LT4208B - Thermal insulating and structuric material - Google Patents

Thermal insulating and structuric material Download PDF

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Publication number
LT4208B
LT4208B LT95-117A LT95117A LT4208B LT 4208 B LT4208 B LT 4208B LT 95117 A LT95117 A LT 95117A LT 4208 B LT4208 B LT 4208B
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LT
Lithuania
Prior art keywords
degrees celsius
forms
gypsum
lime
thermal properties
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LT95-117A
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Lithuanian (lt)
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LT95117A (en
Inventor
Vytas Vaivaras
Original Assignee
Vytas Vaivaras
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Publication date
Application filed by Vytas Vaivaras filed Critical Vytas Vaivaras
Priority to LT95-117A priority Critical patent/LT4208B/en
Publication of LT95117A publication Critical patent/LT95117A/en
Publication of LT4208B publication Critical patent/LT4208B/en

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/18Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mixtures of the silica-lime type
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

Invention applies to the construction industry. The invention aims to improve the thermal properties and strength. The proposed material consists of the following components, in mass percentage: lime 5-17; amorphous silicon dioxide 11-25; cement 0-13; structure forming additives ( natural gypsum or phosphoric gypsum, iron waste of the silicon production process, liquid glass, reinforcing fibre, plasticiser, hydrophobic additions) 0,5-11; pigments 0.2-4; water 0-83. The mass consisting elements are mixture, mixed to form a homogeneous mixture, then poured into forms and put into a steaming chamber or autoclave for a 3 hour hydro-thermal hardening in 90-180 degrees Celsius. Articles taken out from the forms are dried in a 120 degrees Celsius temperature. Materials (concrete, mortars) are distinguished by their high thermal properties and strength characteristics.

Description

Išradimas priklauso statybinių medžiagų pramonei, būtent šiluminėms izoliacinėms ir konstrukcinėms medžiagoms.The invention relates to the building materials industry, namely to thermal insulation and construction materials.

Žinoma šilumos izoliacinė medžiaga, į kurios sudėtį įeina sekantys komponentai, mas.%: ugniai atsparus molis15-30, šamotas - 15-25, ortofosforo rūgštis - 3-7, popieriaus pramonės atliekos - 47-67 (sulfitinė celiuliozė 56-68, kaolinas - 20-32, molžemis - 2-3, klijai - likęs kiekis). (žr.SU Nr.I7598I8, TPK C 04 B 38/00, 28/34, 1992).Known thermal insulating material containing by weight the following components: refractory clay15-30, chamotte 15-25, orthophosphoric acid 3-7, waste paper industry 47-67 (sulphite cellulose 56-68, kaolin) - 20-32, mole - 2-3, glue - remaining). (See SU No.I7598I8, TPK C 04 B 38/00, 28/34, 1992).

Žinoma šilumos izoliacinė ir konstrukcinė medžiaga, į kurios sudėtį įeina sekantys komponentai, mas.%: priemolis - 20-25, aliuminio pudra - 0,06-0,10, šarmas - 0,71,0, molio skalūnas (bitumo skalūnų perdirbimo atliekos) 20-25,· metalurginis šlakas - 22-23, plastifikatorius 0,018-0,02, vanduo - likęs kiekis. (žr.SU Kr„l6788I0,Known thermal insulating and structural material containing the following components by weight: 20-25 loam, 0.06-0.10 aluminum powder, 0.71.0 alkali, waste from the processing of bituminous shale ) 20-25, · metallurgical slag 22-23, plasticizer 0.018-0.02, water remaining. (see SU Kr l6788I0,

TPK C 04 B 38/00, 1991)·TPK C 04 B 38/00, 1991) ·

Pagaminti gaminiai iš žinomų medžiagų prie žemesnių temperatūrų (90-I80°0) nekokybiški ir nepasižymi geromis mechaninėmis savybėmis.Products made from known materials at lower temperatures (90-I80 ° 0) are of poor quality and do not exhibit good mechanical properties.

