MX2013012389A - Catalizadores de metales nobles con baja carga de metal de la deshidrogenaciones oxidativas. - Google Patents

Catalizadores de metales nobles con baja carga de metal de la deshidrogenaciones oxidativas.

Info

Publication number
MX2013012389A
MX2013012389A MX2013012389A MX2013012389A MX2013012389A MX 2013012389 A MX2013012389 A MX 2013012389A MX 2013012389 A MX2013012389 A MX 2013012389A MX 2013012389 A MX2013012389 A MX 2013012389A MX 2013012389 A MX2013012389 A MX 2013012389A
Authority
MX
Mexico
Prior art keywords
metal
plasma
oxidative
dehydrations
noble metal
Prior art date
Application number
MX2013012389A
Other languages
English (en)
Inventor
Georg Seeber
Dirk Grossschmidt
Torsten Maeurer
Christian Baltes
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of MX2013012389A publication Critical patent/MX2013012389A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/466—Osmium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/468—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B01J37/0223—Coating of particles by rotation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/349—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of flames, plasmas or lasers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Toxicology (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La invención se refiere a un método para producir un catalizador que comprende de 0.05 a 0.25 % en peso de metales nobles, preferiblemente para la deshidrogenación oxidativa de alcoholes olefínicamente instaurados, que comprende los siguientes pasos: a) generación de un plasma de corriente directa, b) introducción de metal y material de soporte en el plasma, c) vaporización de metal y material de soporte y material portador en el plasma o "rociado" del cuerpo sólido de metal y material portador en el plasma y haciendo reaccionar las partículas, d) enfriamiento en donde se obtienen las partículas muy pequeñas de un material mixto, y e) aplicación del material mixto al portador de catalizador actual. La invención además se refiere a un catalizador producido correspondientemente y al uso del mismo.
MX2013012389A 2011-04-28 2012-03-13 Catalizadores de metales nobles con baja carga de metal de la deshidrogenaciones oxidativas. MX2013012389A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11164044 2011-04-28
PCT/EP2012/054386 WO2012146436A1 (de) 2011-04-28 2012-03-13 Edelmetallkatalysatoren mit geringer metallbeladung für oxidative dehydrierungen

Publications (1)

Publication Number Publication Date
MX2013012389A true MX2013012389A (es) 2013-11-04

Family

ID=45812801

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2013012389A MX2013012389A (es) 2011-04-28 2012-03-13 Catalizadores de metales nobles con baja carga de metal de la deshidrogenaciones oxidativas.

Country Status (5)

Country Link
EP (1) EP2701840A1 (es)
JP (1) JP6023790B2 (es)
CN (1) CN103501895B (es)
MX (1) MX2013012389A (es)
WO (1) WO2012146436A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109806865A (zh) * 2017-11-20 2019-05-28 中国科学院大连化学物理研究所 一种金催化剂的制备及其在异戊烯醇氧化反应中的应用
CN108080002A (zh) * 2017-12-01 2018-05-29 中海油天津化工研究设计院有限公司 多元活性组分高度分散的低碳烷烃脱氢催化剂及制备方法
WO2020099390A1 (en) 2018-11-13 2020-05-22 Basf Se Catalyst bed comprising silver catalyst bodies and process for the oxidative dehydrogenation of olefinically unsaturated alcohols
WO2023099727A1 (en) 2021-12-03 2023-06-08 Basf Se Process for preparing isoprenal and/or prenal

