MX2011004526A - Reduccion de eteres de hmf con un catalizador metalico. - Google Patents

Reduccion de eteres de hmf con un catalizador metalico.

Info

Publication number
MX2011004526A
MX2011004526A MX2011004526A MX2011004526A MX2011004526A MX 2011004526 A MX2011004526 A MX 2011004526A MX 2011004526 A MX2011004526 A MX 2011004526A MX 2011004526 A MX2011004526 A MX 2011004526A MX 2011004526 A MX2011004526 A MX 2011004526A
Authority
MX
Mexico
Prior art keywords
methanol
alkoxymethyl
furan
tetrahydrofuran
compounds
Prior art date
Application number
MX2011004526A
Other languages
English (en)
Inventor
Paul David Bloom
Alexandra J Sanborn
Original Assignee
Archer Daniels Midland Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Archer Daniels Midland Co filed Critical Archer Daniels Midland Co
Publication of MX2011004526A publication Critical patent/MX2011004526A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/54—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/26—Preparation of ethers by reactions not forming ether-oxygen bonds by introduction of hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C07C43/13—Saturated ethers containing hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/12—Radicals substituted by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/16—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/42—Singly bound oxygen atoms
    • C07D307/44—Furfuryl alcohol
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)
  • Catalysts (AREA)

Abstract

Esta exposición describe métodos para reducir éter de hidroximetilfurfural y derivados de éster para producir, en el caso de los éteres, 5-(alcoximetil)-tetrahidrofurano-2-metanol y derivados de (5-alcoximetil)-furano-2-metanol, o en el caso de los ésteres, 5-(aciloximetil)-tetrahidrofurano-2-metanol y derivados de 5-(aciloximetil)-furano-2-metanol. Los métodos ejemplificados describen la purificación de los mismos. Además, la exposición se refiere a compuestos de n-alcoxi hexano diol, que son compuestos derivados útiles para el reemplazo de compuestos de carbitol a base de petróleo y pueden producirse mediante la reducción adicional del 5-(alcoximetil)-tetrahidrofura no-2-metanol y derivados de (5-alcoximetil)-furano-2-metanol. Los compuestos producidos por los métodos de la presente enseñanza son útiles como solventes y como materiales de inicio para producir otras composiciones que satisfacen los requerimientos de los químicos industriales de base biológica provenientes de recursos renovables.
MX2011004526A 2008-10-30 2009-10-30 Reduccion de eteres de hmf con un catalizador metalico. MX2011004526A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10963408P 2008-10-30 2008-10-30
PCT/US2009/062778 WO2010062689A2 (en) 2008-10-30 2009-10-30 Reduction of hmf ethers with metal catalyst

Publications (1)

Publication Number Publication Date
MX2011004526A true MX2011004526A (es) 2011-12-14

Family

ID=42226332

Family Applications (2)

Application Number Title Priority Date Filing Date
MX2014015367A MX362580B (es) 2008-10-30 2009-10-30 Reduccion de eteres de hmf con un catalizador metalico.
MX2011004526A MX2011004526A (es) 2008-10-30 2009-10-30 Reduccion de eteres de hmf con un catalizador metalico.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
MX2014015367A MX362580B (es) 2008-10-30 2009-10-30 Reduccion de eteres de hmf con un catalizador metalico.

Country Status (9)

Country Link
US (4) US8709286B2 (es)
EP (1) EP2350035B1 (es)
CN (3) CN103626639B (es)
AU (1) AU2009319998B2 (es)
BR (1) BRPI0914384B1 (es)
ES (1) ES2566649T3 (es)
HU (1) HUE029859T2 (es)
MX (2) MX362580B (es)
WO (1) WO2010062689A2 (es)