Žinoma šilumos izoliacinė ir konstrukcinė medžiaga, į kurios sudėtį įeina rišamosios medžiagos: portlandcemen tas, negesintos kalkės, granuliuotas rūdų tirpinamasis šlakas, pelenai, silicio junginiai ,·. akytumą sudaranti medžiaga: aliuminio pudra, struktūros formavimo priedai:Known thermal insulating and structural material containing binders: Portland cement, slaked lime, granulated ore slag, ash, silicon compounds, ·. porosity material: aluminum powder, structure-forming additives:

2.2.

gipsas, kalio karbonatas, kalcionuota soda, skystas natrio stiklas, trietanolaminas, natrio fosfatas, plastifikatorius, natrio šarmas, karboksilmetilceliuliozė, kristalizacinis natrio sulfatas, vanduo, (žr,gypsum, potassium carbonate, soda ash, liquid sodium glass, triethanolamine, sodium phosphate, plasticizer, caustic soda, carboxylmethyl cellulose, crystallizing sodium sulfate, water, (

Ee'TOHN HueHCTĖe. TY FOCT 254-89. ·3τ.ότ5,Ηη. ,γ.’όοκββ) .Ee'TOHN HueHCTĖe. TY FOCT 254-89. · 3τ.ότ5, Ηη. , γ.'όοκββ).

Iš žinomos medžiagos gauti gaminiai nepasižymi gerais fizikiniais-mechaniniais rodikliais.Products obtained from known material do not exhibit good physical-mechanical properties.

Išradimo tikslas - šiluminių savybių ir stiprumo charakteristikų pagerinimas.The object of the invention is to improve the thermal properties and strength characteristics.

Nurodytas tikslas pasiekiamas tuo, kad šilumos izoliacinę ir konstrukcinę medžiagą, į kurios sudėtį įeina rišamosios medžiagos, struktūros formavimo priedai, sudaro sekantys komponentai, mas.%:The stated aim is achieved by the fact that the heat-insulating and structural material containing the binder, the structure-forming accessories, consists of the following components,% by weight:

Kalkės 5-71Lime 5-71

Amorfinis silicio dioksidas II - 25 (Si02 arba SiC^.n^O>50%)Amorphous silica II - 25 (SiO 2 or SiC ^ .n ^ O> 50%)

CementasCement

Struktūros formavimo priedai:Accessories for structure formation:

gamtinis gipsas arba fosfogipsas geležies silicio gamybos atliekos skystas stiklas armuojantis plaušas plastifikatoriai hidrofobiniai priedainatural gypsum or phosphogypsum waste from the manufacture of iron silicon liquid glass reinforcing fiber plasticizers hydrophobic additives

Mineraliniai arba organiniai pigmentaiMineral or organic pigments

VanduoWater

0-130-13

0,5- 50.5-5

0-50-5

0-1 o - 3,50-1 o - 3.5

- 0,5- 0.5

0-10-1

G - 4G - 4

- £3.- £ 3.

Nurodyta šilumos izoliacinė ir konstrukcinė medžiagos sudėtis optimali, kad gauti teigiamą efektą.The specified thermal insulation and structural composition of the material are optimal for a positive effect.

Struktūros formavimo priedus sudarančių komponentų kiekis medžiagoje priklauso nuo jos paskirties ir norimų gauti gaminio mechaninių savybių.The amount of constituent additives in a material depends on its intended use and the mechanical properties of the product desired.

Išradimas iliustruojamas pavyzdžiais.The invention is illustrated by the following examples.

I pavyzdys. Šilumos izoliacinės ir konstrukcinės medžiagos gavimas.Example I. Heat insulating and structural material production.

