MX168629B - Mejoras en el tratamiento de oxidacion de mercaptanos en destilados de hidrocarburos y aparato - Google Patents

Mejoras en el tratamiento de oxidacion de mercaptanos en destilados de hidrocarburos y aparato

Info

Publication number
MX168629B
MX168629B MX002641A MX264186A MX168629B MX 168629 B MX168629 B MX 168629B MX 002641 A MX002641 A MX 002641A MX 264186 A MX264186 A MX 264186A MX 168629 B MX168629 B MX 168629B
Authority
MX
Mexico
Prior art keywords
distillate
hydrocarbon
alkali metal
aqueous alkali
hydrocarbon distillate
Prior art date
Application number
MX002641A
Other languages
English (en)
Inventor
Ralph E Maple
Felipe J Suarez
Original Assignee
Merichem Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Merichem Co filed Critical Merichem Co
Publication of MX168629B publication Critical patent/MX168629B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18—Details relating to the spatial orientation of the reactor
    • B01J2219/182—Details relating to the spatial orientation of the reactor horizontal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La presente invención se refiere a mejoras en el tratamiento de oxidación de mercaptados en destilados de hidrocarburos, que comprende las etapas de poner en contacto el destilado en la presencia de un haz de fibras con un oxidante de oxígeno gaseoso y una primer solución de hidroxilo de metal alcalino, acuosa, que contiene un catalizador de oxidación, durante un período de tiempo suficiente para oxidar al menos una porción de los compuestos mercaptanos en el destilado de hidrocarburos y separar el hidróxilo de metal alcalino acuoso del destilado hidrocarburo tratado, caracterizado por quitar el destilado hidrocarburo y el gas oxidante de la presencia del haz de fibras; poner en contacto el destilado hidrocarburo y gas oxidante con un lecho de catalizador de oxidació soportado, en la presencia de un segundo hidroxido de metal alcalino acuoso, a una temperatura. presión y durante un período de tiempo suficientes para oxidar al menos una porción de los restantes compuestos mercaptanos del destilado hidrocarburo tratado, y recuperar el producto destilado de hisdrocarburo, de la zona de catalizador.
MX002641A 1985-05-30 1986-05-28 Mejoras en el tratamiento de oxidacion de mercaptanos en destilados de hidrocarburos y aparato MX168629B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/739,563 US4675100A (en) 1985-05-30 1985-05-30 Treatment of sour hydrocarbon distillate

Publications (1)

Publication Number Publication Date
MX168629B true MX168629B (es) 1993-06-02

Family

ID=24972876

Family Applications (1)

Application Number Title Priority Date Filing Date
MX002641A MX168629B (es) 1985-05-30 1986-05-28 Mejoras en el tratamiento de oxidacion de mercaptanos en destilados de hidrocarburos y aparato

Country Status (5)

Country Link
US (1) US4675100A (es)
EP (1) EP0203574B1 (es)
JP (1) JPH0692584B2 (es)
DE (2) DE203574T1 (es)
MX (1) MX168629B (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4906354A (en) * 1987-09-10 1990-03-06 Mobil Oil Corporation Process for improving the thermal stability of jet fuels sweetened by oxidation
US4875997A (en) * 1988-11-17 1989-10-24 Montana Refining Company Process for treating hydrocarbons containing mercaptans
US5354482A (en) * 1993-05-07 1994-10-11 Merichem Company Process and apparatus for oxidizing industrial spent caustic and effecting gas-liquid mass transfer and separation
US5705074A (en) * 1996-11-19 1998-01-06 Merichem Company Removal of acidic organic contaminants from refinery waste water
US6251295B1 (en) * 1998-01-08 2001-06-26 Nexell Therapeutics Inc. Method for recirculation washing of blood cells
US5961819A (en) * 1998-02-09 1999-10-05 Merichem Company Treatment of sour hydrocarbon distillate with continuous recausticization
US5997731A (en) * 1998-03-27 1999-12-07 Merichem Company Process for treating an effluent alkaline stream having sulfur-containing and phenolic compounds
AU4718301A (en) * 1999-12-13 2001-06-18 Ds2 Tech, Inc. Process for the demercaptanization of petroleum distillates
EP1261681A1 (en) * 1999-12-13 2002-12-04 DS2 Tech, Inc. Process for desulfurization of petroleum distillates
US8308957B2 (en) 2007-06-14 2012-11-13 Merichem Company Process for separating mercaptans from caustic
US7875185B2 (en) * 2007-09-10 2011-01-25 Merichem Company Removal of residual sulfur compounds from a caustic stream
US8900446B2 (en) * 2009-11-30 2014-12-02 Merichem Company Hydrocarbon treatment process
KR101715437B1 (ko) 2010-03-25 2017-03-22 암웨스트, 엘엘씨 다중 스프링을 가지는 고용량 탄창
US9005432B2 (en) * 2010-06-29 2015-04-14 Saudi Arabian Oil Company Removal of sulfur compounds from petroleum stream
US8574429B2 (en) * 2010-08-31 2013-11-05 Merichem Company Sulfone removal from an oxidized hydrocarbon fuel
WO2012030874A2 (en) 2010-08-31 2012-03-08 President And Fellows Of Harvard College Electrochemically functional membranes
US9296956B2 (en) 2010-10-28 2016-03-29 Chevron U.S.A. Inc. Method for reducing mercaptans in hydrocarbons
US9488423B2 (en) 2011-01-14 2016-11-08 Arm West, Llc Firearm systems and methods
JP6072790B2 (ja) * 2011-07-29 2017-02-01 サウジ アラビアン オイル カンパニー 石油精製原料中の全酸価を減少させる方法
US9656185B2 (en) * 2012-07-11 2017-05-23 Merichem Company Contactor and separation apparatus and process of using same
GB2517985B (en) 2013-09-09 2016-01-06 Berishtenu Agricultural Cooperative Sheaf-based fluid filter
US10059889B2 (en) * 2016-06-22 2018-08-28 Merichem Company Oxidation process
US10488136B2 (en) 2016-09-23 2019-11-26 ArmWest, LLC Selective fire firearm systems and methods
US11198107B2 (en) 2019-09-05 2021-12-14 Visionary Fiber Technologies, Inc. Conduit contactor and method of using the same
CN111135603A (zh) * 2019-12-31 2020-05-12 大连汉诺工程技术有限公司 一种废碱处理方法
NL2032631B1 (en) * 2022-07-28 2024-02-05 Wrt B V Method for scavenging mercaptans in a hydrocarbon fluid

