MX2014010737A - Polimerización radicalaria controlada en una dispersión de agua en agua. - Google Patents

Polimerización radicalaria controlada en una dispersión de agua en agua.

Info

Publication number
MX2014010737A
MX2014010737A MX2014010737A MX2014010737A MX2014010737A MX 2014010737 A MX2014010737 A MX 2014010737A MX 2014010737 A MX2014010737 A MX 2014010737A MX 2014010737 A MX2014010737 A MX 2014010737A MX 2014010737 A MX2014010737 A MX 2014010737A
Authority
MX
Mexico
Prior art keywords
water
radical polymerisation
soluble
group
controlled radical
Prior art date
Application number
MX2014010737A
Other languages
English (en)
Inventor
Mathias Destarac
James David Wilson
Silvia Stoilova
Original Assignee
Rhodia Operations
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Operations filed Critical Rhodia Operations
Publication of MX2014010737A publication Critical patent/MX2014010737A/es

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52Amides or imides
    • C08F220/54Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/56Acrylamide; Methacrylamide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • C08F2/10Aqueous solvent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D153/00Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2400/00Characteristics for processes of polymerization
    • C08F2400/02Control or adjustment of polymerization parameters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/03Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

La presente invención se refiere a un método para preparar una dispersión acuosa de polímeros hidrosolubles que comprende un paso (E) de polimerización radicalaria, donde se ponen en contacto los siguientes componentes en un medio acuoso (M) en el cual el polímero sintetizado no es soluble: -al menos un monómero etilénicamente insaturado que sea soluble en el medio acuoso (M); -al menos una fuente de radicales libres; y -un estabilizador reactivo que comprende: -una cadena polimérica (CP) que sea soluble en el medio (M); -un grupo (G) que proporcione la polimerización radicalaria del paso (E) de naturaleza controlada y viva, tal como, por ejemplo, un grupo que porte un grupo tiocarboniltio -S(C=S)-.
MX2014010737A 2012-03-09 2013-03-11 Polimerización radicalaria controlada en una dispersión de agua en agua. MX2014010737A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1200725A FR2987837B1 (fr) 2012-03-09 2012-03-09 Polymerisation radicalaire controlee en dispersion eau-dans-l'eau
PCT/EP2013/054905 WO2013132108A1 (fr) 2012-03-09 2013-03-11 Polymérisation radicalaire contrôlée en dispersion eau-dans-l'eau

Publications (1)

Publication Number Publication Date
MX2014010737A true MX2014010737A (es) 2015-02-24

Family

ID=47913381

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014010737A MX2014010737A (es) 2012-03-09 2013-03-11 Polimerización radicalaria controlada en una dispersión de agua en agua.

Country Status (11)

Country Link
US (2) US10160821B2 (es)
EP (1) EP2822976B1 (es)
CN (1) CN104395352B (es)
AU (1) AU2013229414B2 (es)
BR (1) BR112014022215B1 (es)
CA (1) CA2866576C (es)
DK (1) DK2822976T3 (es)
FR (1) FR2987837B1 (es)
MX (1) MX2014010737A (es)
RU (1) RU2014140807A (es)
WO (1) WO2013132108A1 (es)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2987837B1 (fr) * 2012-03-09 2014-03-14 Rhodia Operations Polymerisation radicalaire controlee en dispersion eau-dans-l'eau
US10584217B2 (en) 2015-06-25 2020-03-10 Kemira Oyj Method for producing a material with a network of at least two polymers, a product thereof and use of the product
WO2017076661A1 (de) * 2015-11-06 2017-05-11 Basf Se Verfahren zur herstellung eines wässrigen bindemittels
US10035946B2 (en) * 2016-02-23 2018-07-31 Ecolab Usa Inc. Hydrazide crosslinked polymer emulsions for use in crude oil recovery
US20180072909A1 (en) * 2016-09-09 2018-03-15 Rhodia Operations Self-thickening latex for waterborne systems and related methods
CN108070063B (zh) * 2017-12-29 2020-03-24 中国科学院广州能源研究所 一种乙烯基酰胺类嵌段共聚物水合物动力学抑制剂及其制备方法与应用
FR3079833B1 (fr) * 2018-04-10 2020-10-09 Rhodia Operations Composition aqueuse gelifiee pour l'extraction petroliere
CA3115384A1 (en) * 2018-10-11 2020-04-16 Rhodia Operations Polymer dispersion by controlled radical polymerization
EP3874007A1 (en) * 2018-11-02 2021-09-08 Rhodia Operations S.A. Polymer dispersions for wax inhibition during stimulation treatment
JP7271962B2 (ja) * 2019-01-22 2023-05-12 東亞合成株式会社 水溶性ポリマーの製造方法
CA3160563A1 (en) 2019-12-02 2021-06-10 Qing Wang Polymer dispersions for oilfield friction reduction
CN112210087B (zh) * 2020-09-30 2021-10-08 华中农业大学 一种水包水Pickering乳液及其制备方法

