BR112017000810A2 - processo de reação de kolbe de produtividade alta para transformação de ácidos graxos derivados de óleo vegetal e gordura animal - Google Patents

processo de reação de kolbe de produtividade alta para transformação de ácidos graxos derivados de óleo vegetal e gordura animal

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Publication number
BR112017000810A2
BR112017000810A2 BR112017000810A BR112017000810A BR112017000810A2 BR 112017000810 A2 BR112017000810 A2 BR 112017000810A2 BR 112017000810 A BR112017000810 A BR 112017000810A BR 112017000810 A BR112017000810 A BR 112017000810A BR 112017000810 A2 BR112017000810 A2 BR 112017000810A2
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BR
Brazil
Prior art keywords
fatty acids
reaction process
animal fat
kolbe reaction
transformation
Prior art date
Application number
BR112017000810A
Other languages
English (en)
Other versions
BR112017000810B8 (pt
BR112017000810B1 (pt
Inventor
H Joshi Chandrashekhar
Malevich Dzmitry
thomas thornton gibson Graham
Glenn Horner Michael
Original Assignee
Advonex Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US14/331,390 external-priority patent/US8961775B2/en
Application filed by Advonex Int Corp filed Critical Advonex Int Corp
Publication of BR112017000810A2 publication Critical patent/BR112017000810A2/pt
Publication of BR112017000810B1 publication Critical patent/BR112017000810B1/pt
Publication of BR112017000810B8 publication Critical patent/BR112017000810B8/pt

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00Electrolytic production of organic compounds
    • C25B3/20Processes
    • C25B3/29Coupling reactions
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/10Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond in hydrocarbons containing no six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/62Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing platinum group metals or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/02Well-defined hydrocarbons
    • C10M105/04Well-defined hydrocarbons aliphatic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M177/00Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24Phosphines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02Gasoline
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/06Gasoil
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Electrochemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Lubricants (AREA)

Abstract

trata-se de óleos de gorduras vegetais e animais que são hidrolisados para ácidos graxos para uma reação de kolbe. a invenção se refere a um processo de reação de kolbe de produtividade alta para realizar a descarboxilação de modo ele-troquímico de ácidos graxos de c4-c28 com o uso de quantidades pequenas de ácido acético para reduzir tensão de passivação anódica e sintetizar hidrocarbone-tos de c6-c54. os c6-c54 são submetidos ao processo de metátese de olefina e/ou reação de hidroisomerização para sintetizar produtos de óleo de combustível pesa-do, combustível diesel, combustível querosene, óleo de base lubrificante e alfaolefi-na linear úteis como precursores para polímeros, detergentes e outros produtos químicos refinados.
BR112017000810A 2014-07-15 2015-05-22 Método para aumentar a produtividade de uma reação de eletrólise de kolbe que forma um ou mais hidrocarbonetos de c6 a c54 BR112017000810B8 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US14/331,390 2014-07-15
US14/331,390 US8961775B2 (en) 2011-02-01 2014-07-15 High productivity Kolbe reaction process for transformation of fatty acids derived from plant oil and animal fat
PCT/CA2015/050465 WO2016008035A1 (en) 2014-07-15 2015-05-22 High productivity kolbe reaction process for transformation of fatty acids derived from plant oil and animal fat

Publications (3)

Publication Number Publication Date
BR112017000810A2 true BR112017000810A2 (pt) 2017-12-05
BR112017000810B1 BR112017000810B1 (pt) 2022-02-22
BR112017000810B8 BR112017000810B8 (pt) 2023-01-10

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
BR112017000810A BR112017000810B8 (pt) 2014-07-15 2015-05-22 Método para aumentar a produtividade de uma reação de eletrólise de kolbe que forma um ou mais hidrocarbonetos de c6 a c54

Country Status (11)

Country Link
EP (1) EP3177755B1 (pt)
JP (1) JP2017527682A (pt)
KR (1) KR102346418B1 (pt)
CN (1) CN107075698B (pt)
AU (1) AU2015291733B2 (pt)
BR (1) BR112017000810B8 (pt)
CA (1) CA2955050C (pt)
ES (1) ES2732474T3 (pt)
MX (1) MX2017000590A (pt)
MY (1) MY178479A (pt)
WO (1) WO2016008035A1 (pt)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20170055520A (ko) * 2014-09-15 2017-05-19 아드보넥스 인터내셔널 코포레이션 포화 지방산과 불포화 지방산의 혼합물의 콜베 탈카복실화에 의한 탄화수소의 생산
CN111989307A (zh) * 2018-02-12 2020-11-24 格思公司 经改良网格级储能系统和方法
CN109811361B (zh) * 2019-01-25 2021-06-08 华南理工大学 一种(e)-乙烯基硫氰酸酯类化合物的电化学制备方法
TWI821244B (zh) * 2019-02-12 2023-11-11 美商格思公司 經改良網格級儲能系統及方法
CN110016689B (zh) * 2019-04-08 2021-01-15 天津大学 一种烯丙醇的电化学制备方法
CN110079821B (zh) * 2019-04-08 2021-01-15 天津大学 一种由低浓度己二酸溶液电解制备丙烷的方法
CN110042420B (zh) * 2019-04-08 2021-01-15 天津大学 一种甲烷的电化学制备方法
CN109913891B (zh) * 2019-04-08 2021-01-15 天津大学 一种由丁二酸溶液电解制备甲烷的方法
CN110790898B (zh) * 2019-08-31 2022-03-15 忠信世纪电子材料(始兴)有限公司 一种改性环氧树脂及其制备方法
CN116867927A (zh) * 2021-03-05 2023-10-10 国立大学法人东北大学 碱金属/碱土金属氢氧化物的制造方法和该制造方法在羧酸盐废弃物再资源化技术中的应用

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US4018844A (en) * 1972-06-26 1977-04-19 Otto Meresz Long chain internally unsaturated alkenes
US8518680B2 (en) * 2009-04-17 2013-08-27 The United States Of America, As Represented By The Secretary Of Agriculture Biological/electrolytic conversion of biomass to hydrocarbons
WO2011011521A2 (en) * 2009-07-23 2011-01-27 Ceramatec, Inc. Decarboxylation cell for production of coupled radical products
JP2014513149A (ja) 2011-02-01 2014-05-29 エイチ. ジョシ,チャンドラシェカー 植物油及び動物脂肪からの炭化水素燃料の製造

Also Published As

Publication number Publication date
EP3177755A1 (en) 2017-06-14
JP2017527682A (ja) 2017-09-21
BR112017000810B8 (pt) 2023-01-10
EP3177755B1 (en) 2019-03-27
AU2015291733B2 (en) 2019-03-07
MY178479A (en) 2020-10-14
KR20170039682A (ko) 2017-04-11
AU2015291733A1 (en) 2017-03-02
WO2016008035A1 (en) 2016-01-21
MX2017000590A (es) 2017-07-11
ES2732474T3 (es) 2019-11-22
CN107075698A (zh) 2017-08-18
BR112017000810B1 (pt) 2022-02-22
CN107075698B (zh) 2019-07-23
EP3177755A4 (en) 2018-03-21
CA2955050A1 (en) 2016-01-21
CA2955050C (en) 2022-04-19
KR102346418B1 (ko) 2021-12-31

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B06A Patent application procedure suspended [chapter 6.1 patent gazette]
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