KR950702940A - 미세 입자(micro particles) - Google Patents

미세 입자(micro particles) Download PDF

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Publication number
KR950702940A
KR950702940A KR1019950700828A KR19950700828A KR950702940A KR 950702940 A KR950702940 A KR 950702940A KR 1019950700828 A KR1019950700828 A KR 1019950700828A KR 19950700828 A KR19950700828 A KR 19950700828A KR 950702940 A KR950702940 A KR 950702940A
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South Korea
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colloidal
zeolite
dispersion
particle size
particle
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KR1019950700828A
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KR100277243B1 (ko
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얀-에릭 오테르스테트
퍼 요한 스테르트
브리안 요트 쇼만
Original Assignee
케이쓰 로드니 만셀
엑손 케미칼 패턴츠 인코포레이티드
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/023—Preparation of physical mixtures or intergrowth products of zeolites chosen from group C01B39/04 or two or more of groups C01B39/14 - C01B39/48
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/14—Type A
    • C01B39/145—Type A using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C01B39/205—Faujasite type, e.g. type X or Y using at least one organic template directing agent; Hexagonal faujasite; Intergrowth products of cubic and hexagonal faujasite
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/50—Zeolites wherein inorganic bases or salts occlude channels in the lattice framework, e.g. sodalite, cancrinite, nosean, hauynite
    • C01B39/52—Sodalites

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Silicon Compounds (AREA)
  • Colloid Chemistry (AREA)
  • Medicinal Preparation (AREA)

Abstract

본 발명은 콜로이드 제올라이트의 불연속적인 입자의 콜로이드상 현탁액 및 투명한 테트라알킬암모늄 안정화 된 규산알루미늄 용액으로부터 이러한 제올라이트를 제조하는 방법에 관한 것이다. 이러한 규산알루미늄 용액에 잘 규정되고 조절된 금속 수산화물 용액 소량을 첨가하여 특정 제올라이트를 합성할 수 있을 뿐만 아니라 제올라이트 수율도 조정할 수 있다. 콜로이드상 현탁액은 기하 표준편차로서 표시되는 입자 크기 분포가 1.30미만, 바람직하게는 1.20미만이라는 사실과 함께 250nm미만, 바람직하게는 200nm미만의 평균 입자 크기를 갖는 것을 특징으로 한다. 본 발명에 따라 합성된 제올라이트 졸은 콜로이드상 현탁액에 전형적인 틴탈(Tyndal1) 광 산란을 나타내며 또한 작은 입자 크기 때문에 매우 낮은 침강 속도를 나타낸다. 본 발명에 따라 합성되는 제올라이트 졸은 무정형 물질을 거의 함유하지 않도록 제조될 수 있다.

Description

미세 입자(MICRO PARTICLES)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. a) 입자가 불연속적이고, b) 평균 입자 크기가 200nm 미만이며, c) 입자 크기 분포가 1.30미만의 기하표준편차를 갖는 것을 특징으로 하는 결정성 규산 알루미늄의 콜로이드 입자.
  2. 제1항에 있어서, 물중 콜로이드 제올라이트의 안정한 콜로이등상 분산액 형태이며, 이 때 상기 분산액이 a) 필수적으로 무정형 물질을 함유하지 않으며 b) 콜로이드 제올라이트 50중량% 이하의 고체 함량을 갖는 콜로이드 입자.
  3. 제1항에 있어서, 유기 상중 콜로이드 제올라이트의 안정한 콜로이드상 분산액 형태이며, 이 때 상기 분산액이 a) 필수적으로 무정형 물질을 함유하지 않으며 b) 콜로이드 제올라이트 20중량% 이하의 고체 함량을 갖는 콜로이드 입자.
  4. 제1항에 있어서, 필수적으로 무정형 입자를 함유하지 않는, 콜로이드 제올라이트 분말 형태의 콜로이드 입자.
  5. 제1항에 있어서, 제올라이트 Y, 제올라이트 X, 제올라이트 A, ZSM-2, 실리칼라이트 및 하이드록시소달라이트(HS)로 이루어진 군으로부터 선택되는 콜로이드 입자.
  6. 제1항에 있어서, 이온-교환된 형태이며, 이 때 반대 이온이 알킬리금속, 알칼리토금속, 전이금속 및 희토류금속으로 이루어진 군으로부터 선택되는 콜로이드 입자.
  7. 강력하게 혼합하면서 알칼리 안정화된 실리카 또는 알칼리 안정화 된 실리카 화합물의 용액에 테트라메틸 암모늄 알루미네이트 용액을 첨가한 후, 침전된 입자의 필요한 입자 크기가 얻어질 때까지 승온, 바람직하게는 약 100℃에서 열수처리하고, 이어 모액으로부터 결정을 제거함으로써, 제1항 내지 제6항에 따른 콜로이드 입자를 합성하는 방법.
  8. 제7항에 있어서, 알칼리 안정화된 실리카로서 콜로이드 실리카원을 사용하는 한편, 실리카 화합물로서 알칼리 실리케이트 또는 테트라에톡시 실란 같은 유기 실리케이트를 사용하는 것을 특징으로 하는 방법.
  9. 제7항 또는 제8항에 있어서, a) 알칼리 또는 b) 테트라알킬암모늄 알루미네이트와 알칼리의 용액 또는 테트라알킬암모늄 알루미네이트만의 용액 부가량을 결정화 공정동안 강력하게 혼합하면서 용액에 첨가하는 것을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950700828A 1992-09-02 1993-09-01 미세 입자 KR100277243B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
SE9202518A SE9202518L (sv) 1992-09-02 1992-09-02 Mikropartiklar
SE9202518.8 1992-09-02
PCT/SE1993/000715 WO1994005597A1 (en) 1992-09-02 1993-09-01 Micro particles

