KR970025692A - 자발적으로 형성된 투명한 실리콘 마이크로에멀션 - Google Patents

자발적으로 형성된 투명한 실리콘 마이크로에멀션 Download PDF

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KR970025692A
KR970025692A KR1019960056982A KR19960056982A KR970025692A KR 970025692 A KR970025692 A KR 970025692A KR 1019960056982 A KR1019960056982 A KR 1019960056982A KR 19960056982 A KR19960056982 A KR 19960056982A KR 970025692 A KR970025692 A KR 970025692A
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microemulsion
microemulsions
volatile
methyl siloxanes
formed transparent
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KR1019960056982A
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KR100421759B1 (ko
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랜달 미론 힐
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루이스 노만 에드워드
다우 코닝 코포레이션
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/068—Microemulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585—Organosilicon compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y5/00—Nanobiotechnology or nanomedicine, e.g. protein engineering or drug delivery
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/26—Optical properties
    • A61K2800/262—Transparent; Translucent
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/413—Nanosized, i.e. having sizes below 100 nm
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/04—Polysiloxanes

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  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
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  • Polymers & Plastics (AREA)
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  • Dermatology (AREA)
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  • Biophysics (AREA)
  • Molecular Biology (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Cosmetics (AREA)
  • Silicon Polymers (AREA)

Abstract

본 발명은 물(i), 휘발성 사이클릭 메틸 실록산 또는 휘발성 선형 메틸 실록산(ii) 및 실리콘 폴리에테르 계면 활성제(iii)를 혼합함으로써 매우 안정한 투명한 마이크로에 멀션을 자발적으로 형성시키는 방법에 관한 것이다.
각 성분의 양은 조성물이 마이크로에멀션의 형태가 되도록 하는 양이다. 휘발성 메틸 실록산은 평균 직경이 100nm 미만인 입자 형태로서 마이크로에멀션 중에 존재한다. 생성되는 마이크로에멀션은 신체 보호 제품(personal care products)에 유용하다.

Description

자발적으로 형성된 투명한 실리콘 마이크로에멀션
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 실시예 8에 따라서 제조되는 마이크로에멀션의 조성범위를 측정하기 위한, 물, 옥타메틸 사이클로테트라실록산(D4) 및 실리콘 계면활성제를 포함하는 본 발명의 시스템의 3상 상태도(ternary phase diagram)이다.

Claims (2)

  1. 물(i), 화학식{(CH3)2SiO}p의 사이클릭 메틸 실록산 또는 화학식(CH3)3SiO{(CH3)2SiO}qSi(CH3)3의 선형 메틸 실록산(여기서, p는 3 내지 6이고, q는 0 내지 5이다)(ii) 및 하기 화학식(8) 내지 화학식(10)으로 이루어진 그룹으로부터 선택된 실리콘 폴리에테르(iii)를 배합시킴을 포함하여, 마이크로에멀션을 형성시키는 방법.
    상기 화학식(8) 내지 (10)에서, Rl은 탄소수 1 내지 6의 알킬 그룹이고, R2는 라디칼 -(CH2)aO(C2H,4)b(C3H6O)cR3을 나타내며, x는 0 내지 3이고, y는 1 내지 3이며, z는 0 내지 2이고, m은 3 내지 5이며, n은 1이고, a는 3 내지 6이며, b는 6 내지 12이고, c는 0 내지 5이며, R3은 수소원자, 메틸 라디칼 또는 아실라디칼이다.
  2. 제1항에서 정의한 방법에 따라서 제조되고 조성이 첨부한 제1도에 도시한 음영 영역에 의하여 정의되거나 또는 당해 영역내에서 정의되는 마이크로에멀션.
    ※참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019960056982A 1995-11-20 1996-11-20 자발적으로형성된투명한실리콘마이크로에멀션및이의형성방법 KR100421759B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/560,561 US5705562A (en) 1995-11-20 1995-11-20 Spontaneously formed clear silicone microemulsions
US08/560,561 1995-11-20

Publications (2)

Publication Number Publication Date
KR970025692A true KR970025692A (ko) 1997-06-24
KR100421759B1 KR100421759B1 (ko) 2004-05-17

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US (2) US5705562A (ko)
EP (1) EP0774482B1 (ko)
JP (1) JPH09183901A (ko)
KR (1) KR100421759B1 (ko)
AU (1) AU703229B2 (ko)
BR (1) BR9605612A (ko)
CA (1) CA2189835A1 (ko)
DE (1) DE69614637T2 (ko)
ES (1) ES2162983T3 (ko)
MX (1) MX9605682A (ko)
TW (1) TW327639B (ko)

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EP0774482B1 (en) 2001-08-22
US5705562A (en) 1998-01-06
EP0774482A3 (en) 1997-07-30
BR9605612A (pt) 1998-08-18
AU7180296A (en) 1997-05-29
US5707613A (en) 1998-01-13
DE69614637D1 (de) 2001-09-27
ES2162983T3 (es) 2002-01-16
JPH09183901A (ja) 1997-07-15
EP0774482A2 (en) 1997-05-21
KR100421759B1 (ko) 2004-05-17
TW327639B (en) 1998-03-01
MX9605682A (es) 1997-05-31
CA2189835A1 (en) 1997-05-21
AU703229B2 (en) 1999-03-18
DE69614637T2 (de) 2002-09-12

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