KR950703044A - Lead Free Methylcyclopentadienyl Manganese Tricarbonyl Fuel Composition [UNLEADED METHYLCYCLOPENTADIENYL MANGANESE TRICARBONYL (MMT) FUEL COMPOSITION] - Google Patents

Lead Free Methylcyclopentadienyl Manganese Tricarbonyl Fuel Composition [UNLEADED METHYLCYCLOPENTADIENYL MANGANESE TRICARBONYL (MMT) FUEL COMPOSITION] Download PDF

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KR950703044A
KR950703044A KR1019950700815A KR19950700815A KR950703044A KR 950703044 A KR950703044 A KR 950703044A KR 1019950700815 A KR1019950700815 A KR 1019950700815A KR 19950700815 A KR19950700815 A KR 19950700815A KR 950703044 A KR950703044 A KR 950703044A
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combustion
manganese
emissions
fuel
composition
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KR100307417B1 (en
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씨. 오르 윌리암
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씨. 오르 윌리암
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Abstract

무연 연료 조성물은 사이클로메틱 망간 트리카보닐 화합물(CMT), 바람직하게는 메틸사이클로펜타디에닐 망간 트리카보닐(MMT)과, 생성된 배기 방출물이 환경적으로 허용되도록 연소 도중에 대량의 망간산화물의 형성을 감소시키는 수단을 포함한다.The lead-free fuel composition is composed of a cyclomatic manganese tricarbonyl compound (CMT), preferably methylcyclopentadienyl manganese tricarbonyl (MMT), and a large amount of manganese oxide during combustion so that the resulting exhaust emissions are environmentally acceptable. Means for reducing formation.

Description

무연 메틸사이클로펜타디에닐 망간 트리카보닐 연료 조성물 [UNLEADED METHYLCYCLOPENTADIENYL MANGANESE TRICARBONYL (MMT) FUEL COMPOSITION]Lead Free Methylcyclopentadienyl Manganese Tricarbonyl Fuel Composition [UNLEADED METHYLCYCLOPENTADIENYL MANGANESE TRICARBONYL (MMT) FUEL COMPOSITION]

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

제1도는 2부류의 연료 사이의 더욱 높은 하중, 더 큰 EGT 차이를 나타낸다.Figure 1 shows the higher load, larger EGT difference between the two classes of fuel.

Claims (23)

