MX170262B - Fibras de polipropileno estabilizadas, irradiables por rayos gamma y sus articulos esterilizables - Google Patents
Fibras de polipropileno estabilizadas, irradiables por rayos gamma y sus articulos esterilizablesInfo
- Publication number
- MX170262B MX170262B MX019611A MX1961190A MX170262B MX 170262 B MX170262 B MX 170262B MX 019611 A MX019611 A MX 019611A MX 1961190 A MX1961190 A MX 1961190A MX 170262 B MX170262 B MX 170262B
- Authority
- MX
- Mexico
- Prior art keywords
- fibers
- gamma
- alpha
- irradiable
- lightning
- Prior art date
Links
- 239000000835 fiber Substances 0.000 title abstract 6
- -1 POLYPROPYLENE Polymers 0.000 title 1
- 239000004743 Polypropylene Substances 0.000 title 1
- 229920001155 polypropylene Polymers 0.000 title 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 238000005562 fading Methods 0.000 abstract 1
- 230000005251 gamma ray Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229920005629 polypropylene homopolymer Polymers 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
- D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
- C08K5/3462—Six-membered rings
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Hydrogenated Pyridines (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
La presente invención se refiere a un metodo para impartir una fuerza mejorada y resistencia a la decoloración a fibras estabilizadas irradiadas con rayos gamma, el cual comprende incorporar en las fibras de homopolímero de polipropileno, o copolímeros de propileno con una cantidad menor de etileno, estas fibras están esencialmente exentas de un antioxidante, una cantidad eficaz, suficiente para atenuar la degradación por rayos gamma de las fibras, de una acetamida N-(substituída)-1-(piperazin-2-ona alquil)-alfa-(3,5-dialquil-4-hidroxifenil)-alfa,alfa-substituída ("3,5-DHPZNA"), que tiene un átomo de carbono alfa disubstituído, esta 3,5-DHPZNA tiene la estrutura.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/313,700 US5122593A (en) | 1989-02-22 | 1989-02-22 | Stabilized gamma-irradiatable polypropylene fibers and sterilizable articles thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX170262B true MX170262B (es) | 1993-08-12 |
Family
ID=23216766
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX019611A MX170262B (es) | 1989-02-22 | 1990-02-22 | Fibras de polipropileno estabilizadas, irradiables por rayos gamma y sus articulos esterilizables |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5122593A (es) |
| EP (1) | EP0384382A3 (es) |
| JP (1) | JPH02289111A (es) |
| CA (1) | CA2010438A1 (es) |
| MX (1) | MX170262B (es) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5200443A (en) * | 1991-03-29 | 1993-04-06 | Kimberly-Clark Corporation | Radiation stabilized fabric having improved odor characteristics containing an hindered amine compound |
| US5554441A (en) * | 1993-04-16 | 1996-09-10 | Hercules Incorporated | Random macrodomain multiconstituent fibers, their preparation, and nonwoven structures from such fibers |
| CA2120104A1 (en) * | 1993-04-19 | 1994-10-20 | Randall E. Kozulla | Multiconstituent fibers, and nonwoven structures of such fibers |
| FI95153C (fi) * | 1994-02-11 | 1995-12-27 | Suominen Oy J W | Menetelmä gamma-säteillytystä kestävän polypropeenikuidun valmistamiseksi säteilysteriloitavaa kuitukangasta varten sekä tähän liittyvänä mainitun mekaanisesti tai hydraulisesti sidottavan kuitukankaan valmistusmenetelmä |
| US5773375A (en) * | 1996-05-29 | 1998-06-30 | Swan; Michael D. | Thermally stable acoustical insulation |
| TW557313B (en) | 1998-02-02 | 2003-10-11 | Ciba Sc Holding Ag | Oxopiperazinyl derivatives and light stabilized compositions |
| US6664317B2 (en) | 2000-02-18 | 2003-12-16 | Ciba Specialty Chemicals Corporation | Stabilized gamma irradiated polyolefins |
| CA2406666A1 (en) * | 2000-05-11 | 2001-11-15 | The Dow Chemical Company | Method of making elastic articles having improved heat-resistance |
| US6749553B2 (en) * | 2000-05-18 | 2004-06-15 | Theragenics Corporation | Radiation delivery devices and methods for their manufacture |
| CA2414075A1 (en) | 2000-06-05 | 2001-12-13 | Theragenics Corporation | A device for delivering a therapeutic dosage |
| US20050164577A1 (en) * | 2002-03-11 | 2005-07-28 | Reid Rona L. | Stretch fabric with improved chemical resistance and durability |
| US6869982B2 (en) * | 2002-11-27 | 2005-03-22 | Basell Poliolefine Italia S.P.A. | Irradiated, oxidized olefin polymer coupling agents |
| US7291669B2 (en) * | 2004-03-16 | 2007-11-06 | Ciba Specialty Chemicals Corporation | Stabilized polyolefin compositions |
| WO2009003930A1 (en) | 2007-06-29 | 2009-01-08 | Basell Poliolefine Italia S.R.L. | An irradiated polyolefin composition comprising a non - phenolic stabilizer |
| US8389632B2 (en) | 2011-02-09 | 2013-03-05 | Equistar Chemicals, Lp | Co-continuous heterophase polymer compositions containing high melt strength polypropylene for extrusion coating |
| CN105733093B (zh) * | 2016-03-28 | 2018-12-04 | 中国石油化工股份有限公司 | 一种高流动性聚丙烯纤维专用树脂及其制备方法 |
| EP3688090A1 (en) * | 2017-09-29 | 2020-08-05 | Dow Global Technologies LLC | Thermoplastic polyolefin compositions useful for aldehyde abatement |
| CN112535744B (zh) * | 2020-12-03 | 2022-04-01 | 广州华大生物科技有限公司 | 一种实验耗材的辐照灭菌方法 |
| CN114044967B (zh) * | 2021-10-22 | 2023-07-11 | 金发科技股份有限公司 | 一种耐伽玛辐照透明聚丙烯组合物及其制备方法和应用 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2043079B (en) * | 1979-02-26 | 1982-12-08 | El Paso Polyolefins | High energy radiation treatment of stabilised propylene polymers |
| US4780495A (en) * | 1986-07-21 | 1988-10-25 | The B. F. Goodrich Company | N-(substituted)-α-(3,5-dialkyl-4-hydroxyphenyl)-α,α-disubstituted acetamides, and composition stabilized therewith |
| US4797438A (en) * | 1987-05-11 | 1989-01-10 | The B. F. Goodrich Company | Stabilized gamma-irradiated polypropylene and sterilizable articles thereof |
-
1989
- 1989-02-22 US US07/313,700 patent/US5122593A/en not_active Expired - Fee Related
-
1990
- 1990-02-20 EP EP19900103212 patent/EP0384382A3/en not_active Withdrawn
- 1990-02-20 CA CA002010438A patent/CA2010438A1/en not_active Abandoned
- 1990-02-22 MX MX019611A patent/MX170262B/es unknown
- 1990-02-22 JP JP2039892A patent/JPH02289111A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02289111A (ja) | 1990-11-29 |
| EP0384382A3 (en) | 1991-01-09 |
| CA2010438A1 (en) | 1990-08-22 |
| US5122593A (en) | 1992-06-16 |
| EP0384382A2 (en) | 1990-08-29 |
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