KR950032056A - 아크릴산으로부터의 물의 제거방법 - Google Patents
아크릴산으로부터의 물의 제거방법 Download PDFInfo
- Publication number
- KR950032056A KR950032056A KR1019950000599A KR19950000599A KR950032056A KR 950032056 A KR950032056 A KR 950032056A KR 1019950000599 A KR1019950000599 A KR 1019950000599A KR 19950000599 A KR19950000599 A KR 19950000599A KR 950032056 A KR950032056 A KR 950032056A
- Authority
- KR
- South Korea
- Prior art keywords
- water
- acrylic acid
- carried out
- process according
- stage
- Prior art date
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 title claims abstract 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract 5
- 238000001704 evaporation Methods 0.000 claims abstract 4
- 230000008020 evaporation Effects 0.000 claims abstract 3
- 238000000034 method Methods 0.000 claims 7
- 239000012466 permeate Substances 0.000 claims 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 239000012528 membrane Substances 0.000 claims 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims 2
- 238000000926 separation method Methods 0.000 claims 2
- 239000011261 inert gas Substances 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 claims 1
- 238000001223 reverse osmosis Methods 0.000 claims 1
- 238000004821 distillation Methods 0.000 abstract 1
- 238000010626 work up procedure Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/36—Pervaporation; Membrane distillation; Liquid permeation
- B01D61/362—Pervaporation
- B01D61/3621—Pervaporation comprising multiple pervaporation steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/36—Pervaporation; Membrane distillation; Liquid permeation
- B01D61/362—Pervaporation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/04—Acrylic acid; Methacrylic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
아크릴산 수용액으로부터의 물의 제거는 과증발로 10 내지 90%의 물을 제거함으로써 수행된다. 이로 인해 후속적인, 증류에 의한 아크릴산의 후처리가 보다 용이해진다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 일단계 과증발반응을 나타낸 것이다, 제2도는 3-단계 캐스캐이드를 나타낸 것이다.
Claims (9)
10 내지 90%의 물을 막을 사용하여 과증발시킴으로써 제거함을 특징으로 하여, 아크릴산 수용액으로 부터 물을 제거 하는 방법.
제1항에 있어서, 과증발을 60 내지 100℃, 바람직하게는 70 내지 95℃에서 수행함을 특징으로 하는 방법.
제1항에 있어서, 과증발시키는 동안 보유 물질 면의 압력이 0.1 내지 0.2Mpa, 바람직하게는 상압이고, 투과물 면의 압력이 1내지 900hpa, 바람직하게는 70 내지 200hpa임을 특징으로 하는 방법.
제1항에 있어서, 불활성 기체를 투과물 면에 투입함을 특징으로 하는 방법.
제1항에 있어서, 폴리비닐 알콜을 포함하는 분리층 또는 폴리비닐 알코올 90% 초과하는 정도로 포함하는 분리층을 갖는 막을 사용함을 특징으로 하는 방법.
제1항에 있어서, 20 내지 70% 농도, 바람직하게는 40 내지 60% 농도의 용액을 사용하고, 60 내지 95% 농도, 바람직하게는 70 내지 80% 농도의 보유 물질을 수득하고, 아크릴산을 20%미만, 바람직하게는 1 내지 10% 함유하는 투과물을 수득함을 특징으로 하는 방법.
제1항에 있어서, 과증발을 한단계 또는 수단계로 수행함을 특징으로 하는 방법.
제1항에 있어서, 물을 다단계로 제거하고 과증발을 이러한 제거의 제1단계 이상에서 수행함을 특징으로 하는 방법.
제1항 또는 제8항에 있어서, 다단계로 물을 제거하는 경우 역삼투를 최종 단계 및 필요한 경우 제1단계가 아닌 전단계에서도 수행함을 특징으로 하는 방법.
