KR970700156A - 5-포르밀발레르 산 및 5-포르밀발러레이트 에스테르의 제조 방법(process for the preparation of 5-formylvaleric acid and 5-formylvalerate ester) - Google Patents

5-포르밀발레르 산 및 5-포르밀발러레이트 에스테르의 제조 방법(process for the preparation of 5-formylvaleric acid and 5-formylvalerate ester)

Info

Publication number
KR970700156A
KR970700156A KR1019960703576A KR19960703576A KR970700156A KR 970700156 A KR970700156 A KR 970700156A KR 1019960703576 A KR1019960703576 A KR 1019960703576A KR 19960703576 A KR19960703576 A KR 19960703576A KR 970700156 A KR970700156 A KR 970700156A
Authority
KR
South Korea
Prior art keywords
group
pentenoate
ester
phosphite
formylvalerate
Prior art date
Application number
KR1019960703576A
Other languages
English (en)
Other versions
KR100337440B1 (ko
Inventor
베네데트 한센 캐롤리나
게라르두스 드 브레에스 요한너스
Original Assignee
미키엘 크램빈켈
디 에스엠 엔.뷔.
알랭손 지. 보웬, 주니어
이.아이. 듀 퐁 드 느무르 앤드 컴퍼니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=3887699&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=KR970700156(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 미키엘 크램빈켈, 디 에스엠 엔.뷔., 알랭손 지. 보웬, 주니어, 이.아이. 듀 퐁 드 느무르 앤드 컴퍼니 filed Critical 미키엘 크램빈켈
Publication of KR970700156A publication Critical patent/KR970700156A/ko
Application granted granted Critical
Publication of KR100337440B1 publication Critical patent/KR100337440B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
    • C07C69/716—Esters of keto-carboxylic acids or aldehydo-carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/373—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of functional groups containing oxygen only in doubly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

본 발명은 5-포르밀발레르 산 및 5-포르밀발러레이트 에스테르의 제조방법에 관한 것으로서, 5-포르밀발레르산 또는 상응의 5-포르밀발러레이트가 로듐과 포스파이트 리간드로 구성된 촉매의 존재하에 3-펜테노산 또는 3-펜테노에이트 에스테르를 일산화탄소와 수소로 히드로포르밀화시킴으로써 제조되고, 이때 상기 포스파이트 리간드가 하기 일반식으로 표현되는 것을 특징으로 한다.
(식에서, R1및 R2은 동일하거나 다른 방향족 유기기이며, A는 n가의 기 또는 원자이며, n은 2 이상에서 선택된 정수이고, [-O-P(OR1)(OR2)]기는 동일하거나 다를 수 있으며, 상기 포스파이트는 로듐과 킬레이트형 복합물을 형성한다.)

