KR950704266A - 2-플루오로알킬-치환된 벤즈이미다졸, 그의 제조방법 및 농약으로서의 그의 용도(2―Fluoroalkyl―substituted benzimidazoles, their preparation and their use as pesticides) - Google Patents

2-플루오로알킬-치환된 벤즈이미다졸, 그의 제조방법 및 농약으로서의 그의 용도(2―Fluoroalkyl―substituted benzimidazoles, their preparation and their use as pesticides)

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KR950704266A
KR950704266A KR1019950701763A KR19950701763A KR950704266A KR 950704266 A KR950704266 A KR 950704266A KR 1019950701763 A KR1019950701763 A KR 1019950701763A KR 19950701763 A KR19950701763 A KR 19950701763A KR 950704266 A KR950704266 A KR 950704266A
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optionally substituted
trifluoromethyl
alkyl
nitro
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룬켄하이머 빈프리트
바스너 베른트
리이브 폴커
에르델렌 크리스토프
바헨도르프-노이만 울리케
스텐델 빌헬름
괴르겐스 울리히
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귄터 슈마허, 크누트 샤우에르테
바이엘 악티엔게젤샤프트
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
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    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
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    • C07D235/04—Benzimidazoles; Hydrogenated benzimidazoles
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Abstract

본 발명은 하기 일반식(I)의 신규한 치환된 벤즈이미다졸, 그의 제조방법 및 농약으로서 그의 용도에 관한 것이다.
상기식에서, R1은 수소, 알킬, 할로게노알킬, 사이클로알킬 또는 임의로 치환된 아릴을 나타내고, R2는 수소, 알킬, 할로게노알킬, 사이클로알킬 또는 임의로 치환된 아릴을 나타내며, R3는 플루오로알킬을 나타내고, X1, X2, X3및 X4는 서로 독립적으로 각 경우에 수소, 할로겐, 시아노, 니트로, 각 경우에 임의로 치환된 알킬, 알콕시, 알킬티오, 알킬설피닐, 알킬설포닐 또는 사이클로알킬, 임의로 치환되고 융합될 수 있는 디옥시알킬렌, 하이드록시카보닐, 알킬카보닐, 알콕시카보닐, 사이클로알킬옥시카보닐, 각 경우에 임의로 치환된 아미노 또는 아미노카보닐 또는 각 경우에 임의로 치환된 아릴, 아릴옥시, 아릴 티오, 아릴설피닐, 아릴설포닐, 아릴설포닐옥시, 아릴카보닐, 아릴옥시카보닐, 아릴아조 또는 아릴티오메틸설포닐을 나타내지만, 이들 치환체 X1, X2, X3및 X4중의 적어도 하나는 수고가 아니며, 단, 이중에서 화합물 1―(N,N―디메틸아미노설포닐)―2―트리플루오로메틸―4―니트로―6―트리플루오로메틸―벤조이미다졸, 1―(N,N―디메틸아미노설포닐)―2―트리플루오로메틸―4―니트로―6―트리플루오로메틸―벤조이미다졸 및 1―〔N,N―비스―(n―프로필)―아미노설포닐〕―2―트리플루오로메틸―4―니트로―6―트리플루오로메틸―벤조이미다졸은 제외된다.