※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP4401405.8 | 1994-01-19 | ||
| DE4401405A DE4401405A1 (de) | 1994-01-19 | 1994-01-19 | Verfahren zur Entwässerung von Acrylsäure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR950032056A true KR950032056A (ko) | 1995-12-20 |
Family
ID=6508210
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019950000599A KR950032056A (ko) | 1994-01-19 | 1995-01-16 | 아크릴산으로부터의 물의 제거방법 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5463121A (ko) |
| EP (1) | EP0664280A1 (ko) |
| JP (1) | JPH07223994A (ko) |
| KR (1) | KR950032056A (ko) |
| DE (1) | DE4401405A1 (ko) |
| TW (1) | TW339281B (ko) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001269572A (ja) * | 2000-03-28 | 2001-10-02 | Forestry & Forest Products Research Inst Forestry Agency | 無機質多孔粒体の再生方法及び水の浄化方法並びに水の連続浄化装置 |
| JP4074194B2 (ja) | 2001-01-12 | 2008-04-09 | ストックハウゼン ゲーエムベーハー | （メタ）アクリル酸の精製方法及びその製造装置 |
| DE10115182C1 (de) * | 2001-03-27 | 2002-08-14 | Degussa | Verfahren zur Aufkonzentrierung von (Meth)Acrylsäure, Vorrichtung zur Herstellung von (Meth)Acrylsäure und Verwendung der nach dem Verfahren hergestellten (Meth)Acrylsäure |
| DE10211686A1 (de) | 2002-03-15 | 2003-10-02 | Stockhausen Chem Fab Gmbh | (Meth)Acrylsäurekristall und Verfahren zur Herstellung und Aufreinigung von wässriger (Meth)Acrylsäure |
| US6986802B2 (en) * | 2003-08-28 | 2006-01-17 | Bp Corporation North America Inc. | Selective separation of fluid compounds utilizing a membrane separation process |
| TWI529181B (zh) | 2005-02-28 | 2016-04-11 | 贏創德固賽有限責任公司 | 以可更新原料為基之吸水聚合物結構及其生產的方法 |
| DE102008020688B3 (de) | 2008-04-24 | 2009-11-05 | Evonik Stockhausen Gmbh | Verfahren zur Herstellung und Aufreinigung wässriger Phasen |
| DE102008002715A1 (de) | 2008-06-27 | 2009-12-31 | Evonik Röhm Gmbh | 2-Hydroxyisobuttersäure produzierende rekombinante Zelle |
| FR3014870B1 (fr) * | 2013-12-13 | 2015-12-11 | Arkema France | Procede de production d'esters (meth)acryliques |
| CN111646585A (zh) * | 2020-06-03 | 2020-09-11 | 贵州大东风机械股份有限公司 | 一种有机溶剂浓缩方法及装置 |
| CN114887354A (zh) * | 2022-05-26 | 2022-08-12 | 上海淳然环境工程有限公司 | 基于分子筛膜与分子筛吸附耦合的溶剂脱水装置及工艺 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4166774A (en) * | 1977-12-05 | 1979-09-04 | The Standard Oil Company | Acrylic acid recovery and purification |
| DE3220570A1 (de) * | 1982-06-01 | 1983-12-01 | GFT Ingenieurbüro für Industrieanlagenbau, 6650 Homburg | Mehrschichtige membran und ihre verwendung zur trennung von fluessigkeitsgemischen nach dem pervaporationsverfahren |
| US5156740A (en) * | 1982-06-01 | 1992-10-20 | Gft Ingenieurburo Fur Industrieanlagenbau | Multi-layer membrane and the use thereof for the separation of liquid mixtures according to the pervaporation process |
| US4978430A (en) * | 1986-12-06 | 1990-12-18 | Ube Industries, Ltd. | Method for dehydration and concentration of aqueous solution containing organic compound |
| US5296144A (en) * | 1992-01-02 | 1994-03-22 | World Trade Corporation | Composite membrane of a hydrophilic asymmetric membrane coated with an organosiloxane block copolymer |
-
1994
- 1994-01-19 DE DE4401405A patent/DE4401405A1/de not_active Withdrawn
- 1994-10-03 TW TW083109114A patent/TW339281B/zh active
- 1994-10-06 US US08/319,017 patent/US5463121A/en not_active Expired - Fee Related
- 1994-12-01 EP EP94118952A patent/EP0664280A1/de not_active Withdrawn
-
1995
- 1995-01-16 KR KR1019950000599A patent/KR950032056A/ko not_active Application Discontinuation
- 1995-01-17 JP JP7005127A patent/JPH07223994A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP0664280A1 (de) | 1995-07-26 |
| TW339281B (en) | 1998-09-01 |
| JPH07223994A (ja) | 1995-08-22 |
| DE4401405A1 (de) | 1995-07-20 |
| US5463121A (en) | 1995-10-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |