KR960705758A - 개선된 황-코우팅된 요소의 서방성 비료의 제조 방법(process for producing improved sulfur-coated urea slow release fertilizers) - Google Patents
개선된 황-코우팅된 요소의 서방성 비료의 제조 방법(process for producing improved sulfur-coated urea slow release fertilizers)Info
- Publication number
- KR960705758A KR960705758A KR1019960702716A KR19960702716A KR960705758A KR 960705758 A KR960705758 A KR 960705758A KR 1019960702716 A KR1019960702716 A KR 1019960702716A KR 19960702716 A KR19960702716 A KR 19960702716A KR 960705758 A KR960705758 A KR 960705758A
- Authority
- KR
- South Korea
- Prior art keywords
- sulfur
- coated urea
- coated
- diisocyanate
- diethylene glycol
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C9/00—Fertilisers containing urea or urea compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
본 발명은 황-코우팅 위에 균일하고 내구성 있는 중합체 코우팅을 갖는 황-코우팅된 요소의 서방성 과립상 비료를 기술한다. 중합체 코우팅은 황-코우팅된 요소 과립의 표면에 디에틸렌 글리콜-트리에탄올아민 폴리올 및 디이소시아네이트의 직접적 공중합에 의해 생성된다. 중합체 코우팅은 복합 코우팅된 과립의 개선된 내충격성을 제공한다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (8)
1) 예비 가열된 요소 과립을 용융황으로 코우팅시켜 두께의 범위에 있어서 예정된 명목상의 두께를 갖는 코우팅을 수득하고; 2) 단계 1)의 황 코우팅된 요소 과립을 디이소시아네이트 및 디에틸렌글리콜과 트리에탄올아민의 폴리올 혼합물인 반응성 단량체로 코우팅하고, 단량체를 황-코우팅된 요소 과립의 표면상에 중합시켜 내충격성 중합체 밀폐제 코우팅을 형성하며; 3) 단계 2)의 중합체 코우팅되고 황-코우팅된 요소 과립 생성물을 냉각하는 단계로 이루어짐을 특징으로 하는 황-코우팅된 요소 과립비료 생성물의 제조방법.
제1항에 있어서, 디이소시아네이트가 주로 4,4-디페닐메탄 디이소시아네이트로 구성되는 방법.
제1항에 있어서, 디에틸렌 글리콜-트리에타올아민 중합체 혼합물의 일부분이 고분자량이 폴리에스테르 폴리올로 대치되는 방법.
제3항에 있어서, 디에틸렌 글리콜과 트리에탄올아민의 중량비가 2.5:1 내지 4.5:1인 방법.
제4항에 있어서, 디에틸렌 글리콜과 트리에탄올아민의 중량비가 3.5:1인 방법.
제4항에 있어서, 액체 폴리올:디이소시아네이트의 중량비가 0.33:1~0.45:1의 범위내인 방법.
제6항에 있어서, 폴리올:디이소시아네이트의 비가 0.39:1인 방법.
제1항 내지 7항 중 어느 한 항에 따른 방법에 의해 생성된 황-코우팅된 요소 과립상 비료.
※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/311,672 US5599374A (en) | 1994-09-23 | 1994-09-23 | Process for producing improved sulfur-coated urea slow release fertilizers |
US08/311672 | 1994-09-23 | ||
US08/311,672 | 1994-09-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR960705758A true KR960705758A (ko) | 1996-11-08 |
KR100381995B1 KR100381995B1 (ko) | 2003-07-18 |
Family
ID=23207948
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019960702716A KR100381995B1 (ko) | 1994-09-23 | 1995-09-22 | 개선된황-코우팅된요소의서방성비료의제조방법 |
Country Status (16)
Country | Link |
---|---|
US (1) | US5599374A (ko) |
EP (1) | EP0730565B9 (ko) |
JP (1) | JP3006774B2 (ko) |
KR (1) | KR100381995B1 (ko) |
CN (1) | CN1072196C (ko) |
AT (1) | ATE200071T1 (ko) |
AU (1) | AU688602B2 (ko) |
DE (1) | DE69520486T2 (ko) |
DK (1) | DK0730565T3 (ko) |
ES (1) | ES2157347T3 (ko) |
GR (1) | GR3036059T3 (ko) |
MX (1) | MX9601630A (ko) |
NO (1) | NO316510B1 (ko) |
NZ (1) | NZ294141A (ko) |
PT (1) | PT730565E (ko) |
WO (1) | WO1996009267A1 (ko) |
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US6364925B1 (en) | 1999-12-10 | 2002-04-02 | Bayer Corporation | Polyurethane encapsulated fertilizer having improved slow-release properties |
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BR0117303B1 (pt) | 2000-05-17 | 2012-05-29 | processos de preparação de uma composição fertilizante compreendendo uma pluralidade de partìculas e de liberação de enxofre para o solo. | |
US6358296B1 (en) | 2000-07-11 | 2002-03-19 | Bayer Corporation | Slow-release polyurethane encapsulated fertilizer using oleo polyols |
