KR960705758A - 개선된 황-코우팅된 요소의 서방성 비료의 제조 방법(process for producing improved sulfur-coated urea slow release fertilizers) - Google Patents

개선된 황-코우팅된 요소의 서방성 비료의 제조 방법(process for producing improved sulfur-coated urea slow release fertilizers)

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Publication number
KR960705758A
KR960705758A KR1019960702716A KR19960702716A KR960705758A KR 960705758 A KR960705758 A KR 960705758A KR 1019960702716 A KR1019960702716 A KR 1019960702716A KR 19960702716 A KR19960702716 A KR 19960702716A KR 960705758 A KR960705758 A KR 960705758A
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KR
South Korea
Prior art keywords
sulfur
coated urea
coated
diisocyanate
diethylene glycol
Prior art date
Application number
KR1019960702716A
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English (en)
Other versions
KR100381995B1 (ko
Inventor
에이취 데트릭 존
Original Assignee
제임스 티이 퍼어셀
아아르엘시이 테크놀로지스 엘엘시이
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 제임스 티이 퍼어셀, 아아르엘시이 테크놀로지스 엘엘시이 filed Critical 제임스 티이 퍼어셀
Publication of KR960705758A publication Critical patent/KR960705758A/ko
Application granted granted Critical
Publication of KR100381995B1 publication Critical patent/KR100381995B1/ko

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Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C9/00Fertilisers containing urea or urea compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Fertilizers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

본 발명은 황-코우팅 위에 균일하고 내구성 있는 중합체 코우팅을 갖는 황-코우팅된 요소의 서방성 과립상 비료를 기술한다. 중합체 코우팅은 황-코우팅된 요소 과립의 표면에 디에틸렌 글리콜-트리에탄올아민 폴리올 및 디이소시아네이트의 직접적 공중합에 의해 생성된다. 중합체 코우팅은 복합 코우팅된 과립의 개선된 내충격성을 제공한다.

Description

개선된 황-코우팅된 요소의 서방성 비료의 제조 방법(PROCESS FOR PRODUCING IMPROVED SULFUR-COATED UREA SLOW RELEASE FERTILIZERS)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

1) 예비 가열된 요소 과립을 용융황으로 코우팅시켜 두께의 범위에 있어서 예정된 명목상의 두께를 갖는 코우팅을 수득하고; 2) 단계 1)의 황 코우팅된 요소 과립을 디이소시아네이트 및 디에틸렌글리콜과 트리에탄올아민의 폴리올 혼합물인 반응성 단량체로 코우팅하고, 단량체를 황-코우팅된 요소 과립의 표면상에 중합시켜 내충격성 중합체 밀폐제 코우팅을 형성하며; 3) 단계 2)의 중합체 코우팅되고 황-코우팅된 요소 과립 생성물을 냉각하는 단계로 이루어짐을 특징으로 하는 황-코우팅된 요소 과립비료 생성물의 제조방법.
제1항에 있어서, 디이소시아네이트가 주로 4,4-디페닐메탄 디이소시아네이트로 구성되는 방법.
제1항에 있어서, 디에틸렌 글리콜-트리에타올아민 중합체 혼합물의 일부분이 고분자량이 폴리에스테르 폴리올로 대치되는 방법.
제3항에 있어서, 디에틸렌 글리콜과 트리에탄올아민의 중량비가 2.5:1 내지 4.5:1인 방법.
제4항에 있어서, 디에틸렌 글리콜과 트리에탄올아민의 중량비가 3.5:1인 방법.
제4항에 있어서, 액체 폴리올:디이소시아네이트의 중량비가 0.33:1~0.45:1의 범위내인 방법.
제6항에 있어서, 폴리올:디이소시아네이트의 비가 0.39:1인 방법.
제1항 내지 7항 중 어느 한 항에 따른 방법에 의해 생성된 황-코우팅된 요소 과립상 비료.
※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960702716A 1994-09-23 1995-09-22 개선된황-코우팅된요소의서방성비료의제조방법 KR100381995B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/311,672 US5599374A (en) 1994-09-23 1994-09-23 Process for producing improved sulfur-coated urea slow release fertilizers
US08/311672 1994-09-23
US08/311,672 1994-09-23

Publications (2)

Publication Number Publication Date
KR960705758A true KR960705758A (ko) 1996-11-08
KR100381995B1 KR100381995B1 (ko) 2003-07-18

Family

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Family Applications (1)

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KR1019960702716A KR100381995B1 (ko) 1994-09-23 1995-09-22 개선된황-코우팅된요소의서방성비료의제조방법

Country Status (16)

Country Link
US (1) US5599374A (ko)
EP (1) EP0730565B9 (ko)
JP (1) JP3006774B2 (ko)
KR (1) KR100381995B1 (ko)
CN (1) CN1072196C (ko)
AT (1) ATE200071T1 (ko)
AU (1) AU688602B2 (ko)
DE (1) DE69520486T2 (ko)
DK (1) DK0730565T3 (ko)
ES (1) ES2157347T3 (ko)
GR (1) GR3036059T3 (ko)
MX (1) MX9601630A (ko)
NO (1) NO316510B1 (ko)
NZ (1) NZ294141A (ko)
PT (1) PT730565E (ko)
WO (1) WO1996009267A1 (ko)

