MX2017007461A - Composiciones no acuosas de materiales de recubrimiento, recubrimientos producidos a partir de ellas y que tienen mejoradas adhesion y resistencia a los arañazos y tambien el uso de las mismas. - Google Patents
Composiciones no acuosas de materiales de recubrimiento, recubrimientos producidos a partir de ellas y que tienen mejoradas adhesion y resistencia a los arañazos y tambien el uso de las mismas.Info
- Publication number
- MX2017007461A MX2017007461A MX2017007461A MX2017007461A MX2017007461A MX 2017007461 A MX2017007461 A MX 2017007461A MX 2017007461 A MX2017007461 A MX 2017007461A MX 2017007461 A MX2017007461 A MX 2017007461A MX 2017007461 A MX2017007461 A MX 2017007461A
- Authority
- MX
- Mexico
- Prior art keywords
- group
- coating material
- material compositions
- formula
- isocyanate groups
- Prior art date
Links
- 238000000576 coating method Methods 0.000 title abstract 5
- 239000011248 coating agent Substances 0.000 title abstract 3
- 239000000463 material Substances 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title abstract 3
- 229920001228 polyisocyanate Polymers 0.000 abstract 5
- 239000005056 polyisocyanate Substances 0.000 abstract 5
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 abstract 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 abstract 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 2
- 239000000654 additive Substances 0.000 abstract 2
- 230000000996 additive effect Effects 0.000 abstract 2
- 125000005010 perfluoroalkyl group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
- C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
- C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
- C08G18/0847—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of solvents for the polymers
- C08G18/0852—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of solvents for the polymers the solvents being organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
- C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/8064—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
- C08G18/808—Monoamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/8083—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen
- C08G18/8087—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen containing halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/8083—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen
- C08G18/809—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
La presente invención se refiere a composiciones no acuosas del material de recubrimiento que comprenden al menos un componente que contiene un grupo polihidroxilo, al menos un componente que contiene un grupo poliisocianato, al menos un catalizador y al menos un derivado uretano (PF) que tiene al menos un grupo perfluoroalquilo de la fórmula (I) CR13- (CR22)X- (I), donde R1 y R2 independientemente uno de otro son H, F y/o CF3, pero R1 y R2 pueden no ser ambos H, x es 1 a 20, y al menos un grupo silano de la fórmula (II) -X-Si-R3SG3-S (II) donde G es un grupo hidrolizable, x es un radical orgánico, R3 es alquilo, cicloalquilo, arilo o aralquilo, y s es 0 a 2, donde el aditivo uretano (PF) se ha preparado mediante la reacción de 0,5 a 20 % en moles de grupos isocianato originalmente presentes en un poliisocianato (PI) con un componente (la) que tiene al menos un grupo perfluoroalquilo de la fórmula (I) y un grupo que es reactivo hacia los grupos isocianato y 10 a 99,5 % en moles de grupos isocianato originalmente presentes en el poliisocianato (PI) con un componente (IIa) que tiene al menos un grupo guano de la fórmula (II) y un grupo que es reactivo hacia los grupos isocianato. Un tema adicional de la presente invención se refiere a los recubrimientos producidos a partir de estas composiciones del material de recubrimiento, y también su uso.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14196777 | 2014-12-08 | ||
PCT/EP2015/078060 WO2016091638A1 (de) | 2014-12-08 | 2015-11-30 | Nichtwässrige beschichtungsmittelzusammensetzungen, daraus hergestellte beschichtungen mit verbesserter haftung und kratzfestigkeit sowie deren verwendung |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2017007461A true MX2017007461A (es) | 2017-08-10 |
Family
ID=52006928
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2017007461A MX2017007461A (es) | 2014-12-08 | 2015-11-30 | Composiciones no acuosas de materiales de recubrimiento, recubrimientos producidos a partir de ellas y que tienen mejoradas adhesion y resistencia a los arañazos y tambien el uso de las mismas. |