탄화수소로 구성된 무연 가솔린 기재를, 망간의 농도가 연료 조성물 1ℓ당 약 0.000264 내지 약 0.2642g의 망간인 사이클로펜타디에닐 망간 트리카보닐 녹킹 방지(antiknock) 화합물, 연소 속도를 증가시키거나 연소온도를 감소시키거나, 또는 두 작용을 모두 함으로써 망간 산화물을 형성하는 유해한 방출물의 형성을 억제하는 산소화물 부가수단 또는 기계적 수단 및 이들의 조합물과 혼합하고, 연료를 엔진에 공급하여 연소시키고, 생성된 연소 방출물을 엔진으로부터 방출시켜, 탄화수소 방출이 법률적 요건에 부합되도록 함을 포함하여, 무연 연료용으로 고안된 스파크 점화 내연기관 및 배기 시스템의 유해한 연소 방출을 억제하는 방법.Lead-free gasoline substrates composed of hydrocarbons, cyclopentadienyl manganese tricarbonyl antiknock compounds with a concentration of manganese of from about 0.000264 to about 0.2642 g of manganese per liter of fuel composition, increasing combustion rates or decreasing combustion temperatures Mixed with oxygenate addition means or mechanical means and combinations thereof, which inhibit the formation of harmful emissions that form manganese oxide by the action of both, or by both actions, and supply fuel to the engine for combustion, resulting combustion emissions A method of suppressing harmful combustion emissions of spark ignition internal combustion engines and exhaust systems designed for unleaded fuels, including the release of water from the engine to ensure that hydrocarbon emissions meet legal requirements. 제1항에 있어서, 산소화 부가물이 메틸옥시 라디칼을 포함하는 방법.The method of claim 1 wherein the oxygenation adduct comprises a methyloxy radical. 제1항에 있어서, 산소화 부가물이 연소된 조성물의 연료-공기비를 증가시키는 방법.The method of claim 1 wherein the oxygenated adduct increases the fuel-air ratio of the combusted composition. 제1항에 있어서, 산소화 부가물이 연소 도중에 연료의 증기 용적을 증가시키는 방법.The method of claim 1 wherein the oxygenated adduct increases the vapor volume of the fuel during combustion. 제1항에 있어서, 산소화 부가물이 카본산 디메틸 에스테르를 포함하는 방법.The process of claim 1 wherein the oxygenation adduct comprises carboxylic acid dimethyl ester. 제1항에 있어서, 산소화 부가물이 메틸 3급 부틸 에스테르를 포함하는 방법.The process of claim 1 wherein the oxygenation adduct comprises methyl tertiary butyl ester. 제1항에 있어서, 산소화 부가물이 에틸 3급 부틸 에테르를 포함하는 방법.The process of claim 1 wherein the oxygenation adduct comprises ethyl tertiary butyl ether. 제1항에 있어서, 산소화 부가물이 일산화탄소, 메틸렌 디메틸 에테르, 카본산 디메틸 에스테르, 메틸 3급 부틸 에테르, 에틸 3급 부틸 에테르, 메틸 3급 아밀 에테르, 디메틸 에테르, 디이소프로필 에테르 및 이들의 혼합물로 이루어진 그룹으로부터 선택된 산소화물을 포함하는 방법.The process of claim 1 wherein the oxygenated adducts are carbon monoxide, methylene dimethyl ether, carboxylic acid dimethyl ester, methyl tertiary butyl ether, ethyl tertiary butyl ether, methyl tertiary amyl ether, dimethyl ether, diisopropyl ether and mixtures thereof A method comprising an oxygenate selected from the group consisting of. 제1항에 있어서, 배기 시스템이 무연 연료용으로 고안된 규정 방출 조절 배기 시스템인 방법.The method of claim 1 wherein the exhaust system is a regulated emission controlled exhaust system designed for unleaded fuel. 제1항에 있어서, 비점을 변형시키는 조용매 또는 조용매 그룹을 사용함으로써, 비점이 가솔린의 비점보다 높은 탄화수소를 조성물에 혼입시킬 수 있는 단계를 추가로 포함하는 방법.The method of claim 1, further comprising the step of incorporating a hydrocarbon having a boiling point above the boiling point of gasoline into the composition by using a cosolvent or a group of cosolvents that modify the boiling point. 제1항에 있어서, 조성물의 비점을 변형시키는 조용매 또는 조용매 그룹을 사용함으로써, 조성물의 최종 비점을 감소시킬 수 있는 단계를 추가로 포함하는 방법.The method of claim 1, further comprising reducing the final boiling point of the composition by using cosolvents or groups of cosolvents that modify the boiling point of the composition. 제1항에 있어서, 산소화 부가물이 하이드록실 라디칼을 포함하는 방법.The method of claim 1 wherein the oxygenation adduct comprises hydroxyl radicals. 