Į maišytuvą supylė 5 g negesintų kalkių, 83 ml vandens, 0,5 g fosfogipso, 0,5 g armuojančio plaušo - celiuliozės. Masę maišė iki homogeninio mišinio. Po to į masę supylė II g amorfinio silicio dioksido - perlito ir maišė iki homogeninio mišinio. Taip paruoštą masę išpilstė į sandarias formas, kurias patalpino į šutinimo kamerą arba autoklavą hidroterminiam kietinimui 90-I80°C temperatūroje 3-8 h„ Išimtus iš formų sukietintus gaminius džiovino I20°C arba aplinkos temperatūroje.5 g of non-slaked lime, 83 ml of water, 0.5 g of phosphogypsum, 0.5 g of reinforcing fiber - cellulose were added to the mixer. The mass was stirred until homogeneous. Subsequently, II g of amorphous silica-perlite was added to the mixture and stirred until a homogeneous mixture was obtained. The so prepared mass was poured into sealed molds, which were placed in a firing chamber or autoclave for hydrothermal curing at 90-180 ° C for 3-8 h. The molded cured articles were dried at I20 ° C or ambient temperature.

2, 4, 12-14, 16, 17 pavyzdžiai. Analogiškai I pavyzdžiui gavo šilumos izoliacinę ir konstrukcinę medžiagą (žro I lentelę).Examples 2, 4, 12-14, 16, 17. Similarly, I got such heat insulating and structural material (and see Table I).

pavyzdys. Šilumos izoliacinės ir konstrukcinės medžiagos gavimas.example. Heat insulating and structural material production.

Į maišytuvą supylė 41,9 g kalkių tešlos, 1,5 g geležies silicio atliekų, 2,2 g fosfogipso, 2,9 g celiuliozės, 37,8 ml vandens. Masę maišė iki homogeninio mišinio. Po to į masę supylė 13,7 g amorfinio silicio dioksido - silikagelio ir maišė iki homogeninio mišinio. Masę išpilstė į sandarias formas, kurias patalpino į šutinimo' kamerą arba autoklavą hidroterminiam kietinimui 90-I80°C temperatūroje 3-8 h. Išimtus iš formų sukietintus gaminius džiovino41.9 g of lime dough, 1.5 g of iron silicon waste, 2.2 g of phosphogypsum, 2.9 g of cellulose, 37.8 ml of water were added to the mixer. The mass was stirred until homogeneous. Subsequently, 13.7 g of amorphous silica-silica gel was added to the mass and stirred until homogeneous. The mass was poured into sealed molds placed in a firing chamber or autoclave for hydrothermal curing at 90-180 ° C for 3-8 h. The molded cured products were dried

4.4.

I2O°C arba aplinkos temperatūroje.I2O ° C or ambient temperature.

5-II, 15 pavyzdžiai» Analogiškai 3 pavyzdžiui gavo šilumos izoliacinę ir konstrukcinę medžiagą (žr. I lentelę ).Examples 5-II, 15 »Analogously to Example 3, he obtained heat insulating and structural material (see Table I).

Gaminių (betonų) iš pareiškiamos šilumos izoliacinės ir konstrukcinės medžiagos fizikinės-mechaninės savybės pateiktos 2 lentelėje.The physical-mechanical properties of the products (concrete) from the claimed heat insulation and structural material are given in Table 2.

18, 19 (žr. 2 lentelę) gaminių iš žinomos medžiagos savybės.18, 19 (see Table 2) Properties of articles of known material.