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WO2009076627A2 (en) * 2007-12-12 2009-06-18 Archer Daniels Midland Co Conversion of carbohydrates to hydroxy-methylfurfural (hmf) and derivatives
EP2350035B1 (en) * 2008-10-30 2016-01-13 Archer Daniels Midland Co. Reduction of hmf ethers with metal catalyst
CN104011001A (zh) 2011-12-30 2014-08-27 纳幕尔杜邦公司 制备1,6-己二醇的方法
WO2013101970A1 (en) 2011-12-30 2013-07-04 E. I. Du Pont De Nemours And Company Production of 5-hydroxymethyl-2-furfural from levoglucosenone
US8865940B2 (en) 2011-12-30 2014-10-21 E I Du Pont De Nemours And Company Process for preparing 1,6-hexanediol
US8889912B2 (en) 2011-12-30 2014-11-18 E I Du Pont De Nemours And Company Process for preparing 1,6-hexanediol
BR112014015999A8 (pt) 2011-12-30 2017-07-04 Du Pont processo
US8884035B2 (en) 2011-12-30 2014-11-11 E I Du Pont De Nemours And Company Production of tetrahydrofuran-2, 5-dimethanol from isosorbide
US8846985B2 (en) 2012-04-27 2014-09-30 E I Du Pont De Nemours And Company Production of alpha, omega-diols
US8859826B2 (en) 2012-04-27 2014-10-14 E I Du Pont De Nemours And Company Production of alpha, omega-diols
US9018423B2 (en) 2012-04-27 2015-04-28 E I Du Pont De Nemours And Company Production of alpha, omega-diols
CN103073526B (zh) * 2012-12-26 2014-12-03 中国科学院宁波材料技术与工程研究所 一种2，5-二取代的四氢呋喃类混合物的制备方法
MX2015014835A (es) * 2013-04-25 2016-03-11 Archer Daniels Midland Co Sintesis catalitica de derivados de furano reducidos.
AU2014366329A1 (en) * 2013-12-19 2016-06-02 Archer Daniels Midland Company Sulfonates of furan-2,5-dimethanol and (tetrahydrofuran-2,5-diyl)dimethanol and derivatives thereof
SG11201805514VA (en) 2016-01-13 2018-07-30 Stora Enso Oyj Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof
WO2017222532A1 (en) * 2016-06-23 2017-12-28 Archer Daniels Midland Company Preparation of mono- and di-alkyl halide furanic compounds from 2,5-bis(hydroxymethyl)-tetrahydrofurans (bhmthf) and derivatives thereof
US11192872B2 (en) 2017-07-12 2021-12-07 Stora Enso Oyj Purified 2,5-furandicarboxylic acid pathway products
CN115697982A (zh) * 2020-06-22 2023-02-03 东丽精细化工株式会社 四氢呋喃-2-羧酸的制造方法

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Also Published As

Publication number Publication date
EP2350035B1 (en) 2016-01-13
BRPI0914384B1 (pt) 2017-04-18
WO2010062689A3 (en) 2010-07-22
AU2009319998B2 (en) 2015-07-16
EP2350035A2 (en) 2011-08-03
WO2010062689A2 (en) 2010-06-03
CN103626639B (zh) 2016-12-07
MX362580B (es) 2019-01-25
CN102177146A (zh) 2011-09-07
US20160297788A1 (en) 2016-10-13
US9422258B2 (en) 2016-08-23
US20120261618A1 (en) 2012-10-18
CN105801528A (zh) 2016-07-27
US20140200299A1 (en) 2014-07-17
AU2009319998A1 (en) 2010-06-03
US9783516B2 (en) 2017-10-10
US20140239230A1 (en) 2014-08-28
CN105801528B (zh) 2019-06-21
US9416119B2 (en) 2016-08-16
CN103626639A (zh) 2014-03-12
CN102177146B (zh) 2016-02-10
BRPI0914384A2 (pt) 2016-10-18
HUE029859T2 (en) 2017-04-28
ES2566649T3 (es) 2016-04-14
US8709286B2 (en) 2014-04-29
EP2350035A4 (en) 2012-07-25

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