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KR950702940A true KR950702940A (ko) 1995-08-23
KR100277243B1 KR100277243B1 (ko) 2001-02-01

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EP (1) EP0659168B1 (ko)
KR (1) KR100277243B1 (ko)
AT (1) ATE159003T1 (ko)
AU (1) AU4990293A (ko)
CA (1) CA2143687A1 (ko)
DE (1) DE69314500T2 (ko)
ES (1) ES2111177T3 (ko)
SE (1) SE9202518L (ko)
WO (1) WO1994005597A1 (ko)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU724793B2 (en) * 1995-07-10 2000-09-28 Exxon Chemical Patents Inc. Zeolites and processes for their manufacture
SE9600970D0 (sv) * 1996-03-14 1996-03-14 Johan Sterte Förfarande för framställning av mycket tunna filmer av molekylsiktar
US6150293A (en) * 1997-12-03 2000-11-21 Exxon Chemical Patents Inc. Preparation of zeolite bound by MFI structure type zeolite and use thereof
AU1620299A (en) 1997-12-03 1999-06-16 Exxon Chemical Patents Inc. Catalyst comprising a zeolite partially coated with a second zeolite, its use for hydrocarbon conversion
SE512222C2 (sv) 1998-06-29 2000-02-14 Johan Sterte Förfarande för framställning av makrostrukturer av mikroporösa material
US6908604B2 (en) 1999-05-17 2005-06-21 Exxonmobil Chemical Patents Inc. Macrostructures of porous inorganic material and process for their preparation
BR0016539B1 (pt) 1999-12-20 2013-06-04 sols baseados em sÍlica.
CN1307099C (zh) * 2000-12-28 2007-03-28 花王株式会社 微细沸石颗粒
US6537941B2 (en) 2001-01-04 2003-03-25 Exxonmobil Chemical Patents, Inc. Rejuvenating SAPO molecular sieve by freeze drying
US7732495B2 (en) 2004-04-07 2010-06-08 Akzo Nobel N.V. Silica-based sols and their production and use
US7629392B2 (en) 2004-04-07 2009-12-08 Akzo Nobel N.V. Silica-based sols and their production and use
JP6446378B2 (ja) 2013-03-14 2018-12-26 ヨーナス・ヘドルンド 多孔性基板上にゼオライトおよび／またはゼオライト様結晶の結晶膜を製造するための方法
GB201714269D0 (en) 2017-09-05 2017-10-18 Hedlund Jonas Methods for preparing supported zeolite films
IT202000007141A1 (it) * 2020-04-03 2021-10-03 Univ Degli Studi Di Roma “La Sapienza” Procedimento di sintesi e produzione di nanozeoliti o micro-zeoliti mediante un reattore a disco rotante

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1194828B (de) * 1961-03-22 1965-06-16 Union Carbide Corp Verfahren zur Herstellung von synthetischen stickstoffhaltigen kristallinen Zeolithen
US3411874A (en) * 1964-11-09 1968-11-19 Mobil Oil Corp Zsm-2 zeolite and preparation thereof
US3516786A (en) * 1968-02-23 1970-06-23 Grace W R & Co Method of preparing microcrystalline faujasite-type zeolite

Also Published As

Publication number Publication date
WO1994005597A1 (en) 1994-03-17
JP3828571B2 (ja) 2006-10-04
EP0659168A1 (en) 1995-06-28
SE9202518L (sv) 1994-03-03
DE69314500T2 (de) 1998-03-26
DE69314500D1 (de) 1997-11-13
EP0659168B1 (en) 1997-10-08
SE9202518D0 (sv) 1992-09-02
KR100277243B1 (ko) 2001-02-01
ATE159003T1 (de) 1997-10-15
JPH08500574A (ja) 1996-01-23
AU4990293A (en) 1994-03-29
ES2111177T3 (es) 1998-03-01
CA2143687A1 (en) 1994-03-17

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