Kaip matyti iš pateiktų 2 lentelėje duomenų, gaminių iš pareiškiamos medžiagos šiluminės savybės ir stiprumo charakteristikos žymiai geresnės už gaminių iš žinomos medžiagos charakteristikas. Esant 300 kg/mr betono tankiui gaminio iš pareiškiamos medžiagos šilumos laidumo koeficientas 0,064(7 pavyzdys), iš žinomos - 0,08 (18 pavyzdys). Esant 600 kg/m betono tankiui, gaminio iš pareiškiamos medžiagos šilumos laidumo koeficientas 0,109 (II pavyzdys), iš žinomos - 0,13 (19 pavyzdys). Taip pat palyginus gaminių iš pareiškiamos medžiagos ir žinomos stiprumo rodiklius, matosi, kad gaminių iš pareiškiamos medžiagos stiprumo rodikliai, esant tam pačiam medžiagos tankiui, geresni (pavyzdžiui, II, 19 pavyzdžiai).As can be seen from the data presented in Table 2, the thermal properties and the strength characteristics of the articles made from the claimed material are significantly better than those of the known material. At a density of 300 kg / mr concrete, the thermal conductivity coefficient of the product of the claimed material is 0.064 (Example 7), of the known - 0.08 (Example 18). At a density of 600 kg / m of concrete, the thermal conductivity coefficient of the product of the claimed material is 0.109 (Example II), of the known - 0.13 (Example 19). Similarly, comparisons between articles of the claimed material and known potency show that articles of the claimed material have the same strength at the same material density (e.g., Examples II, 19).

Šilumos izoliacinės ir konstrukcinės medžiagos sudėtysCompositions of heat insulating and structural material

I Lentelė tTable I Vol

Į Medžiagą sudarantys komponentai, mas.%Constituents of the substance,% by weight

PavFig

Nr.No.

t f 1 Kalkės J Amorfinis s !________________i siįięio_dioks_. ’ ,Gesin- LNegesin-!Per- Γ Sili- ue 'tos rtos ilitas ! kage- i+e ~ ! ! ! ’ lis !xas tf 1 Lime J Amorphous s! ________________ i siiięio_dioks_. ', Gesin- LNegesin-! Per- Γ Sili- ue ' il that ilta! kage- i + e ~! ! ! lis! xas Į Į !Pig(men·, tasTo! Pig ( men ·, those T I !Van- |duo i T I Van- | duo i T 2 Γ 3 Γ 4 ! 5 ! 5 T 2 Γ 3 Γ 4! 5! 5 T 7 T 7 ! 8 ! 8th

II

I I 5,0 5.0 11,0 11.0 83,0 83.0 2 2 7,0 7.0 15,5 15.5 76,2 76.2 3 3 41,9 41.9 13,7 13.7 37,8 37.8 4 4 71,0 71.0 21,5 21.5 - - 5 5 8,1 8.1 16,5 16.5 74,0 74.0 6 6th 63 63 20,0 20.0 13 13th 4 4 7 7th 23,6 23.6 15,1 15.1 58,5 58.5 8 8th 63 63 25,0 25.0 5,5 5.5 9 9th 45,4  45.4 14,2 14.2 37,6 37.6 10 10th 48,9 48.9 15,2 15.2 15,2 15.2 0,5 0.5 27,3 27.3 II II 50,5 50.5 15,0 15.0 25,1 25.1 12 12th 17,4 17.4 0,6 0.6 55,7 55.7 13 13th 18,4 18.4 18,9 18.9 53,2 53.2 14 14th 20,4 20.4 21,1 21.1 48,5 48.5 15 15th 31,7 31.7 12,9 12.9 13,3 13.3 1,0 1.0 36,2 36.2 16 16th 13,0 13.0 13,7 13.7 13,0 13.0 54,2 54.2 17 17th 8,0 8.0 16,5 16.5 72,5 72.5

5.5.