탄화수소를 포함하는 무연 가솔린 기재를, 망간의 농도가 연료 조성물 ℓ당 약 0.000264 내지 약 0.2642g의 망간이 사이클로펜타디에닐 망간 트리카보닐 녹킹 방지 화합물, 연소 속도를 증가시키거나 연소온도를 감소시키거나, 또는 두 작용을 모두 함으로써 유해한 방출물의 형성을 억제하는 산소화물 부가 수단 또는 기계적 수단과 이들의 조합물 및 비점을 변형시켜 구동성을 개선시키거나 조성물의 최종 비점을 감소시키거나 비점이 가솔린 비점보다 높은 탄화수소를 혼합물에 혼입시키거나 또는 이들 모두를 제공하는 수단과 혼합하고, 혼합물을 엔진에 공급하여 연소시키고, 엔진으로부터 배기 시스템을 통해 생성된 연소 방출물을 방출시켜 탄화수소 방출이 최소한의 법률적 요건에 부합되도록 함을 포함하여, 무연 연료용으로 고안된 스파크 점화 내연기관 및 배기 시스템의 유해한 연소 방출을 억제하는 방법.Lead-free gasoline substrates containing hydrocarbons have a concentration of about 0.000264 to about 0.2642 g of manganese cyclopentadienyl manganese tricarbonyl anti-knock compound, the manganese concentration per liter of fuel composition, to increase the combustion rate or to reduce the combustion temperature Or a combination of oxygenates or mechanical means and combinations thereof, which inhibits the formation of harmful emissions by acting both, to improve operability, reduce the final boiling point of the composition, or Hydrocarbon emissions are the minimum legal requirement by incorporating high hydrocarbons into the mixture or with means that provide both, by feeding the mixture to the engine for combustion, and releasing the combustion emissions produced from the engine through the exhaust system. In spark ignitions designed for unleaded fuel, including How to suppress harmful combustion emissions from smoke pipes and exhaust systems. 제13항에 있어서, 연소된 생성물의 연료-공기비를 증가시키는 단계를 추가로 포함하는 방법.The method of claim 13, further comprising increasing the fuel-air ratio of the combusted product. 제13항에 있어서, 연소 도중에 연료를 증기 용적을 증가시키는 단계를 추가로 포함하는 방법.The method of claim 13, further comprising increasing the vapor volume of the fuel during combustion. 제13항에 있어서, 비점을 변형시키는 수단이 C4-C12공비물질 형성 알콜 및 이들의 혼합물로 이루어진 그룹으로부터 선택된 알콜을 사용하는 방법.The method of claim 13, wherein the means for modifying the boiling point uses an alcohol selected from the group consisting of C 4 -C 12 azeotrope forming alcohols and mixtures thereof. 탄화수소를 포함하는 무연 가소린 기재를, 망간의 농도가 연료 조성물 1ℓ당 약 0.000264 내지 약 0.2642g의 망간인 사이클로펜타디에닐 망간 트리카보닐 녹킹 방지 화합물 및, 일산화탄소, 메틸렌 디메틸 에테르, 카본산 디메틸 에스테르, 메틸 3급 부틸 에테르, 에틸 3급 부틸 에스테르, 메틸 3급 부틸 에테르 및 이들의 혼합물로 이루어진 그룹으로부터 선택된 산소화물을 사용하여 유해한 탄화수소 연소 방출을 억제하는 산소화물 부가수단과 혼합하고, 생성된 연료를 엔진에서 연소시키고, 배기 시스템을 통해 엔진의 연소 방출물을 방출시켜, 탄화수소 방출이 최소한의 법률적 요건에 부합되도록 함을 포함하여, 무연 연료용으로 고안된 스파크 점화 내연기관으로부터 유해한 탄화수소 연소 방출을 억제하는 방법.Lead-free plasticine substrates comprising hydrocarbons include cyclopentadienyl manganese tricarbonyl anti-knock compounds and carbon monoxide, methylene dimethyl ether, carboxylic acid dimethyl esters having a concentration of manganese of from about 0.000264 to about 0.2642 g of manganese per liter of fuel composition; A fuel produced by mixing with an oxygenate addition means that inhibits harmful hydrocarbon combustion emissions using an oxygenate selected from the group consisting of methyl tertiary butyl ether, ethyl tertiary butyl ester, methyl tertiary butyl ether and mixtures thereof To burn harmful hydrocarbon combustion emissions from spark-ignition internal combustion engines designed for lead-free fuels, including combustion in engines and emission of engine combustion emissions through exhaust systems to ensure that hydrocarbon emissions meet minimum legal requirements. How to suppress. 