MX346444B - Componente de catalizador solido, catalizador que comprende dicho componente solido y proceso para la (co)polimerizacion de a-olefinas. - Google Patents
Componente de catalizador solido, catalizador que comprende dicho componente solido y proceso para la (co)polimerizacion de a-olefinas.Info
- Publication number
- MX346444B MX346444B MX2016004980A MX2016004980A MX346444B MX 346444 B MX346444 B MX 346444B MX 2016004980 A MX2016004980 A MX 2016004980A MX 2016004980 A MX2016004980 A MX 2016004980A MX 346444 B MX346444 B MX 346444B
- Authority
- MX
- Mexico
- Prior art keywords
- catalyst
- solid
- component
- olefins
- polymerization
- Prior art date
Links
- 238000006116 polymerization reaction Methods 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 239000011949 solid catalyst Substances 0.000 title abstract 3
- 239000007787 solid Substances 0.000 title abstract 2
- 239000004711 α-olefin Substances 0.000 title 1
- 239000010936 titanium Substances 0.000 abstract 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
- -1 zirconium arene Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
- C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
- C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Un componente de catalizador sólido para la (co)polimerización de a-olefinas que tiene la fórmula general (I): ZrnMAlxClMgp (I), en que: M representa titanio (Ti), vanadio (V) o mezclas de los mismos; n es un número que varía de 0,01 a 2; x es un número que varía de 0,1 a 4; y es un número que varía de 5 a 53; p es un número que varía de 0 a 15; obtenido por medio de un proceso que comprende poner al menos un areno de circonio en contacto con al menos un compuesto de metal y, opcionalmente, con al menos un compuesto de magnesio. Dicho componente de catalizador sólido se puede usar ventajosamente como un componente sólido en un catalizador para la (co)polimerización de a-olefinas. Dicho catalizador se puede usar ventajosamente en un proceso para la (co)polimerización de a-olefinas.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI2010A002401A IT1403290B1 (it) | 2010-12-27 | 2010-12-27 | Componente solido di catalizzatore, catalizzatore comprendente detto componente solido, e procedimento di (co)polimerizzazione delle alfa-olefine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX346444B true MX346444B (es) | 2017-03-21 |
Family
ID=43737054
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2013007521A MX342428B (es) | 2010-12-27 | 2011-12-20 | Componente de catalizador solido, catalizador que comprende dicho componente solido y proceso para la (co)polimerizacion de a-olefinas. |
| MX2016004980A MX346444B (es) | 2010-12-27 | 2013-06-25 | Componente de catalizador solido, catalizador que comprende dicho componente solido y proceso para la (co)polimerizacion de a-olefinas. |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2013007521A MX342428B (es) | 2010-12-27 | 2011-12-20 | Componente de catalizador solido, catalizador que comprende dicho componente solido y proceso para la (co)polimerizacion de a-olefinas. |
Country Status (18)
| Country | Link |
|---|---|
| US (2) | US9290586B2 (es) |
| EP (1) | EP2658885B1 (es) |
| JP (2) | JP5952299B2 (es) |
| KR (1) | KR101985553B1 (es) |
| CN (1) | CN103314017B (es) |
| BR (1) | BR112013016224B1 (es) |
| CA (1) | CA2822354C (es) |
| EA (1) | EA029599B1 (es) |
| ES (1) | ES2639813T3 (es) |
| HU (1) | HUE036393T2 (es) |
| IT (1) | IT1403290B1 (es) |
| LT (1) | LT2658885T (es) |
| MX (2) | MX342428B (es) |
| MY (1) | MY171187A (es) |
| PL (1) | PL2658885T3 (es) |
| PT (1) | PT2658885T (es) |
| RS (1) | RS56276B1 (es) |
| WO (1) | WO2012089562A1 (es) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITUB20159429A1 (it) * | 2015-12-24 | 2017-06-24 | Versalis Spa | Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-imminico di vanadio. |
| CN106932528A (zh) * | 2015-12-31 | 2017-07-07 | 中国石油天然气股份有限公司 | 乙氧基改性的氯氧钒催化剂分子式的分析方法 |
| US11214633B2 (en) * | 2019-09-10 | 2022-01-04 | Braskem America, Inc. | Ziegler-Natta catalyst systems and methods of controlling particle size |
| CN113788736A (zh) * | 2021-10-25 | 2021-12-14 | 电子科技大学长三角研究院(湖州) | 一种高效转化co2成乙醇的催化剂 |
| CN115806314B (zh) * | 2022-12-05 | 2023-06-16 | 达高工业技术研究院(广州)有限公司 | 一种三氯氧钒的制备方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1582141A (en) * | 1977-05-25 | 1980-12-31 | Ici Ltd | Production of transition metal composition useful as an olefine polymerisation catalyst or component thereof |
