KR960706520A - 거대단량체 제조 - Google Patents
거대단량체 제조 Download PDFInfo
- Publication number
- KR960706520A KR960706520A KR1019960703283A KR19960703283A KR960706520A KR 960706520 A KR960706520 A KR 960706520A KR 1019960703283 A KR1019960703283 A KR 1019960703283A KR 19960703283 A KR19960703283 A KR 19960703283A KR 960706520 A KR960706520 A KR 960706520A
- Authority
- KR
- South Korea
- Prior art keywords
- reaction
- process according
- lactone
- phosphoric acid
- temperature
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
- C08G63/08—Lactones or lactides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Steroid Compounds (AREA)
- Saccharide Compounds (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Pyrane Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
200ppm 인산의 존재하에 락톤과 히드록시알킬아크릴레이트사이의 반응에 의한 거대단량체의 제조방법을 제공한다. 반응은 100∼130℃의 온도에서 유리기 억제제의 조재하에 행한다. 바람직하기로는 락톤이 ε-카프로락톤이고 히드록시알킬아크릴레이트를 2-히드록시에틸아크릴레이트와 2-히드록시에틸메타크릴레이트에서 선택하는 것이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (12)
- 촉매가 반응혼합물중 200㎎/㎏ 이상, 바람직하기로는 250㎎/㎏ 이상의 농도로 인산을 함유하고, 방법을 100°∼130℃의 온도에서 행함을 특징으로 하는, 락톤과 히드록시알킬아크릴레이트 사이의 촉매반응에 의한 거대단량체의 제조방법.
- 제1항에 있어서, 인산 농도가 300㎎/㎏ 내지 750㎎/㎏임을 특징으로 하는 제조방법.
- 제1항에 있어서, 인산 농도가 400㎎/㎏ 내지 600㎎/㎏임을 특징으로 하는 제조방법.
- 전술한 항 중 어느 한 항에 있어서, 락톤이 ε-카프로락톤임을 특징으로 한 제조방법.
- 전술한 항 중 어느 한 항에 있어서, 히드록시알킬아크릴레이트를 2-히드록시에틸아크릴레이트와 2-히드록시에틸메타크릴레이트에서 선택함을 특징으로 하는 제조방법.
- 전술한 항 중 어느 한 항에 있어서 반응을 105℃ 또는 그 이상의 온도에서 행함을 특징으로 하는 제조방법.
- 제6항에 있어서, 반응을 110℃ 또는 그 이상의 온도에서 행함을 특징으로 하는 제조방법.
- 전술한 항 중 어느 한 항에 있어서, 반응을 500∼1500㎎/㎏의 농도에서 유리기억제제의 존재하에 행함을 특징으로 하는 제조방법.
- 제8항에 있어서, 유리기억제제가 4-메톡시페놀임을 특징으로 하는 제조방법.
- 촉매가 300㎎/㎏ 내지 750㎎/㎏의 농도로 인산을 함유하고 바능을 105∼130℃의 온도에서 500∼1500㎎/㎏의 유리기 억제제의 존재하에 행함을 특징으로 하는 ε-카프로락톤과 2-히드록시에킬아크릴레이트사이의 촉매 반응에 의한 거대단량체의 제조방법.
- 실시예들에서 서술한 바와같은 락톤과 히드록시알킬아크릴레이트사이의 촉매 반응에 의한 거대단량체의 제조방법.
