CO6650065A1 - Procesos para la obtención de un poliol a partir de aceite de palma, polioles obtenidos a partir de dichos procesos, productos derivados de dicho poliol y su método de preparación - Google Patents

Procesos para la obtención de un poliol a partir de aceite de palma, polioles obtenidos a partir de dichos procesos, productos derivados de dicho poliol y su método de preparación

Info

Publication number
CO6650065A1
CO6650065A1 CO11130078A CO11130078A CO6650065A1 CO 6650065 A1 CO6650065 A1 CO 6650065A1 CO 11130078 A CO11130078 A CO 11130078A CO 11130078 A CO11130078 A CO 11130078A CO 6650065 A1 CO6650065 A1 CO 6650065A1
Authority
CO
Colombia
Prior art keywords
palm oil
polyol
processes
route
polyols
Prior art date
Application number
CO11130078A
Other languages
English (en)
Inventor
Restrepo Margarita Maria Baena
Velasquez Dency Viviana Agudelo
Alvarez Dahiana Toro
Original Assignee
Indupalma Ltda
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Indupalma Ltda filed Critical Indupalma Ltda
Priority to CO11130078A priority Critical patent/CO6650065A1/es
Priority to EP12837878.3A priority patent/EP2765146B1/en
Priority to JP2014534004A priority patent/JP6255345B2/ja
Priority to US14/349,029 priority patent/US10246547B2/en
Priority to MX2014004087A priority patent/MX342415B/es
Priority to MYPI2014700816A priority patent/MY170130A/en
Priority to SG11201401245SA priority patent/SG11201401245SA/en
Priority to PCT/IB2012/001954 priority patent/WO2013050854A1/es
Priority to BR112014008039A priority patent/BR112014008039A2/pt
Publication of CO6650065A1 publication Critical patent/CO6650065A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/348—Hydroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/36—Hydroxylated esters of higher fatty acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
    • C08G18/8009—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
    • C08G18/8012—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203 with diols
    • C08G18/8019—Masked aromatic polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/02—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with glycerol
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
    • C11C3/06—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils with glycerol
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

La presente invención se relaciona con el proceso para la producción de un poliol a partir de aceite de palma y con espumas de poliuretano rígido preparadas a partir de dicho poliol derivado de aceite de palma. De un lado, la presente invención proporciona un método para la obtención de polioles monoméricos obtenidos a partir de aceite de palma y que tienen número de hidroxilo entre 50 y 450 mg KOH/g muestra. Los polioles de la presente solicitud pueden ser obtenidos por medio de un procedimiento basado en las siguientes cuatro rutas madre: Ruta 1: maleinización de los ácidos grasos del aceite de palma; Ruta 2: glicerólisis del aceite de palma; Ruta 3: transesterificación del aceite de palma y Ruta 4: epoxidación de los enlaces insaturados carbono-carbono del aceite de palma. Adicionalmente, otras modalidades de la invención permiten la obtención de polioles a partir de la combinación de estas rutas madre. En otro aspecto de la invención se preparan poliuretanos a partir de los polioles obtenidos mediante alguna de las cuatro rutas o mediante la combinación de las mismas. En una modalidad de la invención los poliuretanos se producen mediante la reacción de una mezcla de un poliol obtenido mediante la presente invención, un poliol comercial, un tensoactivo, un catalizador y un isocianato. Los poliuretanos pueden ser espumas de poliuretano rígido de alta densidad
CO11130078A 2011-10-03 2011-10-03 Procesos para la obtención de un poliol a partir de aceite de palma, polioles obtenidos a partir de dichos procesos, productos derivados de dicho poliol y su método de preparación CO6650065A1 (es)

Priority Applications (9)

Application Number Priority Date Filing Date Title
CO11130078A CO6650065A1 (es) 2011-10-03 2011-10-03 Procesos para la obtención de un poliol a partir de aceite de palma, polioles obtenidos a partir de dichos procesos, productos derivados de dicho poliol y su método de preparación
EP12837878.3A EP2765146B1 (en) 2011-10-03 2012-10-03 Processes for obtaining a polyol from palm oil
JP2014534004A JP6255345B2 (ja) 2011-10-03 2012-10-03 パーム油からポリオールを得る方法、該方法によって得られるポリオール、並びに該ポリオールを用いた製品及びその製造方法
US14/349,029 US10246547B2 (en) 2011-10-03 2012-10-03 Processes for obtaining a polyol from palm oil, polyols obtained from the processes, products derived from such polyol and their method of preparation
MX2014004087A MX342415B (es) 2011-10-03 2012-10-03 Procesos para la obtencion de un poliol a partir de aceite de palma, polioles obtenidos a partir de dichos procesos, productos derivados de dicho poliol y su metodo de preparacion.
MYPI2014700816A MY170130A (en) 2011-10-03 2012-10-03 Processes for obtaining a polyol from palm oil, polyols obtained from the processes, products derived from such polyol and their method of preparation
SG11201401245SA SG11201401245SA (en) 2011-10-03 2012-10-03 Processes for obtaining a polyol from palm oil, polyols obtained from said processes, products derived from said polyol and method for preparing same
PCT/IB2012/001954 WO2013050854A1 (es) 2011-10-03 2012-10-03 Procesos para la obtención de un poliol a partir de aceite de palma, polioles obtenidos a partir de dichos procesos, productos derivados de dicho poliol y su método de preparación
BR112014008039A BR112014008039A2 (pt) 2011-10-03 2012-10-03 processos para obtenção de um poliol a partir de óleo de palma, polióis obtidos a partir dos referidos processos, produtos derivados do referido poliol e método para preparar o mesmo

