MD4319C1 - Hidrat de bis[(iminodiacetat)oxotiomolibdat(V)] de tetrafenilfosfoniu şi procedeu de cultivare a microalgei Spirulina platensis cu utilizarea acestuia - Google Patents
Hidrat de bis[(iminodiacetat)oxotiomolibdat(V)] de tetrafenilfosfoniu şi procedeu de cultivare a microalgei Spirulina platensis cu utilizarea acestuia Download PDFInfo
- Publication number
- MD4319C1 MD4319C1 MDA20130077A MD20130077A MD4319C1 MD 4319 C1 MD4319 C1 MD 4319C1 MD A20130077 A MDA20130077 A MD A20130077A MD 20130077 A MD20130077 A MD 20130077A MD 4319 C1 MD4319 C1 MD 4319C1
- Authority
- MD
- Moldova
- Prior art keywords
- iminodiacetate
- tetraphenylphosphonium
- oxothiomolybdate
- cyanobacterium
- cultivation
- Prior art date
Links
- 235000016425 Arthrospira platensis Nutrition 0.000 title claims abstract description 20
- 240000002900 Arthrospira platensis Species 0.000 title claims abstract description 20
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 241001464430 Cyanobacterium Species 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 title claims abstract description 9
- USFPINLPPFWTJW-UHFFFAOYSA-N tetraphenylphosphonium Chemical compound C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 USFPINLPPFWTJW-UHFFFAOYSA-N 0.000 title claims abstract description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 10
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 235000015097 nutrients Nutrition 0.000 claims abstract description 7
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 5
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910021380 Manganese Chloride Inorganic materials 0.000 claims abstract description 5
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 claims abstract description 5
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000001110 calcium chloride Substances 0.000 claims abstract description 5
- 235000011148 calcium chloride Nutrition 0.000 claims abstract description 5
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 5
- 229910052927 chalcanthite Inorganic materials 0.000 claims abstract description 5
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims abstract description 5
- 235000019797 dipotassium phosphate Nutrition 0.000 claims abstract description 5
- 229910000396 dipotassium phosphate Inorganic materials 0.000 claims abstract description 5
- 229910052564 epsomite Inorganic materials 0.000 claims abstract description 5
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims abstract description 5
- 239000011565 manganese chloride Substances 0.000 claims abstract description 5
- 235000002867 manganese chloride Nutrition 0.000 claims abstract description 5
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229910052939 potassium sulfate Inorganic materials 0.000 claims abstract description 5
- 235000017557 sodium bicarbonate Nutrition 0.000 claims abstract description 5
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims abstract description 5
- 239000011780 sodium chloride Substances 0.000 claims abstract description 5
- 235000010344 sodium nitrate Nutrition 0.000 claims abstract description 5
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229910000368 zinc sulfate Inorganic materials 0.000 claims abstract description 5
- 239000011686 zinc sulphate Substances 0.000 claims abstract description 5
- 235000009529 zinc sulphate Nutrition 0.000 claims abstract description 5
- 238000005286 illumination Methods 0.000 claims abstract description 4
- 239000012153 distilled water Substances 0.000 claims abstract description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 10
- 239000011733 molybdenum Substances 0.000 claims description 10
- 229910052750 molybdenum Inorganic materials 0.000 claims description 10
- 239000002028 Biomass Substances 0.000 abstract description 7
- 230000015572 biosynthetic process Effects 0.000 abstract description 5
- 238000003786 synthesis reaction Methods 0.000 abstract description 3
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 150000004676 glycans Chemical class 0.000 description 9
- 229920001282 polysaccharide Polymers 0.000 description 9
- 239000005017 polysaccharide Substances 0.000 description 9
- 230000002378 acidificating effect Effects 0.000 description 7
- 229940082787 spirulina Drugs 0.000 description 6
- 239000002609 medium Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 150000001720 carbohydrates Chemical class 0.000 description 4
- 235000014633 carbohydrates Nutrition 0.000 description 4
- 239000003446 ligand Substances 0.000 description 4