Country Status (10)
Country | Link |
---|---|
US (1) | US10519341B2 (es) |
EP (1) | EP3230334B1 (es) |
JP (1) | JP6445162B2 (es) |
KR (1) | KR101953499B1 (es) |
CN (1) | CN107001855B (es) |
CA (1) | CA2967878C (es) |
ES (1) | ES2740125T3 (es) |
MX (1) | MX2017007461A (es) |
RU (1) | RU2670274C1 (es) |
WO (1) | WO2016091638A1 (es) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017202692A1 (de) | 2016-05-24 | 2017-11-30 | Basf Coatings Gmbh | Beschichtungsmittel und daraus hergestellte beschichtungen mit verbesserten anschmutzungsresistenzen und (selbst)reinigungseigenschaften sowie deren verwendung |
US10954408B2 (en) | 2018-07-18 | 2021-03-23 | Ppg Industries Ohio, Inc. | Curable film-forming compositions prepared from multiple hydrophobic polymers and method of mitigating dirt build-up on a substrate |
US10840953B2 (en) | 2018-07-18 | 2020-11-17 | Ppg Industries Ohio, Inc. | Coated articles demonstrating electromagnetic radiation transparency and method of mitigating contaminant build-up on a substrate |
US11851573B2 (en) * | 2018-11-01 | 2023-12-26 | Ppg Industries Ohio, Inc. | Solvent-borne coating compositions, coatings formed therefrom, and methods of forming such coatings |
CN110229605A (zh) * | 2019-05-31 | 2019-09-13 | 广东合胜实业股份有限公司 | 一种无溶剂聚氨酯涂料及其制备方法 |
MX2022000566A (es) * | 2019-07-16 | 2022-02-10 | Basf Coatings Gmbh | Dispersiones de poliuretano de un componente, su fabricacion y uso. |
CN111057203B (zh) * | 2019-12-31 | 2022-03-22 | 北京松井工程技术研究院有限公司 | 硅氟聚氨酯丙烯酸树脂及其制备方法与应用 |
CN112920700A (zh) * | 2021-01-29 | 2021-06-08 | 北京九天行歌航天科技有限公司 | 一种火箭低温贮箱用防结冰涂料及其制备方法 |
WO2024165361A1 (en) * | 2023-02-09 | 2024-08-15 | Basf Se | Preparation of polyisocyanates containing iminooxadiazinedione groups and their use |
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DE102007061854A1 (de) * | 2007-12-19 | 2009-06-25 | Basf Coatings Ag | Beschichtungsmittel mit hoher Kratzbeständigkeit und Witterungsstabilität |
EP2085442A1 (de) * | 2008-02-01 | 2009-08-05 | Evonik Degussa GmbH | Fluorhaltige Zusammensetzungen mit verbesserten Oberflächeneigenschaften |
DE102008007190A1 (de) * | 2008-02-01 | 2009-08-06 | Construction Research & Technology Gmbh | Flüssige, fluorhaltige und einkomponentige Zusammensetzung |
JP5634012B2 (ja) * | 2008-02-27 | 2014-12-03 | 株式会社Adeka | 水系ポリウレタン樹脂組成物及びそれを塗布してなる被塗物 |
DE102009030481A1 (de) | 2009-06-24 | 2011-01-05 | Basf Coatings Gmbh | Beschichtungsmittel und daraus hergestellte Beschichtungen mit hoher Kratzfestigkeit bei gleichzeitig guten Ergebnissen in der Prüfung der Erichsentiefung und guten Steinschlagschutzeigenschaften |
CN102844349B (zh) * | 2010-04-21 | 2015-01-14 | 巴斯夫涂料有限公司 | 具有高固含量和良好流平性的涂层剂以及由此制备的多层涂漆及其用途 |
KR101962493B1 (ko) | 2011-06-09 | 2019-03-26 | 바스프 코팅스 게엠베하 | 높은 내스크래치성 및 우수한 연마성을 나타내는 코팅제 조성물, 이로부터 제조된 코팅, 및 이의 용도 |
WO2013081892A1 (en) | 2011-11-30 | 2013-06-06 | U.S. Coatings Ip Co. Llc | Coating composition |
EP2886574A1 (de) | 2013-12-17 | 2015-06-24 | BASF Coatings GmbH | Haftvermittler für lösemittelbasierte Klarlacke |
EP2886208A1 (de) | 2013-12-17 | 2015-06-24 | BASF Coatings GmbH | Haftvermittler für lösemittelbasierte Füller |
-
2015
- 2015-11-30 CA CA2967878A patent/CA2967878C/en active Active
- 2015-11-30 JP JP2017530764A patent/JP6445162B2/ja not_active Expired - Fee Related
- 2015-11-30 US US15/526,843 patent/US10519341B2/en not_active Expired - Fee Related
- 2015-11-30 RU RU2017124191A patent/RU2670274C1/ru active
- 2015-11-30 WO PCT/EP2015/078060 patent/WO2016091638A1/de active Application Filing
- 2015-11-30 ES ES15802081T patent/ES2740125T3/es active Active
- 2015-11-30 EP EP15802081.8A patent/EP3230334B1/de not_active Not-in-force
- 2015-11-30 MX MX2017007461A patent/MX2017007461A/es active IP Right Grant
- 2015-11-30 CN CN201580067167.2A patent/CN107001855B/zh not_active Expired - Fee Related
- 2015-11-30 KR KR1020177018566A patent/KR101953499B1/ko active IP Right Grant
Also Published As
Publication number | Publication date |
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CA2967878A1 (en) | 2016-06-16 |
CA2967878C (en) | 2021-05-25 |
EP3230334A1 (de) | 2017-10-18 |
EP3230334B1 (de) | 2019-05-01 |
CN107001855A (zh) | 2017-08-01 |
KR20170093897A (ko) | 2017-08-16 |
JP2018503712A (ja) | 2018-02-08 |
ES2740125T3 (es) | 2020-02-05 |
JP6445162B2 (ja) | 2018-12-26 |
KR101953499B1 (ko) | 2019-02-28 |
RU2670274C1 (ru) | 2018-10-22 |
US20170355875A1 (en) | 2017-12-14 |
US10519341B2 (en) | 2019-12-31 |
CN107001855B (zh) | 2020-12-04 |
WO2016091638A1 (de) | 2016-06-16 |
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