MX342415B - Procesos para la obtencion de un poliol a partir de aceite de palma, polioles obtenidos a partir de dichos procesos, productos derivados de dicho poliol y su metodo de preparacion. - Google Patents

Procesos para la obtencion de un poliol a partir de aceite de palma, polioles obtenidos a partir de dichos procesos, productos derivados de dicho poliol y su metodo de preparacion.

Info

Publication number
MX342415B
MX342415B MX2014004087A MX2014004087A MX342415B MX 342415 B MX342415 B MX 342415B MX 2014004087 A MX2014004087 A MX 2014004087A MX 2014004087 A MX2014004087 A MX 2014004087A MX 342415 B MX342415 B MX 342415B
Authority
MX
Mexico
Prior art keywords
palm oil
polyol
processes
route
polyols
Prior art date
Application number
MX2014004087A
Other languages
English (en)
Other versions
MX2014004087A (es
Inventor
María Baena Restrepo Margarita
Toro Álvarez Dahiana
Viviana AGUDELO VELÁSQUEZ Dency
Original Assignee
Ind Agraria La Palma Ltda Indupalma Ltda
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ind Agraria La Palma Ltda Indupalma Ltda filed Critical Ind Agraria La Palma Ltda Indupalma Ltda
Publication of MX2014004087A publication Critical patent/MX2014004087A/es
Publication of MX342415B publication Critical patent/MX342415B/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/348—Hydroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/36—Hydroxylated esters of higher fatty acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
    • C08G18/8009—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
    • C08G18/8012—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203 with diols
    • C08G18/8019—Masked aromatic polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/02—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with glycerol
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
    • C11C3/06—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils with glycerol
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

La presente invención se relaciona con el proceso para, la producción de un poliol a partir de aceite de palma y con espumas de poliuretano rígido preparadas a partir de dicho poliol derivado de aceite de palma. De un lado, la presente invención proporciona un método para la obtención de polioles monoméricos obtenidos a partir de aceite de palma y que tienen número de hidroxilo entre 50 y 450 mgKOH/g muestra. Los polioles de la presente solicitud pueden ser obtenidos por medio de un procedimiento basado en las siguientes cuatro rutas madre: Ruta 1: maleinización de los ácidos grasos del aceite de palma; Ruta 2: glicerólisis del aceite de palma; Ruta 3: transesterificación del aceite de palma y Ruta 4: epoxidación de los enlaces insaturados carbono-carbono del aceite de palma. Adicionalmente, otras modalidades de la invención permiten la obtención de polioles a partir de la combinación de estas rutas madre. En otro aspecto de la invención se preparan poliuretanos a partir de elos polioles obtenidos mediante alguna de las cuatro rutas o mediante la combinación de las mismas. En una modalidad de la invención los poliuretanos se producen mediante la reacción de una mezcla de un poliol obtenido mediante la presente invención, un poliol comercial, un tensoactivo, un catalizador y un isocianato. Los poliuretanos pueden ser espumas de poliuretano rígido de alta densidad.
MX2014004087A 2011-10-03 2012-10-03 Procesos para la obtencion de un poliol a partir de aceite de palma, polioles obtenidos a partir de dichos procesos, productos derivados de dicho poliol y su metodo de preparacion. MX342415B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CO11130078A CO6650065A1 (es) 2011-10-03 2011-10-03 Procesos para la obtención de un poliol a partir de aceite de palma, polioles obtenidos a partir de dichos procesos, productos derivados de dicho poliol y su método de preparación
PCT/IB2012/001954 WO2013050854A1 (es) 2011-10-03 2012-10-03 Procesos para la obtención de un poliol a partir de aceite de palma, polioles obtenidos a partir de dichos procesos, productos derivados de dicho poliol y su método de preparación

Publications (2)

Publication Number Publication Date
MX2014004087A MX2014004087A (es) 2014-09-22
MX342415B true MX342415B (es) 2016-09-28

Family

ID=48043223

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014004087A MX342415B (es) 2011-10-03 2012-10-03 Procesos para la obtencion de un poliol a partir de aceite de palma, polioles obtenidos a partir de dichos procesos, productos derivados de dicho poliol y su metodo de preparacion.