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910017299 Mo—O Inorganic materials 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 238000002330 electrospray ionisation mass spectrometry Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 206010028980 Neoplasm Diseases 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000000975 bioactive effect Effects 0.000 description 2
- 238000000921 elemental analysis Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 description 1
- 108091023020 Aldehyde Oxidase Proteins 0.000 description 1
- 102000048262 Aldehyde oxidases Human genes 0.000 description 1
- 229910017311 Mo—Mo Inorganic materials 0.000 description 1
- 108010027912 Sulfite Oxidase Proteins 0.000 description 1
- 102000043440 Sulfite oxidase Human genes 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 208000007502 anemia Diseases 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000002429 anti-coagulating effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 208000006673 asthma Diseases 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000007942 carboxylates Chemical group 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000001784 detoxification Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000001483 mobilizing effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000013630 prepared media Substances 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- -1 tetraphenylphosphonium cations Chemical class 0.000 description 1
- WAGFXJQAIZNSEQ-UHFFFAOYSA-M tetraphenylphosphonium chloride Chemical compound [Cl-].C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 WAGFXJQAIZNSEQ-UHFFFAOYSA-M 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 210000004881 tumor cell Anatomy 0.000 description 1
Landscapes
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Peptides Or Proteins (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MDA20130077A MD4319C1 (ro) | 2013-10-17 | 2013-10-17 | Hidrat de bis[(iminodiacetat)oxotiomolibdat(V)] de tetrafenilfosfoniu şi procedeu de cultivare a microalgei Spirulina platensis cu utilizarea acestuia |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MDA20130077A MD4319C1 (ro) | 2013-10-17 | 2013-10-17 | Hidrat de bis[(iminodiacetat)oxotiomolibdat(V)] de tetrafenilfosfoniu şi procedeu de cultivare a microalgei Spirulina platensis cu utilizarea acestuia |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MD4319B1 MD4319B1 (mo) | 2015-01-31 |
| MD4319C1 true MD4319C1 (ro) | 2015-08-31 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MDA20130077A MD4319C1 (ro) | 2013-10-17 | 2013-10-17 | Hidrat de bis[(iminodiacetat)oxotiomolibdat(V)] de tetrafenilfosfoniu şi procedeu de cultivare a microalgei Spirulina platensis cu utilizarea acestuia |
Country Status (1)
| Country | Link |
|---|---|
| MD (1) | MD4319C1 (mo) |
Citations (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4057565A (en) * | 1975-07-22 | 1977-11-08 | E. I. Du Pont De Nemours And Company | 2-Dialkylaminobenzyl and 2-dialkylaminomethylphenyl derivatives of selected transition metals |
| US4585882A (en) * | 1984-07-27 | 1986-04-29 | Exxon Research And Engineering Co. | Sulfido(disulfido)bis(N,N-substituted dithiocarbamato)W(VI) complexes |
| US4588829A (en) * | 1984-07-27 | 1986-05-13 | Exxon Research & Engineering Company | (Disulfido)tris(N,N-substituted dithiocarbamato)Mo(V) complexes |
| CA1250590A (en) * | 1985-08-02 | 1989-02-28 | Wie-Hin Pan | (disulfido)tris(n,n-substituted dithiocarbamato) mo(v) complexes |
| MD167F1 (ro) * | 1993-03-18 | 1995-02-28 | Iurie Potapov | Termogenerator si dispozitiv pentru incalzirea lichidelor |
| MD2501F1 (en) * | 2004-01-15 | 2004-07-31 | Valeriu Rudic | Process for Spirulina platensis biomass obtaining |
| MD3625F1 (ro) * | 2007-07-11 | 2008-06-30 | Universitatea De Stat Din Moldova | Heptaazotat de hexa-(m-b-alanin-(O,O'))-m3-oxo-tri(aqua)trifier(III) 3,5-hidrat si procedeu de obtinere a biomasei de Spirulina platensis |
| UA37571U (en) * | 2006-05-03 | 2008-12-10 | Институт Биологии Южных Морей Им. О.О. Ковалевского Нан Украины | Method for cultivation of spirulina spirulina platensis (nordst.) geitl |
| MD3781F1 (en) * | 2008-03-18 | 2008-12-31 | Universitatea De Stat Din Moldova | Process for obtaining an antioxidant thermostable preparation from Spirulina platensis cyanobacterium biomass |
| MD4026B1 (en) * | 2009-11-13 | 2010-03-31 | Universitatea De Stat Din Moldova | Hydrate-2-{[2-(2-hydroxyethylamino)-ethylimino]-methyl}-benzene-1,4-dihydroxy-(2-)copper and process for the cultivation of cyanobacterium Spirulina platensis |
| MD4043B1 (en) * | 2010-01-18 | 2010-05-31 | Universitatea De Stat Din Moldova | Acetato-N-[2-(2-hydroxyethylamino)-ethyl]-salicylideneimino(1-)copper and process for cultivation of cyanobacterium Spirulina platensis |