Description

2―플루오로알킬―치환된 벤즈이미다졸, 그의 제조방법 및 농약으로서의 그의 용도(2―Fluoroalkyl―substituted benzimidazoles, their preparation and rheir use as pesticides)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 일반식(I)의 치환된 벤즈이미다졸.
    상기식에서, R1은 수소, 알킬, 할로게노알킬, 사이클로알킬 또는 임의로 치환된 아릴을 나타내고, R2는 수소, 알킬, 할로게노알킬, 사이클로알킬 또는 임의로 치환된 아릴을 나타내며, R3는 플루오로알킬을 나타내고, X1, X2, X3및 X4는 서로 독립적으로 각 경우에 수소, 할로겐, 시아노, 니트로, 각 경우에 임의로 치환된 알킬, 알콕시, 알킬티오, 알킬설피닐, 알킬설포닐 또는 사이클로알킬, 임의로 치환되고 융합될 수 있는 디옥시알킬렌, 하이드록시카보닐, 알킬카보닐, 알콕시카보닐, 사이클로알킬옥시카보닐, 각 경우에 임의로 치환된 아미노 또는 아미노카보닐 또는 각 경우에 임의로 치환된 아릴, 아릴옥시, 아릴 티오, 아릴설피닐, 아릴설포닐, 아릴설포닐옥시, 아릴카보닐, 아릴옥시카보닐, 아릴아조 또는 아릴티오메틸설포닐을 나타내지만, 이들 치환체 X1, X2, X3및 X4중의 적어도 하나는 수고가 아니며, 단, 이중에서 화합물 1―(N,N―디메틸아미노설포닐)―2―트리플루오로메틸―4―니트로―6―트리플루오로메틸―벤조이미다졸, 1―(N,N―디메틸아미노설포닐)―2―트리플루오로메틸―4―니트로―6―트리플루오로메틸―벤조이미다졸 및 1―〔N,N―비스―(n―프로필)―아미노설포닐〕―2―트리플루오로메틸―4―니트로―6―트리플루오로메틸―벤조이미다졸은 제외된다.
  2. 일반식(II)의 1H―벤즈아미다졸을 임의로 희석제의 존재하 및 임의로 반응 보조제의 존재하에서, 일반식(III)의 할로게노설폰아미드와 반응시킴을 특징으로 하여, 일반식(I)의 치환된 벤즈이미다졸을 제조하는 방법.
    상기식에서, R1은 수소, 알킬, 할로게노알킬, 사이클로알킬 또는 임의로 치환된 아릴을 나타내고, R2는 수소, 알킬, 할로게노알킬, 사이클로알킬 또는 임의로 치환된 아릴을 나타내며, R3는 플루오로알킬을 나타내고, X1, X2, X3및 X4는 서로 독립적으로 각 경우에 수소, 할로겐, 시아노, 니트로, 각 경우에 임의로 치환된 알킬, 알콕시, 알킬티오, 알킬설피닐, 알킬설포닐 또는 사이클로알킬, 임의로 치환되고 융합될 수 있는 디옥시알킬렌, 하이드록시카보닐, 알킬카보닐, 알콕시카보닐, 사이클로알킬옥시카보닐, 각 경우에 임의로 치환된 아미노 또는 아미노카보닐 또는 각 경우에 임의로 치환된 아릴, 아릴옥시, 아릴 티오, 아릴설피닐, 아릴설포닐, 아릴설포닐옥시, 아릴카보닐, 아릴옥시카보닐, 아릴아조 또는 아릴티오메틸설포닐을 나타내지만, 이들 치환체 X1, X2, X3및 X4중의 적어도 하나는 수고가 아니며, Hal은 할로겐을 나타내고, 단 일반식(I)의 화합물 중에서 화합물 1―(N,N―디메틸아미노설포닐)―2―트리플루오로메틸―4―니트로―6―트리플루오로메틸―벤조이미다졸, 1―(N,N―디메틸아미노설포닐)―2―트리플루오로메틸―4―니트로―6―트리플루오로메틸―벤조이미다졸 및 1―〔N,N―비스―(n―프로필)―아미노설포닐〕―2―트리플루오로메틸―4―니트로―6―트리플루오로메틸―벤조이미다졸은 제외된다.
  3. 제1항에 있어서, 일반식(I)의 치환된 벤즈이미다졸을 적어도 하나 함유함을 특징으로 하는 농약.
  4. 해중을 구제하기 위한 제1항에 따르는 일반식(I)의 치환된 벤즈이미다졸의 용도.
  5. 제1항에 따른 일반식(I)의 치환된 벤즈이미다졸을 증량제 및/또는 계면활성제와 혼합시킴을 특징으로하여, 농약을 제조하는 방법.
  6. 일반식(II)의 화합물.
    상기식에서, X1, X2, X3및 X4는 하기 의미를 가지며
    Z는 플루오로 ―C1―7―알킬을 나타낸다.
    ※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019950701763A 1992-11-06 1993-10-25 2-플루오로알킬-치환된벤즈이미다졸,그의제조방법 및 농약으로서의 그의용도 KR100298002B1 (ko)

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Application Number Priority Date Filing Date Title
DE4237597A DE4237597A1 (de) 1992-11-06 1992-11-06 Substituierte Benzimidazole
DEP4237597.5 1992-11-06
PCT/EP1993/002947 WO1994011350A1 (de) 1992-11-06 1993-10-25 2-fluoralkyl-substituierte benzimidazole, ihre herstellung und ihre verwendung als schädlingsbekämpfungsmittel

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KR950704266A true KR950704266A (ko) 1995-11-17
KR100298002B1 KR100298002B1 (ko) 2001-10-24

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AU (1) AU5337894A (ko)
BR (1) BR9307393A (ko)
CA (1) CA2148605A1 (ko)
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HU (1) HU217906B (ko)
WO (1) WO1994011350A1 (ko)

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DE4237557A1 (de) * 1992-11-06 1994-05-11 Bayer Ag Substituierte Benzimidazole
DE4237579A1 (de) * 1992-11-06 1994-05-11 Bayer Ag Fluorierte 1,3-Benzo- und 1,3-Pyrido-dioxole, ihre Herstellung und ihre Verwendung
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EP0667862A1 (de) 1995-08-23
US5585395A (en) 1996-12-17
AU5337894A (en) 1994-06-08
HUT71740A (en) 1996-01-29
CA2148605A1 (en) 1994-05-26
BR9307393A (pt) 1999-08-24
WO1994011350A1 (de) 1994-05-26
DE4237597A1 (de) 1994-05-11
JPH08502983A (ja) 1996-04-02
KR100298002B1 (ko) 2001-10-24

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