MX166768B - Proceso para la produccion de un componente de referencia de alta pureza selectivamente adsorbido de una mezcla de gases - Google Patents

Proceso para la produccion de un componente de referencia de alta pureza selectivamente adsorbido de una mezcla de gases

Info

Publication number
MX166768B
MX166768B MX014393A MX1439388A MX166768B MX 166768 B MX166768 B MX 166768B MX 014393 A MX014393 A MX 014393A MX 1439388 A MX1439388 A MX 1439388A MX 166768 B MX166768 B MX 166768B
Authority
MX
Mexico
Prior art keywords
bed
reference component
high purity
beds
production
Prior art date
Application number
MX014393A
Other languages
English (en)
Inventor
William Paul Schmidt
Alan David Abel
Ravi Kumar
Original Assignee
Air Prod & Chem
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/138,983 external-priority patent/US4813977A/en
Application filed by Air Prod & Chem filed Critical Air Prod & Chem
Publication of MX166768B publication Critical patent/MX166768B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B01D53/0476—Vacuum pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/10—Single element gases other than halogens
    • B01D2257/102—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40043—Purging
    • B01D2259/4005—Nature of purge gas
    • B01D2259/40052—Recycled product or process gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40058—Number of sequence steps, including sub-steps, per cycle
    • B01D2259/40062—Four
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40058—Number of sequence steps, including sub-steps, per cycle
    • B01D2259/40064—Five
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/403—Further details for adsorption processes and devices using three beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/404—Further details for adsorption processes and devices using four beds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

La presente invención se refiere a un procedimiento para la producción de un componente de referencia más selectivamente adsorbido, de alta pureza, de una mezcla de gas que contiene el componente de referencia y uno o más componentes secundarios menos selectivamente absorbidos utilizando una pluralidad de lechos paralelos de adsorción, el procedimiento está caracterizado porque comprende: a) extraer dicha mezcla de gas a través del extremo de alimentación de un primer lecho de adsorbente, conectando el extremo de efluente de dicho lecho al extremo de efluente de un lecho paralelo, el cual en este momento se ha evacuado, a manera de adsorber selectivamente el componente de referencia sobre el primer lecho de adsorbente, y permitir que uno o más componente secundarios pasen a través del primer lecho; b) enjuagar concurrentemente dicho primer lecho con componente de referencia de alta pureza para separar cualquier componente secundario co-adsorbido y cualquier componente secundario en los espacios intersticiales de dicho lecho; c) desorber a contracorriente el primer lecho mediante reducción de presión, en una o más etapas, a una presión inferior a la atmosférica, para recuperar un gas de enjuague para otro de la pluralidad de lechos que en este momento está sometido a la etapa (b) y un producto de componente de referencia de alta pureza; d) represurizar a contracorriente el primer lecho mediante conexión del extremo de efluente del primer lecho a su presión inferior a la atmosférica al final de la etapa (c) con el extremo de efluente de otro de la pluralidad de lechos que en ese momento está sometido a la adsorción de la eta pa (a), y (e) continuar esta serie de tapas con la pluralidad de lechos para formar un procedimiento continuo para la producción de componente de referencia de alta pureza.
MX014393A 1987-12-29 1988-12-29 Proceso para la produccion de un componente de referencia de alta pureza selectivamente adsorbido de una mezcla de gases MX166768B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/138,983 US4813977A (en) 1987-12-29 1987-12-29 Adsorptive nitrogen generation utilizing multiple adsorption beds
US07/285,468 US4892565A (en) 1987-12-29 1988-12-16 Adsorptive separation utilizing multiple adsorption beds

Publications (1)

Publication Number Publication Date
MX166768B true MX166768B (es) 1993-02-03

Family

ID=26836750

Family Applications (1)

Application Number Title Priority Date Filing Date
MX014393A MX166768B (es) 1987-12-29 1988-12-29 Proceso para la produccion de un componente de referencia de alta pureza selectivamente adsorbido de una mezcla de gases

Country Status (6)

