MX166296B - Procedimiento para la produccion de articulos de moldeo elastomericos de poliuretano - Google Patents
Procedimiento para la produccion de articulos de moldeo elastomericos de poliuretanoInfo
- Publication number
- MX166296B MX166296B MX206387A MX20638785A MX166296B MX 166296 B MX166296 B MX 166296B MX 206387 A MX206387 A MX 206387A MX 20638785 A MX20638785 A MX 20638785A MX 166296 B MX166296 B MX 166296B
- Authority
- MX
- Mexico
- Prior art keywords
- weight
- iii
- reaction mixture
- mixture
- production
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000465 moulding Methods 0.000 title abstract 2
- 239000004814 polyurethane Substances 0.000 title abstract 2
- 229920002635 polyurethane Polymers 0.000 title abstract 2
- 239000012948 isocyanate Substances 0.000 abstract 3
- 150000002513 isocyanates Chemical class 0.000 abstract 3
- 239000011541 reaction mixture Substances 0.000 abstract 3
- 239000011701 zinc Substances 0.000 abstract 3
- 229910052725 zinc Inorganic materials 0.000 abstract 3
- -1 zinc carboxylate Chemical class 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 2
- 239000004970 Chain extender Substances 0.000 abstract 1
- 150000004984 aromatic diamines Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000007942 carboxylates Chemical group 0.000 abstract 1
- 230000001413 cellular effect Effects 0.000 abstract 1
- 239000006082 mold release agent Substances 0.000 abstract 1
- 239000005056 polyisocyanate Substances 0.000 abstract 1
- 229920001228 polyisocyanate Polymers 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 229920013730 reactive polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/6505—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6523—Compounds of group C08G18/3225 or C08G18/3271 or polyamines of C08G18/38
- C08G18/6529—Compounds of group C08G18/3225 or polyamines of C08G18/38
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
- C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2120/00—Compositions for reaction injection moulding processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2125/00—Compositions for processes using internal mould release agents
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Molding Of Porous Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
La presente invención se refiere a procedimiento para la producción de artículos de moldeo elastométicos de poliuretano, opcionalmente celulares, caracterizado porque comprende reaccionar una mezcla de reacción una mezcla de reacción que comprende I) un poliisocianato; ii) un polímero reactivo con isocianato que tiene un peso molecular de 1,800 a 12,000 aproximadamente; III) 5 a 50 por ciento en peso, basado en el peso del componente (II) de un extendedor de cadena que comprende una diamina aromática estéricamente impedida y IV) una mezcla de agene de desprendimiento de molde interno que comprende: a) 0.5 a 10 por ciento en peso, aproximadamente basado en el peso de los componentes (II) y (III) de un carboxilato de zinc conteniendo 8 a 24 átomos de carbono por grupo carboxilato y b) un compatibilizador que comprende un elemento seleccionado del grupo consistente en compuestos acíclicos conteniendo nitrógeno, reactivos con isocianatos en una cantidad suficiente para solubilizar el carboxilato de zinc de manera que cuando la mezcla de agente de desprendimiento de molde interno se encuentre combinada con los componentes (II) y (III), el carboxilato de zinc posee una resistencia mejorada a la precipitacion procesándose la mezcla de reacción como un sistema de un "sólo golpe" por el proceso RIM, a un índice isocianato de 70 a 130 aproximadamente.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/643,612 US4519965A (en) | 1984-08-23 | 1984-08-23 | Internal mold release agent for use in reaction injection molding |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX166296B true MX166296B (es) | 1992-12-28 |
