 2017-07-27 | 2019-01-27 | Terves Inc. | Degradable metal matrix composite |
| JPWO2019131952A1 (ja) * | 2017-12-28 | 2020-11-19 | 日本合成化学工業株式会社 | 地下処理用目止め材、地下処理方法及び坑井壁の目止め方法 |
| CN108587587B (zh) * | 2018-04-24 | 2020-12-04 | 东方宝麟科技发展(北京)有限公司 | 一种高强度可降解的油气井暂堵球及其制备方法与应用 |
| CN110591280A (zh) * | 2018-06-12 | 2019-12-20 | 中国科学院化学研究所 | 一种全可溶的桥塞中心管及其制备方法与用途 |
| US10683399B2 (en) | 2018-06-26 | 2020-06-16 | Intrinsic Advanced Materials, LLC | Biodegradable textiles, masterbatches, and method of making biodegradable fibers |
| CN108949189B (zh) * | 2018-08-07 | 2020-08-04 | 陕西科技大学 | 一种农业土壤水分阻滞剂及制备方法 |
| WO2020055395A1 (en) | 2018-09-12 | 2020-03-19 | Halliburton Energy Services, Inc. | Multi-functional diverter particulates |
| DE102019200596A1 (de) | 2019-01-17 | 2020-07-23 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung einer additivzusammensetzung zum kontrollierten beschleunigten abbau von kondensationspolymeren |
| BR112022016524A2 (pt) * | 2020-02-19 | 2022-10-11 | Triplew Ltd | Métodos e sistemas para produção de ácido lático e reciclagem de ácido polilático |
| CN111335863B (zh) * | 2020-04-10 | 2021-03-12 | 西南石油大学 | 一种常规和胶囊型可溶支撑剂交替注入的通道压裂方法 |
| IT202000007963A1 (it) * | 2020-04-15 | 2021-10-15 | Novamont Spa | Composizione polimerica biodegradabile per la realizzazione di articoli stampati. |
| DE102020205100A1 (de) | 2020-04-22 | 2021-10-28 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein | Additivzusammensetzung sowie deren verwendung, kondensationspolymerzusammensetzung, formmasse und hieraus hergestellte formmassen und formteile und deren verwendung |
| DE102020205094A1 (de) | 2020-04-22 | 2021-10-28 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein | Additivzusammensetzung sowie deren Verwendung, Kondensationspolymerzusammensetzung, Formmasse und hieraus hergestellte Formmassen und Formteile und deren Verwendung |
| CN111961323B (zh) * | 2020-08-28 | 2022-11-22 | 上海浦景化工技术股份有限公司 | 一种适用于低温井的可降解材料及其制备方法与应用 |
| CN111995996B (zh) * | 2020-08-28 | 2022-08-19 | 上海浦景化工技术股份有限公司 | 一种适用于地下储层压裂作业的可降解材料及其制备方法 |
| CN112176450A (zh) * | 2020-11-27 | 2021-01-05 | 嘉兴学院 | 一种可降解聚酯纤维及其制备方法 |
| CN113291023A (zh) * | 2021-05-07 | 2021-08-24 | 太仓高腾复合材料有限公司 | 一种可降解保温抗菌复合材料及其制备方法 |
| US12049557B2 (en) | 2021-07-07 | 2024-07-30 | CNPC USA Corp. | Bi-continuos epoxy microstructure for fabrication of degradable thermoset composite used in HTHP downhole conditions |
| CN119365513A (zh) * | 2022-06-12 | 2025-01-24 | 中国石油天然气集团有限公司 | 可降解聚酯复合材料的制备及其应用 |
| US12252645B2 (en) | 2023-07-26 | 2025-03-18 | Cnpc Usa Corporation | Formulation and setup method of in-situ dissolvable plug |
| CN120442228B (zh) * | 2025-07-11 | 2025-09-26 | 中国石油大学(华东) | 一种适用于非常规储层自降解储层保护暂堵剂及其制备方法与应用 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5916678A (en) | 1995-06-30 | 1999-06-29 | Kimberly-Clark Worldwide, Inc. | Water-degradable multicomponent fibers and nonwovens |
| US5766748A (en) | 1995-11-30 | 1998-06-16 | Mitsui Chemicals, Inc. | Stretched film of lactic acid-based polymer |