Country Status (9)

Country Link
US (1) US10246547B2 (es)
EP (1) EP2765146B1 (es)
JP (1) JP6255345B2 (es)
BR (1) BR112014008039A2 (es)
CO (1) CO6650065A1 (es)
MX (1) MX342415B (es)
MY (1) MY170130A (es)
SG (1) SG11201401245SA (es)
WO (1) WO2013050854A1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015183070A1 (en) * 2014-05-26 2015-12-03 Universiti Kebangsaan Malaysia (Ukm) Method to produce natural oil-based polyurethane prepolymer
CN109320684B (zh) * 2018-09-29 2020-09-04 南京工业大学 一种聚氨酯多元醇及其制备方法和应用
CN115594885B (zh) * 2022-11-23 2024-06-11 广东远承化工有限公司 一种复合增塑剂及其应用

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2806046A (en) * 1953-10-12 1957-09-10 Shell Dev Alcoholizing fatty oils with polyhydric tertiary alcohols
US3424766A (en) * 1966-08-03 1969-01-28 Celanese Coatings Co Epoxidized urethane oils
CA2174502A1 (en) * 1993-10-20 1995-04-27 Wolfgang Klauck Binders based on fat chemical reaction products
US5543472A (en) * 1995-05-16 1996-08-06 Shell Oil Company Concurrent epoxidation and catalyst residue extraction
SG55223A1 (en) * 1995-08-07 1998-12-21 Palm Oil Res & Dev Board Polyurethane foams from palm oil and palm oil products
US6121398A (en) * 1997-10-27 2000-09-19 University Of Delaware High modulus polymers and composites from plant oils
US6433121B1 (en) 1998-11-06 2002-08-13 Pittsburg State University Method of making natural oil-based polyols and polyurethanes therefrom
WO2006012344A1 (en) 2004-06-25 2006-02-02 Pittsburg State University Modified vegetable oil-based polyols
MY142992A (en) * 2004-07-16 2011-02-14 Univ Malaya A process for producing polyol and polyurethane adhesives
MY144777A (en) * 2005-08-04 2011-11-15 Malaysian Palm Oil Board Mpob A process for the production of polyurethane products
MY144354A (en) 2005-11-08 2011-09-15 Malaysian Palm Oil Board Mpob A process for the production of a polyol monomer
CN101410429A (zh) * 2006-03-27 2009-04-15 匹兹堡州立大学 来自棕榈基油类的低聚多元醇和由其制得的聚氨酯组合物
CN100528819C (zh) * 2007-02-07 2009-08-19 上海中科合臣股份有限公司 一种高羟值植物油多元醇的制备方法
MY145702A (en) * 2007-05-22 2012-03-30 Malaysian Palm Oil Board Mpob A process to produce polyols
WO2009058367A1 (en) 2007-11-01 2009-05-07 Cargill, Incorporated Natural oil-derived polyester polyols and polyurethanes made therefrom
US8664352B2 (en) 2007-11-01 2014-03-04 Cargill, Incorporated Natural oil-derived polyester polyols and polyurethanes made therefrom
WO2010058918A2 (ko) * 2008-11-19 2010-05-27 (주)에스엠피오티 폴리올 에스테르 제조 방법
EP2226311A1 (en) * 2009-03-02 2010-09-08 Rohm and Haas Company Bio-based polyol
MY147203A (en) * 2009-11-23 2012-11-14 Universiti Of Malaya Fibreboard from agricultural wastes and a method for manufacturing the same

Also Published As

Publication number Publication date
CO6650065A1 (es) 2013-04-15
EP2765146B1 (en) 2017-04-05
US10246547B2 (en) 2019-04-02
US20140309322A1 (en) 2014-10-16
EP2765146A4 (en) 2015-06-24
JP2014529002A (ja) 2014-10-30
MX2014004087A (es) 2014-09-22
SG11201401245SA (en) 2014-09-26
WO2013050854A1 (es) 2013-04-11
MY170130A (en) 2019-07-05
JP6255345B2 (ja) 2017-12-27
BR112014008039A2 (pt) 2017-06-13
EP2765146A1 (en) 2014-08-13

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