Family
ID=24581565
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX206387A MX166296B (es) | 1984-08-23 | 1985-08-22 | Procedimiento para la produccion de articulos de moldeo elastomericos de poliuretano |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4519965A (es) |
| EP (2) | EP0173888B2 (es) |
| JP (1) | JPS6183215A (es) |
| AU (1) | AU583846B2 (es) |
| BR (1) | BR8504031A (es) |
| DE (1) | DE3573436D1 (es) |
| ES (1) | ES8802167A1 (es) |
| MX (1) | MX166296B (es) |
Families Citing this family (78)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5011647A (en) * | 1983-02-16 | 1991-04-30 | The Dow Chemical Company | Internal mold release compositions |
| US4876019A (en) * | 1983-02-16 | 1989-10-24 | The Dow Chemical Company | Internal mold release compositions |
| US5008033A (en) * | 1983-02-16 | 1991-04-16 | The Dow Chemical Company | Internal mold release compositions |
| US4585803A (en) * | 1984-08-17 | 1986-04-29 | The Dow Chemical Company | Internal mold release compositions |
| US4687851A (en) * | 1985-08-15 | 1987-08-18 | The Dow Chemical Company | Polyurethane elastomers prepared from high equivalent weight polyahls |
| DE3535711A1 (de) * | 1985-10-05 | 1987-04-09 | Basf Ag | Verfahren zur herstellung von zelligen oder kompakten polyurethan-polyharnstoff-formkoerpern mit verbesserten entformungseigenschaften sowie innere formtrennmittel und deren verwendung fuer das polyisocyanat-polyadditionsverfahren |
| JPS6297808A (ja) * | 1985-10-24 | 1987-05-07 | Sumitomo Bayer Urethane Kk | ポリウレタン樹脂成形品の製造方法 |
| US4689356A (en) * | 1985-12-10 | 1987-08-25 | The Dow Chemical Company | Polyurethane elastomers prepared in a two-step process using mixtures of chain extenders |
| DE3607447A1 (de) * | 1986-03-07 | 1987-09-10 | Basf Ag | Verfahren zur herstellung von formkoerpern mit einem zelligen kern und einer verdichteten randzone mit verbesserten entformungseigenschaften |
| DE3626673A1 (de) * | 1986-08-07 | 1988-02-11 | Bayer Ag | Trennmittelkomposition, diese trennmittelkomposition enthaltende gemische, ein verfahren zur herstellung von elastischen formkoerpern und die nach diesem verfahren erhaltenen formkoerper |
| DE3629630A1 (de) * | 1986-08-30 | 1988-03-03 | Basf Ag | Verfahren zur herstellung von elastischen, im wesentlichen kompakten polyurethan-formkoerpern mit verbesserten entformungseigenschaften |
| JPS6372757A (ja) * | 1986-09-16 | 1988-04-02 | Sumitomo Bayer Urethane Kk | 内部離型剤組成物 |
| JPH02209961A (ja) * | 1986-09-16 | 1990-08-21 | Sumitomo Bayer Urethane Kk | ポリウレタン/ポリウレア成形品の製造方法 |
| DE3631842A1 (de) * | 1986-09-19 | 1988-03-24 | Basf Ag | Innere formtrennmittel, deren verwendung zur herstellung von formkoerpern nach dem polyisocyanat-polyadditionsverfahren und verfahren zur herstellung der formkoerper |
| DE3639502A1 (de) * | 1986-11-20 | 1988-06-01 | Bayer Ag | Trennmittelkomposition, diese trennmittelkomposition enthaltende gemische, ein verfahren zur herstellung von elastischen formkoerpern und die nach diesem verfahren enthaltenen formkoerper |
| DE3703739A1 (de) * | 1987-02-07 | 1988-08-18 | Bayer Ag | Verfahren zur herstellung von formkoerpern, hierzu geeignete gemische von gegenueber isocyanatgruppen reaktionsfaehigen verbindungen und die nach dem verfahren erhaltenen formkoerper |
| EP0328159A3 (en) * | 1987-03-11 | 1989-10-25 | Imperial Chemical Industries Plc | Improved polyurea reaction injection molding compositions |
| AU1488488A (en) * | 1987-03-16 | 1988-10-10 | Mallinckrodt, Inc. | Preparation of solutions of metal soaps in amines |
| US4758604A (en) * | 1987-04-07 | 1988-07-19 | The Dow Chemical Company | Polyurea rim systems having improved processibility |
| US4806615A (en) * | 1987-06-01 | 1989-02-21 | Texaco Inc. | Reaction injection molded elastomers prepared from amine terminated polyethers, a blend of an aromatic amine terminated chain extender, a substituted acyclic aliphatic amine terminated chain extender and an aromatic polyisocyanate |