Description

5-포르밀발레르 산 및 5-포르밀발러레이트 에스테르의 제조방법(PROCESS FOR THE PREPARATION OF 5-FORMYLVALERIC ACID AND 5-FORMYLVALERATE ESTER)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 로듐과 포스파이트 리간드로 구성된 촉매 존재시 3-펜테노산 또는 3-펜테노에이트 에스테르를 일산화탄소와 수소로 히드로포르밀화 시킴으로써 5-포르밀발레르산 또는 상응의 5-포르밀발러레이트 에스테르를 제조하는 방법에 있어서, 상기 포스파이트 리간드가 하기 일반식으로 표현되는 것을 특징으로 하는 5-포르밀발레르산 또는 상응의 5-포르밀발러레이트 에스테르의 제조 방법.
    (식에서, R1및 R2은 동일하거나 다른 1가의 방향족 유기이고, A는 n 가의 기 또는 원자이고, n은 적어도 2의 정수이며, [-O-P(OR1)(OR2)]기는 동일한 기 또는 다른 기 일수 있으며, 포스파이트는 로듐과 함께 킬레이트형 복합물을 형성한다.
  2. 제1항에 있어서, 상기 유기기 R1및 R2이 수소 원자가 아닌 기로 오르토 치환되는 것을 특징으로 하는 방법.
  3. 제2항에 있어서, 상기 유기기 R1및 R2이 3 내지 6개의 탄소 원자를 갖는 가지형 알킬기로 치환되는 것을 특징으로 하는 방법.
  4. 제1항 내지 제3항 중 어느 한 항에 있어서, 상기 R1및 R2은 서로 독립적으로 페닐기 또는 β-나프틸기인 것을 특징으로 하는 방법.
  5. 제1항 내지 제4항 중 어느 한 항에 있어서, A가 C-(CH2-)4인 것을 특징으로 하는 방법.
  6. 제1항 내지 제5항 중 어느 한 항에 있어서, 3-펜테노에이트가 하기 일반식 (2)로 표현되는 것을 특징으로 하는 방법.
    (2)
  7. 제1항 내지 제6항 중 어느 한 항에 있어서, 3-펜테노이트 이외에, 다량의 4- 및 2-펜테노에이트가 또한 존재하고, 3-펜테노에이트 에스테르의 농도가 50% 이상인 것을 특징으로 하는 방법.
  8. 상기 명세서 및 실시예에 실질적으로 기술된 것과 같은 방법.
KR1019960703576A 1993-12-30 1994-12-23 5-포르밀발레르산및5-포르밀발러레이트에스테르의제조방법 KR100337440B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
BE9301483 1993-12-30
BE9304183 1993-12-30
BE9301483A BE1007944A3 (nl) 1993-12-30 1993-12-30 Werkwijze voor de bereiding van 5-formylvaleriaanzuur en -ester.
PCT/NL1994/000324 WO1995018089A1 (en) 1993-12-30 1994-12-23 Process for the preparation of 5-formylvaleric acid and 5-formylvalerate ester

Publications (2)

Publication Number Publication Date
KR970700156A true KR970700156A (ko) 1997-01-08
KR100337440B1 KR100337440B1 (ko) 2002-12-28

Family

ID=3887699

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019960703576A KR100337440B1 (ko) 1993-12-30 1994-12-23 5-포르밀발레르산및5-포르밀발러레이트에스테르의제조방법

Country Status (12)

