MX2014009863A - Proceso para convertir sulfuro de hidrogeno en disulfuro de carbono. - Google Patents
Proceso para convertir sulfuro de hidrogeno en disulfuro de carbono.Info
- Publication number
- MX2014009863A MX2014009863A MX2014009863A MX2014009863A MX2014009863A MX 2014009863 A MX2014009863 A MX 2014009863A MX 2014009863 A MX2014009863 A MX 2014009863A MX 2014009863 A MX2014009863 A MX 2014009863A MX 2014009863 A MX2014009863 A MX 2014009863A
- Authority
- MX
- Mexico
- Prior art keywords
- hydrogen sulfide
- carbon disulfide
- processes
- converting hydrogen
- bromine
- Prior art date
Links
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 title abstract 9
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title abstract 6
- 229910000037 hydrogen sulfide Inorganic materials 0.000 title abstract 6
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 2
- 229910052794 bromium Inorganic materials 0.000 abstract 2
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/70—Compounds containing carbon and sulfur, e.g. thiophosgene
- C01B32/72—Carbon disulfide
- C01B32/75—Preparation by reacting sulfur or sulfur compounds with hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/70—Compounds containing carbon and sulfur, e.g. thiophosgene
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/09—Bromine; Hydrogen bromide
- C01B7/096—Bromine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
- C10L3/101—Removal of contaminants
- C10L3/102—Removal of contaminants of acid contaminants
- C10L3/103—Sulfur containing contaminants
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/38—Applying an electric field or inclusion of electrodes in the apparatus
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
- C10L2290/541—Absorption of impurities during preparation or upgrading of a fuel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
- C10L2290/543—Distillation, fractionation or rectification for separating fractions, components or impurities during preparation or upgrading of a fuel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
- C10L2290/545—Washing, scrubbing, stripping, scavenging for separating fractions, components or impurities during preparation or upgrading of a fuel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Gas Separation By Absorption (AREA)
- Carbon And Carbon Compounds (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Se describen procesos para formar disulfuro de carbono a partir de una corriente gaseosa que contiene sulfuro de hidrógeno. Una corriente gaseosa que contiene alcanos de peso molecular inferior y sulfuro de hidrógeno puede ponerse en contacto con suficiente bromo a una temperatura desde aproximadamente 250°C hasta aproximadamente 530°C para convertir prácticamente todo el sulfuro de hidrógeno en disulfuro de carbono. La corriente gaseosa puede contener desde aproximadamente 0.001 hasta aproximadamente3 20% molar de sulfuro de hidrógeno. La relación molar de bromo a sulfuro de hidrógeno puede ser alrededor de 2:1.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261599498P | 2012-02-16 | 2012-02-16 | |
US13/760,291 US20130217938A1 (en) | 2012-02-16 | 2013-02-06 | Processes for converting hydrogen sulfide to carbon disulfide |
PCT/US2013/025706 WO2013122916A1 (en) | 2012-02-16 | 2013-02-12 | Processes for converting hydrogen sulfide to carbon disulfide |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2014009863A true MX2014009863A (es) | 2015-02-04 |
Family
ID=48982769
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014009863A MX2014009863A (es) | 2012-02-16 | 2013-02-12 | Proceso para convertir sulfuro de hidrogeno en disulfuro de carbono. |
Country Status (13)
Country | Link |
---|---|
US (1) | US20130217938A1 (es) |
