KR950018321A - Manufacturing method of water glass multifunctional paint - Google Patents

Manufacturing method of water glass multifunctional paint Download PDF

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Publication number
KR950018321A
KR950018321A KR1019940034200A KR19940034200A KR950018321A KR 950018321 A KR950018321 A KR 950018321A KR 1019940034200 A KR1019940034200 A KR 1019940034200A KR 19940034200 A KR19940034200 A KR 19940034200A KR 950018321 A KR950018321 A KR 950018321A
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South Korea
Prior art keywords
silicate
metal
paint
water glass
aluminum
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KR1019940034200A
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Korean (ko)
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김성진
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원본미기재
가부시끼가이샤 다이에이 기카이
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Publication of KR950018321A publication Critical patent/KR950018321A/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/10—Anti-corrosive paints containing metal dust
    • C09D5/103—Anti-corrosive paints containing metal dust containing Al
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/10—Anti-corrosive paints containing metal dust
    • C09D5/106—Anti-corrosive paints containing metal dust containing Zn
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

본 발명은 폴리규산화합물로 변성시킨 전색제에 아연, 알루미늄금속 및 그 합금 미분말금속과 알칼리토류금속, 희토류금속이온으로 일부 또는 전부를 이온교환한 알모실리케이트와 금속산화물 및 탄산물의 한 종류 또는 두종류를 분산제로 첨가하여 종래 무기질 방녹방오도료를 개량한 무공해 방오방식기능을 가지는 물유리-금속, 합금미분말 다기능 도료의 제조방법으로서, 규산염 M2O·nSiO2(M : K, Na, Li, CH3, C2H5, n=2.0~3.0)의 용액에 관능기를 가지는 폴리에틸렌 글리콜, 폴리프로필렌글리콜화합물(n=2~2000)을 첨가하여 규산함유함유량이 높은 탄성겔(이하 PSE라고 한다)을 만들고, 이것을 PSE/SiO2의 중량비가 0.1~100으로 되도록 규산염 M2O·nSiO2(M : K, Na, Li, CH3, C2H5, n=2~3)용액에 용해시킨후, Al2O3(또는 B2O3)/SiO2의 몰비가 0.05~5.0으로 되도록 알루미늄화합물(황산알루미늄, 명반, 알루민산염)을 첨가하고, 30~100℃으로 가열변성시켜 규산염콜로이드 전색제를 얻어 이 전색체에 알칼리토류금속이온 또는 전이금속이온으로 교환한 알모실리케이트, 아연 또는 알루미늄금속미분말 또는 그들의 합금미분말과 알칼리토류금속 또는 금속산화물중 하나이상의 충전제와 임의의 색소를 첨가한 것을 특징으로 한다.The present invention relates to one or two kinds of almosilicates, metal oxides, and carbonic acid, which are ion-exchanged in part or all with zinc, aluminum metal and its alloy fine powder metals, alkaline earth metals, and rare earth metal ions. As a method for preparing a water glass-metal and alloy fine powder multifunctional paint having a pollution-free antifouling function by adding a dispersant and improving an inorganic antifouling antifouling paint, silicate M 2 O · nSiO 2 (M: K, Na, Li, CH 3 , Polyethylene glycol and polypropylene glycol compound having functional groups (n = 2 to 2000) are added to a solution of C 2 H 5 , n = 2.0 to 3.0 to form an elastic gel having a high silicic acid content (hereinafter referred to as PSE), This was dissolved in a solution of silicate M 2 O.nSiO 2 (M: K, Na, Li, CH 3 , C 2 H 5 , n = 2 to 3) so that the weight ratio of PSE / SiO 2 was 0.1 to 100, followed by Al 2 O 3 (or B 2 O 3) molar ratio of / SiO 2 to 0.05 to 5.0 Aluminum compound (aluminum sulphate, alum, aluminate) is added, and it is heat-modified to 30-100 ° C to obtain a silicate colloidal developer, which is converted into an alkali earth metal ion or a transition metal ion, almosilicate, zinc or aluminum. It is characterized in that the fine powder of the metal or their alloys, and one or more fillers of an alkaline earth metal or a metal oxide are added.