NZ511606A (en) * | 2001-05-09 | 2002-11-26 | Summit Quinphos Nz Ltd | Fertiliser compositions comprising urea granules coated with wet ground sulphur |
US6617412B2 (en) | 2001-10-12 | 2003-09-09 | Bayer Corporation | Fertilizer encapsulation using sulfur containing polyols |
US6787234B2 (en) | 2002-05-15 | 2004-09-07 | Oms Investments, Inc. | Triggered start products and processes for the production and use thereof |
PL203418B1 (pl) * | 2002-06-17 | 2009-10-30 | Yara International Asa | Sposób wytwarzania nawozu mocznikowego z siarką elementarną i wytworzony produkt |
US7416785B2 (en) * | 2004-05-26 | 2008-08-26 | Basf Corporation | Polyurethane-encapsulated particle comprising polyol derived from aromatic amine-based initiator |
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WO2008098409A1 (fr) * | 2007-02-12 | 2008-08-21 | Nanjing University Of Science And Technology | Procédé d'enrobage d'un film composite contenant du soufre |
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MY181825A (en) | 2010-11-10 | 2021-01-08 | Agrium U S Inc | Cross-linked polyols for controlled release fertilizers |
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-
1994
- 1994-09-23 US US08/311,672 patent/US5599374A/en not_active Expired - Lifetime
-
1995
- 1995-09-22 DK DK95934488T patent/DK0730565T3/da active
- 1995-09-22 NZ NZ294141A patent/NZ294141A/xx not_active IP Right Cessation
- 1995-09-22 EP EP95934488A patent/EP0730565B9/en not_active Expired - Lifetime
- 1995-09-22 AT AT95934488T patent/ATE200071T1/de active
- 1995-09-22 DE DE69520486T patent/DE69520486T2/de not_active Expired - Lifetime
- 1995-09-22 MX MX9601630A patent/MX9601630A/es unknown
- 1995-09-22 WO PCT/US1995/012060 patent/WO1996009267A1/en active IP Right Grant
- 1995-09-22 CN CN95190939A patent/CN1072196C/zh not_active Expired - Lifetime
- 1995-09-22 PT PT95934488T patent/PT730565E/pt unknown
- 1995-09-22 JP JP8511086A patent/JP3006774B2/ja not_active Expired - Fee Related
- 1995-09-22 ES ES95934488T patent/ES2157347T3/es not_active Expired - Lifetime
- 1995-09-22 AU AU36811/95A patent/AU688602B2/en not_active Ceased
- 1995-09-22 KR KR1019960702716A patent/KR100381995B1/ko not_active IP Right Cessation
-
1996
- 1996-05-22 NO NO962090A patent/NO316510B1/no not_active IP Right Cessation
-
2001
- 2001-06-15 GR GR20010400901T patent/GR3036059T3/el not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CN1072196C (zh) | 2001-10-03 |
GR3036059T3 (en) | 2001-09-28 |
DE69520486T2 (de) | 2001-08-09 |
NO962090L (no) | 1996-06-21 |
NO962090D0 (no) | 1996-05-22 |
JP3006774B2 (ja) | 2000-02-07 |
EP0730565A1 (en) | 1996-09-11 |
ES2157347T3 (es) | 2001-08-16 |
US5599374A (en) | 1997-02-04 |
WO1996009267A1 (en) | 1996-03-28 |
CN1135745A (zh) | 1996-11-13 |
MX9601630A (es) | 1997-05-31 |
EP0730565B1 (en) | 2001-03-28 |
AU3681195A (en) | 1996-04-09 |
JPH10513144A (ja) | 1998-12-15 |
KR100381995B1 (ko) | 2003-07-18 |
EP0730565A4 (en) | 1998-01-07 |
DK0730565T3 (da) | 2001-07-16 |
EP0730565B9 (en) | 2002-05-08 |
NO316510B1 (no) | 2004-02-02 |
NZ294141A (en) | 1999-03-29 |
DE69520486D1 (de) | 2001-05-03 |
ATE200071T1 (de) | 2001-04-15 |
PT730565E (pt) | 2001-07-31 |
AU688602B2 (en) | 1998-03-12 |
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