| MD228Y (en) * | 2010-01-28 | 2010-06-30 | Universitatea De Stat Din Moldova | Process for cultivation of cyanobacterium Spirulina platensis |
| MD4069B1 (ro) * | 2010-02-08 | 2010-09-30 | Universitatea De Stat Din Moldova | Bromo-{3-[(2-hidroxi-5-nitro-benziliden)-amino]-propan-1,2-dihidroxi}(1-)cupru si procedeu de cultivare a cianobacteriei Spirulina platentis |
| RU2009126459A (ru) * | 2009-07-13 | 2011-01-20 | Закрытое акционерное общество "Ива фарм" (RU) | Биядерные координационные соединения биологически активных d-элементов с алифатическими тиолами как средства повышения эффективности лекарственных препаратов |
| MD4108B1 (en) * | 2010-09-27 | 2011-04-30 | Univ De Stat Din Moldova | Process for cultivation of cyanobacterium Spirulina platensis |
| MD4122B1 (en) * | 2011-02-24 | 2011-07-31 | Valeriu Rudic | Strain of Spirulina platensis (Nordst) Geitl alga as a source of biologically active substances |
| UA72020U (ru) * | 2011-11-11 | 2012-08-10 | Александр Николаевич Мельниченко | Способ усовершенствования питательного среды по кобальту для биотехнологии культивирования spirulina platensis |
-
2013
- 2013-10-17 MD MDA20130077A patent/MD4319C1/ro not_active IP Right Cessation
Patent Citations (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4057565A (en) * | 1975-07-22 | 1977-11-08 | E. I. Du Pont De Nemours And Company | 2-Dialkylaminobenzyl and 2-dialkylaminomethylphenyl derivatives of selected transition metals |
| US4585882A (en) * | 1984-07-27 | 1986-04-29 | Exxon Research And Engineering Co. | Sulfido(disulfido)bis(N,N-substituted dithiocarbamato)W(VI) complexes |
| US4588829A (en) * | 1984-07-27 | 1986-05-13 | Exxon Research & Engineering Company | (Disulfido)tris(N,N-substituted dithiocarbamato)Mo(V) complexes |
| CA1250590A (en) * | 1985-08-02 | 1989-02-28 | Wie-Hin Pan | (disulfido)tris(n,n-substituted dithiocarbamato) mo(v) complexes |
| MD167F1 (ro) * | 1993-03-18 | 1995-02-28 | Iurie Potapov | Termogenerator si dispozitiv pentru incalzirea lichidelor |
| MD2501F1 (en) * | 2004-01-15 | 2004-07-31 | Valeriu Rudic | Process for Spirulina platensis biomass obtaining |
| UA37571U (en) * | 2006-05-03 | 2008-12-10 | Институт Биологии Южных Морей Им. О.О. Ковалевского Нан Украины | Method for cultivation of spirulina spirulina platensis (nordst.) geitl |
| MD3625F1 (ro) * | 2007-07-11 | 2008-06-30 | Universitatea De Stat Din Moldova | Heptaazotat de hexa-(m-b-alanin-(O,O'))-m3-oxo-tri(aqua)trifier(III) 3,5-hidrat si procedeu de obtinere a biomasei de Spirulina platensis |
| MD3781F1 (en) * | 2008-03-18 | 2008-12-31 | Universitatea De Stat Din Moldova | Process for obtaining an antioxidant thermostable preparation from Spirulina platensis cyanobacterium biomass |
| RU2009126459A (ru) * | 2009-07-13 | 2011-01-20 | Закрытое акционерное общество "Ива фарм" (RU) | Биядерные координационные соединения биологически активных d-элементов с алифатическими тиолами как средства повышения эффективности лекарственных препаратов |
| MD4026B1 (en) * | 2009-11-13 | 2010-03-31 | Universitatea De Stat Din Moldova | Hydrate-2-{[2-(2-hydroxyethylamino)-ethylimino]-methyl}-benzene-1,4-dihydroxy-(2-)copper and process for the cultivation of cyanobacterium Spirulina platensis |
| MD4043B1 (en) * | 2010-01-18 | 2010-05-31 | Universitatea De Stat Din Moldova | Acetato-N-[2-(2-hydroxyethylamino)-ethyl]-salicylideneimino(1-)copper and process for cultivation of cyanobacterium Spirulina platensis |
| MD228Y (en) * | 2010-01-28 | 2010-06-30 | Universitatea De Stat Din Moldova | Process for cultivation of cyanobacterium Spirulina platensis |
| MD4069B1 (ro) * | 2010-02-08 | 2010-09-30 | Universitatea De Stat Din Moldova | Bromo-{3-[(2-hidroxi-5-nitro-benziliden)-amino]-propan-1,2-dihidroxi}(1-)cupru si procedeu de cultivare a cianobacteriei Spirulina platentis |
| MD4108B1 (en) * | 2010-09-27 | 2011-04-30 | Univ De Stat Din Moldova | Process for cultivation of cyanobacterium Spirulina platensis |
| MD4122B1 (en) * | 2011-02-24 | 2011-07-31 | Valeriu Rudic | Strain of Spirulina platensis (Nordst) Geitl alga as a source of biologically active substances |
| UA72020U (ru) * | 2011-11-11 | 2012-08-10 | Александр Николаевич Мельниченко | Способ усовершенствования питательного среды по кобальту для биотехнологии культивирования spirulina platensis |
Non-Patent Citations (1)
| Title |
|---|
| Rudic V. Aspecte noi ale biotehnologiei moderne. Chişinău, Ştiinţa, 1993, 140 p. * |
Also Published As
| Publication number | Publication date |
|---|---|
| MD4319B1 (mo) | 2015-01-31 |
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