| US7380600B2 (en) | 2004-09-01 | 2008-06-03 | Schlumberger Technology Corporation | Degradable material assisted diversion or isolation |
| US7275596B2 (en) | 2005-06-20 | 2007-10-02 | Schlumberger Technology Corporation | Method of using degradable fiber systems for stimulation |
| US7775278B2 (en) | 2004-09-01 | 2010-08-17 | Schlumberger Technology Corporation | Degradable material assisted diversion or isolation |
| US20060083917A1 (en) | 2004-10-18 | 2006-04-20 | Fiber Innovation Technology, Inc. | Soluble microfilament-generating multicomponent fibers |
| GB2422839B (en) | 2005-01-11 | 2009-06-24 | Schlumberger Holdings | Degradable polymers for wellbore fluids and processes |
| US7565929B2 (en) | 2006-10-24 | 2009-07-28 | Schlumberger Technology Corporation | Degradable material assisted diversion |
| US7786051B2 (en) | 2006-12-07 | 2010-08-31 | Schlumberger Technology Corporation | Method of preventing or reducing fluid loss in subterranean formations |
| US20080196896A1 (en) * | 2007-02-15 | 2008-08-21 | Oscar Bustos | Methods and apparatus for fiber-based diversion |
| US7703521B2 (en) | 2008-02-19 | 2010-04-27 | Schlumberger Technology Corporation | Polymeric microspheres as degradable fluid loss additives in oilfield applications |
| US7748452B2 (en) | 2008-02-19 | 2010-07-06 | Schlumberger Technology Corporation | Polymeric microspheres as degradable fluid loss additives in oilfield applications |
| US8188185B2 (en) * | 2008-06-30 | 2012-05-29 | Kimberly-Clark Worldwide, Inc. | Biodegradable packaging film |
| US20100273685A1 (en) | 2009-04-22 | 2010-10-28 | Halliburton Energy Services, Inc. | Methods and composition relating to the chemical degradation of degradable polymers |
| JP2011219555A (ja) * | 2010-04-06 | 2011-11-04 | Unitika Ltd | 生分解性合成紙およびその製造方法 |
| US20120067581A1 (en) | 2010-09-17 | 2012-03-22 | Schlumberger Technology Corporation | Mechanism for treating subteranean formations with embedded additives |
-
2012
- 2012-12-21 MX MX2014007880A patent/MX355586B/es active IP Right Grant
- 2012-12-21 CN CN201811042191.2A patent/CN109456580A/zh active Pending
- 2012-12-21 AU AU2012362652A patent/AU2012362652B2/en not_active Ceased
- 2012-12-21 US US14/369,115 patent/US9617462B2/en active Active
- 2012-12-21 CA CA2861787A patent/CA2861787C/en active Active
- 2012-12-21 WO PCT/US2012/071166 patent/WO2013101712A1/en not_active Ceased
- 2012-12-21 BR BR112014016047A patent/BR112014016047A8/pt not_active IP Right Cessation
- 2012-12-21 CN CN201280070762.8A patent/CN104136011A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US9617462B2 (en) | 2017-04-11 |
| US20140360728A1 (en) | 2014-12-11 |
| MX2014007880A (es) | 2014-09-22 |
| CN109456580A (zh) | 2019-03-12 |
| WO2013101712A1 (en) | 2013-07-04 |
| CN104136011A (zh) | 2014-11-05 |
| BR112014016047A2 (pt) | 2017-06-13 |
| CA2861787C (en) | 2021-02-23 |
| BR112014016047A8 (pt) | 2017-07-04 |
| CA2861787A1 (en) | 2013-07-04 |
| AU2012362652A1 (en) | 2014-07-03 |
| AU2012362652B2 (en) | 2017-01-05 |
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