Country Link
US (1) US4892565A (es)
EP (1) EP0327732A1 (es)
JP (1) JPH01258721A (es)
KR (1) KR910004122B1 (es)
CA (1) CA1313630C (es)
MX (1) MX166768B (es)

Families Citing this family (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3716898A1 (de) * 1987-05-20 1988-12-15 Bergwerksverband Gmbh Verfahren und vorrichtung zur heliumanreicherung
DE3716899C1 (de) * 1987-05-20 1988-08-04 Bergwerksverband Gmbh Verfahren und Vorrichtung zur Heliumgewinnung
US5106396A (en) * 1989-12-28 1992-04-21 Mitariten Michael J Adsorption processes with intermediate product recovery using two adsorption zones
US5084075A (en) * 1990-04-10 1992-01-28 Air Products And Chemicals, Inc. Vacuum swing adsorption process for production of 95+% n2 from ambient air
US5232474A (en) * 1990-04-20 1993-08-03 The Boc Group, Inc. Pre-purification of air for separation
US5074892A (en) * 1990-05-30 1991-12-24 Union Carbide Industrial Gases Technology Corporation Air separation pressure swing adsorption process
US5624477A (en) * 1991-05-09 1997-04-29 The Boc Group Plc Pressure swing adsorption plants
FR2684023B1 (fr) * 1991-11-26 1994-01-14 Air Liquide Procede de production d'un gaz a teneur substantielle en oxygene.
US5529610A (en) * 1993-09-07 1996-06-25 Air Products And Chemicals, Inc. Multiple zeolite adsorbent layers in oxygen separation
US5415683A (en) * 1993-11-17 1995-05-16 Praxair Technology, Inc. Vacuum pressure swing adsorption process
US5395427A (en) * 1994-01-12 1995-03-07 Air Products And Chemicals, Inc. Two stage pressure swing adsorption process which utilizes an oxygen selective adsorbent to produce high purity oxygen from a feed air stream
GB9412310D0 (en) * 1994-06-20 1994-08-10 Boc Group Plc Recovery of substances from exhaust streams
FR2721531B1 (fr) * 1994-06-27 1996-08-23 Air Liquide Procédé de traitement d'un mélange gazeux par adsorption à variation de pression.
US5707425A (en) * 1994-10-21 1998-01-13 Nitrotec Corporation Helium recovery from higher helium content streams
US5542966A (en) * 1994-10-21 1996-08-06 Nitrotec Corporation Helium recovery
US5536300A (en) * 1994-10-21 1996-07-16 Nitrotec Corporation Natural gas enrichment process
US5632803A (en) * 1994-10-21 1997-05-27 Nitrotec Corporation Enhanced helium recovery
US5792239A (en) * 1994-10-21 1998-08-11 Nitrotec Corporation Separation of gases by pressure swing adsorption
US5656067A (en) * 1996-02-23 1997-08-12 Air Products And Chemicals, Inc. VSA adsorption process with energy recovery
US5661987A (en) * 1996-10-25 1997-09-02 Pacific Consolidated Industries Three-bed nonimmobilized rapid pressure-swing adsorber
DE29719775U1 (de) * 1996-12-11 1998-02-05 Sgi Prozess Technik Gmbh Druckwechselanlage zur Gewinnung von Sauerstoff aus der Luft
EP0847791B1 (de) * 1996-12-11 2004-03-17 SGI-PROZESS-TECHNIK GmbH Verfahren zum Betrieb einer Druckwechselanlage zur Gewinnung von Sauerstoff aus der Luft
US5906673A (en) * 1997-05-15 1999-05-25 Nitrotec Corporation Pressure swing system with auxiliary adsorbent bed
US6214084B1 (en) * 1997-09-03 2001-04-10 The Boc Group, Inc. Iron manufacturing process
US6183537B1 (en) * 1997-11-04 2001-02-06 Praxair Technology, Inc. Rotary blowers for pressure swing adsorption process and system
US5993517A (en) * 1998-03-17 1999-11-30 The Boc Group, Inc. Two stage pressure swing adsorption process
US5997612A (en) * 1998-07-24 1999-12-07 The Boc Group, Inc. Pressure swing adsorption process and apparatus
US6113672A (en) * 1999-01-21 2000-09-05 The Boc Group, Inc. Multiple equalization pressure swing adsorption process