I Lentelės tęsinysContinuation of Table I

Medžiagą sudarantys komponentai, mas„% x------------------------------------------Struktūros formavimo priedaiComponents that make up the material,% x ------------------------------------------ Structure forming accessories

Nr. No. , Geležies!frosfoįsilicio .'gipsas 'gamybos ! 'atliekos! ; t Į Į , Iron! Frosfossil .'gypsum 'production! 'waste! ; t To 1 !Armuo j. iplaušas ! (celiuiliozė) j t 1 ! Army j. whoops! (cellulose) j t !Skys, tas ' stik! las Į t ! Liquid, that's it! las To t JPlastifi- .katorįus (SMR; t t 1 JPlastifi- .cator (SMR; t t 1 !Hidrofo!binis ,priedas !(hidrome !tiicelių ,liozė ! Hydrophobic !, additive! (Hydrome! Thixel, lysose I I 9 9th 10 10th II II 12 12th 13 13th 14 14th I I 0,5 0.5 0,5 0.5 2 2 1,3 1.3 3 3 1,5 1.5 2,2 2.2 3,5 3.5 4 4 5,0 5.0 1,0 1.0 0,5 0.5 1,0 1.0 5 5 1,4 1.4 6 6th 7 7th 1,7 1.7 1,1 1.1 8 8th 3,0 3.0 3,5 3.5 9 9th , 2,4 , 2.4 2,7 2.7 2,7 2.7 10 10th 2,3 2.3 3,3 3.3 3,0 3.0 II II 3,0 3.0 3,7 3.7 2,7 2.7 12 12th 3,2 3.2 3,1 3.1 2,9 2.9 13 13th 3,4 3.4 3,3 3.3 2,8 2.8 14 14th 3,5 3.5 3,7 3.7 2,8 2.8 15 15th 1,5 1.5 2,3 2.3 2,1 2.1 16 16th 1,8 1.8 2,3 2.3 2,0 2.0 17 17th 1,5 1.5 0,5 0.5 1,0 1.0

4- Plastifikatoriai: pavyzdžiui,·' SMR (sulfitinis mielių raugas, superplastifikatorius S-3, modifikuotas techninis lignosulfonatas, LST, MT,.4- Plasticizers: for example · 'SMR (sulfite yeast yeast, superplasticizer S-3, modified technical lignosulfonate, LST, MT ,.

++ Hidrofobiniai priedai: pavyzdžiui, silicio organiniai junginiai, Γ'ΚΧ-ΙΟ, ΓΚΧ-ΙΙ, ΓΚΧ-94, hidmetilceliuliozė.++ Hydrophobic additives: such as organosilicon, Γ'Γ-ΙΟ, ΓΚΧ-ΙΙ, ΓΚΧ-94, hydroxymethylcellulose.

Gaminių iš šilumos izoliacinės ir konstrukcinės medžiagos fizikinės-mechaninės savybės lentelėTable of physical-mechanical properties of products made from heat insulating and structural materials

J Pa v o '' Hr, ! Į J Pa v o '' Hr ,! To į Tank i s,o kg/rrr to Tank i s, while kg / rrr !Šilumos laidumo ,koef. 25+5 C xi ’ temperatūroj e’,' f \\/ (m.K)Thermal conductivity, coeff. 25 + 5 C xi 'at e', 'f \\ / (mK) t +++ !Stiprumas .gniuždant, : MPa t +++ ! Strength. Crushing, : MPa I ++ + + 'Sorbcinis !drėgnumas, ! % I ++ ++ 'Sorption! Moisture, ! % I I 180 180 0,051 0.051 0,15 0.15 10 10th 2 2 200 200 0,053 0.053 0,3 0.3 10 10th 3 3 450 450 0,086 0.086 4,2 4.2 12 12th 4 4 780 780 0,155 0.155 10,8 10.8 12 12th 5 5 250 250 0,059 0.059 0,6 0.6 10 10th 6 6th 760 760 0,150 0.150 10,2 10.2 12 12th 7 7th 300 300 0,064 0.064 1,0 1.0 10 10th 8 - 8 - 820 820 0,162 0.162 12,0 12.0 12 12th 9 9th 500 500 0,094 0.094 5,0 5.0 12 12th 10 10th 550 550 0,100 0.100 5, 6 5, 6 12 12th II II 600 600 0,109 0.109 6, 6 6, 6 12 12th 12 12th 650 650 0,121 0.121 8,2 8.2 12 12th 13 13th 700 700 0,133 0.133 10,0 10.0 12 12th •14 • 14 300 300 0,160 0.160 12,0 12.0 12 12th 15 15th 610 610 0,120 0.120 2,5 2.5 12 12th 16 16th 703 703 0,140 0.140 3,5 3.5 12 12th 17 17th 245 245 0,058 0.058 0,57 0.57 10 10th 18 18th 300 300 0,080 0.080 12 12th 19 19th 600 600 0,130 0.130 ___2χ2_____ ___ 2χ2 _____ 12 12th