| US4929697A (en) * | 1987-08-07 | 1990-05-29 | Mobay Corporation | Use of ester group containing polyols in a rim process |
| US5003027A (en) * | 1987-08-07 | 1991-03-26 | Mobay Corporation | Ester group containing polyols in a RIM process |
| US4758603A (en) * | 1987-08-28 | 1988-07-19 | The Dow Chemical Company | Dithiocarbamate internal mold release agents |
| DE3734163A1 (de) * | 1987-10-09 | 1989-04-20 | Bayer Ag | Verfahren zur herstellung von gegebenenfalls zellfoermigen formkoerpern |
| GB8807684D0 (en) * | 1988-03-31 | 1988-05-05 | Ici Plc | Internal mould release composition |
| JP2613441B2 (ja) * | 1988-07-18 | 1997-05-28 | トヨタ自動車株式会社 | 発泡ポリウレタンの製法 |
| US4886838A (en) * | 1988-08-31 | 1989-12-12 | Mobay Corporation | Internal mold release agent for use in reaction injection molding |
| US4897428A (en) * | 1988-08-31 | 1990-01-30 | Mobay Corporation | Internal mold release agent for use in molding polyurethanes and/or polyureas |
| US5019600A (en) * | 1988-08-31 | 1991-05-28 | Mobay Corporation | Internal mold release agent for use in reaction injection molding |
| US5002999A (en) * | 1988-09-07 | 1991-03-26 | Mobay Corporation | Internal mold release agent for use in reaction injection molding |
| US5211749A (en) * | 1988-09-12 | 1993-05-18 | Miles Inc. | Internal mold release agent for use in reaction injection molding |
| US5076989A (en) * | 1988-09-12 | 1991-12-31 | Mobay Corporation | Internal mold release agent for use in reaction injection molding |
| US4868224A (en) * | 1988-10-21 | 1989-09-19 | Mobay Corporation | Process for the production of molded products using internal mold release agents |
| US4963640A (en) * | 1989-02-13 | 1990-10-16 | Mobay Corporation | Process and compositions for production of moldings |
| US4937366A (en) * | 1989-02-13 | 1990-06-26 | Mobay Corporation | Process and compositions for production of moldings |
| US4946922A (en) * | 1989-05-03 | 1990-08-07 | The Dow Chemical Company | Internal mold release agents for polyisocyanurate systems |
| US5019317A (en) * | 1989-05-24 | 1991-05-28 | Mobay Corporation | Process for the production of molded products using internal mold release agents |
| US4965293A (en) * | 1989-06-08 | 1990-10-23 | Mobay Corporation | Polyurea elastomers with improved surface quality |
| US4954537A (en) * | 1989-06-08 | 1990-09-04 | Mobay Corporation | Internal mold release agent for use in polyurea rim systems |
| GB8916573D0 (en) * | 1989-07-20 | 1989-09-06 | Atlas Europol Spa | Internal mould release compositions |
| US5135962A (en) * | 1990-04-06 | 1992-08-04 | Miles Inc. | Internal mold release agent for use in polyurea rim systems |
| GB9021524D0 (en) * | 1990-10-03 | 1990-11-14 | Ici Plc | Isocyanate reactive blends and internal mould release compositions |
| JPH0816143B2 (ja) * | 1990-10-17 | 1996-02-21 | 住友バイエルウレタン株式会社 | 内部離型剤組成物 |
| BR9105449A (pt) * | 1990-12-11 | 1992-08-25 | Dow Chemical Co | Composicao para preparar um artigo polimerico espumado moldado e processo para a compatibilizacao de um polial de peso molecular relativamente alto |
| US5160538A (en) * | 1991-04-22 | 1992-11-03 | Miles Inc. | Internal release agents, active hydrogen containing mixtures which contain such agents and the use thereof in a process for the production of molded products |
| US5158607A (en) * | 1991-05-08 | 1992-10-27 | Miles Inc. | Internal release agents, active hydrogen containing mixtures which contain such agents and the use thereof in a process for the production of molded products |
| US5125974A (en) * | 1991-04-22 | 1992-06-30 | Miles Inc. | Internal mold release agents and the use thereof in the production of molded products |
| US5125973A (en) * | 1991-04-22 | 1992-06-30 | Miles Inc. | Internal mold release agents and use thereof in the production of molded products |