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3658772A (en) 1966-10-20 1972-04-25 Dow Chemical Co Acrylic acid polymers
US3493500A (en) 1966-10-20 1970-02-03 Dow Chemical Co Acrylic acid polymers
JPS50127991A (es) 1974-03-29 1975-10-08
JPS5252006A (en) 1975-10-24 1977-04-26 Mitsubishi Heavy Ind Ltd Moisture separation heater outlet steam temperature control system
US5763548A (en) 1995-03-31 1998-06-09 Carnegie-Mellon University (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
ES2166092T3 (es) * 1996-07-10 2002-04-01 Du Pont Polimerizacion con caracteristicas vivientes.
FR2764892B1 (fr) 1997-06-23 2000-03-03 Rhodia Chimie Sa Procede de synthese de polymeres a blocs
JP2001510208A (ja) 1997-07-15 2001-07-31 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド ニトロソ化合物又はニトロン化合物から誘導されたアルコキシアミン化合物を含む重合可能な組成物
AU1911399A (en) 1997-12-18 1999-07-05 Commonwealth Scientific And Industrial Research Organisation Polymerization process with living characteristics and polymers made therefrom
KR100687663B1 (ko) 1998-12-18 2007-02-28 바스프 악티엔게젤샤프트 중합체 반응 생성물의 제조 방법
PL197702B1 (pl) 1998-12-23 2008-04-30 Basf Ag Środki powłokowe i ich zastosowanie
FR2794463B1 (fr) 1999-06-04 2005-02-25 Rhodia Chimie Sa Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates halogenes
FR2802208B1 (fr) 1999-12-09 2003-02-14 Rhodia Chimie Sa Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates
FR2812293B1 (fr) 2000-07-28 2002-12-27 Rhodia Chimie Sa Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee
US6569969B2 (en) 2000-09-28 2003-05-27 Symyx Technologies, Inc. Control agents for living-type free radical polymerization, methods of polymerizing and polymers with same
FR2848556B1 (fr) * 2002-12-13 2006-06-16 Bio Merieux Procede de polymerisation radicalaire controlee
US6753391B1 (en) * 2003-05-05 2004-06-22 3M Innovative Properties Company Ring-opened azlactone chain transfer agents for radical polymerization
FR2879606B1 (fr) 2004-12-22 2007-06-08 Snf Sas Soc Par Actions Simpli Dispersions aqueuses salines de (co)polymeres anioniques ou amphoteres, leur procede de fabrication et leurs applications
FR2903109B1 (fr) * 2006-06-30 2012-08-03 Rhodia Recherches & Tech Polymerisation a partir d'une amine di-allylique et compose comprenant une chaine macromoleculaire comprenant des unites derivant de cette amine
FR2917415B1 (fr) * 2007-06-14 2012-10-12 Rhodia Recherches Et Tech Microgel polymerique comprenant des unites cationiques
US7789160B2 (en) * 2007-10-31 2010-09-07 Rhodia Inc. Addition of nonionic surfactants to water soluble block copolymers to increase the stability of the copolymer in aqueous solutions containing salt and/or surfactants
US8912273B2 (en) * 2008-06-17 2014-12-16 Basf Se Process for the preparation of an aqueous polymer dispersion
EP2534205B1 (en) * 2010-02-12 2016-05-04 Rhodia Operations Rheology modifier compositions and methods of use
GB201003970D0 (en) * 2010-03-10 2010-04-21 Univ Sheffield Polymer synthesis
FR2965564B1 (fr) * 2010-09-30 2012-10-26 Rhodia Operations Preparation de polymeres hydrophiles de haute masse par polymerisation radicalaire controlee
US9255163B2 (en) * 2012-01-31 2016-02-09 Rhodia Operations Dispersed phase polymerization of halogenated vinyl monomers in the presence of live reactive stabilizers
WO2013113750A1 (fr) * 2012-01-31 2013-08-08 Rhodia Operations Stabilisants réactifs poly(n-vinyl lactame) vivants pour polymérisation en phase dispersée
FR2987837B1 (fr) * 2012-03-09 2014-03-14 Rhodia Operations Polymerisation radicalaire controlee en dispersion eau-dans-l'eau

Also Published As

Publication number Publication date
BR112014022215B1 (pt) 2021-08-31
BR112014022215A2 (es) 2017-06-20
CA2866576C (fr) 2020-03-24
US20190085110A1 (en) 2019-03-21
EP2822976B1 (fr) 2016-10-19
AU2013229414A1 (en) 2014-09-25
RU2014140807A (ru) 2016-04-27
EP2822976A1 (fr) 2015-01-14
US11168165B2 (en) 2021-11-09
WO2013132108A1 (fr) 2013-09-12
AU2013229414B2 (en) 2016-11-17
CA2866576A1 (fr) 2013-09-12
CN104395352B (zh) 2017-07-14
US10160821B2 (en) 2018-12-25
CN104395352A (zh) 2015-03-04
FR2987837B1 (fr) 2014-03-14
US20150057411A1 (en) 2015-02-26
FR2987837A1 (fr) 2013-09-13
DK2822976T3 (en) 2017-02-06

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