MX2007005169A - Procedimiento para el desenriquecimiento de substratos enantiomericamente enriquecidos. - Google Patents
Procedimiento para el desenriquecimiento de substratos enantiomericamente enriquecidos.Info
- Publication number
- MX2007005169A MX2007005169A MX2007005169A MX2007005169A MX2007005169A MX 2007005169 A MX2007005169 A MX 2007005169A MX 2007005169 A MX2007005169 A MX 2007005169A MX 2007005169 A MX2007005169 A MX 2007005169A MX 2007005169 A MX2007005169 A MX 2007005169A
- Authority
- MX
- Mexico
- Prior art keywords
- optionally substituted
- enantiomerically enriched
- heteroatom
- optionally
- enantiomer
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B55/00—Racemisation; Complete or partial inversion
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B31/00—Reduction in general
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
- C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/07—Optical isomers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Se provee un procedimiento para el desenriquecimiento de composiciones enantiomericamente enriquecidas que comprende hacer reaccionar una composicion enantiomericamente enriquecida que comprende por lo menos un primer enantiomero o diastereomero de un substrato que comprende un enlace carbono-heteroatomo, en donde el carbono es un centro quiral y el heteroatomo es un heteroatomo del grupo VI, en la presencia de un sistema catalizador y opcionalmente un promotor de reaccion para dar una composicion de producto que comprende primeros y segundos enantiomeros o diastereomeros del substrato que tiene un enlace carbono-heteroatomo, la relacion de segundo a primer enantiomero o diastereomero en la composicion de producto es mayor que la relacion de segundo a primer enantiomero o diastereomero en la composicion enantiomericamente enriquecida. Substratos preferidos incluyen compuestos de Formula (I) (ver Formula (1)) en donde X representa O, S; R1, R2 cada uno representa independientemente un hidrocarbilo opcionalmente substituido, un hidrocarbilo perthalogenado, un grupo heterociclico opcionalmente substituido; o R1 y R2 se unen opcionalmente a fin de formar un anillo(s) opcionalmente substituido; con la condicion de que R1, R2 se seleccionan de tal manera que * es un centro quiral. En un procedimiento preferido se puede obtener un compuesto de Formula (2) (ver Formula (2)) en donde: X representa O, S; R1, R2 cada uno representa independientemente un hidrocarbilo opcionalmente substituido, un hidrocarbilo perthalogenado, un grupo heterociclico opcionalmente substituido; o R1 y R2 se unen opcionalmente a fin de formar un anillo(s) opcionalmente substituido; con la condicion de que R1, R2 son diferentes.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0424000.8A GB0424000D0 (en) | 2004-10-29 | 2004-10-29 | Process |
PCT/GB2005/004179 WO2006046062A1 (en) | 2004-10-29 | 2005-10-27 | Process for the de-enrichment of enantiomerically enriched substrates |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2007005169A true MX2007005169A (es) | 2007-07-04 |
Family
ID=33515740
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2007005169A MX2007005169A (es) | 2004-10-29 | 2005-10-27 | Procedimiento para el desenriquecimiento de substratos enantiomericamente enriquecidos. |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP1809586A1 (es) |
JP (1) | JP2008517990A (es) |
KR (1) | KR20070068428A (es) |
CN (1) | CN101052604A (es) |
BR (1) | BRPI0517243A (es) |
CA (1) | CA2583821A1 (es) |
GB (1) | GB0424000D0 (es) |
IL (1) | IL182589A0 (es) |
MX (1) | MX2007005169A (es) |
WO (1) | WO2006046062A1 (es) |
ZA (1) | ZA200702979B (es) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008056768A1 (fr) * | 2006-11-10 | 2008-05-15 | Wako Pure Chemical Industries, Ltd. | Catalyseur de métaux porteur de composites carbone/éthylénédiamine et son procédé de production |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5476964A (en) * | 1994-11-21 | 1995-12-19 | Uop | Continuous racemization of benzylic alcohols, ethers, and esters by solid acid catalyst |
EP1300381B1 (en) * | 1995-12-06 | 2006-03-08 | Japan Science and Technology Agency | Process for preparing optically active alcohols |
CA2165125A1 (en) * | 1995-12-13 | 1997-06-14 | David W. House | Continuous process for racemization of benzylic alcohols, ethers, and esters by solid acid catalyst |
GB0029356D0 (en) * | 2000-12-01 | 2001-01-17 | Avecia Ltd | Transfer hydrogenation |
DE10062729A1 (de) * | 2000-12-15 | 2002-06-20 | Basf Ag | Verfahren zur Racemisierung von optisch aktiven Aminen |
DE10133783A1 (de) * | 2001-07-16 | 2003-02-06 | Degussa | Verfahren zur Racemisierung von Alkoholen |
-
2004
- 2004-10-29 GB GBGB0424000.8A patent/GB0424000D0/en not_active Ceased
-
2005
- 2005-10-27 BR BRPI0517243-8A patent/BRPI0517243A/pt not_active Application Discontinuation
- 2005-10-27 EP EP05804713A patent/EP1809586A1/en not_active Withdrawn
- 2005-10-27 KR KR1020077009554A patent/KR20070068428A/ko not_active Application Discontinuation
- 2005-10-27 CN CNA2005800374723A patent/CN101052604A/zh active Pending
- 2005-10-27 WO PCT/GB2005/004179 patent/WO2006046062A1/en active Application Filing
- 2005-10-27 CA CA002583821A patent/CA2583821A1/en not_active Abandoned
- 2005-10-27 MX MX2007005169A patent/MX2007005169A/es unknown
- 2005-10-27 JP JP2007538513A patent/JP2008517990A/ja active Pending
-
2007
- 2007-04-11 ZA ZA200702979A patent/ZA200702979B/xx unknown
- 2007-04-16 IL IL182589A patent/IL182589A0/en unknown
Also Published As
Publication number | Publication date |
---|---|
CA2583821A1 (en) | 2006-05-04 |
IL182589A0 (en) | 2007-07-24 |
EP1809586A1 (en) | 2007-07-25 |
ZA200702979B (en) | 2008-08-27 |
KR20070068428A (ko) | 2007-06-29 |
BRPI0517243A (pt) | 2008-10-07 |
GB0424000D0 (en) | 2004-12-01 |
WO2006046062A1 (en) | 2006-05-04 |
JP2008517990A (ja) | 2008-05-29 |
CN101052604A (zh) | 2007-10-10 |
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