MX2016007862A - Sulfonatos de furan-2, 5-dimetanol y (tetrahidrofuran-2, 5-diil)dimetanol y derivados de los mismos. - Google Patents
Sulfonatos de furan-2, 5-dimetanol y (tetrahidrofuran-2, 5-diil)dimetanol y derivados de los mismos.Info
- Publication number
- MX2016007862A MX2016007862A MX2016007862A MX2016007862A MX2016007862A MX 2016007862 A MX2016007862 A MX 2016007862A MX 2016007862 A MX2016007862 A MX 2016007862A MX 2016007862 A MX2016007862 A MX 2016007862A MX 2016007862 A MX2016007862 A MX 2016007862A
- Authority
- MX
- Mexico
- Prior art keywords
- dimethanol
- sulfonates
- furan
- diyl
- tetrahydrofuran
- Prior art date
Links
- DSLRVRBSNLHVBH-UHFFFAOYSA-N 2,5-furandimethanol Chemical compound OCC1=CC=C(CO)O1 DSLRVRBSNLHVBH-UHFFFAOYSA-N 0.000 title abstract 4
- 150000003871 sulfonates Chemical class 0.000 title abstract 3
- YCZZQSFWHFBKMU-UHFFFAOYSA-N [5-(hydroxymethyl)oxolan-2-yl]methanol Chemical compound OCC1CCC(CO)O1 YCZZQSFWHFBKMU-UHFFFAOYSA-N 0.000 title abstract 2
- 239000003153 chemical reaction reagent Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 230000000269 nucleophilic effect Effects 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000012038 nucleophile Substances 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/42—Singly bound oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/12—Radicals substituted by oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/18—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/24—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/42—Singly bound oxygen atoms
- C07D307/44—Furfuryl alcohol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
- C07D307/48—Furfural
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/52—Radicals substituted by nitrogen atoms not forming part of a nitro radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/54—Quaternary phosphonium compounds
- C07F9/5456—Arylalkanephosphonium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Furan Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Se describe un proceso para preparar moléculas de mono- y/o disulfonato furánico a partir de productos de reducción de HMF, en particular, a partir de 2,5-bis-hidroximetiltetrahidrofuranos (THF-dioles) o furan-2,5-dimetanol (FDM) en condiciones relativamente suaves. El proceso implica hacer reaccionar THF-dioles o FDM con al menos una especie de sulfonato, y un reactivo de 1) una base nucleófila o 2) combinación una base no nucleófila y un nucleófilo, como dos reactivos diferentes. También se proporcionan los sulfonatos furánicos sintetizados de acuerdo con el proceso y algunos de los compuestos asociados que pueden derivatizarse a partir de los sulfonatos.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201361918217P | 2013-12-19 | 2013-12-19 | |
PCT/US2014/070012 WO2015094965A1 (en) | 2013-12-19 | 2014-12-12 | Sulfonates of furan-2,5-dimethanol and (tetrahydrofuran-2,5-diyl)dimethanol and derivatives thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2016007862A true MX2016007862A (es) | 2016-09-07 |
Family
ID=53403550
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2016007862A MX2016007862A (es) | 2013-12-19 | 2014-12-12 | Sulfonatos de furan-2, 5-dimetanol y (tetrahidrofuran-2, 5-diil)dimetanol y derivados de los mismos. |
Country Status (10)
Country | Link |
---|---|
US (1) | US20160304479A1 (es) |
EP (1) | EP3083577A4 (es) |
JP (1) | JP2017504562A (es) |
KR (1) | KR20160098290A (es) |
CN (1) | CN105814031A (es) |
AU (1) | AU2014366329A1 (es) |
CA (1) | CA2931552A1 (es) |
HK (1) | HK1226392A1 (es) |
MX (1) | MX2016007862A (es) |
WO (1) | WO2015094965A1 (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102017008073A1 (de) * | 2017-08-28 | 2019-02-28 | Henkel Ag & Co. Kgaa | Neue anionische Tenside und Wasch- und Reinigungsmittel, welche diese enthalten |
US11242305B2 (en) | 2017-12-15 | 2022-02-08 | Sironix Renewables, Inc. | Reactive distillation for forming surfactants |