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09202683A (ja) * 1996-01-23 1997-08-05 Sumitomo Chem Co Ltd 被覆肥料の製造方法
TW349082B (en) * 1996-02-08 1999-01-01 Sumitomo Chemical Co Coated fertilizer
US5984994A (en) * 1998-01-16 1999-11-16 Hudson; Alice P. Sulfur coated fertilizers with improved abrasion resistance
US6001147A (en) * 1998-07-23 1999-12-14 Bayer Corporation Unsymmetrical polyureaurethane fertilizer encapsulation
US6152981A (en) * 1998-07-23 2000-11-28 Bayer Corporation Sulfur containing isocyanate compositions
US6165550A (en) * 1998-07-23 2000-12-26 Bayer Corporation Symmetrical Polyurea-urethane fertilizer encapsulation
US6338746B1 (en) * 1999-07-23 2002-01-15 Rlc Technologies, L.L.C. Polymer-sulfur-polymer coated fertilizers
US6364925B1 (en) 1999-12-10 2002-04-02 Bayer Corporation Polyurethane encapsulated fertilizer having improved slow-release properties
CA2300237A1 (en) 2000-03-09 2001-09-09 Mikhail Pildysh A coated substrate having controlled release properties and a method for the production thereof
BR0117303B1 (pt) 2000-05-17 2012-05-29 processos de preparação de uma composição fertilizante compreendendo uma pluralidade de partìculas e de liberação de enxofre para o solo.
US6358296B1 (en) 2000-07-11 2002-03-19 Bayer Corporation Slow-release polyurethane encapsulated fertilizer using oleo polyols
NZ511606A (en) * 2001-05-09 2002-11-26 Summit Quinphos Nz Ltd Fertiliser compositions comprising urea granules coated with wet ground sulphur
US6617412B2 (en) 2001-10-12 2003-09-09 Bayer Corporation Fertilizer encapsulation using sulfur containing polyols
US6787234B2 (en) 2002-05-15 2004-09-07 Oms Investments, Inc. Triggered start products and processes for the production and use thereof
PL203418B1 (pl) * 2002-06-17 2009-10-30 Yara International Asa Sposób wytwarzania nawozu mocznikowego z siarką elementarną i wytworzony produkt
US7416785B2 (en) * 2004-05-26 2008-08-26 Basf Corporation Polyurethane-encapsulated particle comprising polyol derived from aromatic amine-based initiator
US7494525B2 (en) * 2005-02-22 2009-02-24 Tessenderlo Kerley, Inc. Calcium polysulfide, potassium polysulfide, calcium thiosulfate, and magnesium thiosulfate as urease inhibitors
CN100540512C (zh) * 2005-08-26 2009-09-16 南京理工大学 环保复合包膜型缓释肥料
CN100475749C (zh) * 2005-08-26 2009-04-08 南京理工大学 含硫混合物膜层的涂覆方法
CN100369871C (zh) * 2005-12-08 2008-02-20 华南农业大学 一种肥料的包膜组合物与使用这种组合物生产包膜肥料的方法与所得到的包膜肥料
CN101100405B (zh) * 2006-07-06 2011-12-07 南京理工大学 含硫包膜型缓释化肥
US7834269B2 (en) * 2006-08-31 2010-11-16 Niles Martin S Protection of electrical power transmission systems
US7862642B2 (en) * 2006-12-14 2011-01-04 Georgia-Pacific Chemicals Llc Extended-release urea-based granular fertilizer
WO2008098409A1 (fr) * 2007-02-12 2008-08-21 Nanjing University Of Science And Technology Procédé d'enrobage d'un film composite contenant du soufre
US7771505B2 (en) * 2008-07-16 2010-08-10 Agrium Inc. Controlled release fertilizer composition
MY181825A (en) 2010-11-10 2021-01-08 Agrium U S Inc Cross-linked polyols for controlled release fertilizers
EP2637989B1 (en) 2010-11-10 2019-10-30 Agrium U.S. Inc. Cross-linked modified waxes for controlled release fertilizers
WO2012064727A1 (en) 2010-11-10 2012-05-18 Agrium Advanced Technologies Controlled release fertilizers made from cross-linked glyceride mixtures
US8329072B2 (en) 2010-11-24 2012-12-11 Brimrock International Inc. Method and system for generating sulfur seeds and granules
WO2012173938A1 (en) 2011-06-13 2012-12-20 Invista Technologies S.A.R.L. Aliphatic polyester polyols from cyclohexane oxidation byproduct streams as precursors for polyurethane and polyisocyanurate polymers
ES2637663T3 (es) 2011-08-26 2017-10-16 Ekompany International B.V. Proceso para la producción de un fertilizante recubierto