Family Cites Families (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2176806A (en) * 1938-01-24 1939-10-17 Skelly Oil Co Method and apparatus for contacting immiscible liquids
US2853432A (en) * 1954-12-28 1958-09-23 Universal Oil Prod Co Regeneration of used alkaline reagents by oxidizing the same in the presence of a phthalocyanine catalyst
US2921021A (en) * 1957-12-18 1960-01-12 Universal Oil Prod Co Treatment of sour hydrocarbon distillate
US3107213A (en) * 1959-02-12 1963-10-15 Exxon Research Engineering Co Caustic treating process
US2988500A (en) * 1959-03-13 1961-06-13 Universal Oil Prod Co Treatment of hydrocarbon distillates
US3408287A (en) * 1966-04-20 1968-10-29 Universal Oil Prod Co Oxidation of mercaptans
US3409543A (en) * 1966-04-20 1968-11-05 Universal Oil Prod Co Treatment of sour organic streams
US3413215A (en) * 1966-05-16 1968-11-26 Universal Oil Prod Co Oxidation of mercapto compounds
US3515677A (en) * 1966-06-24 1970-06-02 Universal Oil Prod Co Phthalocyanine-impregnated honeycombed ceramic catalyst
US3371031A (en) * 1967-03-02 1968-02-27 Universal Oil Prod Co Oxidation of mercapto compounds
US3445380A (en) * 1967-07-07 1969-05-20 Universal Oil Prod Co Treating sour hydrocarbon distillates containing mercapto compounds and acidic,surface-active materials
US3574093A (en) * 1969-01-22 1971-04-06 Universal Oil Prod Co Combination process for treatment of hydrocarbon streams containing mercapto compounds
US3758404A (en) * 1971-07-09 1973-09-11 Merichem Co Liquid liquid mass transfer process and apparatus
US3977829A (en) * 1973-05-18 1976-08-31 Merichem Company Liquid-liquid mass transfer apparatus
US3923645A (en) * 1973-09-07 1975-12-02 Ashland Oil Inc Method for oxidizing mercaptans occurring in petroleum refining streams
US3992156A (en) * 1975-07-23 1976-11-16 Merichem Company Mass transfer apparatus
US4070271A (en) * 1975-09-22 1978-01-24 Uop Inc. Catalytic oxidation of mercaptans and removal of naphthenic acids, catalyst toxins, and toxin precursors from petroleum distillates
US4019869A (en) * 1975-11-10 1977-04-26 Uop Inc. Combination reactor-separator apparatus
US4070307A (en) * 1976-08-12 1978-01-24 Uop Inc. Method of catalyst manufacture
US4124531A (en) * 1977-01-03 1978-11-07 Uop Inc. Catalytic composite for the treatment of sour petroleum distillates
US4199440A (en) * 1977-05-05 1980-04-22 Uop Inc. Trace acid removal in the pretreatment of petroleum distillate
US4121999A (en) * 1977-08-08 1978-10-24 Uop Inc. Catalytic oxidation of petroleum distillates with charcoal and with supported metal phthalocyanine
US4124493A (en) * 1978-02-24 1978-11-07 Uop Inc. Catalytic oxidation of mercaptan in petroleum distillate including alkaline reagent and substituted ammonium halide
US4206079A (en) * 1978-02-24 1980-06-03 Uop Inc. Catalytic composite particularly useful for the oxidation of mercaptans contained in a sour petroleum distillate
US4298502A (en) * 1978-11-06 1981-11-03 Uop Inc. Catalytic composite particularly useful for the oxidation of mercaptans and the removal of gums contained in a sour petroleum distillate
US4206043A (en) * 1978-11-06 1980-06-03 Uop Inc. Conversion of mercaptans contained in a sour petroleum distillate
US4213877A (en) * 1978-12-26 1980-07-22 Uop Inc. Method of reactivating a catalytic composite of an adsorptive carrier material and a mercaptan oxidation catalyst
GB2064975B (en) * 1979-10-18 1984-03-14 Johnson Matthey Co Ltd Fibrous catalytic materials
US4364843A (en) * 1979-11-28 1982-12-21 Uop Inc. Catalytic composite, method of manufacture, and process for use
US4362614A (en) * 1981-04-30 1982-12-07 Uop Inc. Mercaptan extraction process with recycled alkaline solution
US4392947A (en) * 1981-09-30 1983-07-12 Mobil Oil Corporation Integrated refining process
US4412912A (en) * 1983-03-01 1983-11-01 Uop Inc. Hydrocarbon treating process having minimum gaseous effluent
US4490246A (en) * 1983-11-18 1984-12-25 Uop Inc. Process for sweetening petroleum fractions
US4498977A (en) * 1983-11-29 1985-02-12 Uop Inc. Catalytic oxidation of mercaptan in petroleum distillate
US4498978A (en) * 1983-11-29 1985-02-12 Uop Inc. Catalytic oxidation of mercaptan in petroleum distillate
US4481106A (en) * 1983-12-05 1984-11-06 Uop Inc. Hydrocarbon treating process
US4502949A (en) * 1984-02-15 1985-03-05 Uop Inc. Catalytic oxidation of mercaptan in petroleum distillate
US4481107A (en) * 1984-04-06 1984-11-06 Uop Inc. Oxidation of difficultly oxidizable mercaptans