US6245127B1 (en) 1999-05-27 2001-06-12 Praxair Technology, Inc. Pressure swing adsorption process and apparatus
US6340382B1 (en) * 1999-08-13 2002-01-22 Mohamed Safdar Allie Baksh Pressure swing adsorption process for the production of hydrogen
KR100535153B1 (ko) * 2000-06-19 2005-12-07 현대중공업 주식회사 가열세정을 이용한 강흡착 성분 흡착분리방법
US6527830B1 (en) * 2001-10-03 2003-03-04 Praxair Technology, Inc. Pressure swing adsorption process for co-producing nitrogen and oxygen
US6699307B1 (en) * 2002-10-11 2004-03-02 H2Gen Innovations, Inc. High recovery PSA cycles and apparatus with reduced complexity
AU2007202742B2 (en) * 2002-10-11 2008-07-17 Lummus Technology Inc. High recovery PSA cycles and apparatus with reduced complexity
US6878186B2 (en) * 2003-09-09 2005-04-12 David Lloyd Neary Pure vacuum swing adsorption system and apparatus
US7311763B2 (en) * 2005-04-22 2007-12-25 David Lloyd Neary Gas separation vessel apparatus
US20090229459A1 (en) 2005-06-27 2009-09-17 John Lee Warren Process and Apparatus for Generating and Delivering an Enriched Gas Fraction
US7396387B2 (en) * 2005-11-01 2008-07-08 Praxair Technology, Inc. Pressure swing adsorption process for large capacity oxygen production
US8444750B2 (en) * 2007-05-18 2013-05-21 Exxonmobil Research And Engineering Company Removal of CO2, N2, or H2S from gas mixtures by swing adsorption with low mesoporosity adsorbent contactors
US8545602B2 (en) 2007-05-18 2013-10-01 Exxonmobil Research And Engineering Company Removal of CO2, N2, and H2S from gas mixtures containing same
US8529662B2 (en) 2007-05-18 2013-09-10 Exxonmobil Research And Engineering Company Removal of heavy hydrocarbons from gas mixtures containing heavy hydrocarbons and methane
US8529663B2 (en) * 2007-05-18 2013-09-10 Exxonmobil Research And Engineering Company Process for removing a target gas from a mixture of gases by swing adsorption
CA2688551C (en) * 2007-05-18 2013-09-10 Exxonmobil Research And Engineering Company Process for removing a target gas from a mixture of gases by thermal swing adsorption
CA2688638C (en) * 2007-05-18 2016-06-21 Exxonmobil Research And Engineering Company Removal of a target gas from a mixture of gases by swing adsorption with use of a turboexpander
US7959720B2 (en) 2007-05-18 2011-06-14 Exxonmobil Research And Engineering Company Low mesopore adsorbent contactors for use in swing adsorption processes
US8137435B2 (en) * 2009-03-31 2012-03-20 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Carbon dioxide recovery from low concentration sources
JP5518503B2 (ja) * 2010-01-25 2014-06-11 大陽日酸株式会社 高圧且つ高純度の窒素ガス供給装置及び供給方法
EP2524726A1 (en) * 2011-05-18 2012-11-21 Total S.A. Low energy cyclic PSA process
US20130205828A1 (en) * 2011-10-06 2013-08-15 Rustam H. Sethna Integration of a liquefied natural gas liquefier with the production of liquefied natural gas
CN103924213A (zh) * 2014-04-29 2014-07-16 清华大学 用于场发射器件的二硫化钼薄膜的制备方法
US9808755B2 (en) 2015-07-24 2017-11-07 Air Products And Chemicals, Inc. Sour pressure swing adsorption process
EP3473323A1 (de) * 2017-10-19 2019-04-24 Linde Aktiengesellschaft Prozess und anlage zur gewinnung von ethylen
US11148092B2 (en) 2018-06-27 2021-10-19 University Of South Carolina Temperature-vacuum swing adsorption process for capture of CO2
US11007473B2 (en) 2018-07-09 2021-05-18 University Of South Carolina Removal of water vapor from streams containing carbon dioxide and/or carbon monoxide
KR102156825B1 (ko) * 2018-12-14 2020-09-16 재단법인 포항산업과학연구원 일산화탄소의 분리 및 회수를 위한 압력변동흡착 공정
US11471832B1 (en) * 2021-08-03 2022-10-18 Hamilton Sundstrand Corporation Solid amine combined carbon dioxide separation process