| DE4122872A1 (de) * | 1991-07-11 | 1993-01-14 | Bayer Ag | Formschaumstoffe |
| US5255483A (en) * | 1991-08-30 | 1993-10-26 | Donnelly Corporation | Squeak resistant panel/window assembly for vehicles |
| GB9125918D0 (en) * | 1991-12-05 | 1992-02-05 | Ici Plc | Reaction system for preparing polyurethane/polyurea |
| US5208268A (en) * | 1992-09-25 | 1993-05-04 | Miles Inc. | Internal release agents, active hydrogen containing mixtures which contain such agents and the use thereof in a process for the production of molded products |
| CA2107950C (en) * | 1992-10-22 | 2001-08-14 | Bayer Corporation | Stabilization of rim systems containing acidic additives |
| US5358985A (en) * | 1992-12-16 | 1994-10-25 | Air Products And Chemicals, Inc. | Ionic siloxane as internal mold release agent for polyurethane, polyurethaneurea and polyurea elastomers |
| US5324759A (en) * | 1993-01-26 | 1994-06-28 | Air Products And Chemicals, Inc. | RIM polyol blends containing acidic siloxane internal mold release agents and quaternary ammonium phenoxides |
| US5420186A (en) * | 1993-01-26 | 1995-05-30 | Air Products And Chemicals, Inc. | Internal mold release agents comprising metallic soaps compatibilized with liquid quaternary ammonium salts |
| CA2120648C (en) * | 1993-04-22 | 2004-06-22 | Neil H. Nodelman | Novel catalyst package for use in rim systems containing acidic additives |
| US5424387A (en) * | 1993-05-28 | 1995-06-13 | Hoechst Celanese Corporation | Di-amino compounds and processes for preparing the same |
| US5500176A (en) * | 1993-09-17 | 1996-03-19 | Bayer Corporation | Process for the production of molded products using internal mold release agents |
| US5389696A (en) * | 1993-09-17 | 1995-02-14 | Miles Inc. | Process for the production of molded products using internal mold release agents |
| US5529739A (en) * | 1994-11-15 | 1996-06-25 | Bayer Corporation | Process for the production of molded products using internal mold release agents |
| WO1996022182A1 (en) * | 1995-01-19 | 1996-07-25 | The Dow Chemical Company | Internal mould release composition |
| US5741865A (en) * | 1995-07-18 | 1998-04-21 | Witco Corporation | Fatty alkly diethanolamines to stabilize the optical clarity of polyols containing zinc fatty acid salts |
| DE19651994A1 (de) | 1996-12-13 | 1998-06-18 | Basf Ag | Verfahren zur Herstellung von selbsttrennenden, kompakten oder zelligen, gegebenenfalls Verstärkungsmittel enthaltenden Formkörpern aus Polyisocyanat-Polyadditionsprodukten und innere Formtrennmittel hierfür |
| BR9812689A (pt) | 1997-09-29 | 2000-08-22 | Bayer Ag | Agentes de desprendimento interno, aperfeiçoados para a preparação de corpos de poliuretano |
| US6448364B1 (en) | 2001-03-16 | 2002-09-10 | Bayer Corporation | IMR having synergistic effect with stabilizing system additives and catalyst package |
| TW593450B (en) | 2001-03-21 | 2004-06-21 | Hoya Corp | Transparent molded articles, optical components, plastic lenses and preparation method thereof |
| US20050131136A1 (en) | 2003-12-16 | 2005-06-16 | Rosthauser James W. | Soft polyurethaneurea spray elastomers with improved abrasion resistance |
| DE102005007470A1 (de) * | 2005-02-18 | 2006-08-31 | Bayer Materialscience Ag | Verstärkte Polyurethanharnstoffelastomere und deren Verwendung |
| US8101107B2 (en) | 2005-11-23 | 2012-01-24 | Milgard Manufacturing Incorporated | Method for producing pultruded components |
| US7875675B2 (en) | 2005-11-23 | 2011-01-25 | Milgard Manufacturing Incorporated | Resin for composite structures |
| US7901762B2 (en) | 2005-11-23 | 2011-03-08 | Milgard Manufacturing Incorporated | Pultruded component |
| US8597016B2 (en) | 2005-11-23 | 2013-12-03 | Milgard Manufacturing Incorporated | System for producing pultruded components |
| JP2011040300A (ja) * | 2009-08-12 | 2011-02-24 | Ushio Spex Inc | 照明器具の取付治具 |
| ES2685842T3 (es) | 2013-04-19 | 2018-10-11 | Covestro Llc | Encapsulación de tarjeta de circuito impreso electrónico en molde y conjunto |