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CO11130078A CO6650065A1 (es) 2011-10-03 2011-10-03 Procesos para la obtención de un poliol a partir de aceite de palma, polioles obtenidos a partir de dichos procesos, productos derivados de dicho poliol y su método de preparación

Publications (1)

Publication Number Publication Date
CO6650065A1 true CO6650065A1 (es) 2013-04-15

Family

ID=48043223

Family Applications (1)

Application Number Title Priority Date Filing Date
CO11130078A CO6650065A1 (es) 2011-10-03 2011-10-03 Procesos para la obtención de un poliol a partir de aceite de palma, polioles obtenidos a partir de dichos procesos, productos derivados de dicho poliol y su método de preparación

Country Status (9)

Country Link
US (1) US10246547B2 (es)
EP (1) EP2765146B1 (es)
JP (1) JP6255345B2 (es)
BR (1) BR112014008039A2 (es)
CO (1) CO6650065A1 (es)
MX (1) MX342415B (es)
MY (1) MY170130A (es)
SG (1) SG11201401245SA (es)
WO (1) WO2013050854A1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015183070A1 (en) * 2014-05-26 2015-12-03 Universiti Kebangsaan Malaysia (Ukm) Method to produce natural oil-based polyurethane prepolymer
CN109320684B (zh) * 2018-09-29 2020-09-04 南京工业大学 一种聚氨酯多元醇及其制备方法和应用
CN115594885B (zh) * 2022-11-23 2024-06-11 广东远承化工有限公司 一种复合增塑剂及其应用

Family Cites Families (19)

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US2806046A (en) * 1953-10-12 1957-09-10 Shell Dev Alcoholizing fatty oils with polyhydric tertiary alcohols
US3424766A (en) * 1966-08-03 1969-01-28 Celanese Coatings Co Epoxidized urethane oils
CA2174502A1 (en) * 1993-10-20 1995-04-27 Wolfgang Klauck Binders based on fat chemical reaction products
US5543472A (en) * 1995-05-16 1996-08-06 Shell Oil Company Concurrent epoxidation and catalyst residue extraction
SG55223A1 (en) * 1995-08-07 1998-12-21 Palm Oil Res & Dev Board Polyurethane foams from palm oil and palm oil products
US6121398A (en) * 1997-10-27 2000-09-19 University Of Delaware High modulus polymers and composites from plant oils
US6433121B1 (en) 1998-11-06 2002-08-13 Pittsburg State University Method of making natural oil-based polyols and polyurethanes therefrom
WO2006012344A1 (en) 2004-06-25 2006-02-02 Pittsburg State University Modified vegetable oil-based polyols
MY142992A (en) * 2004-07-16 2011-02-14 Univ Malaya A process for producing polyol and polyurethane adhesives
MY144777A (en) * 2005-08-04 2011-11-15 Malaysian Palm Oil Board Mpob A process for the production of polyurethane products
MY144354A (en) 2005-11-08 2011-09-15 Malaysian Palm Oil Board Mpob A process for the production of a polyol monomer
CN101410429A (zh) * 2006-03-27 2009-04-15 匹兹堡州立大学 来自棕榈基油类的低聚多元醇和由其制得的聚氨酯组合物
CN100528819C (zh) * 2007-02-07 2009-08-19 上海中科合臣股份有限公司 一种高羟值植物油多元醇的制备方法
MY145702A (en) * 2007-05-22 2012-03-30 Malaysian Palm Oil Board Mpob A process to produce polyols
WO2009058367A1 (en) 2007-11-01 2009-05-07 Cargill, Incorporated Natural oil-derived polyester polyols and polyurethanes made therefrom
US8664352B2 (en) 2007-11-01 2014-03-04 Cargill, Incorporated Natural oil-derived polyester polyols and polyurethanes made therefrom
WO2010058918A2 (ko) * 2008-11-19 2010-05-27 (주)에스엠피오티 폴리올 에스테르 제조 방법
EP2226311A1 (en) * 2009-03-02 2010-09-08 Rohm and Haas Company Bio-based polyol
MY147203A (en) * 2009-11-23 2012-11-14 Universiti Of Malaya Fibreboard from agricultural wastes and a method for manufacturing the same

Also Published As

Publication number Publication date
EP2765146B1 (en) 2017-04-05
MX342415B (es) 2016-09-28
US10246547B2 (en) 2019-04-02
US20140309322A1 (en) 2014-10-16
EP2765146A4 (en) 2015-06-24
JP2014529002A (ja) 2014-10-30
MX2014004087A (es) 2014-09-22
SG11201401245SA (en) 2014-09-26
WO2013050854A1 (es) 2013-04-11
MY170130A (en) 2019-07-05
JP6255345B2 (ja) 2017-12-27
BR112014008039A2 (pt) 2017-06-13
EP2765146A1 (en) 2014-08-13

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