Country Link
US (1) US5719312A (ko)
EP (1) EP0737180B1 (ko)
JP (1) JPH09507223A (ko)
KR (1) KR100337440B1 (ko)
CN (1) CN1065522C (ko)
BE (1) BE1007944A3 (ko)
CA (1) CA2180264A1 (ko)
DE (1) DE69414134T2 (ko)
ES (1) ES2124997T3 (ko)
MY (1) MY113306A (ko)
SG (1) SG48183A1 (ko)
WO (1) WO1995018089A1 (ko)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5710306A (en) * 1996-03-15 1998-01-20 Dsm N.V. Process to prepare a multidentate phosphite compound
EP0839787A1 (en) † 1996-11-04 1998-05-06 Dsm N.V. Process for the preparation of an aldehyde
FR2754257B1 (fr) * 1996-10-04 2001-04-13 Rhone Poulenc Fibres Preparation de caprolactame
US6274773B1 (en) 1996-11-04 2001-08-14 Dsm Process for the continuous preparation of alkyl 5-formylvalerate compounds using homogeneous rhodium hydroformylation catalysts
EP0839794A1 (en) * 1996-11-04 1998-05-06 Dsm N.V. Process for the continuous preparation of an alkyl 5-formylvalerate compound
US5710344A (en) * 1996-11-08 1998-01-20 E. I. Du Pont De Nemours And Company Process to prepare a linear aldehyde
US5925754A (en) * 1997-04-15 1999-07-20 Union Carbide Chemicals & Plastics Technology Corporation Epsilon caprolactam compositions
US5886236A (en) * 1997-04-15 1999-03-23 Union Carbide Chemicals & Plastics Technology Corporation Process for producing aldehyde acid salts
US5962680A (en) * 1997-04-15 1999-10-05 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing epsilon caprolactams
US5919978A (en) * 1997-04-15 1999-07-06 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing aldehyde acids or salts
MY120454A (en) 1997-07-29 2005-10-31 Du Pont Improved process of preparation of linear aldehydes
EP0895811A1 (en) 1997-08-08 1999-02-10 Dsm N.V. Process to separate a group 8-10 metal/phosphite ligand complex from an organic liquid
US5932772A (en) * 1998-02-02 1999-08-03 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
US5952530A (en) * 1998-02-02 1999-09-14 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
US6017843A (en) * 1998-06-19 2000-01-25 Industrial Technology Research Institute Catalyst composition for preparing 5-formyl valaric esters from pentenoic esters
US6307107B1 (en) 1999-09-20 2001-10-23 E.I. Du Pont De Nemours And Company Hydroformylation of acyclic monoethylenically unsaturated compounds to corresponding terminal aldehydes
US6310260B1 (en) 2000-03-15 2001-10-30 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
US6307110B1 (en) 2000-03-15 2001-10-23 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
US6303829B1 (en) 2000-03-15 2001-10-16 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
US6303830B1 (en) 2000-03-15 2001-10-16 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US6307108B1 (en) 2000-03-15 2001-10-23 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US6294700B1 (en) 2000-03-15 2001-09-25 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
US6307109B1 (en) 2000-03-15 2001-10-23 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
US9205398B2 (en) 2012-08-21 2015-12-08 Uop Llc Production of butanediol from a methane conversion process
US9656229B2 (en) 2012-08-21 2017-05-23 Uop Llc Methane conversion apparatus and process using a supersonic flow reactor
US9308513B2 (en) 2012-08-21 2016-04-12 Uop Llc Production of vinyl chloride from a methane conversion process
US9023255B2 (en) * 2012-08-21 2015-05-05 Uop Llc Production of nitrogen compounds from a methane conversion process
US8927769B2 (en) 2012-08-21 2015-01-06 Uop Llc Production of acrylic acid from a methane conversion process
US9370757B2 (en) 2012-08-21 2016-06-21 Uop Llc Pyrolytic reactor
US8933275B2 (en) 2012-08-21 2015-01-13 Uop Llc Production of oxygenates from a methane conversion process
US9434663B2 (en) 2012-08-21 2016-09-06 Uop Llc Glycols removal and methane conversion process using a supersonic flow reactor
US9327265B2 (en) 2012-08-21 2016-05-03 Uop Llc Production of aromatics from a methane conversion process
US9707530B2 (en) 2012-08-21 2017-07-18 Uop Llc Methane conversion apparatus and process using a supersonic flow reactor
US9689615B2 (en) 2012-08-21 2017-06-27 Uop Llc Steady state high temperature reactor
US8937186B2 (en) 2012-08-21 2015-01-20 Uop Llc Acids removal and methane conversion process using a supersonic flow reactor
WO2014163506A1 (en) 2013-04-05 2014-10-09 Universiteit Leiden Process to prepare epsilon-caprolactam
EP3318569B1 (de) * 2016-11-08 2019-07-17 Evonik Degussa GmbH Bisphosphite mit 2,4-tert.-butylphenyl-einheiten und deren verwendung als liganden in der hydroformylierung
DE102017206200A1 (de) 2017-04-11 2018-10-11 Evonik Degussa Gmbh Verfahren zur Hydroformylierung von Pentensäureestern

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL283484A (ko) * 1962-09-12 1900-01-01
TW213465B (ko) * 1991-06-11 1993-09-21 Mitsubishi Chemicals Co Ltd
JP3416956B2 (ja) * 1991-06-11 2003-06-16 三菱化学株式会社 ヒドロホルミル化法およびビスホスファイト化合物
GB9200448D0 (en) * 1992-01-10 1992-02-26 British Petroleum Co Plc Hydroformylation process
DE4204808A1 (de) * 1992-02-18 1993-08-19 Basf Ag Verfahren zur herstellung von (omega)-formylalkancarbonsaeureestern