탄화수소를 포함하는 무연 가솔린 기재, 망간의 농도가 연료 조성물 1ℓ당 약 0.000264 내지 약 0.2642g인 망간인 사이클로펜타디에닐 망간 트리카보닐 녹킹 방지 화합물 및 연소 속도를 증가시키거나 연소온도를 감소시키거나, 또는 두 작용을 모두 함으로써, 생성된 방출이 최소한의 법률적 요건에 부합되도록 유해한 탄화수소 방출물의 형성을 감소시키는 산소화물 무가수단 또는 기계적 수단 및 이들의 조합물을 포함하는, 무연 연료용으로 고안된 스파크 점화 내연기관 및 배기 시스템의 유해한 연소 방출물 억제용 연료 조성물,Lead-free gasoline substrates comprising hydrocarbons, cyclopentadienyl manganese tricarbonyl anti-knock compounds and manganese having a concentration of manganese of from about 0.000264 to about 0.2642 g per liter of fuel composition and increasing combustion rates or reducing combustion temperatures, Or a spark ignition designed for unleaded fuel, including oxygen free and / or mechanical means and combinations thereof that reduce the formation of harmful hydrocarbon emissions such that the resulting emissions meet minimum legal requirements by both actions. Fuel compositions for suppressing harmful combustion emissions of internal combustion engines and exhaust systems, 제18항에 있어서, 조성물의 비점을 변형시켜 구동성을 개선시키기 위해 조용매, 조용매 그룹, 고비점 탄화수소 또는 탄화수소 그룹 및 이들의 혼합물을 추가로 포함하는 조성물.19. The composition of claim 18, further comprising a cosolvent, cosolvent group, high boiling point hydrocarbon or hydrocarbon group and mixtures thereof to modify the boiling point of the composition to improve driveability. 탄화수소를 포함하는 무연 가솔린 기재, 망간의 농도가 연료 조성물 1ℓ당 약 0.000264 내지 약 0.2642g의 망간인 사이클로펜타디에닐 망간 트리카보닐 녹킹 방지 화합물 및 탄화수소 방출이 최소한의 법률적 요건에 부합되도록 하는 카본산 디메틸 에스테르를 사용하는 수단을 포함하는, 스파크 점화 내연기관으로부터의 유해한 탄화수소 연소 방출물 억제용 연료 조성물.Lead-free gasoline substrates containing hydrocarbons, cyclopentadienyl manganese tricarbonyl anti-knock compounds with a concentration of manganese of from about 0.000264 to about 0.2642 g of manganese per liter of fuel composition, and carbon to ensure that hydrocarbon emissions meet minimum legal requirements A fuel composition for inhibiting harmful hydrocarbon combustion emissions from a spark ignition internal combustion engine, comprising means for using acid dimethyl ester. 제20항에 있어서, 내연기관이 무연 가솔린용으로 고안된 연료 조성물.21. The fuel composition of claim 20, wherein the internal combustion engine is designed for unleaded gasoline. 탄화수소를 포함하는 무연 가솔린 기재, 망간의 농도가 연료 조성물 1ℓ당 약 0.000264 내지 약 0.2642g의 망간인 사이클로펜타디에닐 망간 트리카보닐 녹킹 방지 화합물 및 탄화수소 방출이 최소한의 법률적 요건에 부합되도록 하는 메틸 3급 부틸 에테르를 사용하는 수단을 포함하는, 스파크 점화 내연기관으로부터의 유해한 탄화수소 연소 방출을 억제용 연료 조성물.Lead-free gasoline substrates containing hydrocarbons, cyclopentadienyl manganese tricarbonyl anti-knock compounds with a concentration of manganese of about 0.000264 to about 0.2642 g of manganese per liter of fuel composition, and methyl to ensure that hydrocarbon emissions meet minimum legal requirements A fuel composition for inhibiting harmful hydrocarbon combustion emissions from a spark ignition internal combustion engine, comprising means using tertiary butyl ether. 탄화수소를 포함하는 무연 가솔린 기재, 망간의 농도가 연료 조성물 1ℓ당 약 0.000264 내지 약 0.2642g의 망간인 사이클로펜타디에닐 망간 트리카보닐 녹킹 방지 화합물 및 생성된 조성물의 연소 방출이 최소한의 법률적 요건에 부합되도록 하는, 일산화탄소, 메틸렌 디메틸 에테르, 카본산 디메틸 에스테르, 메틸 3급 부틸 에테르, 에틸 3급 부틸 에테르, 메틸 3급 아밀 에테르 및 이들의 혼합물로 이루어진 그룹으로부터 선택된 산소화물을 사용하는 산소화물 부가수단을 포함하는, 무연 연료용으로 고안된 스파크 점화 내연기관 및 배기 시스템으로부터의 유해한 탄화수소 연소 방출을 억제용 연료 조성물.Lead-free gasoline substrates comprising hydrocarbons, cyclopentadienyl manganese tricarbonyl anti-knock compounds with a concentration of manganese of from about 0.000264 to about 0.2642 g of manganese per liter of fuel composition, and the combustion release of the resulting composition is subject to minimum legal requirements. Oxygenation addition means using an oxygenate selected from the group consisting of carbon monoxide, methylene dimethyl ether, carboxylic acid dimethyl ester, methyl tertiary butyl ether, ethyl tertiary butyl ether, methyl tertiary amyl ether and mixtures thereof to be matched A fuel composition for inhibiting harmful hydrocarbon combustion emissions from a spark ignited internal combustion engine and an exhaust system designed for unleaded fuel, comprising: a. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
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