| WO2018045466A1 (en) * | 2016-09-09 | 2018-03-15 | Clausi Robert N | Surface modifying agent formulation |
| US20210385937A1 (en) | 2018-10-09 | 2021-12-09 | Covestro Llc | Insert-molded electronic modules using thermally conductive polycarbonate and molded interlocking features |
| EP4605484A1 (en) * | 2022-11-10 | 2025-08-27 | Dow Global Technologies LLC | Polyurethane adhesive |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB980139A (en) * | 1962-03-30 | 1965-01-13 | Ici Ltd | Improvements in or relating to the manufacture of polyurethane foams |
| US3705860A (en) * | 1970-09-23 | 1972-12-12 | Basf Wyandotte Corp | Antifoam agent |
| US4201847A (en) * | 1973-02-16 | 1980-05-06 | Bayer Aktiengesellschaft | Process of preparing foams with internal mold-release agents |
| DE2349835B2 (de) * | 1973-10-04 | 1979-06-07 | Basf Ag, 6700 Ludwigshafen | Formmassen aus verstärkten Polyamiden |
| US4067845A (en) * | 1975-12-08 | 1978-01-10 | The Budd Company | Maturation of polyester compositions for viscosity index control |
| US4218543A (en) * | 1976-05-21 | 1980-08-19 | Bayer Aktiengesellschaft | Rim process for the production of elastic moldings |
| US4076695A (en) * | 1977-02-07 | 1978-02-28 | Dow Corning Corporation | Silicone containing reaction injection molded polyurethanes |
| US4119594A (en) * | 1977-05-31 | 1978-10-10 | General Motors Corporation | Catalyzed one-shot system for molding thermoset polyurethanes |
| US4263411A (en) * | 1978-10-30 | 1981-04-21 | Mooney Chemicals, Inc. | Polyurethane compositions and process for preparing polyurethane emitting reduced amounts of toxic fumes on burning using a cobalt, copper, nickel or manganese salt |
| US4269945A (en) * | 1980-01-24 | 1981-05-26 | The Dow Chemical Company | Reaction injection molded polyurethanes employing aliphatic amine chain extenders |
| US4379100A (en) * | 1981-02-02 | 1983-04-05 | Ex-Cell-O Corporation | Polyurethane molding process with siloxane internal release agent |
| US4374222A (en) * | 1981-03-02 | 1983-02-15 | The Dow Chemical Company | Compositions containing mold release agents |
| BE893509A (fr) * | 1981-07-06 | 1982-10-01 | Dart Ind Inc | Agents de demoulage internes et leur utilisation |
| US4396729A (en) * | 1982-04-23 | 1983-08-02 | Texaco Inc. | Reaction injection molded elastomer containing an internal mold release made by a two-stream system |
| US4442235A (en) * | 1983-05-09 | 1984-04-10 | Mobay Chemical Corporation | Process and composition for the production of polyurethane elastomer moldings |
| US4585803A (en) * | 1984-08-17 | 1986-04-29 | The Dow Chemical Company | Internal mold release compositions |
-
1984
- 1984-08-23 US US06/643,612 patent/US4519965A/en not_active Expired - Fee Related
-
1985
- 1985-08-12 EP EP85110086A patent/EP0173888B2/en not_active Expired - Lifetime
- 1985-08-12 EP EP87103914A patent/EP0250717A1/en not_active Withdrawn
- 1985-08-12 DE DE8585110086T patent/DE3573436D1/de not_active Expired
- 1985-08-21 JP JP60181963A patent/JPS6183215A/ja active Granted
- 1985-08-22 MX MX206387A patent/MX166296B/es unknown
- 1985-08-22 BR BR8504031A patent/BR8504031A/pt not_active IP Right Cessation
- 1985-08-22 AU AU46575/85A patent/AU583846B2/en not_active Withdrawn - After Issue
- 1985-08-23 ES ES546385A patent/ES8802167A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP0173888B2 (en) | 1995-03-22 |
| BR8504031A (pt) | 1986-06-10 |
| ES8802167A1 (es) | 1988-04-01 |
| EP0173888B1 (en) | 1989-10-04 |
| ES546385A0 (es) | 1988-04-01 |
| AU583846B2 (en) | 1989-05-11 |
| AU4657585A (en) | 1986-02-27 |
| DE3573436D1 (en) | 1989-11-09 |
| EP0173888A1 (en) | 1986-03-12 |
| US4519965A (en) | 1985-05-28 |
| EP0250717A1 (en) | 1988-01-07 |
| JPH0339533B2 (es) | 1991-06-14 |
| JPS6183215A (ja) | 1986-04-26 |
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