MX2017000590A - Proceso de reaccion de kolbe de alta productividad para la transformacion de acidos grasos derivados de aceite vegetal y grasa animal. - Google Patents

Proceso de reaccion de kolbe de alta productividad para la transformacion de acidos grasos derivados de aceite vegetal y grasa animal.

Info

Publication number
MX2017000590A
MX2017000590A MX2017000590A MX2017000590A MX2017000590A MX 2017000590 A MX2017000590 A MX 2017000590A MX 2017000590 A MX2017000590 A MX 2017000590A MX 2017000590 A MX2017000590 A MX 2017000590A MX 2017000590 A MX2017000590 A MX 2017000590A
Authority
MX
Mexico
Prior art keywords
fatty acids
reaction process
high productivity
kolbe reaction
transformation
Prior art date
Application number
MX2017000590A
Other languages
English (en)
Inventor
H Joshi Chandrashekhar
Glenn Horner Michael
Malevich Dzmitry
thomas thornton gibson Graham
Original Assignee
Advonex Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US14/331,390 external-priority patent/US8961775B2/en
Application filed by Advonex Int Corp filed Critical Advonex Int Corp
Publication of MX2017000590A publication Critical patent/MX2017000590A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/29—Coupling reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/10—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond in hydrocarbons containing no six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/62—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/02—Well-defined hydrocarbons
    • C10M105/04—Well-defined hydrocarbons aliphatic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/06—Gasoil
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Electrochemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Lubricants (AREA)

Abstract

Los aceites de plantas y grasas animales se hidrolizan para obtener ácidos grasos para una reacción de kolbe. La invención se refiere a un proceso de reacción de Kolbe de alta productividad para descarboxilar electroquímicamente ácidos grasos CA-C28 usando pequeñas cantidades de ácido acético para reducir el voltaje de pasivación anódica y sintetizar hidrocarburos C6-C54. C6-C54 se someten a un proceso de reacción de metátesis olefínica y/o hidroisomerización para sintetizar productos de fuelóleo pesado, combustible diésel, combustible queroseno, aceite básico lubricante y alfaolefina lineal útiles como precursores para polímeros, detergentes y otros productos químicos refinados.
MX2017000590A 2014-07-15 2015-05-22 Proceso de reaccion de kolbe de alta productividad para la transformacion de acidos grasos derivados de aceite vegetal y grasa animal. MX2017000590A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14/331,390 US8961775B2 (en) 2011-02-01 2014-07-15 High productivity Kolbe reaction process for transformation of fatty acids derived from plant oil and animal fat
PCT/CA2015/050465 WO2016008035A1 (en) 2014-07-15 2015-05-22 High productivity kolbe reaction process for transformation of fatty acids derived from plant oil and animal fat

Publications (1)

Publication Number Publication Date
MX2017000590A true MX2017000590A (es) 2017-07-11

Family

ID=55077758

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2017000590A MX2017000590A (es) 2014-07-15 2015-05-22 Proceso de reaccion de kolbe de alta productividad para la transformacion de acidos grasos derivados de aceite vegetal y grasa animal.

Country Status (11)

Country Link
EP (1) EP3177755B1 (es)
JP (1) JP2017527682A (es)
KR (1) KR102346418B1 (es)
CN (1) CN107075698B (es)
AU (1) AU2015291733B2 (es)
BR (1) BR112017000810B8 (es)
CA (1) CA2955050C (es)
ES (1) ES2732474T3 (es)
MX (1) MX2017000590A (es)
MY (1) MY178479A (es)
WO (1) WO2016008035A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6849586B2 (ja) * 2014-09-15 2021-03-24 アドヴォネックス インターナショナル コーポレーション 飽和及び不飽和脂肪酸の混合物のコルベ脱炭酸反応による炭化水素の生成
US11891708B2 (en) * 2018-02-12 2024-02-06 Gridthink Inc. Grid level energy storage system and process
CN109811361B (zh) * 2019-01-25 2021-06-08 华南理工大学 一种(e)-乙烯基硫氰酸酯类化合物的电化学制备方法
TWI821244B (zh) * 2019-02-12 2023-11-11 美商格思公司 經改良網格級儲能系統及方法
CN109913891B (zh) * 2019-04-08 2021-01-15 天津大学 一种由丁二酸溶液电解制备甲烷的方法
CN110016689B (zh) * 2019-04-08 2021-01-15 天津大学 一种烯丙醇的电化学制备方法
CN110079821B (zh) * 2019-04-08 2021-01-15 天津大学 一种由低浓度己二酸溶液电解制备丙烷的方法
CN110042420B (zh) * 2019-04-08 2021-01-15 天津大学 一种甲烷的电化学制备方法
CN110790898B (zh) * 2019-08-31 2022-03-15 忠信世纪电子材料(始兴)有限公司 一种改性环氧树脂及其制备方法
CN116867927A (zh) * 2021-03-05 2023-10-10 国立大学法人东北大学 碱金属/碱土金属氢氧化物的制造方法和该制造方法在羧酸盐废弃物再资源化技术中的应用

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4018844A (en) * 1972-06-26 1977-04-19 Otto Meresz Long chain internally unsaturated alkenes
US8518680B2 (en) * 2009-04-17 2013-08-27 The United States Of America, As Represented By The Secretary Of Agriculture Biological/electrolytic conversion of biomass to hydrocarbons
WO2011011521A2 (en) * 2009-07-23 2011-01-27 Ceramatec, Inc. Decarboxylation cell for production of coupled radical products
JP2014513149A (ja) 2011-02-01 2014-05-29 エイチ． ジョシ，チャンドラシェカー 植物油及び動物脂肪からの炭化水素燃料の製造

Also Published As

Publication number Publication date
CN107075698B (zh) 2019-07-23
BR112017000810B8 (pt) 2023-01-10
WO2016008035A1 (en) 2016-01-21
CN107075698A (zh) 2017-08-18
JP2017527682A (ja) 2017-09-21
EP3177755A1 (en) 2017-06-14
CA2955050A1 (en) 2016-01-21
BR112017000810A2 (pt) 2017-12-05
CA2955050C (en) 2022-04-19
KR20170039682A (ko) 2017-04-11
AU2015291733B2 (en) 2019-03-07
EP3177755A4 (en) 2018-03-21
ES2732474T3 (es) 2019-11-22
EP3177755B1 (en) 2019-03-27
AU2015291733A1 (en) 2017-03-02
BR112017000810B1 (pt) 2022-02-22
MY178479A (en) 2020-10-14
KR102346418B1 (ko) 2021-12-31

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