MX2014014142A - Regeneracion de catalizadores para la hidrogenacion de azucares. - Google Patents

Regeneracion de catalizadores para la hidrogenacion de azucares.

Info

Publication number
MX2014014142A
MX2014014142A MX2014014142A MX2014014142A MX2014014142A MX 2014014142 A MX2014014142 A MX 2014014142A MX 2014014142 A MX2014014142 A MX 2014014142A MX 2014014142 A MX2014014142 A MX 2014014142A MX 2014014142 A MX2014014142 A MX 2014014142A
Authority
MX
Mexico
Prior art keywords
catalyst
hydrogenation
sugars
regeneration
catalysts
Prior art date
Application number
MX2014014142A
Other languages
English (en)
Other versions
MX357913B (es
Inventor
Chicheng Ma
Original Assignee
Archer Daniels Midland Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Archer Daniels Midland Co filed Critical Archer Daniels Midland Co
Publication of MX2014014142A publication Critical patent/MX2014014142A/es
Publication of MX357913B publication Critical patent/MX357913B/es

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/462Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/755Nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • B01J23/94Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • B01J23/96Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00Catalysts of the Raney type
    • B01J25/02Raney nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00Catalysts of the Raney type
    • B01J25/04Regeneration or reactivation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/90Regeneration or reactivation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/04Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/06Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using steam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/54Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids halogen-containing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/60Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/64Liquid treating or treating in liquid phase, e.g. dissolved or suspended using alkaline material; using salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/70Wet oxidation of material submerged in liquid
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/62Catalyst regeneration
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Saccharide Compounds (AREA)

Abstract

Se describe un proceso para regenerar catalizadores que se han desactivado o envenenado durante la hidrogenación de biomasa, azúcares y polisacáridos, en el que se pueden eliminar las especies polimerizadas que se hayan aglomerado en las superficies del catalizador lavando el catalizador con agua caliente a temperaturas subcríticas. Una característica del proceso regenera los catalizadores in situ, lo cual permite adaptar el proceso para usarlo en sistemas de reactores de producción continua. También se describe un proceso de hidrogenación continuo que incorpora el proceso de regeneración de la presente.
MX2014014142A 2012-05-24 2013-04-17 Regeneración de catalizadores para la hidrogenación de azúcares. MX357913B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261651021P 2012-05-24 2012-05-24
PCT/US2013/036901 WO2013176803A1 (en) 2012-05-24 2013-04-17 Regeneration of catalyst for hydrogenation of sugars

Publications (2)

Publication Number Publication Date
MX2014014142A true MX2014014142A (es) 2015-02-04
MX357913B MX357913B (es) 2018-07-27

Family

ID=49624238

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014014142A MX357913B (es) 2012-05-24 2013-04-17 Regeneración de catalizadores para la hidrogenación de azúcares.

Country Status (16)

Country Link
US (3) US9144797B2 (es)
EP (2) EP2855013B1 (es)
JP (1) JP6216779B2 (es)
KR (2) KR20150020591A (es)
CN (1) CN104302396B (es)
AU (2) AU2013266809B2 (es)
BR (1) BR112014028940B1 (es)
CA (1) CA2873359C (es)
ES (1) ES2912749T3 (es)
HU (1) HUE058866T2 (es)
IN (1) IN2014DN10635A (es)
MX (1) MX357913B (es)
MY (3) MY172662A (es)
PL (1) PL2855013T3 (es)
PT (1) PT2855013T (es)
WO (1) WO2013176803A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6518259B2 (ja) * 2014-02-10 2019-05-29 アーチャー−ダニエルズ−ミッドランド カンパニー 改善された多相低混合プロセス
EP3416740B1 (en) 2016-02-19 2021-01-06 Intercontinental Great Brands LLC Processes to create multiple value streams from biomass sources
US20190345185A1 (en) * 2016-12-20 2019-11-14 Archer-Daniels-Midland Company Continuous process for hydrogenation of maltose to maltitol
MX2020002011A (es) 2017-08-23 2020-07-13 Ecolab Usa Inc Dispersante de azufre elemental para controlar las incrustaciones en sistemas de agua.
JP7483705B2 (ja) * 2018-11-20 2024-05-15 イーエスエス テック インコーポレーテッド レドックスフロー電池用電解液の状態管理
KR20200082438A (ko) * 2018-12-28 2020-07-08 한화솔루션 주식회사 수소화 촉매의 재생 방법
CN111686824A (zh) * 2020-06-11 2020-09-22 中科合成油内蒙古有限公司 一种固定床费托合成钌基催化剂的原位再生方法
WO2023023290A1 (en) * 2021-08-19 2023-02-23 Virent, Inc. Systems and methods for wet air oxidation regeneration of catalysts
JP2026501881A (ja) * 2023-01-19 2026-01-16 ヴィレント,インコーポレイテッド 酸素雰囲気と窒素雰囲気との間の切り替えを伴うバイオマス水素化触媒の湿式酸化再生の方法;それを含むバイオマス水素化方法
AU2024225941A1 (en) 2023-02-20 2025-09-04 Johnson Matthey Davy Technologies Limited Systems and methods for wet air oxidation regeneration of catalysts with ion exchange

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US5206194A (en) * 1991-06-20 1993-04-27 Union Oil Company Of America Process for reactivating a deactivated crystalline molecular sieve group VIII metal catalyst
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DE10061863A1 (de) * 2000-12-12 2002-06-13 Basf Ag Verfahren zur Herstellung von Triethylendiamin (TEDA)
US6566539B1 (en) * 2002-07-18 2003-05-20 E.I. Du Pont De Nemours And Company Catalyst regeneration by treatment with an oxidizing agent
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Also Published As

Publication number Publication date
EP2855013B1 (en) 2022-03-16
CA2873359C (en) 2019-06-25
US9144797B2 (en) 2015-09-29
EP4070886A1 (en) 2022-10-12
MY183297A (en) 2021-02-18
BR112014028940A8 (pt) 2020-09-24
AU2017202169B2 (en) 2017-06-22
US9687839B2 (en) 2017-06-27
BR112014028940A2 (pt) 2017-06-27
MX357913B (es) 2018-07-27
KR102046288B1 (ko) 2019-11-18
HUE058866T2 (hu) 2022-09-28
EP2855013A1 (en) 2015-04-08
JP2015523906A (ja) 2015-08-20
MY170884A (en) 2019-09-11
US9427733B2 (en) 2016-08-30
AU2013266809B2 (en) 2017-03-09
CN104302396B (zh) 2018-02-13
KR20150020591A (ko) 2015-02-26
BR112014028940B1 (pt) 2021-01-05
CA2873359A1 (en) 2013-11-28
ES2912749T3 (es) 2022-05-27
CN104302396A (zh) 2015-01-21
WO2013176803A1 (en) 2013-11-28
US20150360219A1 (en) 2015-12-17
JP6216779B2 (ja) 2017-10-18
US20160332154A1 (en) 2016-11-17
PL2855013T3 (pl) 2022-05-30
KR20190020844A (ko) 2019-03-04
EP2855013A4 (en) 2016-09-14
PT2855013T (pt) 2022-05-04
AU2017202169A1 (en) 2017-04-20
IN2014DN10635A (es) 2015-09-11
AU2013266809A1 (en) 2014-11-06
MY172662A (en) 2019-12-09
US20150126784A1 (en) 2015-05-07

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