| DE3064564D1 (en) * | 1979-04-30 | 1983-09-22 | Shell Int Research | Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions |
| GB8525954D0 (en) * | 1985-10-21 | 1985-11-27 | Mcneilab Inc | Chlorination of carbohydrates &c alcohols |
| IT1227053B (it) | 1988-09-09 | 1991-03-14 | Enichem Anic Spa | Componente di catalizzatore e gatalizzatore per la polimerizzazione di etilene e per la copolimerizzazione di etilene con alfa olefine. |
| IT1229737B (it) | 1989-05-16 | 1991-09-07 | Enichem Anic Spa | Procedimento per la produzione di vanadio areni. |
| IT1238071B (it) | 1990-01-19 | 1993-07-03 | Enichem Anic Srl | Procedimento perfezionato per la produzione di vanadio areni |
| AU647296B2 (en) | 1991-07-12 | 1994-03-17 | Ecp Enichem Polimeri S.R.L. | Procedure for the producing of vanadium bis-arenes from vanadium oxychloride |
| BE1005982A3 (fr) * | 1992-06-09 | 1994-04-12 | Solvay | Procede de fabrication d'un solide catalytique, solide catalytique et procede de (co)polymerisation d'olefines au moyen de ce solide catalytique. |
| IT1256665B (it) * | 1992-12-28 | 1995-12-12 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1269805B (it) * | 1994-05-20 | 1997-04-15 | Enichem Spa | Catalizzatore per la (co)polimerizzazione dell'etilene e procedimento per il suo ottenimento |
| IT1397080B1 (it) * | 2009-11-23 | 2012-12-28 | Polimeri Europa Spa | Catalizzatore di tipo ziegler-natta per la (co)polimerizzazione delle alfa-olefine con elevata produttivita' |
-
2010
- 2010-12-27 IT ITMI2010A002401A patent/IT1403290B1/it active
-
2011
- 2011-12-20 US US13/997,967 patent/US9290586B2/en not_active Expired - Fee Related
- 2011-12-20 KR KR1020137016320A patent/KR101985553B1/ko active IP Right Grant
- 2011-12-20 MY MYPI2013002400A patent/MY171187A/en unknown
- 2011-12-20 RS RS20170881A patent/RS56276B1/sr unknown
- 2011-12-20 EP EP11802086.6A patent/EP2658885B1/en active Active
- 2011-12-20 CN CN201180062664.5A patent/CN103314017B/zh not_active Expired - Fee Related
- 2011-12-20 EA EA201390964A patent/EA029599B1/ru not_active IP Right Cessation
- 2011-12-20 JP JP2013545315A patent/JP5952299B2/ja not_active Expired - Fee Related
- 2011-12-20 PL PL11802086T patent/PL2658885T3/pl unknown
- 2011-12-20 HU HUE11802086A patent/HUE036393T2/hu unknown
- 2011-12-20 LT LTEP11802086.6T patent/LT2658885T/lt unknown
- 2011-12-20 CA CA2822354A patent/CA2822354C/en not_active Expired - Fee Related
- 2011-12-20 ES ES11802086.6T patent/ES2639813T3/es active Active
- 2011-12-20 WO PCT/EP2011/073429 patent/WO2012089562A1/en active Application Filing
- 2011-12-20 MX MX2013007521A patent/MX342428B/es active IP Right Grant
- 2011-12-20 BR BR112013016224-4A patent/BR112013016224B1/pt not_active IP Right Cessation
- 2011-12-20 PT PT118020866T patent/PT2658885T/pt unknown
-
2013
- 2013-06-25 MX MX2016004980A patent/MX346444B/es unknown
-
2015
- 2015-11-04 US US14/932,743 patent/US9944726B2/en not_active Expired - Fee Related
-
2016
- 2016-06-07 JP JP2016113649A patent/JP6290304B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| KR20140035317A (ko) | 2014-03-21 |
| BR112013016224A2 (pt) | 2016-09-27 |
| WO2012089562A1 (en) | 2012-07-05 |
| MY171187A (en) | 2019-09-30 |
| EP2658885B1 (en) | 2017-06-14 |
| PL2658885T3 (pl) | 2018-09-28 |
| ES2639813T3 (es) | 2017-10-30 |
| CN103314017B (zh) | 2017-07-18 |
| HUE036393T2 (hu) | 2018-07-30 |
| JP5952299B2 (ja) | 2016-07-13 |
| LT2658885T (lt) | 2017-09-25 |
| MX2013007521A (es) | 2013-12-02 |
| US20160060370A1 (en) | 2016-03-03 |
| US9944726B2 (en) | 2018-04-17 |
| ITMI20102401A1 (it) | 2012-06-28 |
| PT2658885T (pt) | 2017-08-14 |
| EA029599B1 (ru) | 2018-04-30 |
| CA2822354C (en) | 2018-08-07 |
| US20130303360A1 (en) | 2013-11-14 |
| US9290586B2 (en) | 2016-03-22 |
| EA201390964A1 (ru) | 2013-12-30 |
| JP2014501830A (ja) | 2014-01-23 |
| MX342428B (es) | 2016-09-29 |
| CA2822354A1 (en) | 2012-07-05 |
| IT1403290B1 (it) | 2013-10-17 |
| EP2658885A1 (en) | 2013-11-06 |
| BR112013016224B1 (pt) | 2020-11-03 |
| RS56276B1 (sr) | 2017-12-29 |
| JP6290304B2 (ja) | 2018-03-07 |
| CN103314017A (zh) | 2013-09-18 |
| JP2016194080A (ja) | 2016-11-17 |
| KR101985553B1 (ko) | 2019-06-03 |
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