- 새로운 특징 또는 특징의 조합으로 서술한 바와같이 락톤과 히드록시알킬아크릴레이트사이의 촉매 반응에 의한 거대단량체의 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9326511A GB9326511D0 (en) | 1993-12-29 | 1993-12-29 | Macromonomer preparation |
GB9326511.4 | 1993-12-29 | ||
PCT/GB1994/002748 WO1995018170A1 (en) | 1993-12-29 | 1994-12-16 | Macromonomer preparation |
Publications (2)
Publication Number | Publication Date |
---|---|
KR960706520A true KR960706520A (ko) | 1996-12-09 |
KR100333407B1 KR100333407B1 (ko) | 2002-11-20 |
Family
ID=10747266
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019960703283A KR100333407B1 (ko) | 1993-12-29 | 1994-12-16 | 거대단량체의제조방법 |
Country Status (15)
Country | Link |
---|---|
US (1) | US5731406A (ko) |
EP (1) | EP0737218B1 (ko) |
JP (1) | JP3084485B2 (ko) |
KR (1) | KR100333407B1 (ko) |
AT (1) | ATE169942T1 (ko) |
AU (1) | AU692500B2 (ko) |
BR (1) | BR9408426A (ko) |
DE (1) | DE69412645T2 (ko) |
DK (1) | DK0737218T3 (ko) |
ES (1) | ES2123230T3 (ko) |
GB (1) | GB9326511D0 (ko) |
MY (1) | MY114255A (ko) |
TW (1) | TW321655B (ko) |
WO (1) | WO1995018170A1 (ko) |
ZA (1) | ZA9410313B (ko) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100266912B1 (ko) | 1992-02-28 | 2000-12-01 | 파라비 레이 | 조직접촉물질이며 방출조절운반체인 광중합성 생분해성 하이드로겔 |
JPH0995643A (ja) * | 1995-07-27 | 1997-04-08 | Mazda Motor Corp | ポリオレフィン系樹脂成形品の塗料用樹脂組成物、それを用いた塗料組成物、及びその塗装方法 |
JP2001192421A (ja) * | 2000-01-07 | 2001-07-17 | Nippon Paint Co Ltd | 反応性重合体の製造方法およびそれを含む硬化性樹脂組成物 |
US6916547B2 (en) * | 2002-02-01 | 2005-07-12 | Awi Licensing Company | Multi-functional unsaturated polyester polyols |
US20040242831A1 (en) * | 2003-05-30 | 2004-12-02 | Dong Tian | Enzyme catalyzed polyesters and polyol polymers |
US20080138284A1 (en) * | 2006-09-26 | 2008-06-12 | Lipid Sciences, Inc. | Novel Peptides That Promote Lipid Efflux |
FR2953523B1 (fr) | 2009-12-08 | 2013-02-15 | Arkema France | Procede de preparation d'un polymere d'au moins un monomere cyclique |
EP3061781B1 (en) | 2013-10-24 | 2020-03-18 | Nippon Soda Co., Ltd. | Polyol composition |
SG11202110047UA (en) * | 2019-04-15 | 2021-10-28 | Agency Science Tech & Res | Synthesis of polyester based polymers without use of organic solvents |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1257638A (ko) * | 1968-11-20 | 1971-12-22 | ||
US4683287A (en) * | 1982-11-02 | 1987-07-28 | Union Carbide Corporation | Compositions containing a reactive monomer derived from a lactone |
CA1237239A (en) * | 1982-11-02 | 1988-05-24 | Joseph V. Koleske | Compositions containing a reactive monomer derived from a lactone |
-
1993
- 1993-12-29 GB GB9326511A patent/GB9326511D0/en active Pending
-
1994
- 1994-12-16 JP JP07517840A patent/JP3084485B2/ja not_active Expired - Fee Related
- 1994-12-16 BR BR9408426A patent/BR9408426A/pt not_active IP Right Cessation
- 1994-12-16 DE DE69412645T patent/DE69412645T2/de not_active Expired - Fee Related
- 1994-12-16 ES ES95903426T patent/ES2123230T3/es not_active Expired - Lifetime
- 1994-12-16 DK DK95903426T patent/DK0737218T3/da active
- 1994-12-16 KR KR1019960703283A patent/KR100333407B1/ko not_active IP Right Cessation
- 1994-12-16 EP EP95903426A patent/EP0737218B1/en not_active Expired - Lifetime
- 1994-12-16 TW TW083111777A patent/TW321655B/zh active
- 1994-12-16 US US08/663,206 patent/US5731406A/en not_active Expired - Fee Related
- 1994-12-16 AU AU12478/95A patent/AU692500B2/en not_active Ceased
- 1994-12-16 AT AT95903426T patent/ATE169942T1/de not_active IP Right Cessation
- 1994-12-16 MY MYPI94003376A patent/MY114255A/en unknown
- 1994-12-16 WO PCT/GB1994/002748 patent/WO1995018170A1/en active IP Right Grant
- 1994-12-27 ZA ZA9410313A patent/ZA9410313B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
JP3084485B2 (ja) | 2000-09-04 |
MY114255A (en) | 2002-09-30 |
WO1995018170A1 (en) | 1995-07-06 |
ATE169942T1 (de) | 1998-09-15 |
GB9326511D0 (en) | 1994-03-02 |
EP0737218A1 (en) | 1996-10-16 |
JPH09507255A (ja) | 1997-07-22 |
KR100333407B1 (ko) | 2002-11-20 |
DE69412645D1 (de) | 1998-09-24 |
DE69412645T2 (de) | 1999-04-15 |
AU692500B2 (en) | 1998-06-11 |
US5731406A (en) | 1998-03-24 |
ES2123230T3 (es) | 1999-01-01 |
EP0737218B1 (en) | 1998-08-19 |
AU1247895A (en) | 1995-07-17 |
BR9408426A (pt) | 1997-08-26 |
DK0737218T3 (da) | 1999-05-25 |
ZA9410313B (en) | 1995-08-14 |
TW321655B (ko) | 1997-12-01 |
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Legal Events
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E902 | Notification of reason for refusal | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 20060327 Year of fee payment: 5 |
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LAPS | Lapse due to unpaid annual fee |