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2020865C3 (de) 1970-04-29 1975-05-07 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von alpha, beta-ungesättigten Carbonylverbindungen
DE2715209C3 (de) 1977-04-05 1981-11-05 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von 3-Alkyl-buten-l-alen
NL8201396A (nl) * 1982-04-01 1983-11-01 Dow Chemical Nederland Zilver katalysator en een werkwijze voor de bereiding daarvan.
DE3612213A1 (de) 1986-04-11 1987-10-15 Basf Ag Rohrbuendelreaktor, dessen verwendung bei exothermen organischen reaktionen und verfahren zur herstellung von ketonen und aldehyden mit hilfe des rohrbuendelreaktors
DE3633885A1 (de) * 1986-10-04 1988-04-07 Basf Ag Verfahren zur kontinuierlichen herstellung von aliphatischen aldehyden und ketonen
DE68925767T2 (de) 1988-08-30 1996-08-14 Union Carbide Corp Katalysatoren für die Herstellung von Ethylenoxid und Verfahren zur deren Herstellung
DE4311608A1 (de) 1993-04-08 1994-12-15 Huels Chemische Werke Ag Silberkatalysator zur Oxidation von Ethylen zu Ethylenoxid und Verfahren zur Herstellung von Ethylenoxid
DE19748299A1 (de) * 1996-10-31 1998-05-07 Sumitomo Chemical Co Verfahren zur Herstellung von Chlor
US5989648A (en) * 1997-05-06 1999-11-23 The Penn State Research Foundation Plasma generation of supported metal catalysts
DE19722567A1 (de) 1997-05-28 1998-12-03 Basf Ag Verfahren zur kontinuierlichen technischen Herstellung ungesättigter aliphatischer Aldehyde in einem Rohrbündelreaktor
JP4000392B2 (ja) * 1997-11-05 2007-10-31 独立行政法人産業技術総合研究所 炭化水素の部分酸化用触媒及び含酸素有機化合物の製法
JPH11323192A (ja) * 1998-05-15 1999-11-26 Mitsubishi Materials Corp 帯電防止効果のある光触媒膜とその形成用の光触媒塗料
EP1034843A1 (de) * 1999-03-10 2000-09-13 Sulzer Metco AG Verfahren zur Herstellung einer beschichteten Struktur, die sich zum Durchführen von heterogenen Katalysen eignet
JP2001261337A (ja) * 2000-03-23 2001-09-26 C I Kasei Co Ltd 銀微粒子を複合した二酸化チタン微粒子の製造方法
US6689192B1 (en) 2001-12-13 2004-02-10 The Regents Of The University Of California Method for producing metallic nanoparticles
EP1743043A4 (en) * 2004-04-19 2008-08-27 Sdc Materials Llc HIGH-THROUGHPUT DISCOVERY OF MATERIALS BY MEANS OF STEAM PHASE SYNTHESIS
EP1810001A4 (en) 2004-10-08 2008-08-27 Sdc Materials Llc DEVICE AND METHOD FOR SAMPLING AND COLLECTING POWDERS FLOWING IN A GASSTROM
JP4565191B2 (ja) * 2006-01-30 2010-10-20 国立大学法人山梨大学 微粒子触媒の製造方法、微粒子触媒、及び改質装置
JP2007302612A (ja) * 2006-05-12 2007-11-22 Nippon Shokubai Co Ltd ケトンの製造方法
JP4970120B2 (ja) * 2007-04-13 2012-07-04 公立大学法人首都大学東京 金微粒子を担体に分散・固定する方法
WO2008140786A1 (en) * 2007-05-11 2008-11-20 Sdc Materials, Inc. Method and apparatus for making uniform and ultrasmall nanoparticles
DE102008014910A1 (de) 2008-03-19 2009-09-24 Basf Se Verwendung eines geträgerten edelmetallhaltigen Katalysators zur oxidativen Dehydrierung
EP2392401A1 (en) * 2009-02-02 2011-12-07 Pioneer Corporation TiO2 NANOPARTICLES
JP5278189B2 (ja) * 2009-06-19 2013-09-04 株式会社明電舎 光触媒再生方法及び腐食性ガス浄化装置
CN102470346B (zh) * 2009-07-02 2015-07-08 巴斯夫欧洲公司 用于氧化脱氢或环氧化的负载型含贵金属催化剂
DE102009034773A1 (de) * 2009-07-25 2011-01-27 Bayer Materialscience Ag Verfahren zur Herstellung von Chlor durch Gasphasenoxidation an nanostrukturierten Rutheniumträgerkatalysatoren
US8669202B2 (en) * 2011-02-23 2014-03-11 SDCmaterials, Inc. Wet chemical and plasma methods of forming stable PtPd catalysts

Also Published As

Publication number Publication date
EP2701840A1 (de) 2014-03-05
CN103501895A (zh) 2014-01-08
JP2014516770A (ja) 2014-07-17
JP6023790B2 (ja) 2016-11-09
CN103501895B (zh) 2016-05-25
WO2012146436A1 (de) 2012-11-01

Similar Documents

Publication Publication Date Title
SA112330632B1 (ar) تركيبة للوحات وأنابيب بحجم النانو وطرق لإنتاجها
EP4360756A3 (en) Nanostructured battery active materials and methods of producing same
MY175308A (en) Compositions and methods for activating "stimulator of interferon gene"-dependent signalling
IN2014CN02974A (es)
WO2009089513A3 (en) Methods of generating supported nanocatalysts and compositions thereof
MX365479B (es) Metodo para producir articulo curvo y miembro de estructura de esqueleto para carroceria de automovil.
MX2013012389A (es) Catalizadores de metales nobles con baja carga de metal de la deshidrogenaciones oxidativas.
MX2015006893A (es) Reactores y metodos para producir materiales de carbono solido.
MY180714A (en) Factor viii chimeric and hybrid polypeptides, and methods of use thereof
MX2012005588A (es) Metodo para aumentar la eficiencia en un proceso de separacion de minerales por medio de particulas magneticas hidrofobicas mediante la entrada focalizada de energia mecanica.
TW200942492A (en) Sodium/molybdenum composite metal powders, products thereof, and methods for producing photovoltaic cells
WO2011101300A3 (de) Herstellung von kohlenstoffnanoröhrchen
WO2013150305A3 (en) Alcohol production process
MX2012001157A (es) Procedimiento para la preparacion de 2,2-difluoroetilamina.
MY180633A (en) Solid particles, containing lactam, activator, and catalyst, method for producing said solid particles, and use of said solid particles
MY163070A (en) Process to produce valerolactone from levulinic acid
GB2503838A (en) Electrolytic exfoliation of graphite
MX2015010622A (es) Materiales grafiticos funcionalizados.
CA2864377A1 (en) Catalytically active body for the synthesis of dimethyl ether from synthesis gas
WO2016020656A3 (en) Methanol production catalyst and methanol production process
MX2014005854A (es) Procedimiento de produccion de un cojinete deslizante que comprende un compuesto de cuni2si, cufe2p o cusnx.
WO2014179648A3 (en) Direct anti-markovnikov addition of acids to alkenes
GB201200360D0 (en) Component production method
MX2012008679A (es) Una planta para la fabricacion continua de granulado plastico expandible asi como el metodo para producirlo.
IN2014DN07057A (es)