US9090518B2 (en) 2011-08-26 2015-07-28 Ekompany Agro B.V. Process for producing a coated fertilizer comprising boron
WO2013090287A1 (en) 2011-12-12 2013-06-20 Koch Agronomic Services, Llc Conditioned urea-based granular fertilizers and methods of making thereof
CN104379540A (zh) 2012-05-18 2015-02-25 巴斯夫欧洲公司 抑尘聚集体
MX2014013879A (es) 2012-05-18 2015-03-05 Basf Se Particula encapsulada.
CA2821909A1 (en) 2012-07-27 2014-01-27 Carbon Basis Company Ltd. Biochar products and method of manufacture thereof
JP6516677B2 (ja) 2012-11-16 2019-05-22 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se カプセル化粒子
US9321699B2 (en) * 2012-11-21 2016-04-26 The Mosaic Company Granular fertilizers having improved dust control
US9174885B2 (en) 2013-03-15 2015-11-03 University Of Kentucky Research Foundation Nitrogen fertilizer composition and method to improve detection and lessen the explosive potential of nitrogen-based fertilizers
WO2015073451A1 (en) 2013-11-12 2015-05-21 Nous, Llc System for coating granular materials
US10330654B2 (en) * 2014-07-20 2019-06-25 Sabic Global Technologies B.V. Methods for determining low sulfate concentrations in synthetic urea samples, produced in a manufacturing process and containing high levels of impurities
WO2016070184A1 (en) 2014-10-31 2016-05-06 Koch Agronomic Services, Llc Nitrification inhibitor compositions and methods of making thereof
MA42900A (fr) * 2015-07-07 2018-05-16 Yara Int Asa Procédé de fabrication de matériau particulaire à base d'urée contenant du soufre élémentaire
CN105001023B (zh) * 2015-07-14 2018-01-16 吉林云天化农业发展有限公司 硫酸脲包膜尿素缓释颗粒肥及其制备方法
EP3359617A4 (en) 2015-10-08 2019-08-14 The Carbon Basis Company Ltd. BIO COAL PRODUCTS AND METHOD FOR THE PRODUCTION THEREOF
US10273194B2 (en) 2016-07-04 2019-04-30 Gary David McKnight Process to conserve cyano-function and improve performance of low molecular weight nitrification inhibitors to improve fertilizer efficiency
CN109843833A (zh) * 2016-10-05 2019-06-04 努斯有限责任公司 用于粒状材料的包覆物的系统
JOP20190274A1 (ar) 2017-05-23 2019-11-24 Mosaic Co حبيبات أسمدة متضخمة تحتوي على الكبريت المعدني مع زيادة معدلات الأكسدة
CN108424267A (zh) * 2018-05-22 2018-08-21 苏州硒谷科技有限公司 一种淀粉改性聚氨酯包膜缓释硒肥及其制备方法
MX2022003991A (es) 2019-10-03 2022-06-16 Carbo Ceramics Inc Particulas de compuesto nucleo-cubierta y metodos para hacerlas.
CN211005182U (zh) * 2019-11-27 2020-07-14 湖北富邦科技股份有限公司 一种用于颗粒肥料外包喷涂液体硫磺的装置
EP4365155A1 (en) 2022-11-07 2024-05-08 Fertilizantes Gombau, S.L. Fertilizer urea-based compositions comprising sulfur and process and system thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5238361A (en) * 1975-09-22 1977-03-24 Ube Industries Slowly available coated granular fertilizer
US4969947A (en) * 1988-04-12 1990-11-13 Melamine Chemicals, Inc. One-step method of coating nutrient particles
US5219465A (en) * 1991-03-08 1993-06-15 The O.M. Scott & Sons Company Sulfur coated fertilizers and process for the preparation thereof
DE4127459A1 (de) * 1991-08-20 1993-02-25 Aglukon Spezialduenger Gmbh Verfahren zur herstellung von membranumhuellten duengemittelgranulaten

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CN1072196C (zh) 2001-10-03
GR3036059T3 (en) 2001-09-28
DE69520486T2 (de) 2001-08-09
NO962090L (no) 1996-06-21
NO962090D0 (no) 1996-05-22
JP3006774B2 (ja) 2000-02-07
EP0730565A1 (en) 1996-09-11
ES2157347T3 (es) 2001-08-16
US5599374A (en) 1997-02-04
WO1996009267A1 (en) 1996-03-28
CN1135745A (zh) 1996-11-13
MX9601630A (es) 1997-05-31
EP0730565B1 (en) 2001-03-28
AU3681195A (en) 1996-04-09
JPH10513144A (ja) 1998-12-15
KR100381995B1 (ko) 2003-07-18
EP0730565A4 (en) 1998-01-07
DK0730565T3 (da) 2001-07-16
EP0730565B9 (en) 2002-05-08
NO316510B1 (no) 2004-02-02
NZ294141A (en) 1999-03-29
DE69520486D1 (de) 2001-05-03
ATE200071T1 (de) 2001-04-15
PT730565E (pt) 2001-07-31
AU688602B2 (en) 1998-03-12

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