Also Published As

Publication number Publication date
EP0203574A2 (en) 1986-12-03
JPS62586A (ja) 1987-01-06
JPH0692584B2 (ja) 1994-11-16
EP0203574B1 (en) 1990-09-19
DE203574T1 (de) 1987-06-11
US4675100A (en) 1987-06-23
DE3674246D1 (de) 1990-10-25
EP0203574A3 (en) 1988-07-13

Similar Documents

Publication Publication Date Title
MX168629B (es) Mejoras en el tratamiento de oxidacion de mercaptanos en destilados de hidrocarburos y aparato
ES2027056T3 (es) Procedimiento para la oxidacion de 5-hidroximetilfurfural.
EP0638114A1 (en) PROCESS FOR DESULPHURIZATION AND DESALINATION OF FOSSIL FUELS.
DE3760958D1 (en) Process for the production of medicinal white oils and medicinal paraffins
KR880005064A (ko) 고순도 테레프탈산의 제조방법
ES2092319T3 (es) Desulfuracion de gases residuales.
ES2188055T3 (es) Sistema de purificacion de co2.
NO875238D0 (no) Fremgangsmaate for aa eliminere gjeninnfoerte disulfider ved en mercaptanekstraksjonsprosess.
CO4370113A1 (es) Procedimiento para la oxidacion parcial catalitica de hidro- carburos
EP0140045A3 (en) Process for the desulfurisation of gases containing h2s
DE3688352D1 (de) Verfahren zum reinigen von schwefelwasserstoff und schwefeldioxid enthaltendem abgas.
ES2009824B3 (es) Oxideshidrogenacion regenerativa catalitica de acido isoburitico o desus esteres.
DE3374321D1 (en) Hydrocarbon treating process having minimum gaseous effluent
ES2171511T3 (es) Catalizadores para el tratamiento de los gases que contienen compuestos azufrados, utilizacion y procedimiento de tratamiento de un gas que contiene compuestos azufrados.
MX9101855A (es) Metodo mejorado para la purificacion de acetominofen
KR860003972A (ko) 이산화탄소의 정제방법
KR890009452A (ko) 유화수소 함유 배가스 처리방법
US2606099A (en) Regeneration of alkaline solutions used in the removal of sulfur contaminants from hydrocarbon oils
DK0392896T3 (da) Præparat og fremgangsmåde til reduktion af korrosiviteten af oxygenholdige saltopløsninger ved gennembobling med sure gasser
HUT43966A (en) Method for purifying gas mixtures
BR8802028A (pt) Processo de recuperacao do vanadio
NO970588L (no) Fremgangsmåte for ekstrahering av lavmolekylære merkaptaner fra petroleum og gasskondensat, og katalysator anvendt ved fremgangsmåten
ES8604635A1 (es) Un procedimiento para tratar hidrocarburos
DE3473295D1 (en) Process for sweetening petroleum fractions
ES2035931T3 (es) Procedimiento e instalacion de tratamiento con oxigeno de efluentes gaseosos que contienen dioxido de azufre.