MX2009010709A - Catalizadores de oxido de metal mixto mejorados y procedimientos para (am) oxidacion de hidrocarburos de alcano inferior. - Google Patents

Catalizadores de oxido de metal mixto mejorados y procedimientos para (am) oxidacion de hidrocarburos de alcano inferior.

Info

Publication number
MX2009010709A
MX2009010709A MX2009010709A MX2009010709A MX2009010709A MX 2009010709 A MX2009010709 A MX 2009010709A MX 2009010709 A MX2009010709 A MX 2009010709A MX 2009010709 A MX2009010709 A MX 2009010709A MX 2009010709 A MX2009010709 A MX 2009010709A
Authority
MX
Mexico
Prior art keywords
mixed metal
lower alkane
alkane hydrocarbons
metal oxide
compositions
Prior art date
Application number
MX2009010709A
Other languages
English (en)
Inventor
James F Brazdil Jr
Alakananda Bhattacharyya
Gerry W Zajac
Bhagya Chandra Sutradhar
Original Assignee
Ineos Usa Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ineos Usa Llc filed Critical Ineos Usa Llc
Publication of MX2009010709A publication Critical patent/MX2009010709A/es

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057—Selenium or tellurium; Compounds thereof
    • B01J27/0576—Tellurium; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Se describen composiciones y procedimientos catalíticos para conversiones económicas de hidrocarburos de alcano inferior. En términos generales, la presente invención describe composiciones sólidas tratadas con promotor que contienen óxidos de metal mixtos que presentan actividad catalítica para amoxidación de hidrocarburos de alcano inferior para producir un nitrilo insaturado con rendimientos altos. En general, estas composiciones de oxido sólidas comprenden, como elementos componentes, molibdeno (Mo), vanadio (V), niobio (Nb) y por lo menos un elemento activo que se selecciona a partir del grupo que consiste de elementos que tienen la capacidad de formar iones positivos. Las composiciones catalíticas de óxido de metal mixto, de manera conveniente, se forman mediante pasos de procedimiento que comprenden impregnación de un catalizador base con un medio acuoso que comprende fuentes de uno o más elementos promotores, secado del material resultante; y después de esto someter el material seco a tratamiento con calor, bajo una atmósfera gaseosa que está sustancialmente libre de dioxígeno, a temperaturas elevadas de por lo menos 400ºC. También se describen métodos para formar los catalizadores mejorados que tienen la estructura cristalina deseada y procedimientos de amoxidación para conversión de alcanos inferiores.
MX2009010709A 2007-04-03 2008-04-01 Catalizadores de oxido de metal mixto mejorados y procedimientos para (am) oxidacion de hidrocarburos de alcano inferior. MX2009010709A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/732,213 US20080248947A1 (en) 2007-04-03 2007-04-03 Mixed metal oxide catalysts and catalytic processes for conversions of lower alkane hydrocarbons
PCT/US2008/004227 WO2008123974A1 (en) 2007-04-03 2008-04-01 Improved mixed metal oxide catalysts and process for (amm) oxidation of lower alkane hydrocarbons

Publications (1)

Publication Number Publication Date
MX2009010709A true MX2009010709A (es) 2009-10-26

Family

ID=39545017

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2009010709A MX2009010709A (es) 2007-04-03 2008-04-01 Catalizadores de oxido de metal mixto mejorados y procedimientos para (am) oxidacion de hidrocarburos de alcano inferior.

Country Status (9)

Country Link
US (1) US20080248947A1 (es)
EP (1) EP2134466A1 (es)
JP (1) JP2010523314A (es)
KR (1) KR20100016115A (es)
CN (1) CN101678327A (es)
BR (1) BRPI0809952A2 (es)
MX (1) MX2009010709A (es)
RU (1) RU2009140375A (es)
WO (1) WO2008123974A1 (es)

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US8697596B2 (en) * 2007-04-03 2014-04-15 Ineos Usa Llc Mixed metal oxide catalysts and catalytic conversions of lower alkane hydrocarbons
US20090005586A1 (en) * 2007-06-29 2009-01-01 Brazdil Jr James F Mixed metal oxide catalysts for the ammoxidation of propane and isobutane
US7919428B2 (en) * 2007-12-04 2011-04-05 Ineos Usa Llc Method of making mixed metal oxide catalysts for ammoxidation and/or oxidation of lower alkane hydrocarbons
MY162465A (en) * 2011-04-21 2017-06-15 Asahi Kasei Chemicals Corp Silica-supported catalyst
CN104661745A (zh) * 2012-09-27 2015-05-27 旭化成化学株式会社 复合氧化物催化剂及其制造方法、和不饱和腈的制造方法
US9409156B2 (en) 2012-10-19 2016-08-09 Instituto Mexicano Del Petroleo Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process
CA2936448C (en) * 2016-07-19 2024-02-20 Nova Chemicals Corporation Controlled pressure hydrothermal treatment of odh catalyst
JPWO2018066158A1 (ja) * 2016-10-05 2019-07-25 東亞合成株式会社 金属酸化物触媒およびその製造方法
EA202190812A1 (ru) * 2018-10-18 2021-07-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Катализатор окислительного дегидрирования алканов и/или окисления алкенов

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Also Published As

Publication number Publication date
CN101678327A (zh) 2010-03-24
BRPI0809952A2 (pt) 2014-10-07
WO2008123974A1 (en) 2008-10-16
RU2009140375A (ru) 2011-05-10
JP2010523314A (ja) 2010-07-15
EP2134466A1 (en) 2009-12-23
KR20100016115A (ko) 2010-02-12
US20080248947A1 (en) 2008-10-09

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