EP (1) | EP2814792A4 (es) |
JP (1) | JP2015510486A (es) |
KR (1) | KR20140133580A (es) |
CN (1) | CN104271538A (es) |
AU (1) | AU2013221804A1 (es) |
CA (1) | CA2864792A1 (es) |
IL (1) | IL234060A0 (es) |
IN (1) | IN2014DN07137A (es) |
MX (1) | MX2014009863A (es) |
RU (1) | RU2014137320A (es) |
SG (1) | SG11201404974UA (es) |
WO (1) | WO2013122916A1 (es) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080275284A1 (en) | 2004-04-16 | 2008-11-06 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
WO2017147681A1 (en) | 2016-03-04 | 2017-09-08 | Bogdan Wojak | Sulphur-assisted carbon capture and utilization (ccu) methods and systems |
US11472924B2 (en) | 2018-12-20 | 2022-10-18 | Gas Technology Institute | Methods and systems to decarbonize natural gas using sulfur to produce hydrogen and polymers |
WO2021198175A1 (en) * | 2020-03-30 | 2021-10-07 | Total Se | Gas to olefins process with coproduction of hydrogen together with electrified reactional section |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3240564A (en) * | 1966-03-15 | Manufacture (if carbon desulfhde | ||
US2809930A (en) * | 1954-11-18 | 1957-10-15 | American Dev Corp | Removal of sulfur compounds from fluids |
LU87923A1 (de) * | 1991-04-24 | 1992-11-16 | Euratom | Verfahren zum entfernen von schwefelwasserstoff und/oder schwefelkohlenstoff aus abgasen |
US5385650A (en) * | 1991-11-12 | 1995-01-31 | Great Lakes Chemical Corporation | Recovery of bromine and preparation of hypobromous acid from bromide solution |
US8173851B2 (en) * | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
EA011939B1 (ru) * | 2005-04-21 | 2009-06-30 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способы получения нефти и/или газа и системы для их осуществления |
CN101289162B (zh) * | 2008-05-24 | 2011-01-12 | 孔庆然 | 一种由硫化氢生产氢气和二硫化碳的方法 |
US20090312586A1 (en) * | 2008-06-13 | 2009-12-17 | Marathon Gtf Technology, Ltd. | Hydrogenation of multi-brominated alkanes |
US20100234637A1 (en) * | 2009-03-16 | 2010-09-16 | Fong Howard Lam Ho | Integrated process to coproduce aromatic hydrocarbons and ethylene and propylene |
US20110015458A1 (en) * | 2009-07-15 | 2011-01-20 | Marathon Gtf Technology, Ltd. | Conversion of hydrogen bromide to elemental bromine |
-
2013
- 2013-02-06 US US13/760,291 patent/US20130217938A1/en not_active Abandoned
- 2013-02-12 SG SG11201404974UA patent/SG11201404974UA/en unknown
- 2013-02-12 CN CN201380014188.9A patent/CN104271538A/zh active Pending
- 2013-02-12 AU AU2013221804A patent/AU2013221804A1/en not_active Abandoned
- 2013-02-12 IN IN7137DEN2014 patent/IN2014DN07137A/en unknown
- 2013-02-12 CA CA2864792A patent/CA2864792A1/en not_active Abandoned
- 2013-02-12 KR KR20147025802A patent/KR20140133580A/ko not_active Application Discontinuation
- 2013-02-12 WO PCT/US2013/025706 patent/WO2013122916A1/en active Application Filing
- 2013-02-12 JP JP2014557717A patent/JP2015510486A/ja active Pending
- 2013-02-12 MX MX2014009863A patent/MX2014009863A/es unknown
- 2013-02-12 RU RU2014137320A patent/RU2014137320A/ru not_active Application Discontinuation
- 2013-02-12 EP EP13749494.4A patent/EP2814792A4/en not_active Withdrawn
-
2014
- 2014-08-11 IL IL234060A patent/IL234060A0/en unknown
Also Published As
Publication number | Publication date |
---|---|
WO2013122916A1 (en) | 2013-08-22 |
EP2814792A4 (en) | 2015-11-04 |
US20130217938A1 (en) | 2013-08-22 |
KR20140133580A (ko) | 2014-11-19 |
SG11201404974UA (en) | 2014-10-30 |
IN2014DN07137A (es) | 2015-04-24 |
AU2013221804A1 (en) | 2014-09-25 |
CN104271538A (zh) | 2015-01-07 |
EP2814792A1 (en) | 2014-12-24 |
IL234060A0 (en) | 2014-09-30 |
JP2015510486A (ja) | 2015-04-09 |
RU2014137320A (ru) | 2016-04-10 |
CA2864792A1 (en) | 2013-08-22 |
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