-ί- Nustatyta pagal GOST f-!- Nustatyta pagal GOST-ί- Set by GOST f -! - Set by GOST

4-4-4- Nustatyta pagal GOST 4-4-4-4- Nustatyta pagal GOST4-4-4- GOST Set 4-4-4-4- GOST Set

127301-87, GOST 27005-86. 7076-87.127301-87, GOST 27005-86. 7076-87.

10180-89, GOST 18105-86. 17177-87, GOST 24816-81.10180-89, GOST 18105-86. 17177-87, GOST 24816-81.

Claims (1)

Išradimo apibrėžtisDefinition of the Invention Šilumos izoliacinė ir konstrukcinė medžiaga, į kurios sudėtį įeina rišamosios medžiagos, struktūros formavimo priedai, besiskirianti tuo, kad ją sudaro sekantys komponentai, mas.%:Thermal insulation and structural material containing binders, structure-forming accessories, characterized in that it consists of the following components,% by weight: Kalkės Lime 5-71. 5-71. Amorfinis silicio dioksidas Amorphous silica II - 25 II - 25 (Si02 arba SiO^.nH^O ^>50%)(Si0 2 or SiO ^ .nH ^ O ^> 50%) Cementas Cement 0-13 0-13 Struktūros formavimo priedai: Accessories for structure formation: gamtinis gipsas arba fosfogipsas natural gypsum or phosphogypsum 0,5- 5 0.5-5 geležies silicio gamybos atliekos wastes from the manufacture of iron silicon 0-5 0-5 skystas stiklas the liquid glass 0-1 0-1 armuojantis plaušas reinforcing fiber 0 - 3,5 0 to 3.5 plastifikatoriai plasticizers 0 - 0,5 0 to 0.5 hidrofobiniai priedai hydrophobic additives 0-1 0-1 Mineraliniai arba organiniai pigmentai Mineral or organic pigments 0-4 0-4 Vanduo Water 0 - 83. 0-83.
LT95-117A 1995-11-08 1995-11-08 Thermal insulating and structuric material LT4208B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LT5939B (en) 2011-07-15 2013-05-27 Vilniaus Gedimino technikos universitetas Structural thermal insulation composite from local technogenic waste
LT6432B (en) 2015-10-22 2017-08-10 Vilniaus Gedimino technikos universitetas Construction thermal insulation material from local technogenical waste

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1678810A1 (en) 1989-04-27 1991-09-23 Ростовский инженерно-строительный институт Mixture of raw materials for manufacturing structural heat insulating ceramic articles
SU1759818A1 (en) 1990-08-27 1992-09-07 Пензенский Политехнический Институт Mixture for producing heat insulating products

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1678810A1 (en) 1989-04-27 1991-09-23 Ростовский инженерно-строительный институт Mixture of raw materials for manufacturing structural heat insulating ceramic articles
SU1759818A1 (en) 1990-08-27 1992-09-07 Пензенский Политехнический Институт Mixture for producing heat insulating products

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LT5939B (en) 2011-07-15 2013-05-27 Vilniaus Gedimino technikos universitetas Structural thermal insulation composite from local technogenic waste
LT6432B (en) 2015-10-22 2017-08-10 Vilniaus Gedimino technikos universitetas Construction thermal insulation material from local technogenical waste

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