Also Published As

Publication number Publication date
CN1141030A (zh) 1997-01-22
CN1065522C (zh) 2001-05-09
ES2124997T3 (es) 1999-02-16
WO1995018089A1 (en) 1995-07-06
DE69414134D1 (de) 1998-11-26
MY113306A (en) 2002-01-31
EP0737180B1 (en) 1998-10-21
DE69414134T2 (de) 1999-06-24
EP0737180A1 (en) 1996-10-16
SG48183A1 (en) 1998-04-17
BE1007944A3 (nl) 1995-11-21
JPH09507223A (ja) 1997-07-22
US5719312A (en) 1998-02-17
KR100337440B1 (ko) 2002-12-28
CA2180264A1 (en) 1995-07-06

Similar Documents

Publication Publication Date Title
KR970700156A (ko) 5-포르밀발레르 산 및 5-포르밀발러레이트 에스테르의 제조 방법(process for the preparation of 5-formylvaleric acid and 5-formylvalerate ester)
KR900014032A (ko) 카르보닐화 촉매 시스템 및 신규 포스핀과 그의 제조방법
ATE266628T1 (de) Verfahren zum carbonylieren von pentennitril
ATE266617T1 (de) Verfahren zum carbonylieren von aethylenisch ungesättigten verbindungen
ATE17566T1 (de) Verfahren und katalytische zusammensetzung zur herstellung von aldehyden, und so erhaltene aldehyde.
PL264408A1 (en) A catalyst and a method of production of co-polymers of carbon monoxide olefine unsaturated organic compounds by the use of this with catalyst
KR870007872A (ko) 올레핀 형으로 불포화된 화합물을 팔라듐 촉매로 카르보닐화시키는 방법
KR830002795A (ko) 액상 조성물중 트리오르가노 포스핀의 제거방법
KR950032064A (ko) 5-포르밀발러레이트의 제조방법
KR900014031A (ko) 신규한 포스핀, 그의 제조방법, 그를 포함한 촉매계, 및 촉매계를 사용한 아세틸렌형 또는 올레핀형 불포화화합물의 카르보닐화 방법
KR910011727A (ko) 알데히드의 제조공정
DE3576150D1 (de) Verfahren zur herstellung von aldehyden.
AU7404601A (en) Bidentate ligands useful in catalyst system
MY117848A (en) Process to prepare a terminal aldehyde
KR960700993A (ko) 카르보닐화 방법(carbonylation process)
KR880007427A (ko) 공역 디엔의 카르보닐화 방법 및 이를 위한 촉매 시스템
DE68928508D1 (de) Verfahren zur Herstellung eines Schmieröl-Additivkonzentrats
JPS5561937A (en) Catalyst for asymmetric hydrogenation
ATE50557T1 (de) Verfahren zur herstellung von 8- und 9-formyltricyclo-(5,2,1,0, 2,6)-decen-3.
DE69108125D1 (de) Verfahren zur Herstellung von arylsubstituierten Propionsäureestern.
DE59701125D1 (de) Verfahren zur Herstellung von Arylamiden heteroaromatischer Carbonsäuren
DE69107070D1 (de) Diacylierte dipercarbonsäure als bleichmittel.
DE60321335D1 (de) Verfahren zur herstellung von enantiomerenangereinigten verbindungen
KR960703839A (ko) 아세틸렌형 불포화 화합물의 카르보닐화 방법(process for the carbonylation of acetyleically unsaturated compounds)
DE60315710D1 (de) Verfahren zur hydroformylierung von ethylenisch ungesättigten verbindungen in anwesenheit einer säure und eines tertiären monophosphins

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20050429

Year of fee payment: 4

LAPS Lapse due to unpaid annual fee