BR112021000309A2 (pt) | 2018-07-12 | 2021-04-06 | Sironix Renewables, Inc. | Método para formar um surfactante, e, composto |
US20210380567A1 (en) * | 2018-10-11 | 2021-12-09 | Drexel University | Renewable bio-based non-toxic aromatic-furanic monomers for use in thermosetting and thermoplastic polymers |
WO2021225932A1 (en) * | 2020-05-04 | 2021-11-11 | Sironix Renewables, Inc. | Furan surfactant compositions and methods |
EP4176028A1 (en) * | 2020-07-06 | 2023-05-10 | Unilever IP Holdings B.V. | Irritation mitigating surfactants |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3953596A (en) * | 1973-06-14 | 1976-04-27 | Ici United States Inc. | 8-Oxa-3-azabicyclo(3.2.1)octane analgesic compositions and method of alleviating pain in animals |
DK0863905T3 (da) * | 1995-09-18 | 2001-01-02 | Pfizer | Imidazollipoxygenaseinhibitorer |
PT1140924E (pt) * | 1998-12-14 | 2006-08-31 | Astellas Pharma Inc | Derivados de piperazina |
WO2000047585A1 (en) * | 1999-02-11 | 2000-08-17 | Novartis Ag | 3-hydroxy-4-aryl-5-pyrazoline derivatives as herbicides |
WO2001017352A1 (de) * | 1999-09-07 | 2001-03-15 | Syngenta Participations Ag | Herbizides mittel |
IL150912A0 (en) * | 2000-02-25 | 2003-02-12 | Hoffmann La Roche | Adenosine receptor modulators |
DE10244810A1 (de) * | 2002-09-26 | 2004-04-08 | Bayer Ag | Neue Morpholin-überbrückte Indazolderivate |
JP2006515276A (ja) * | 2002-10-22 | 2006-05-25 | オスコテック株式会社 | 骨粗鬆症の予防及び治療効果を有するフラン誘導体並びにこれを含む薬学的組成物 |
CN105801528B (zh) * | 2008-10-30 | 2019-06-21 | 阿彻丹尼尔斯米德兰德公司 | 用金属催化剂还原hmf醚 |
EP2430010B1 (en) * | 2009-05-14 | 2015-04-29 | Archer Daniels Midland Co. | Oxidation of furfural compounds |
WO2013007585A1 (fr) * | 2011-07-08 | 2013-01-17 | Rhodia Operations | Nouveau polyamide, procede de preparation et utilisations |
KR101374219B1 (ko) * | 2012-03-18 | 2014-03-13 | 서울대학교산학협력단 | 알킬암모늄아세테이트염을 이용한 새로운 5-아세트옥시메틸푸르푸랄의 제조방법 |
BR112015026885A2 (pt) * | 2013-04-29 | 2017-07-25 | Archer Daniels Midland Co | método de preparação de um sulfonato de 5-(hidroximetil)furan-2-carbaldeído (hmf), composto químico, método de preparação de um composto derivado furânico de um hmf-sulfonato e composto derivado furânico |
US9422304B2 (en) * | 2013-06-12 | 2016-08-23 | Archer Daniels Midland Company | Synthesis of isohexide dicarbamates and derivatives thereof |
KR20160024938A (ko) * | 2013-06-28 | 2016-03-07 | 아처 다니엘 미드랜드 캄파니 | 테트라하이드로푸란-2,5-디카브알데하이드(디포르밀-테트라하이드로푸란, dfthf) 및 이의 제조 방법 |
KR20160083865A (ko) * | 2013-10-17 | 2016-07-12 | 아처 다니엘 미드랜드 캄파니 | Thf-디올로부터의 디애시드, 디알데히드 또는 디아민의 합성 |
CA2931554C (en) * | 2013-12-19 | 2020-10-13 | Archer Daniels Midland Company | Mono- and dialkyl ethers of furan-2,5-dimethanol and (tetra-hydrofuran-2,5-diyl)dimethanol and amphiphilic derivatives thereof |
-
2014
- 2014-12-12 JP JP2016530006A patent/JP2017504562A/ja active Pending
- 2014-12-12 WO PCT/US2014/070012 patent/WO2015094965A1/en active Application Filing
- 2014-12-12 CN CN201480067993.2A patent/CN105814031A/zh active Pending
- 2014-12-12 EP EP14870859.7A patent/EP3083577A4/en not_active Withdrawn
- 2014-12-12 AU AU2014366329A patent/AU2014366329A1/en not_active Abandoned
- 2014-12-12 CA CA2931552A patent/CA2931552A1/en not_active Abandoned
- 2014-12-12 KR KR1020167017409A patent/KR20160098290A/ko not_active Application Discontinuation
- 2014-12-12 US US15/038,061 patent/US20160304479A1/en not_active Abandoned
- 2014-12-12 MX MX2016007862A patent/MX2016007862A/es unknown
-
2016
- 2016-12-22 HK HK16114627A patent/HK1226392A1/zh unknown
Also Published As
Publication number | Publication date |
---|---|
WO2015094965A1 (en) | 2015-06-25 |
HK1226392A1 (zh) | 2017-09-29 |
AU2014366329A1 (en) | 2016-06-02 |
EP3083577A1 (en) | 2016-10-26 |
CA2931552A1 (en) | 2015-06-25 |
US20160304479A1 (en) | 2016-10-20 |
JP2017504562A (ja) | 2017-02-09 |
CN105814031A (zh) | 2016-07-27 |
EP3083577A4 (en) | 2017-08-16 |
KR20160098290A (ko) | 2016-08-18 |
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