Description

물유리 다기능 도료의 제조방법Manufacturing method of water glass multifunctional paint

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (7)

규산염 M2O·nSiO2(M : K, Na, Li, CH3, C2H5, n=2.0~3.0)의 용액에 관능기를 가지는 폴리에틸렌글리콜, 폴리프로필렌글리콜화합물(n=2~2000)을 첨가하여 규산함유함이 높은 탄성겔(이하 PSE라고 한다)을 만들고, 이것을 PSE/SiO2의 중량비가 0.1~100으로 되도록 규산염 M2O·nSiO2(M : K, Na, Li, CH3, C2H5, n=2~3)용액에 용해시킨후, Al2O3(또는 B2O3)/SiO2의 몰비가 0.05~5.0으로 되도록 알루미늄화합물(황산알루미늄, 명반, 알루민산염)을 첨가하고, 30~100℃으로 가열변성시켜 규산염콜로이드 전색제를 얻어 이 전색체에 알칼리토류금속이온 또는 천이금속이온으로 교환한 알모실리케이트, 아연 또는 알루미늄금속미분말 또는 그들의 합금미분말과 알칼리토금속 또는 금속산화물중 하나이상의 충전제와 임의의 색소를 첨가한 것을 특징으로 하는 1액1고성물 유리다기능 도료의 제조방법.Polyethylene glycol, polypropylene glycol compound having functional groups in a solution of silicate M 2 O.nSiO 2 (M: K, Na, Li, CH 3 , C 2 H 5 , n = 2.0 to 3.0) (n = 2 to 2000) Was added to make an elastic gel having a high silicic acid content (hereinafter referred to as PSE), and the silicate M 2 O.nSiO 2 (M: K, Na, Li, CH 3 so that the weight ratio of PSE / SiO 2 was 0.1 to 100). And aluminum compound (aluminum sulfate, alum, alumina) so that the molar ratio of Al 2 O 3 (or B 2 O 3 ) / SiO 2 is 0.05 to 5.0 after dissolution in a solution of C 2 H 5 , n = 2 to 3). Acid salt), and heat-modified to 30 to 100 ° C. to obtain a silicate colloidal developer. Alkosilicate, zinc or aluminum metal fine powders or their alloy fine powders and alkaline earth metals which have been exchanged with alkaline earth metal ions or transition metal ions in the chromosome 1-liquid 1-solid glass, characterized in that at least one filler of a metal oxide and an optional pigment are added The method of coating. 제1항에 있어서, 몰비가 n=2.0~3.0의 범위에 있는 규산염용액에 폴리에틸렌글리콜, 폴리프로필렌글리콜화합물(중합도 n=2~2000)을 작용시켜 pH6.5~7.5의 중성에 가까운 변성규산탄성겔을 얻는 것을 특징으로 하는 물유리 다기능 도료의 제조방법.The modified silicate elasticity close to the neutrality of pH 6.5-7.5 by applying a polyethyleneglycol and a polypropylene glycol compound (polymerization degree n = 2-2000) to the silicate solution whose molar ratio is n = 2.0-3.0. A method for producing a water glass multifunctional paint, comprising obtaining a gel. 제1항 또는 제2항에 있어서, PSE/SiO2의 중량비가 1.0~10의 용액에 Al2O3(또는 B2O3)/SiO2의 몰비가 0.9~5.0으로 되도록 알루미늄화합물 또는 붕산염을 가하고 30~100℃로 가열변성시킨 폴리규산탄성겔을 포함하는 전색제를 얻는 것을 특징으로 하는 물유리 다기능 도료의 제조방법.The aluminum compound or borate salt according to claim 1 or 2, wherein the molar ratio of Al 2 O 3 (or B 2 O 3 ) / SiO 2 is 0.9 to 5.0 in a solution having a weight ratio of PSE / SiO 2 of 1.0 to 10. A method for producing a water glass multifunctional paint, comprising adding and obtaining a colorant comprising a polysilicate elastic gel heated and denatured at 30 to 100 ° C. 제1항 내지 제3항중의 어느 한항에 있어서, 변성폴리규산탄성겔전색제에 아연, 알루미늄 또는 그 합금금속미분말을 5~90% 가하고 이에 알모실리케이트를 중량비가 5~40%, 희토류금속산화물, 황산바륨, 금속산화물(ZnO, TiO2, Cu2O, CuO, Fe2O3, Fe3O4, MnO2, Mn3O4, Cr2O3, Al2O3)및 금속탄산염, SiO2, C등을 10%~50% 첨가한 다기능도료를 얻는 것을 특징으로 하는 물유리 다기능 도료의 제조방법.The method of claim 1, wherein 5 to 90% of zinc, aluminum or its alloy metal fine powder is added to the modified polysilicate elastic gel developer, and the almosilicate is 5 to 40% by weight, rare earth metal oxide, sulfuric acid. Barium, metal oxides (ZnO, TiO 2 , Cu 2 O, CuO, Fe 2 O 3 , Fe 3 O 4 , MnO 2 , Mn 3 O 4 , Cr 2 O 3 , Al 2 O 3 ) and metal carbonates, SiO 2 A method for producing a water glass multifunctional paint, comprising obtaining a multifunctional paint containing 10% to 50% of C or the like. 규산염 M2O·nSiO2(M : K, Na, Li, CH3, C2H5, n=2.0~3.0)의 용액 또는 그를 물로 희석시킨 용액을 전색제로 하고 청구범위 제4항의 고체분산제에 상기 알루미늄화합물 또는 붕산염의 하나 또는 두종류를 사용하는 전색제의 0.001~1.0%, 바람직하기로는 0.05~0.09% 하고 n=2~2000인 폴리에틸렌글리콜, 또는 폴리프로필렌글리콜을 겔형성제 및 경화제로 고체분산제의 0.01~5%을 균일혼합하여 슬러리암료를 만들고 이에 청구범위 제1, 2항 및 제3항의 전색제 또는 상기의 규산염을 가하여 2액 도료로한 것을 특징으로 하는 물유리 다기능 도료의 제조방법.A solution of silicate M 2 O.nSiO 2 (M: K, Na, Li, CH 3 , C 2 H 5 , n = 2.0 to 3.0) or a solution diluted with water is used as a colorant and the solid dispersant according to claim 4 0.001 to 1.0%, preferably 0.05 to 0.09%, of polyethylene glycol or polypropylene glycol of n = 2 to 2000, and a polydispersant as a gel-forming agent and a curing agent. Method for producing a water glass multi-functional paint, characterized in that the mixture of 0.01 to 5% of the slurry to make a slurry dark and to the two-component paint by adding the above-mentioned the first or second claim 3 or the silicate. 제1항 내지 제5항중 어느 한 항에 있어서, 도막의 물리화학적특성에 의하여 선박선저와 해양구조물에 바다생물이 부착하는 것을 방지하는 무공해방오효과와 방녹효과를 함께 가지는 선저 및 해양구조물용 도료를 얻는 것을 특징으로 하는 물유리 다기능 도료의 제조방법.The paint according to any one of claims 1 to 5, which has a pollution-free antifouling effect and an antirust effect which prevents marine organisms from adhering to the vessel bottom and the marine structure by the physical and chemical properties of the coating film. A method for producing a water glass multifunctional paint, characterized by the above-mentioned. 제1항 내지 제6항중 어느 한 항에 있어서, 물유리변성전색제를 포함하는 2액형의 다기능도료로서 철, 철합금, 스텔레스, 목재, 콘트리트, 스레트, 유리, 아마등에 사용할 수 있는 것을 특징으로 하는 물유리 다기능 도료의 제조방법.The two-component type multifunctional paint comprising a water glass modified colorant, which can be used for iron, iron alloy, stainless steel, wood, concrete, thread, glass, flax, and the like. Method for producing water glass multifunctional paint. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019940034200A 1993-12-14 1994-12-14 Manufacturing method of water glass multifunctional paint KR950018321A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP93-348323 1993-12-14
JP5348323A JPH07166126A (en) 1993-12-14 1993-12-14 Production of polyfunctional water glass coating material