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3313091A (en) * 1963-11-04 1967-04-11 Exxon Research Engineering Co Vacuum cycle adsorption
CH417534A (de) * 1964-07-01 1966-07-31 Exxon Research Engineering Co Adsorptionsverfahren
FR1602353A (es) * 1968-08-08 1970-11-16
US3564816A (en) * 1968-12-30 1971-02-23 Union Carbide Corp Selective adsorption process
GB1437344A (en) * 1972-05-17 1976-05-26 Boc International Ltd Gas separation
GB1449864A (en) * 1973-10-24 1976-09-15 Boc International Ltd Adsorption system
US3957463A (en) * 1973-12-12 1976-05-18 Air Products And Chemicals, Inc. Oxygen enrichment process
US4000990A (en) * 1975-04-16 1977-01-04 Nrg Nufuel Company Adsorption process
US4013429A (en) * 1975-06-04 1977-03-22 Air Products And Chemicals, Inc. Fractionation of air by adsorption
GB1559325A (en) * 1976-02-27 1980-01-16 Boc Ltd Gas separation
NZ183389A (en) * 1976-02-27 1979-10-25 Boc Ltd Gas separation by pressure swing adsorption: feed mixture supplied in substantially unpressurized condition
US4222750A (en) * 1976-08-16 1980-09-16 Champion Spark Plug Company Oxygen enrichment system for medical use
US4077779A (en) * 1976-10-15 1978-03-07 Air Products And Chemicals, Inc. Hydrogen purification by selective adsorption
US4144038A (en) * 1976-12-20 1979-03-13 Boc Limited Gas separation
GB1594454A (en) * 1976-12-23 1981-07-30 Boc Ltd Gas separation
US4264340A (en) * 1979-02-28 1981-04-28 Air Products And Chemicals, Inc. Vacuum swing adsorption for air fractionation
US4477265A (en) * 1982-08-05 1984-10-16 Air Products And Chemicals, Inc. Argon purification
US4539019A (en) * 1983-09-29 1985-09-03 Air Products & Chemicals, Inc. Control system for air fractionation by selective adsorption
DE3413895A1 (de) * 1984-04-13 1985-10-17 Bayer Ag, 5090 Leverkusen Druckwechselverfahren zur adsorptiven trennung von gasgemischen
US4599094A (en) * 1985-03-07 1986-07-08 Union Carbide Corporation Enhanced pressure swing adsorption processing
JPS61216712A (ja) * 1985-03-20 1986-09-26 Kobe Steel Ltd 圧力スイング吸着方法
US4711645A (en) * 1986-02-10 1987-12-08 Air Products And Chemicals, Inc. Removal of water and carbon dioxide from atmospheric air
US4770676A (en) * 1986-05-16 1988-09-13 Air Products And Chemicals, Inc. Recovery of methane from land fill gas
US4705541A (en) * 1987-02-12 1987-11-10 Air Products And Chemicals, Inc. Production of mixed gases of controlled composition by pressure swing adsorption
US4813977A (en) * 1987-12-29 1989-03-21 Air Products And Chemicals, Inc. Adsorptive nitrogen generation utilizing multiple adsorption beds

Also Published As

Publication number Publication date
CA1313630C (en) 1993-02-16
EP0327732A1 (en) 1989-08-16
KR910004122B1 (ko) 1991-06-22
KR890009450A (ko) 1989-08-02
US4892565A (en) 1990-01-09
JPH01258721A (ja) 1989-10-16

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