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KR950018321A true KR950018321A (en) 1995-07-22

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100405652B1 (en) * 1995-12-29 2004-04-03 고려화학 주식회사 Heat resistant and corrosion resistant inorganic coating composition

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Publication number Priority date Publication date Assignee Title
CN1072697C (en) * 1997-11-28 2001-10-10 化学工业部海洋化工研究院 Non-toxic anti-pollution paint for sea
TWI230186B (en) * 1998-10-19 2005-04-01 Toto Ltd Antifouling material and process for producing the same, and coating composition for said material
DE10104341A1 (en) * 2001-02-01 2002-08-08 Colfirmit Rajasil Gmbh & Co Kg Coating with adsorbing properties for interior surfaces
CH704939B1 (en) * 2008-03-10 2012-11-15 Akzo Nobel Chemicals Int Bv Translucent heat protection element with aluminate or boratmodifiziertem silica.
KR102348234B1 (en) * 2020-12-24 2022-01-11 대한민국 Tissue and foam cleaner for cleaning personal protective equipment to remove heavy metals and polycyclic aromatic hydrocarbons
CN114958048A (en) * 2022-06-27 2022-08-30 上海雷鸟涂料有限公司 Bi-component zinc-rich primer and preparation method thereof

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DE9116748U1 (en) * 1990-12-05 1993-09-23 Hungsong Corp., Pjöngjang/Pyongyang COMPLETELY INORGANIC, PERMANENT CORROSION-PREVENTING, HARMFUL PAINT PREVENTION-PREVENTING

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100405652B1 (en) * 1995-12-29 2004-04-03 고려화학 주식회사 Heat resistant and corrosion resistant inorganic coating composition

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JPH07166126A (en) 1995-06-27
GB2284822A (en) 1995-06-21
AU670986B2 (en) 1996-08-08
GB2284822B (en) 1997-07-16
GB9402788D0 (en) 1994-04-06
TW280827B (en) 1996-07-11
AU5524194A (en) 1995-07-13

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WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid